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Energetic organo-silicon compoundsNieder, Anian 22 October 2013 (has links) (PDF)
The results of the experimental and theoretical work with structurally simple silanes containing energetic or potentially energetic moieties are presented.
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Energetic materials based on isocyanuric acid and 1,2,4-oxadiazole derivativesMayr, Norbert 21 March 2013 (has links) (PDF)
The synthesis and properties of explosive urea and triazine derivatives is investigated on behalf of the explosive parameters and the full characterization of the molecules. (Chapter I-III)
The class of oxadiazole derivatives is enhanced from the known explosive 1,2,5 oxadiazole (furazane) derivatives to the 1,2,4 oxadiazole derivatives. This molecule class is thoroughly investigated by all terms of chemical and explosive material matter and especially the 1,2,4-oxadiazol-5-one derivatives are compared to the corresponding tetrazole derivatives which were by far the most investigated molecule moiety of Prof. Dr. T.M. Klapoetke et al. for more than the last ten years.
The 1,2,4 oxadiazol-5-one derivatives do only value as comparable model molecule to the tetrazole but were found to be good explosives themselves. So the triaminoguanidinium 1,2,4-oxadiazol-5-onate is suitable as low temperature propellant, the potassium and cesium 1,2,4-oxadiazol-5-onate are found to be good additions for NIR-flares and last but not least the best performing molecule was found to be the 3,5-diamino-1,2,4-oxadiazolium 5-aminotetrazolate, which combines the stability of the oxadiazole moiety with the very exothermic properties of a tetrazole in its best way. (Chapter IV-V)
The 3-amino-1,2,4(4H)-oxadiazol-5-one is investigated thoroughly and detected to be a chemically and thermodynamically more stable system which can be functionalized according to methods known prior in the working group.
The 3-dinitromethyl-1,2,4(4H)-oxadiazol-5-one is found a promising explosive class which can be combined as anion with a wide range of cations to tailor the stability and performance.
The overall conclusion is that the 1,2,4-oxadiazole are chemical suitable as well as secondary explosives, propellants and pyrotechnics.
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Angulare BenzoperylentetracarbonsäurebisimideBöck, Bernd 02 November 2011 (has links) (PDF)
No description available.
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Modeling transposon recognition in Drosphila melanogasterElmer, Anna Katharina 16 May 2013 (has links) (PDF)
No description available.
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Structural interplay of key factors in the human microRNA pathwayPfaff, Janina Michelle 18 April 2013 (has links) (PDF)
No description available.
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Degradation of lipid based drug delivery systems and characterization of semi-synthetic spider silk proteins for the application in pharmaceutical technologySchwab, Martin 13 August 2009 (has links) (PDF)
No description available.
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Proteins and azobenzenesReiter, Alwin 29 April 2013 (has links) (PDF)
No description available.
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Beschreibung dynamischer molekularer Systeme mit effizienten linear-skalierenden QM- und QM/MM-MethodenFlaig, Denis Benjamin January 2012 (has links) (PDF)
No description available.
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New routes for the synthesis of novel aceanthrene green, phenazine and azaperylene dyes and lateral ring extension of aceanthrene green dyesAly, Sherif Abdel moez Mohamed Ahmed 12 July 2011 (has links) (PDF)
No description available.
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The adaptor protein Migfilin is dispensable for mouse development and homeostasis, but suppresses tetraploidy and acts as a tumor suppressor in skinMoik, Daniel V. 12 May 2011 (has links) (PDF)
No description available.
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