[pt] Este trabalho apresenta o estudo de comunicação óptica quântica no infravermelho, utilizando um sistema híbrido fibra-óptica – espaço-livre, como prova de princípio para o estabelecimento de chaves secretas a fim de utilização em criptografia do tipo one-time pad. Ao modular a polarização da luz de um laser em polarizações ortogonais, podem-se codificar os bits clássicos 1 e 0 em cada uma dessas polarizações, sendo detectadas por detectores contadores de fótons únicos, e, assim, utilizar o canal quântico para transmissão dos bits quânticos entre dois interlocutores, utilizandoos para o estabelecimento da chave criptográfica, que pode ser usada em qualquer tipo de informação a ser transmitida por um canal clássico ou quântico. Ao realizar a transmissão em espaço-livre, sujeita a variações climáticas, como temperatura atmosférica, luz solar, presença de nuvens, chuva e vento, foi também estudada a influência destes fenômenos na qualidade da transmissão e dos dados obtidos. Os resultados experimentais demonstraram consistência com a teoria e com outros trabalhos publicados na área até esta data com relação às taxas de erro de bit quântico e também à taxa de transmissão de bits. As taxas de erro obtidas, por estarem abaixo do limiar teórico para segurança da informação em comunicação quântica, provam, ainda, a possibilidade de estabelecimento de chave secreta para criptografia através do uso de distribuição quântica das chaves (QKD). Os resultados também apresentaram boa qualidade da informação recuperada após a descriptografia. / [en] This work presents the study of optical quantum communication in the infrared region, using a hybrid optical-fiber – free-space system, as proof of principle for the agreement on secret keys by two parties for use in one-time pad encryption. By modulating the polarization of laser light into orthogonal polarizations, one can encode the classic bits 1 and 0 in each of these polarizations, being detected by single photon counter detectors, and can use the quantum channel to transmit the quantum bits between two interlocutors. It is then possible to use those bits to establish the cryptographic key, which can be used in any type of information to be transmitted by a classic or quantum channel. While carrying out transmission in free space optics, subject to climatic variations, such as atmospheric temperature, sunlight, presence of clouds and rain, and the presence of wind, the influence of these phenomena on the quality of transmission and on the data obtained was also studied. The experimental results showed consistency with the theory and with other works published to date with regard to quantum bit error rates and to the bit rate. The error rates obtained, being below the theoretical threshold for information security in quantum communication, further proves the possibility of establishing a secret key for encryption through the use of quantum key distribution (QKD). It also presented good quality on the information recovered after decryption.

Optimizing a modulator driver for linear and high-speed operation, while simultaneously achieving a high output voltage swing is very challenging. This paper investigates the design of a highlylinear, high-bandwidth yet power-efficient Mach-Zehnder modulator driver based on the breakdown voltage doubler concept, which overcomes the transistors' physical limitations and enables output voltage swings twice as high as conventional differential pair amplifiers can provide. The low-power design was enabled by the use of an open-collector topology for the output stage as well as by employing resistors instead of current mirrors in order to provide the bias currents for the emitter-follower (EF) stages. We show that by means of this EF implementation approach, the power consumption can be reduced by 19% without sacrificing the circuit's bandwidth and linearity. The driver achieves peak-to-peak differential output voltage swings above 6.5 Vpp,d and consumes 670mWof DC power, being one of the most power-efficient drivers in the literature. The 3-dB bandwidth is 61.2 GHz and the total harmonic distortion is 1%, measured at 1 GHz and for the output swing of 6.5 Vpp,d. To the best of the authors' knowledge, these are the highest linearity and output voltage swing reported in the literature for modulator drivers with bandwidths above 40 GHz.

The need to consider groundwater and surface water as a single resource has fostered the interest of the scientific community on the interactions between surface water and groundwater. The region below and alongside rivers where surface hydrology and subsurface hydrology concur is the hyporheic zone. This is the region where water exchange determines many biogeochemical and ecological processes of great impact on the functioning of rivers. However, the complex processes taking place in the hyporheic zone require a multidisciplinary approach. The combination of innovative point and distributed techniques originally developed in separated disciplines is of great advantage for the indirect identification of water exchange in the hyporheic zone. Distributed techniques using temperature as a tracer such as fiber-optic distributed temperature sensing can identify the different components of groundwater-surface water interactions based on their spatial and temporal thermal patterns at the sediment-water interface. In particular, groundwater, interflow discharge and local hyporheic exchange flows can be differentiated based on the distinct size, duration and sign of the temperature anomalies. The scale range and resolution of fiber-optic distributed temperature sensing are well complemented by geophysics providing subsurface structures with a similar resolution and scale. Thus, the use of fiber-optic distributed temperature sensing to trace flux patterns supported by the exploration of subsurface structures with geophysics enables spatial and temporal investigation of groundwater-surface water interactions with an unprecedented level of accuracy and resolution. In contrast to the aforementioned methods that can be used for pattern identification at the interface, other methods such as point techniques are required to quantify hyporheic exchange fluxes. In the present PhD thesis, point methods based on hydraulic gradients and thermal profiles are used to quantify hyporheic exchange flows. However, both methods are one-dimensional methods and assume that only vertical flow occurs while the reality is much more complex. The study evaluates the accuracy of the available methods and the factors that impact their reliability. The applied methods allow not only to quantify hyporheic exchange flows but they are also the basis for an interpretation of the sediment layering in the hyporheic zone. For upscaling of the previous results three-dimensional modelling of flow and heat transport in the hyporheic zone combines pattern identification and quantification of fluxes into a single framework. Modelling can evaluate the influence of factors governing groundwater-surface water interactions as well as assess the impact of multiple aspects of model design and calibration of high impact on the reliability of the simulations. But more importantly, this modelling approach enables accurate estimation of water exchange at any location of the domain with unparalleled resolution. Despite the challenges in 3D modelling of the hyporheic zone and in the integration of point and distributed data in models, the benefits should encourage the hyporheic community to adopt an integrative approach comprising from the measurement to the upscaling of hyporheic processes.