<p> High resolution measurements of the far-infrared absorption spectra due to a number of substitutional impurities in KBr and KCl are presented. Several Van Hove singularities of the phonon spectrum of the host lattice are directly observed and found to shift to higher frequencies as the impurity concentration is increased. The first direct experimental evidence for the change of shape or metamorphism of singularities is also presented. The experimental spectra are compared with numerical calculations based on the ordinary shell model for the defect together with phonon data obtained from inelastic neutron scattering experiments. Agreement between experiment and calculation is generally good when impurity resonant modes are absent.</p> / Thesis / Doctor of Philosophy (PhD)

A 'model-to-radiance' comparison of simulated brightness temperatures and radiances from the Hadley Centre Global Environmental Model 2 (HadGEM2-A) with longwave measurements from the High Resolution Infrared Radiation Sounder/4 (HIRS/4) and the Infrared Atmospheric Sounding Interfermeter (IASI) onboard the MetOp-A satellite is presented for all-sky and clear-sky global means. The fast Radiative Transfer model for TOVS 10 (RTTOV-10) is applied to HadGEM2 output to simulate observational-equivalent data. The results are compared with corresponding broadband analyses. A method is developed to extend hyperspectral IASI radiances to cover the whole outgoing terrestrial spectrum, in order to identify any compensating biases, and explore wavebands in the unobserved Far Infrared (FIR) region. For the all-sky HIRS analysis, the model overestimates brightness temperatures in the atmospheric window region with the greatest biases over areas associated with deep convective cloud. In contrast to many global climate models, much smaller clear-sky biases are found indicating that model clouds are the dominating source of error. Simulated values in upper atmospheric CO2 channels approximate observations better as a result of compensating cold biases at the poles and warm biases at lower latitudes, due to a poor representation of the Brewer Dobson circulation in the 38 level 'low-top' configuration of the model. Simulated all and clear-sky outgoing longwave radiation evaluated against the Clouds and the Earth's Radiant Energy System (CERES) and HIRS OLR products reveal good agreement, in part due to cancellation of positive and negative biases. Through physical arguments relating to the spectral energy balance within a cloud, it is suggested that broadband agreement could be the result of a balance between positive window biases and unseen negative biases originating from the water vapour rotational band in the FIR (not sampled by HIRS). Simple sensitivity tests show that dramatically altering existing cloud properties has little effect on the prominent window biases, however raising clouds a maximum of 5 atmospheric levels minimises the error in cloud contaminated channels, due to the introduction of spatially compensating errors. Sensitivities to the way ice clouds are parameterised in RTTOV-10 display a range of up to 2.5 K in window channels but absolute biases still exceed 3 K for all choices. Because of the lack of satellite based FIR observations due to a technological gap in the spectral region, an algorithm is created to 'fill in' the available data. Correlations between selected IASI channels and simulated unobserved wavelengths in the far infrared are used to estimate radiances between 25.25 - 644.75 cm-1 at 0.5 cm-1 intervals. The same method is used in the 2760 - 3000 cm-1 region. The spectrum is validated by comparing the Integrated Nadir Longwave Radiance (INLR) product (spanning the whole 25.25 - 3000 cm-1 range) with the corresponding broadband measurements from the Clouds and the Earth's Radiant Energy System (CERES) instrument on the Terra and Aqua satellites at simultaneous nadir overpasses, revealing mean differences of 0.3 Wm-2sr-1 (0.5% relative difference) lower for IASI relative to CERES and significantly lower biases in nighttime only scenes. Averaged global data over a single month produces mean differences of about 1 Wm-2sr-1 in both the all and the clear-sky (1.2% relative difference). The new high resolution spectrum is presented for global mean clear and total skies where the far infrared is shown to contribute 44% and 47% to the total OLR respectively, which is consistent with previous estimates. In terms of spectral cloud radiative forcing, the FIR contributes 19% and in some subtropical instances appears to be negative, results that would go un-observed with a traditional broadband analysis. The equivalent complete IASI OLR model product is simulated from GCM data using RTTOV-10. The same process of applying predictors to the satellite measurements is applied to the model simulated radiances, with appropriate modifications, to produce a directly comparable model product. Annual mean all-sky radiances are still greatly overestimated at all wavenumbers with a total radiance bias of 4.52 Wm-2 across the whole range. Compensating negative biases outside of the HIRS coverage that were hypothesised are absent, with the far infrared contributing to the overall bias rather than cancelling it. Equivalent clear-sky biases are much lower overall at 0.39 Wm-2, in part due to spectral and spatial cancellation of errors. A flux-to-flux comparison is enabled by estimating the spatial distribution of anisotropic factors, using collated HIRS OLR fluxes and IASI OLR radiances, which yields global mean model fluxes in excess of 12 Wm-2 higher than observations in the all-sky. The difference between this and the fluxes calculated using the climate model's broadband radiation code (Edward-Slingo) are around 10 Wm-2 which is outside the range of uncertainty in the method used to estimate the flux. However, it is discussed that tuning of the climate model's broadband code to known flux values is a required practice to ensure global energy budgets balance but can produce inaccurate parameterised variables. An equivalent analysis adjusting the ice cloud parametrisation to reflect the radiances that have the biggest differences to the original configuration selected showed a bias reduction of 4.5 Wm-2, which is still not enough to completely explain its size, suggesting the existence of residual cloud problems. Finally, it is suggested that the way forward in separating and constraining cloud errors, in both radiative transfer codes, is a rigorous process of testing them with observation cloud properties and reanalysis data as inputs.

This thesis proposes a metallic hole array of a rectangular converging-diverging channel (RCDC) shape with extraordinary transmission. We use a three-dimensional (3D) finite element method to analyze the transmission characteristics of two-dimensional metallic hole arrays (2D-MHA) with RCDC. For a straight channel MHA, when the aperture size is reduced, the transmission peaks have a blue-shift. The same result is observed for a smaller gap throat for the RCDC structure. For the rectangular holes with a high length-width ratio, a similar blue-shift in the transmission peaks as well as a narrower full width at half maximum (FWHM) are observed. The asymmetry from the rectangular shape gives this structure high selectivity for light with different polarizations. Furthermore, the RCDC shape gives extra degrees of geometrical variables to 2D-MHA for tuning the location of the transmission peak and FWHM. The tunable transmission property of this structure shows promise for applications in tunable filters, photonic circuits, and biosensors. / text

No description available.

Electromagnetic radiation in the frequency range between about 100 GHz and 5 THz can be used for spectroscopy and microscopy, but it is also promising for security screening and even wireless communication. In the present thesis a planar photoconducting large-area THz radiation source is presented. The device exhibits outstanding properties, in particular high THz field strength and generation efficiency and large spectral bandwidth with short THz pulse length. The THz emission is based on acceleration and deceleration of photoexcited carriers in semiconductor substrates. A metallic interdigitated structure at the surface of semi-insulating GaAs provides the electrodes of an Auston switch. In a biased structure photoexcited charge carriers are accelerated. Hence electromagnetic waves are emitted. An appropriately structured second metallization, electrically isolated from the electrodes, prevents destructive interference of the emitted waves. The structure investigated here combines several advantages of different conventional photoconducting THz sources. First, it provides high electric acceleration fields at moderate voltages owing to the small electrode separation. Second, the large active area in the mm2 range allows excitation by large optical powers of some mW. Optical excitation with near-infrared femtosecond lasers is possible with repetition rates in the GHz range. The presented results point out the excellent characteristics regarding the emitted THz field strength, average power, spectral properties, and easy handling of the interdigitated structure in comparison to various conventional emitter structures. Various modifications of the semiconductor substrate and the optimum excitation conditions were investigated. In the second part of this thesis the dynamic conductivity of GaAs/AlxGa1-xAs superlattices in an applied static electric field was investigated with time-resolved THz spectroscopy. The original goal was to explore whether the predicted effect of gain of electromagnetic radiation at THz frequencies is present in such structures. Superlattice samples were grown according to the experimental requirements, which include high specific resistance and sufficient THz transparency. The characterization of the superlattices by Fourier transform infrared spectroscopy and photoluminescence spectroscopy confirms the pronounced miniband properties of the bandstructure. Furthermore indications of Bloch oscillations were found by transport measurements. However, we could not measure a change of the dynamic conductivity when the electric field was toggled. Specific reasons for this and related experiments of other groups are discussed. / Elektromagnetische Strahlung im Frequenzbereich zwischen etwa 100 GHz und 5 THz wird für verschiedene Anwendungen wie Spektroskopie und Mikroskopie genutzt, kann aber auch für Sicherheitstechnik oder sogar Datenübertragung interessant sein. In der hier vorgestellten Forschungsarbeit wird eine großflächige fotoleitende THz-Strahlungsquelle beschrieben, die sich durch eine große THz-Feldstärke und große spektrale Bandbreite auszeichnet. Die THz-Emission basiert auf der Beschleunigung und Verzögerung fotogenerierter Ladungen in Halbleitersubstraten. Eine metallische Interdigitalstruktur auf der Oberfläche von semi-isolierendem GaAs bildet die Elektroden eines Fotoschalters. Ist an diese Struktur eine Spannung angeschlossen, werden optisch generierte Ladungsträger beschleunigt und strahlen elektromagnetische Wellen ab. Eine geeignet strukturierte und isolierte zweite Metallisierung verhindert destruktive Interferenzen der abgestrahlten Wellen. Die vorgeschlagene Struktur vereinigt dabei die Vorteile verschiedener herkömmlicher fotoleitender THz-Quellen. Einerseits ermöglicht der kleine Elektrodenabstand große elektrische Felder zur Beschleunigung fotogenerierter Ladungen schon bei moderaten Spannungen. Andererseits kann die große aktive Fläche von einigen mm2 mit großen optischen Leistungen im Bereich einiger mW angeregt werden. Die optische Anregung mit Nahinfrarot-Femtosekunden- Lasern kann mit Wiederholraten bis in den GHz-Bereich geschehen. Bedingt durch die Eigenschaften der Anregungspulse entstehen kurze spektral breite THz-Pulse. Die vorliegenden Ergebnisse verdeutlichen die hervorragenden Eigenschaften der Interdigitalstruktur im Vergleich zu verschiedenen herkömmlichen Geometrien bezüglich der Feldstärke der abgestrahlten Wellen, der mittleren Leistung und der spektralen Eigenschaften. Dabei ist die Struktur sehr einfach zu handhaben. Es wurden verschiedene Modifikationen des Substrates und die optimalen Bedingungen der optischen Anregung untersucht. Der zweite Teil dieser Arbeit behandelt die Erforschung der dynamische Leitfähigkeit von GaAs/AlxGa1-xAs-Übergittern in Abhängigkeit von einem elektrischen Feld mit Hilfe der zeitaufgelösten THz-Spektroskopie. Es sollte geklärt werden, ob der vorhergesagte Effekt der Verstärkung elektro-magnetischer Strahlung in solchen Strukturen möglich ist. Dazu wurden Übergitterproben gemäß den experimentellen Anforderungen hergestellt. Zu den Vorgaben gehört ein hoher spezifischer Widerstand und ausreichende Transparenz im THz-Bereich. Die Charakterisierung der Übergitter mit Fotolumineszenz- und Fourier-Transformations-IR-Spektroskopie bestätigte die ausgeprägten Minibandeigenschaften der Bandstruktur. Hinweise auf Bloch-Oszillationen wurden durch Ladungstransportmessungen gefunden. Dennoch war eine Änderung der dynamischen Leitfähigkeit beim Schalten des elektrischen Feldes nicht messbar. Gründe dafür und ähnliche Experimente anderer Gruppen werden diskutiert.

Terahertz (THz) heterodyne receiver systems are required by NASA to monitor gas concentrations related to the Earth's ozone depletion. To this end, NASA needs compact, solid state, tunable THz local oscillators. THz LOs have been developed using three means: 1) All-electronic LOs using mixers in combination with Gunn oscillators, 2) Hybrid Photo-electronic LOs using a cw analog of the Auston switch, and 3) All-photonic THz LOs using coherent sources, such as vapor lasers or solid-state Quantum Cascade Lasers, and down converting lasers using nonlinear crystals. In this dissertation, we began with two frequency stabilized Nd:YAG lasers, locked to a common reference cavity, as a starting point to having a stable input into a nonlinear optical frequency conversion system. Following this, we explored the nonlinear crystals useful for THz generation, and the phasematching schemes that could be employed by each. We concluded by settling on highly insulating III-V semiconductor crystals as the proper choice of nonlinear element, and put together a new phasematching method that is most useful for them.

Orientador: Ioshiaki Doi / Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Elétrica e de Computação / Made available in DSpace on 2018-08-20T21:32:16Z (GMT). No. of bitstreams: 1 Neli_RobertoRibeiro_D.pdf: 20995056 bytes, checksum: 0072f9af377dc8c222632b4d9608b5b0 (MD5) Previous issue date: 2012 / Resumo: Este trabalho tem como objetivo a fabricação e caracterização de sensores térmicos descritos como bolométricos, que são dedicados a detecção da radiação infravermelha distante. Estes sensores são construídos a partir de técnicas de microfabricação, utilizando filmes finos seletivos a corrosão úmida. Estas microestruturas mecânicas são formadas sobre laminas de silício a partir de um ataque químico úmido sobre a superfície da mesma. Como estas estruturas são obtidas utilizando-se técnicas convencionais de fabricação de circuitos integrados, torna-se possível a integração monolítica de circuitos eletrônicos e dispositivos mecânicos, permitindo o desenvolvimento de microssistemas integrados. O ouro poroso ou "ouro negro" foi estudado e caracterizado, sendo utilizado como absorvedor de radiação e apresentou neste trabalho índices de absorção superiores a 80%. Foi desenvolvido também um processo para integrar este filme ao dispositivo. O silício policristalino, submetido a dopagem de boro, foi desenvolvido para se obter valores de TCR próximos a -2%K-1 e resistências abaixo de 1k'ômega'. Finalmente, foram desenvolvidos os layouts, fabricadas e testadas as microestruturas de diversas geometrias, como pontes, vigas, membranas, espiras, entre outras. Os dispositivos bolométricos testados apresentaram TCR de -2,54%K-1 , um tempo de resposta de aproximadamente 2 ms, uma responsividade de 0,35 V/W e uma detectividade específica de 6,04.109 mHz1/2W-1, quando submetido a uma radiação de 0,85 THz / Abstract: This work has as a main goal the fabrication and characterization of thermal sensors, described as bolometrics, which are dedicated to detection of far infrared radiation. These sensors are fabricated using microfabrication techniques and the thin films are selectives to wet etching. These mechanical microstructures are formed on silicon wafers using a surface wet etching. As these structures are obtained using conventional techniques for CI's manufacturing, it becomes possible perform a monolithic integration of electronics and mechanical devices, allowing the integrated microsystems development. The porous gold or "gold black" used as a radiation absorber, was studied and characterized, and this study showed absorption index greater than 80%. Was developed a process to integrate this film to device. The doped polycrystalline silicon was performed to obtain TCR values near to -2% K-1 and resistance less than 1k'omega'. Finally, the layouts are designed, performed and tested the microstructure of various geometries such as bridges, beams, membranes, coils, among others. The devices tested presented TCR about -2.54% K-1, a response time of approximately 2 ms, responsivity about 0.35 V / W and specific detectivity about 6.04x109 mHz1/2W-1 when subjected to a 0,85 THz radiation / Doutorado / Eletrônica, Microeletrônica e Optoeletrônica / Doutor em Engenharia Elétrica

The most intensely star-forming galaxies lie at z ∼ 2 and are thought to be the progenitors of the most massive galaxies today, yet study of this important population has been hampered by vast quantities of dust, making them almost invisible in the optical and ultraviolet (UV) regimes, and by the low sensitivity and angular resolution of many infrared (IR) facilities. Chapter 2 describes the use of the flux and angular extent boost provided by strong gravitational lensing in the detailed study of individual high-redshift dusty star-forming galaxies (DSFGs). The low number density of such systems has been overcome by recent wide area far-infrared (FIR)–mm surveys, and a sample of candidate systems which are bright enough to study with single-dish FIR telescopes are assembled from these surveys. The chapter further describes spectra of these galaxies obtained using the the Spectral and Photometric Imaging REceiver (SPIRE; Griffin et al. 2010) Fourier transform spectrometer (FTS) on board the Herschel Space Observatory (Pilbratt et al. 2010), exploiting the increased flux densities to search for FIR atomic and ionic spectral lines: important coolants of warm gas surrounding star-formation regions. Chapter 3 describes the first “blind” redshift obtained using Herschel, via the detection of [C ii] 158 μm in one of our spectra. Confirmation of this redshift was provided by detection of CO lines with the Combined Array for Research in Millimeter-wave Astronomy (CARMA) and the Plateau de Bure Interferometer (PdBI), and along with multi-wavelength photometric follow-up, allowed a characterisation of the galaxy, indicating both a merger-driven starburst and an active galactic nucleus (AGN) within the system. Chapter 4 describes the first detection of a massive outflow of molecular gas at high-redshift. Stacking five repeat spectra of the Cosmic Eyelash, one of the best-studied strongly lensed DSFGs, one of the massive star-forming clumps is shown to drive this outflow, albeit likely at a velocity lower than that required to become unbound from the hosting gravitational potential well. Chapter 5 describes line measurements and spectral energy distribution (SED) fitting from the full set of spectra and Herschel PACS mini scan maps. The spectra are stacked to search for faint lines, and compared to a detailed interstellar medium (ISM) model to determine average physical properties of the star-forming gas. Photodissociation region (PDR) properties are found to be similar to those derived using other models, however a cosmic ray ionisation rate of 103 times that of the Milky Way, expected in galaxies of this type cannot reproduce the observed line ratios, in particular the low [O i] 63 μm flux. Chapter 6 finally describes the conclusions drawn from the work presented in this thesis and how these data and analysis add to our knowledge and interpretation of high-redshift DSFGs.

One of the primary drivers in the development of large format millimeter detector arrays is the study of sub-millimeter galaxies (SMGs) - a population of very luminous high-redshift dust-obscured starbursts that are widely believed to be the dominant contributor to the Far-Infrared Background (FIB). The characterization of such a population requires the ability to map large patches of the (sub-)millimeter sky to high sensitivity within a feasible amount of time. I present this dissertation on the design, integration, and characterization of the 144-pixel AzTEC millimeter-wave camera and its application to the study of the sub-millimeter galaxy population. In particular, I present an unprecedented characterization of the "blank-field" (fields with no known mass bias) SMG number counts by mapping over 0.5 deg 2 to 1.1mm depths of ∼1mJy - a previously unattained depth on these scales. This survey provides the tightest SMG number counts available, particularly for the brightest and rarest SMGs that require large survey areas for a significant number of detections. These counts are compared to the predictions of various models of the evolving mm/sub-mm source population, providing important constraints for the ongoing refinement of semi-analytic and hydrodynamical models of galaxy formation. I also present the results of an AzTEC 0.15 deg 2 survey of the COSMOS field, which uncovers a significant over-density of bright SMGs that are spatially correlated to foreground mass structures, presumably as a result of gravitational lensing. Finally, I compare the results of the available SMG surveys completed to date and explore the effects of cosmic variance on the interpretation of individual surveys.

No description available.