Advances in fiber optic communications and the convergence of the optical-wireless network will dramatically increase the network heterogeneity and complexity. The goal of our research is to create smart receivers that can autonomously identify and demodulate, without prior knowledge, nearly any signal emerging from the next-generation of high-speed optical communication networks.

Hydrogen peroxide (H2O2) is extensively used in a broad range of industrial and medical applications, such as aseptic processing of food and pharmaceuticals, disinfection, water treatment plants, and decontamination of industrial effluents. H2O2 is believed to be responsible for chemical degradation of polymer membranes in Polymer-Electrolyte-Membrane (PEM) fuel cells. Therefore, a versatile H2O2 sensor that functions in different environments with different conditions is of practical importance in various fields. This dissertation presents the fabrication of a fiber-optic H2O2 sensing probe (optrode) and its H2O2 sensing behavior in different conditions. An H2O2 optrode is fabricated using chemical deposition of Prussian blue (PB) onto the tip of a multimode optical fiber. Sensing tests are performed in aqueous solutions at a constant pH and different concentrations of H2O2. Sensing features of the optrode (i.e. repeatability, durability, and reproducibility) are assessed by performing multiple sensing tests with several optrodes. The results show the prepared optrode is able to detect concentrations of H2O2 in aqueous solutions at a constant pH of 4 and the optrode features a repeatable and durable response at this condition. The functionality of optrodes at different pH values is further investigated by performing additional sensing experiments. These experiments are carried out in aqueous solutions with different concentrations of H2O2 at different pH values (i.e. pH 2-7). The sensor detects the presence of H2O2 at a range of pH values. Sensing behavior of optrodes toward detection and measurement of H2O2 concentrations is studied at the pH value corresponding to an operating PEM fuel cell (i.e. pH 2). The optrode is able to detect concentrations of H2O2 at this condition with a repeatable and durable response. The stability of PB films, prepared through different conditions, is investigated to address the stability of optrodes at elevated temperatures. PB films are first deposited onto the glass slides through three different chemical processes, and then at different synthesis temperatures. The PB films are left in Phosphate-Buffer-Solutions (PBS) with pH 2 and at elevated temperatures for a day. Finally, PB films are characterized using Fourier transform infrared spectroscopy (FTIR) to analyze their stability following PBS processing at operating temperatures and pH value corresponding to an operating PEM fuel cell (i.e. 80 °C and pH 2). The results of these experiments illustrate the PB films prepared through the single-source precursor (SSP) technique and at synthesis temperatures above 60 °C remain stable after the PBS processing. The proposed optrode shows reliable sensing behavior toward detection and measurement of H2O2 concentrations in aqueous solutions at different conditions. The prepared optrode has the potential for being developed and used in different industrial and medical fields, as well as an operating PEM fuel cell, to detect and measure H2O2 concentrations. / Graduate / 0794 / 0548 / 0485 / hakbarik@uvic.ca

Améliorer la sécurité routière passe par une meilleure compréhension des causes d'accidents. Il est donc nécessaire de développer des observatoires discrets pour étudier la manière de conduire de tous les automobilistes. Une partie de cette analyse implique l'utilisation de capteurs mesurant les trajectoires des véhicules sur une portion de route. Deux capteurs innovants ont été crées pour pallier au manque de capteurs suffisamment précis pour ces travaux de recherche : le premier est un capteur à fibres optiques présentant une succession de réseaux de Bragg et le second, protégé par un brevet, est fondé sur une technologie résistive. Le premier repère la déformation locale de fibres optiques noyées à moins d'un centimètre sous la surface de la chaussée. Il utilise la variation de longueurs d'onde engendré par l'extension de la fibre à la zone de contact roue - sol. En utilisant un algorithme adéquat, il est insensible à la température. Le second est constitué de deux conducteurs dont un est résistif. Le poids du véhicule engendre un contact électrique entre les deux conducteurs, transformant la résistance électrique de l'ensemble. Les modèles développés, électrique ainsi que de variation thermique, permettent sa meilleure utilisation. Ils ont été soumis à une expérimentation sur une route départementale. Le capteur optique s'avère plus performant mais coûteux. Le deuxième n'est pas assez robuste mais présente des perspectives intéressantes. / This action stake is not technology for itself. It is a great help the development of new safety functions, e.g. the estimation of driver’s behaviour based uponthe vehicle’s trajectory. This trajectory is determined via two sensors we developed. This system must not disturb the driver and should therefore remain invisible to him. The first one is a fiber Bragg grating (FBG) sensor. It detects local strain due to the vehicle weight. The fiber is embedded in the road thanks to resin used in other traffic sensors. The vehicle location is spotted according to the variations of Bragg wavelengths. The fiber extension located under the ground - wheel contact zone changes the step of the Bragg grating. The second one is based upon two conductors. One of them has a grater electrical resistance. The vehicle’s weight creates a link between the two conductors. The resulting electrical resistance provides a lateral position estimation of the vehicle. Electrical and thermic models and simulation even increase the sensor reliability. A caveat is lodged. Both of them were tested on a secondary road. To put in a nutshell, the FBG sensor gives better results but is very expensive (sensors and interrogator too). The resistance sensor is not much raw nevertheless it has interesting perspectives.

Achieving and maintaining sustainability in irrigated agriculture production in the era of rapidly increasing stress on our natural resources require, among other essential actions, optimum control and management of the applied water. Thus, a significant upgrade of the currently available soil water monitoring technologies is needed. The primary goal of this work was to reduce the uncertainties of spatially variable soil water in the field. Two approaches are suggested: 1) The Bayesian decision model that implicitly accounts for spatial variability at minimal cost based on limited field data, and 2) The Actively Heated Fiber Optic (AHFO) method that explicitly accounts for spatial variability with high sampling density at relatively low cost per measurement point. The Bayesian decision model uses an algorithm to integrate information embodied in independent estimates of soil water depletion to derive a posterior estimation of soil water status that has the potential to reduce the risk of costly errors in irrigation scheduling decisions. The sources of information are obtained from an ET based water balance model, soil water measurements, and expert opinion. The algorithm was tested in a numerical example based on a field experiment where soil water depletion measurements were made at 43 sites in an agricultural field under center pivot irrigation. The results showed that the estimates of the average soil water depletion in the field obtained from the posterior distributions of soil water depletion proved to outperform simple averaging of n soil water depletion measurements, up to n = 35 measurements. For n< 3, the model also provided a 39% average reduction in risk of error derived from non-representative measurements. The AHFO method observes the heating and cooling of a buried fiber optic (FO) cable through the course of a pulse application of energy as monitored by a distributed temperature sensing (DTS) system to reveal soil water content simultaneously at sub-meter scale along the FO cable that can potentially exceeds kilometers in length. A new and simple interpretation of heat data that takes advantage of the characteristics of FO temperature measurements is presented. The results demonstrate the feasibility of AHFO method application to obtain <0.05 m³m⁻³ error distributed measurements of soil water content under laboratory controlled conditions. The AHFO method was then tested under field conditions using 750 m of FO cables buried at 30, 60, and 90 cm depths in agricultural field. The calibration curve relating soil water content to the thermal response of the soil to a heat pulse was developed in the lab. It was successively applied to the 30 and 60 cm depths cables, while the 90 cm depth cable illustrated the challenges of soil heterogeneity for this technique. The method was used to map with high spatial (1m) and temporal (1hr) resolution the spatial variability of soil water content and fluxes induced by the non-uniformity of water application at the surface. / Graduation date: 2012

The objective of this thesis is to study of optical effects, arising in the form of non-uniform waveguide structure, complicated refractive index profiles or due to pulse propagation in dense wavelength division multiplexing (DWDM) optical communication systems. These effects are important and critically influence the performance of DWDM optical systems. A comprehensive survey of current literature on optical effects due to nonuniform optical structure and nonlinear optical effects is first done, showing their advantages and disadvantage in optical communication systems. A survey on methods of optical waveguide analysis is also done. The main contribution has been made to three main aspects of the problem : Accurate analysis of uniform/non-uniform optical waveguides with arbitary refractive index profiles Pulse propagation and distortion in DWDM Raman amplification systems. Use of non-uniform FBG to compensate for pulse distortion We study several existing analytical techniques developed so far for analyzing the mode of non-uniform optical waveguide structures. Later, we verify the analytical results by finite element method (FEM). The convergence study is also carried out. A new computational technique is proposed modifying the finite element method to analyze complex refractive index profiles required for the analysis, namely single mode step index profile, multi clad fiber, W -profile, chirp profile etc. An accuracy of 10−4 in the calculation of propagation constant/eigen-value is demonstrated. Dispersion characteristics of optical fibers w.r.t. different profile parameters is evaluated. A modification to scalar BPM is proposed and applied to study the effects of inhomogeneities along the propagation direction. The applicability and accuracy of the method is tested using integrated optic waveguide devices, namely, graded index slab waveguide. The proposed BPM uses Fourier decomposition of the transverse field. Coupled mode theory (CMT) of optical waveguides in non-homogeneous optical medium is applied to study the interaction of lightwaves propagation together such as in a DWDM system. The BPM results is verified by CMT. The inhomogeneous waveguide theory is extended to study pulse propagation in DWDM optical communication system. Nonlinear optical effects are an important aspects of DWDM systems with fiber Raman amplifier. Finite difference time domain (FDTD) method is necessary to study these nonlinear optical effects as other conventional methods are not suitable here. Here, we discuss DWDM optical communication systems due to nonlinearity in the form of SRS effect. In case of FRA, we study the various kinds of fiber profile design parameters, for the purpose to achieve and extend the flat gain bandwidth over the EDFA window. We also propose and study, a new bi-directional optical fiber transmission scheme with various constraints, using Raman amplification process with and without pump depletion. Our scheme, provides an advantage like high SNR, low pump induced noise, for long-haul communication link. We find that, there is a quite significant crosstalk and power coupling among the dense DWDM channels but earlier discussed BPM fails to account for possible interference effects among the channels. To reduce the harmful nonlinear optical effects like four wave mixing (FWM), we need to deploy a high chromatic dispersion fiber, which will ultimately lead to high pulse walk-off rate among the DWDM channels; hence for high bit rate long haul systems, walk-off effect can not be ignored. Application of FDTD provided an improved insight into the effect of GVD on stimulated Raman scattering crosstalk than different modulation techniques and line codes. It is shown through analysis that pulse walk-off phenomena may distort the data asymmetrically; especially for case of wide-band DWDM transmission system. Hence, the pulse walk-off effect should be considered in future systems containing optical amplifier. It is shown, that large walk-off rate may reduce the crosstalk among DWDM channels but tends to increase the asymmetric pulse distortion. Data may lose due to high walk-off effect. We also investigate channel addition/removal process in DWDM fiber Raman amplifier. We also demonstrate that the pulse walk-off effect tends to lead significantly to positive chirp for higher frequency channels. This feature can be exploited to overcome the chromatic dispersion effects in DWDM transmission systems. Pulse walk-off induced chirp, can be compensated by using the nonuniform fiber Bragg grating (NUFBG). The CMT due to periodic perturbation of the circular cylindrical waveguide structures is applied here. Here, we discuss the function of fiber Bragg grating as a transmission versus reflecting grating filter. We also discuss, FBG application to gain flattening of an EDFA window as well as how the group velocity dispersion (GVD) will be affected with bandwidth and coupling coefficient. We develop a new analytical technique to estimate the bandwidth of FBG based optical system. Finally, we investigate the dispersion compensation properties, pulse distortion, peak reflectivity analysis in uniform/non-uniform FBG due to an uniform/non-uniform incoming signal. More complicated refractive index profile can significantly reduce the GVD as well as side lobes intensity. Dispersion characteristic due to an arbitrary refractive index profile is discussed in details for the case of non-uniform FBG. Thus, we concluded that wide band DWDM optical communication system need to closely take into account various inhomogeneities and nonlinearities of optical fibers w.r.t. wave and pulse propagation.

Carbon dioxide sequestration is one of many mitigation tools available to help reduce carbon dioxide emissions while other disposal/repurposing methods are being investigated. Geologic sequestration is the most stable option for long-term storage of carbon dioxide (CO2), with significant CO2 trapping occurring through mineralization within the first 20-50 years. A fiber optic based monitoring system has been proposed to provide real time concentrations of CO2 at various points throughout the geologic formation. The proposed sensor is sensitive to the refractive index (RI) of substances in direct contact with the sensing component. As RI is a measurement of light propagating through a bulk medium relative to light propagating through a vacuum, the extraction of the effects of any specific component of that medium to the RI remains very difficult. Therefore, a requirement for a selective barrier to be able to prevent confounding substances from being in contact with the sensor and specifically isolate CO2 is necessary. As such a method to evaluate the performance of the selective element of the sensor was investigated. Polybenzimidazole (PBI) and VTEC polyimide (PI) 1388 are high performance polymers with good selectivity for CO2 used in high temperature gas separations. These polymers were spin coated onto a glass substrate and cured to form ultra-thin (>10 μm) membranes for gas separation. At a range of pressures (0.14 –0.41 MPa) and a set temperature of 24.2±0.8 °C, intrinsic permeabilities to CO2 and nitrogen (N2) were investigated as they are the gases of highest prevalence in underground aquifers. Preliminary RI testing for proof of concept has yielded promising results when the sensor is exposed exclusively to CO2 or N2. However, the use of both PBI and VTEC PI in these trials resulted in CO2 selectivities of 0.72 to 0.87 and 0.33 to 0.63 respectively, for corresponding feed pressures of 0.14 to 0.41 MPa. This indicates that both of the polymers are more selective for N2 and should not be used in CO2 sensing applications as confounding gas permeants, specifically N2, will interfere with the sensing element. / Graduate / 0428 / 0495 / 0542 / ben.t.davies@gmail.com

The central objective of this thesis is to suggest and develop one simple, unified method for communication over optical fiber networks, valid for all values of dispersion and nonlinearity parameters, and for a single-user channel or a multiple-user network. The method is based on the nonlinear Fourier transform (NFT), a powerful tool in soliton theory and exactly solvable models for solving integrable partial differential equations governing wave propagation in certain nonlinear media. The NFT decorrelates signal degrees of freedom in such models, in much the same way that the Fourier transform does for linear systems. In this thesis, this observation is exploited for data transmission over integrable channels such as optical fibers, where pulse propagation is governed by the nonlinear Schr\"odinger (NLS) equation. In this transmission scheme, which can be viewed as a nonlinear analogue of orthogonal frequency-division multiplexing commonly used in linear channels, information is encoded in the nonlinear spectrum of the signal. Just as the (ordinary) Fourier transform converts a linear convolutional channel into a number of parallel scalar channels, the nonlinear Fourier transform converts a nonlinear dispersive channel described by a \emph{Lax convolution} into a number of parallel scalar channels. Since, in the spectral coordinates the NLS equation is multiplicative, users of a network can operate in independent nonlinear frequency bands with no deterministic inter-channel interference. Unlike most other fiber-optic transmission schemes, this technique deals with both dispersion and nonlinearity directly and unconditionally without the need for dispersion or nonlinearity compensation methods. This thesis lays the foundations of such a nonlinear frequency-division multiplexing system.

The central objective of this thesis is to suggest and develop one simple, unified method for communication over optical fiber networks, valid for all values of dispersion and nonlinearity parameters, and for a single-user channel or a multiple-user network. The method is based on the nonlinear Fourier transform (NFT), a powerful tool in soliton theory and exactly solvable models for solving integrable partial differential equations governing wave propagation in certain nonlinear media. The NFT decorrelates signal degrees of freedom in such models, in much the same way that the Fourier transform does for linear systems. In this thesis, this observation is exploited for data transmission over integrable channels such as optical fibers, where pulse propagation is governed by the nonlinear Schr\"odinger (NLS) equation. In this transmission scheme, which can be viewed as a nonlinear analogue of orthogonal frequency-division multiplexing commonly used in linear channels, information is encoded in the nonlinear spectrum of the signal. Just as the (ordinary) Fourier transform converts a linear convolutional channel into a number of parallel scalar channels, the nonlinear Fourier transform converts a nonlinear dispersive channel described by a \emph{Lax convolution} into a number of parallel scalar channels. Since, in the spectral coordinates the NLS equation is multiplicative, users of a network can operate in independent nonlinear frequency bands with no deterministic inter-channel interference. Unlike most other fiber-optic transmission schemes, this technique deals with both dispersion and nonlinearity directly and unconditionally without the need for dispersion or nonlinearity compensation methods. This thesis lays the foundations of such a nonlinear frequency-division multiplexing system.

Submitted by Valquíria Barbieri (kikibarbi@hotmail.com) on 2017-11-01T20:08:00Z No. of bitstreams: 1 DISS_2012_Danilo Costa Bertoloto.pdf: 8430681 bytes, checksum: 18a9ced8f731a2447eed45c8e94c3954 (MD5) / Approved for entry into archive by Jordan (jordanbiblio@gmail.com) on 2017-12-15T14:56:18Z (GMT) No. of bitstreams: 1 DISS_2012_Danilo Costa Bertoloto.pdf: 8430681 bytes, checksum: 18a9ced8f731a2447eed45c8e94c3954 (MD5) / Made available in DSpace on 2017-12-15T14:56:18Z (GMT). No. of bitstreams: 1 DISS_2012_Danilo Costa Bertoloto.pdf: 8430681 bytes, checksum: 18a9ced8f731a2447eed45c8e94c3954 (MD5) Previous issue date: 2012-08-30 / Esta dissertação de caráter descritivo e exploratório busca traçar um panorama do nível de conexão que o Brasil, mais precisamente a Cidade de Cuiabá, capital do estado de Mato Grosso, está inserida. Busca-se apresentar, também, como se dão as conexões e quais backbones fazem parte da malha óptica que liga a cidade aos grandes centros e como estes se interligam com o mundo. O interesse principal da presente pesquisa é entender como Cuiabá, sede da Copa do Mundo de Futebol de 2014 se comportará como produtora, gestora e vendedora de informação, e se a conexão citada acima suportará essa demanda de tráfego. Busca-se então, levantar dados do mega-evento Copa do Mundo de futebol de 2010 para se apontar a demanda de infra-estrutura de comunicação baseada em fibra óptica para a Copa de 2014 no Brasil, Cuiabá. / This dissertation was a descriptive and exploratory search to give an overview of the level of connection that Brazil, more precisely the city of Cuiabá, capital of Mato Grosso, is inserted. Search is also present, as it gives the connections and backbones which are part of the optical network that connects the city to major centers and how they interrelate with the world. However, the ultimate concern of this research is to understand how to Cuiabá, the headquarters of the Football World Cup 2014, will behave as a producer, manager and seller information, and the connection to the above mentioned support the traffic demand. The aim is then to collect data from mega-event World Cup 2010 soccer pointing to the demand for communication infrastructure based on optical fiber for the 2014 World Cup in Brazil, Cuiabá.

För att uppnå ett långsiktigt hållbart samhälle krävs ekologisk, ekonomisk och social hållbar utveckling. Ett sätt att uppnå hållbarhet är genom digitalisering, men detta förutsätter att det finns robust och framtidssäker infrastruktur. Detta examensarbete syftar till att bidra med ökad kunskap om de möjligheter som kan skapas med hjälp av höghastighetsbredband genom fiber, samt att påvisa hur fiberutbyggnaden kan bidra till en hållbar utveckling. Genom att besvara de tre frågeställningarna ”Vilka möjligheter skapar höghastighetsbredband genom fiber?”, ”Vilka utmaningar finns för fiberutbyggnaden?” och ”Hur ska Sveriges kommuner arbeta för att underlätta fiberutbyggnaden och bidra till ett hållbart samhällsbyggande?” är målet att utreda olika lösningar för att uppnå hållbar samhällsplanering och samhällsbyggande genom digitalisering. De metoder som har valts för att framställa denna rapport är litteraturstudier, intervjuer, mailkontakt och möten med ett antal olika personer med olika positioner och roller inom offentlig sektor. Största delen av rapportens innehåll baseras på litteraturstudier från Sverige. Andra metoder som har tillämpats kompletterar litteraturstudien. Resultaten visade att höghastighetsbredband skapar nya möjligheter och bättre förutsättningar för vård och omsorg, utbildning, ökad tillväxt, minskad klimatpåverkan samt ekonomiska besparingar för privatpersoner och näringsverksamhet. Av resultaten framkom även att det finns ett antal faktorer som kan hindra utvecklingen av en effektiv utbyggnad av höghastighetsbredband. En utmaning är att skapa gemensam och enhetlig tillståndsprocess för marktillträde i Sveriges olika kommuner med olika geografiska skillnader och olika förutsättningar. En annan utmaning är att det saknas tillräcklig samverkan och samordning mellan olika offentliga myndigheter. Ökad samordning mellan olika interna funktioner, samt i vilken grad offentliga myndigheter samplanerar infrastrukturarbeten är viktiga delar för att lösa dessa utmaningar. Vidare är implementering av digitala system för hantering av kommunala tillståndsprocesser en effektiv lösning för att främja en hållbar samhällsutveckling. Slutsatsen av arbetet är att dagens och framtidens samhälle är beroende av välfungerande IT-infrastruktur. Det finns många hinder och utmaningar på vägen som måste lösas innan en hållbar samhällsutveckling kan uppnås. Med rätt planering, strategiskt arbete och helhetstänk kan dessa utmaningar omvandlas till helt nya möjligheter. / In order to achieve a long-term sustainable society, it requires ecological, economic and socially sustainable development. One way of achieving sustainability is through digitization, but this requires robust and future-proof infrastructure. This thesis aims to contribute to increased knowledge about the possibilities that can be created by using high-speed broadband through the fiber, as well as demonstrating how the development of fiber can contribute to sustainable development. By answering the three research questions "What opportunities create high-speed bandwidth through fiber?", "What challenges are there for fiber expansion?" and "How will Sweden's municipalities work to facilitate the fiber expansion and contribute to sustainable community building?" the goal is to investigate different solutions for achieving sustainable social planning and community building through digitization. The methods chosen to meet the objectives are literature studies, interviews, mail contacts and meetings with a number of different people with different positions and roles in the public sector. The majority of this report's content is based on literature studies from Sweden. Other methods that have been applied complement the literature study. The results showed that high-speed broadband creates new opportunities and better conditions for care and education, increased growth, reduced climate impact and economic savings for individuals and business. The results also revealed that there are a number of factors that could hinder the development of an efficient expansion of high-speed broadband. One challenge is to create a common and unified permission process for land access in Sweden's different municipalities, with different geographic differences and different conditions. Another challenge is that there are insufficient cooperation and coordination between different public authorities. By increasing coordination between various internal functions, as well as the extent to which public authorities jointly plan the infrastructure work is key components in addressing these challenges. Furthermore, implementation of digital systems for managing municipal permission processes is an effective solution for promoting sustainable social development. The conclusion of this thesis is that today's and tomorrow's society is dependent on well-functioning IT-infrastructure. There are many obstacles and challenges that must be solved before sustainable development can be achieved. With proper planning, strategic work, and a holistic thinking these challenges can be transformed into new possibilities.