It is now a well established fact that fatigue cracks initiate from persistent slip bands (PSBs). Previous work on copper fatigued in reverse bending has revealed that the PSBs form much earlier near indentations or surface pits than in regions well away from them. The cause of this effect has been attributed partly to a dislocation microstructure introduced by the indentations as well as possible contribution from the residual stresses resulting from them and geometric stress raising effects. To study this phenomenon in a greater depth, an attempt has been made to make a comprehensive study of the plastic deformation around indentations and to study their effect on the low ampltude fatigue cycling of mono and polycrystalline copper. This effect has been studied using both surface as well as Transmission Electron Microscope (TEM) observations. The project was divided into four main categories; a study of the deformation around indentations; a study of the fatigue cycling mechanism; a study of the low strain amplitude fatigue cycling of the indented specimens and a study of the effect of indentation on the fatigued specimens. The surface topographical studies were made on specially designed polycrystalline and single crystal specimens of copper. The transmission electron microscope study has been done mainly on thin strips sliced and prepared from two bulk single crystals with axial orientation close to [124] and [012]. The dislocation structures due to indentations were studied in regions at different positions in relation to the indentations and included a study of the microstructures close to the surface as well as ~ 50mum from it. Specimens were fatigued in air, at room temperature, at total strain amplitudes in the range = 2x10-4 to 9.8x10-4 for bulk specimens and a 0.8x10-3 to 1.9x10-3 for thin foil specimens. The number of fatigue cycles given to the specimens varied (from specimen to specimen) from a few cycles to several hundred thousand cycles. The Dyer model (1965) has been satisfactorily extended from ball to pyramid indentations to explain the hill formation and the general surface topography around indentations. Dislocation, microstructures around indentations in the 'indented' and 'indented and fatigued' specimens of the same orientation have been analysed and compared. Such an analysis has revealed that in the regions of indentations in which PSBs are initiated more readily, the dislocation microstructure due to indentation contained predominantly the Burgers vectors +/-a/2 [110] or +/-a/2 [011] and +/-a/2 [110] or +/-a/2 [011]. In contrast to these, the most frequently found Burgers vectors in the same regions of the indentation followed by fatigue were +/-a/2 [101] and +/-a/2 [011], which reveals that the Burgers vectors of the dislocations introduced by the indentation in these regions are quite favourable for the later stage of fatigue cycling, with an enhanced density of dislocations. A little work was also done to study the effect of the indentations made in the fatigued specimens. It has showed an enhancement of the inhomogeneous and anisotropic deformation around the indentations caused by fatigue cycling as well as a significantly different type of slip bands.

Asphalt’s fatigue and modulus characteristics play an important role in pavement design. Ultimately they govern the required thickness of asphalt to structurally support heavy vehicles. The thickness of the asphalt layer is a major contributor to the cost of construction. In New Zealand, the design of structural asphalt layers has been a problem for some time and gives rise to two areas of concern. First, the present fatigue failure criterion, the Shell fatigue transfer function, which has been adopted from overseas, not only underestimates the fatigue life of the country’s asphalts, but does not accurately characterise the fatigue behaviour of our local asphalt mixes. Consequently, asphalt thicknesses are overdesigned. Second, asphalt’s fatigue behaviour is influenced by numerous factors and therefore can be difficult to characterise. The primary objective of this thesis is to develop fatigue and modulus models, by carrying out fatigue and modulus tests, to characterise the behaviour of two typical New Zealand structural asphalts. Both resilient and stiffness moduli tests were performed at a range of temperatures and loading rates developing moduli master curves, which predict the asphalt’s modulus for any pavement temperature and vehicle speed. A general full factorial experiment was carried out utilising the four-point flexural beam fatigue test. Tests were carried out at different strain levels, temperatures, and loading rates. An analysis of variance showed that the impacts of strain amplitude, temperature, binder type, the interaction of strain amplitude and temperature, and the interaction of strain amplitude and binder type have a significant effect on fatigue behaviour. The developed models, which account for temperature effects give the pavement engineer the ability to undergo a more accurate assessment of fatigue damage than at present for different climatic temperatures demonstrated by using an incremental damage analysis approach. The research shows that with such characterisation for the given pavement’s design life, thinner and less expensive roads can be constructed in New Zealand.

Estudos de condições oceanográficas tornam-se imperativos a cada dia, tanto no fornecimento de dados para fins de pesquisa quanto para aplicações de engenharia. Tais usos variam desde a validação de modelos de previsão de ondas até a determinação de forças em estruturas offshore, bem como em condições de navegabilidade e operações logísticas. O uso dos movimentos do navio para determinar qual condição de mar os induziu, adotando a embarcação como um sensor, em analogia às boias oceanográficas, é uma das tecnologias disponíveis para a medição das condições oceanográficas. Esta destaca-se pela simplicidade na implementação, além de atender às necessidades da indústria petrolífera, uma vez que o interesse é voltado para eventos de ondas extremas, os quais são bem representados pela tecnologia considerada, como verificado nesta tese. A facilidade de obtenção de dados através da tecnologia mencionada, sem a necessidade de equipamentos adicionais { especialmente no caso de plataformas de petróleo devido à disponibilidade de bases inerciais em muitas embarcações deste tipo { foi essencial para garantir ao presente trabalho um conjunto de dados de campo composto por registros ininterruptos dos movimentos de uma plataforma FPSO durante dois anos, através do qual foi possível realizar estimativas das ondas em intervalos de trinta minutos. Esta rica base de dados, inédita na literatura especializada, aliada às estimativas fornecidas simultaneamente por um sistema de radar de ondas, permitiu um estudo detalhado das características e padrões dos espectros direcionais de onda e uma importante validação da aplicação da tecnologia em campo. Face às incertezas inerentes ao processo, no entanto, observa-se que, para um mesmo registro de movimentos, muitas soluções diferentes e quase equiprováveis podem ser obtidas, uma característica que favorece a aplicação de um método de inferência Bayesiana, afim de fornecer alguma informação a priori sobre as variáveis de estimação. Na presente abordagem, esta informação corresponde a uma suposição de suavidade dos espectros direcionais de onda a serem estimados, cujo grau é controlado pelos chamados hiperparâmetros do processo de inferência - parâmetros dentro do método que controlam a influência da informação a priori sobre a solução. Estudos prévios realizados na EPUSP demonstraram que o uso de hiperparâmetros fixos ou pré-calibrados é vantajoso para tornar o método de estimação operacionalmente aplicável, proporcionando um tempo de execução compatível com aplicações em tempo real. Dada a importância do papel desempenhado pela informação a priori na determinação de soluções viáveis no intervalo de incertezas do método, torna-se patente a necessidade de se definir valores apropriados para estes hiperparâmetros. Assim, neste trabalho, é apresentada uma metodologia de calibração para os hiperparâmetros baseada na dependência destes no período médio de onda e no parâmetro espectral de largura de banda. Esta nova abordagem traz dois aspectos inovadores para a pesquisa: O primeiro é o desenvolvimento de um método iterativo e autossuficiente capaz de identificar erros de estimação causados por incertezas no modelo de previsão de movimentos do navio. O segundo ponto é a capacidade do método de mitigar os erros encontrados, forçando a suavidade espectral ao longo do intervalo de frequências de onda. / Studies of oceanographic conditions become imperative every day, both in the provision of data for research purposes and for engineering applications. Such uses range from the validation of wave prediction models to the determination of forces in offshore structures, as well as navigability and logistical operations. The use of vessel movements to determine which is the condition induced by them, adopting the vessel as a sensor, in analogy to oceanographic buoys, is one of the available technologies for the measurement of oceanographic conditions. It stands out for the simplicity of the implementation, in addition it meets the needs of the oil industry, since the interest is focused on extreme wave events, which are well represented by the technology considered, as verified in this thesis. Ease of data attainment through the mentioned technology, without the need for additional equipment - especially in the case of oil platforms due to the availability of inertial bases in many vessels of this type - was essential to guarantee the present work the data set of field the FPSO platform for two years, through which it was possible to make estimates of the waves in intervals of thirty minutes. This rich database, unprecedented in the specialized literature, together with the estimates provided by a wave radar system, allowed a detailed study of the characteristics and patterns of the directional wave spectra and an important validation of the application of the technology in the field. Given the uncertainties inherent in the process, however, it can be observed that, for the same record of movements, many different and almost equiprobable solutions can be obtained, a feature that favors the application of a Bayesian inference method, in order to provide some information on the variables of estimation. In the present approach, this information corresponds to an assumption of smoothness of the directional wave spectra to be estimated, the degree of which is controlled by so-called hyperparameters of the inference process - parameters within the method that control the influence of a priori information on the solution. Previous studies conducted at EPUSP have demonstrated that the use of fixed or precalibrated hyperparameters is advantageous to make the estimation method operationally applicable, providing a runtime compatible with real-time applications. Given the importance of the role played by a priori information in determining viable solutions in the uncertainty range of the method, it becomes clear that it is necessary to define appropriate values for these hyperparameters. Thus, in this work, the calibration methodology for the hyperparameters is presented, based on the dependency of these on wave mean period and on bandwidth spectral parameter. The _rst is the development of an iterative, self-sufficient method, capable of identifying estimations errors caused by uncertainties on the ship\'s motions prediction model. The second is the ability of the method to mitigate the errors found, forcing spectral smoothness throughout the range of wave frequencies.

Fatigue cracking and moisture damage are two important modes of distresses in asphalt pavements. Recently, the Dynamic Mechanical Analyzer (DMA) was used to characterize fatigue cracking and evaluate the effects of moisture damage on the Fine Aggregate Matrix (FAM) portion of asphalt mixtures. The FAM specimens should be properly fabricated to represent the composition and structure of the fine portion of the mixture. The objective of the first phase of this study was to develop a standard test procedure for preparing FAM specimens such that it is representative of the mixture. The method consists of preparing loose full asphalt mixtures and sieving through different sizes. Then, the ignition oven was used to determine the binder content associated with the small size materials (passing on sieve #16). Sieve #16 is used to separate fine aggregates from the coarse aggregates. The applicability of this new method will be evaluated using a number of asphalt mixtures. The objective of the second phase of this study was to develop software to analyze the data from DMA test. Such software will enable engineers and researchers to perform the complex analysis in very short time. This is Microsoft Windows ® based software, executable in any hardware configuration under this operational system.

Studies show that the microstructure of the fine aggregate matrix has a significant influence on the mechanical properties and evolution of damage in an asphalt mixture. However, very little work has been done to quantitatively characterize the microstructure of the asphalt binder within the fine aggregate matrix of asphalt mixtures. The first objective of this study was to quantitatively characterize the three dimensional microstructure of the asphalt binder within the fine aggregate matrix (FAM) of an asphalt mixture and compare the influence of binder content, coarse aggregate gradation, and fine aggregate gradation on this microstructure. Studies indicate that gradation of the fine aggregate has the most influence of the degree of anisotropy whereas gradation of the coarse aggregate has the most influence on the direction anisotropy of the asphalt mastic within the fine aggregate matrix. Addition of asphalt binder or adjustments to the fine aggregate gradation also resulted in a more uniform distribution of the asphalt mastic within the fine aggregate matrix. The second objective of this study was to compare the internal microstructure of the mortar within a full-scale asphalt mixture to the internal microstructure of the FAM specimen and also conduct a limited evaluation of the influence of mixture properties and methods of compaction on the engineering properties of the FAM specimens. Fatigue cracking is a significant form of pavement distress in flexible pavements. The properties of the sand-asphalt mortars or FAM can be used to characterize the evolution of fatigue crack growth and self-healing in full-scale asphalt mixtures. The results from this study, although limited in number, indicate that in most cases the SGC (Superpave Gyratory Compactor) compacted FAM specimen had a microstructure that most closely resembled the microstructure of the mortar within a full-scale asphalt mixture. Another finding from this study was that, at a given level of damage, the healing characteristic of the three different types of FAM mixes evaluated was not significantly different. This indicates that the healing rate is mostly dictated by the type of binder and not significantly influenced by the gradation or binder content, as long as the volumetric distribution of the mastic was the same. / text

Thermal and fatigue cracking are pavement distresses that deteriorate asphalt pavements in Canada. However, the current AASHTO M320 standard specification protocol does not give satisfactory correlation between the properties measured in the laboratory to thermal and fatigue cracking performance of the asphalt in service. This thesis is aimed at validating the newly developed MTO LS-299 and LS-308 specification test methods for predicting pavement distress. A secondary objective is to determine how well laboratory-aged and field-aged binders correlate with each other in terms of their chemical and physical properties. Chemical testing using infrared (IR) spectroscopy and X-ray fluorescence (XRF), as well as physical and mechanical testing using the regular bending beam rheometer (BBR), extended BBR (eBBR), dynamic shear rheometer (DSR), and double edge notched tension (DENT) tests were performed on laboratory-aged and recovered binders from Highway 417. Asphalt cements with significant amounts of waste engine oil residues as determined by XRF data were found to have cracked severely due to their high tendency for chemical aging. Western Canadian binders modified with styrene-butadiene-styrene polymer showed low affinity for both chemical and physical aging as determined from their carbonyl indices. Asphalt binders with smaller paraffinic structures exhibited insignificant pavement deterioration while the opposite occurred to those with low aromatic indices according to their IR data. The DSR data show that chemical aging occurs much faster in the laboratory-aged binders than the field-aged binders. The DENT test is able to separate superior performing binders from inferior ones with 86% accuracy according to their CTOD data. The regular BBR gave poor correlation between the laboratory test methods and the performance of the pavements. Good correlation exists between the laboratory test methods and the performance of the pavements in service according to the eBBR data. Pavements without any cracks showed lower grade losses, while pavements with severe thermal cracking recorded higher grade losses after three days of conditioning prior to testing. The study has shown that the eBBR and DENT tests are better tools for predicting pavement performance and provide good specification tests for the control of thermal and fatigue cracking in modern pavements. / Thesis (Master, Chemistry) -- Queen's University, 2012-02-28 13:16:02.222

Estudos de condições oceanográficas tornam-se imperativos a cada dia, tanto no fornecimento de dados para fins de pesquisa quanto para aplicações de engenharia. Tais usos variam desde a validação de modelos de previsão de ondas até a determinação de forças em estruturas offshore, bem como em condições de navegabilidade e operações logísticas. O uso dos movimentos do navio para determinar qual condição de mar os induziu, adotando a embarcação como um sensor, em analogia às boias oceanográficas, é uma das tecnologias disponíveis para a medição das condições oceanográficas. Esta destaca-se pela simplicidade na implementação, além de atender às necessidades da indústria petrolífera, uma vez que o interesse é voltado para eventos de ondas extremas, os quais são bem representados pela tecnologia considerada, como verificado nesta tese. A facilidade de obtenção de dados através da tecnologia mencionada, sem a necessidade de equipamentos adicionais { especialmente no caso de plataformas de petróleo devido à disponibilidade de bases inerciais em muitas embarcações deste tipo { foi essencial para garantir ao presente trabalho um conjunto de dados de campo composto por registros ininterruptos dos movimentos de uma plataforma FPSO durante dois anos, através do qual foi possível realizar estimativas das ondas em intervalos de trinta minutos. Esta rica base de dados, inédita na literatura especializada, aliada às estimativas fornecidas simultaneamente por um sistema de radar de ondas, permitiu um estudo detalhado das características e padrões dos espectros direcionais de onda e uma importante validação da aplicação da tecnologia em campo. Face às incertezas inerentes ao processo, no entanto, observa-se que, para um mesmo registro de movimentos, muitas soluções diferentes e quase equiprováveis podem ser obtidas, uma característica que favorece a aplicação de um método de inferência Bayesiana, afim de fornecer alguma informação a priori sobre as variáveis de estimação. Na presente abordagem, esta informação corresponde a uma suposição de suavidade dos espectros direcionais de onda a serem estimados, cujo grau é controlado pelos chamados hiperparâmetros do processo de inferência - parâmetros dentro do método que controlam a influência da informação a priori sobre a solução. Estudos prévios realizados na EPUSP demonstraram que o uso de hiperparâmetros fixos ou pré-calibrados é vantajoso para tornar o método de estimação operacionalmente aplicável, proporcionando um tempo de execução compatível com aplicações em tempo real. Dada a importância do papel desempenhado pela informação a priori na determinação de soluções viáveis no intervalo de incertezas do método, torna-se patente a necessidade de se definir valores apropriados para estes hiperparâmetros. Assim, neste trabalho, é apresentada uma metodologia de calibração para os hiperparâmetros baseada na dependência destes no período médio de onda e no parâmetro espectral de largura de banda. Esta nova abordagem traz dois aspectos inovadores para a pesquisa: O primeiro é o desenvolvimento de um método iterativo e autossuficiente capaz de identificar erros de estimação causados por incertezas no modelo de previsão de movimentos do navio. O segundo ponto é a capacidade do método de mitigar os erros encontrados, forçando a suavidade espectral ao longo do intervalo de frequências de onda. / Studies of oceanographic conditions become imperative every day, both in the provision of data for research purposes and for engineering applications. Such uses range from the validation of wave prediction models to the determination of forces in offshore structures, as well as navigability and logistical operations. The use of vessel movements to determine which is the condition induced by them, adopting the vessel as a sensor, in analogy to oceanographic buoys, is one of the available technologies for the measurement of oceanographic conditions. It stands out for the simplicity of the implementation, in addition it meets the needs of the oil industry, since the interest is focused on extreme wave events, which are well represented by the technology considered, as verified in this thesis. Ease of data attainment through the mentioned technology, without the need for additional equipment - especially in the case of oil platforms due to the availability of inertial bases in many vessels of this type - was essential to guarantee the present work the data set of field the FPSO platform for two years, through which it was possible to make estimates of the waves in intervals of thirty minutes. This rich database, unprecedented in the specialized literature, together with the estimates provided by a wave radar system, allowed a detailed study of the characteristics and patterns of the directional wave spectra and an important validation of the application of the technology in the field. Given the uncertainties inherent in the process, however, it can be observed that, for the same record of movements, many different and almost equiprobable solutions can be obtained, a feature that favors the application of a Bayesian inference method, in order to provide some information on the variables of estimation. In the present approach, this information corresponds to an assumption of smoothness of the directional wave spectra to be estimated, the degree of which is controlled by so-called hyperparameters of the inference process - parameters within the method that control the influence of a priori information on the solution. Previous studies conducted at EPUSP have demonstrated that the use of fixed or precalibrated hyperparameters is advantageous to make the estimation method operationally applicable, providing a runtime compatible with real-time applications. Given the importance of the role played by a priori information in determining viable solutions in the uncertainty range of the method, it becomes clear that it is necessary to define appropriate values for these hyperparameters. Thus, in this work, the calibration methodology for the hyperparameters is presented, based on the dependency of these on wave mean period and on bandwidth spectral parameter. The _rst is the development of an iterative, self-sufficient method, capable of identifying estimations errors caused by uncertainties on the ship\'s motions prediction model. The second is the ability of the method to mitigate the errors found, forcing spectral smoothness throughout the range of wave frequencies.

No description available.

No description available.

No description available.