Hydraulic fracturing is a popular stimulation method in tight gas and shale gas reservoirs that uses a viscous fluid to fracture the reservoir rock and uniformly transport proppant to create a highly conductive path that is kept open by the proppant after fracturing. This method is used to improve the productivity of the otherwise low permeability reservoirs. Hydraulic fracturing, though in general beneficial, is a complex process that has a number of challenges in fracturing design and execution. This research focuses on studying the damage caused by the fracturing fluid (gel) to the fracture and the conditions to remove the damage. Guar gum and its derivatives have been the most commonly used polymers to increase the viscosity of fracturing fluids. The fracturing fluid gets dehydrated under pressure leaving behind a highly concentrated unbroken residue called filter cake which causes permeability impairment in the proppant pack, resulting in low fracture conductivity and decreased effective fracture length. This study seeks to characterize filter cakes. By measuring its thickness and with the leak off volume, the concentration and yield stress of the filter cake can be estimated. The thickness of the filter cake was measured with a precise laser profilometer. Correlations are proposed to estimate filter cake properties (thickness, concentration and yield stress) based on pumping conditions (pump rate, time and net pressure) and rock properties. With these properties known, a required flow back rate of the reservoir fluid can be estimated to clean up the filter cake modeled as a non-newtonian fluid exhibiting a yield stress. Typical field conditions were referenced and scaled down in the lab to closely represent the field conditions. Recommendations are provided on gel damage based on the observation of the study.

With the rapidly increasing demand for energy and the increasing prices for oil and gas, the role of unconventional gas reservoirs (UGRs) as energy sources is becoming more important throughout the world. Because of high risks and uncertainties associated with UGRs, their profitable development requires experts to be involved in the most critical development stages, such as drilling, completion, stimulation, and production. However, many companies operating UGRs lack this expertise. The advisory system we developed will help them make efficient decisions by providing insight from analogous basins that can be applied to the wells drilled in target basins. In North America, UGRs have been in development for more than 50 years. The petroleum literature has thousands of papers describing best practices in management of these resources. If we can define the characteristics of the target basin anywhere in the world and find an analogous basin in North America, we should be able to study the best practices in the analogous basin or formation and provide the best practices to the operators. In this research, we have built an advisory system that we call the Unconventional Gas Reservoir (UGR) Advisor. UGR Advisor incorporates three major modules: BASIN, PRISE and Drilling & Completion (D&C) Advisor. BASIN is used to identify the reference basin and formations in North America that are the best analogs to the target basin or formation. With these data, PRISE is used to estimate the technically recoverable gas volume in the target basin. Finally, by analogy with data from the reference formation, we use D&C Advisor to find the best practice for drilling and producing the target reservoir. To create this module, we reviewed the literature and interviewed experts to gather the information required to determine best completion and stimulation practices as a function of reservoir properties. We used these best practices to build decision trees that allow the user to take an elementary data set and end up with a decision that honors the best practices. From the decision trees, we developed simple computer algorithms that streamline the process.

With the growing interest in low-permeability gas plays, foam fracturing fluids are now well established as a viable alternative to traditional fracturing fluids. Present practices in energized fracturing treatments remain nonetheless rudimentary in comparison to other fracturing fluid technologies because of our limited understanding of multi-phase fluid-loss and phase behavior occurring in these complex fluids. This report assesses the fluid-loss benefits introduced by energizing the fracturing fluid. A new laboratory apparatus has been specifically designed and built for measuring the leak-off rates for both gas and liquid phases under dynamic fluid-loss conditions. This report provides experimental leak-off results for linear guar gels and for N2-guar foam-based fracturing fluids under a wide range of fracturing conditions. In particular, the effects of the rock permeability, the foam quality, and the pressure drop are investigated. Analysis of dynamic leak-off data provide an understanding of the complex mechanisms of viscous invasion and filter-cake formation occurring at the pore-scale. This study presents data supporting the superior fluid-loss behavior of foams, which exhibit minor liquid invasion and limited damage. It also shows direct measurements of the ability of the gas component to leak-off into the invaded zone, thereby increasing the gas saturation around the fracture and enhancing the gas productivity during flowback. Our conclusions not only confirm, but add to the findings of McGowen and Vitthal (1996) for linear gels, and the findings of Harris (1985) for nitrogen foams. / text

Hydraulic fracturing is an important stimulation method for producing unconventional gas reserves. Natural fractures are present in many low-permeability gas environments and often provide important production pathways for natural gas. The production benefit from natural fractures can be immense, but it is difficult to quantify. The Mesaverde Group in the Piceance Basin in Colorado is a gas producing reservoir that has low matrix permeability but is also highly naturally fractured. Wells in the Piceance Basin are hydraulically fractured, so the production enhancements due to natural fracturing and hydraulic fracturing are difficult to decouple. In this thesis, dipole sonic logs were used to quantify geomechanical properties by combining stress equations with critically-stressed faulting theory. The properties derived from this log-based evaluation were used to numerically model hydraulic fracture treatments that had previously been pumped in the basin. The results from these hydraulic fracture models, in addition to the log-derived reservoir properties were used to develop reservoir models. Several methods for simulating the reservoir were compared and evaluated, including layer cake models, geostatistical models, and models simulating the fracture treatment using water injection. The results from the reservoir models were compared to actual production data to quantify the effect of both hydraulic fractures and natural fractures on production. This modeling also provided a framework upon which completion techniques were economically evaluated. / text

Although many fracture models are based on two-dimensional plane strain approximations, accurately predicting fracture propagation geometry requires accounting for the three-dimensional aspects of fractures. In this study, we implemented 3-D displacement discontinuity (DD) boundary element modeling to investigate the following intrinsically 3-D natural or hydraulic fracture propagation problems: the effect of fracture height on lateral propagation of vertical natural fractures, joint development in the vicinity of normal faults, and hydraulic fracture height growth and non-planar propagation paths. Fracture propagation is controlled by stress intensity factor (SIF) and its determination plays a central role in LEFM. The DD modeling is used to evaluate SIF in Mode I, II and III at the tip of an arbitrarily-shaped embedded crack by using crack-tip element displacement discontinuity. We examine the accuracy of SIF calculation is for rectangular, penny-shaped, and elliptical planar cracks. Using the aforementioned model for lateral propagation of overlapping fractures shows that the curving path of overlapping fractures is strongly influenced by the spacing-to-height ratio of fractures, as well as the differential stress magnitude. We show that the angle of intersection between two non-coincident but parallel en-echelon fractures depends strongly on the fracture height-to-spacing ratio, with intersection angles being asymptotic for "tall" fractures (large height-to-spacing ratios) and nearly orthogonal for "short" fractures. Stress perturbation around normal faults is three-dimensionally heterogeneous. That perturbation can result in joint development at the vicinity of normal faults. We examine the geometrical relationship between genetically related normal faults and joints in various geologic environments by considering a published case study of fault-related joints in the Arches National Park region, Utah. The results show that joint orientation is dependent on vertical position with respect to the normal fault, the spacing-to-height ratio of sub-parallel normal faults, and Poisson's ratio of the media. Our calculations represent a more physically reasonable match to measured field data than previously published, and we also identify a new mechanism to explain the driving stress for opening mode fracture propagation upon burial of quasi-elastic rocks. Hydraulic fractures may not necessarily start perpendicular to the minimum horizontal remote stress. We use the developed fracture propagation model to explain abnormality in the geometry of fracturing from misaligned horizontal wellbores. Results show that the misalignment causes non-planar lateral propagation and restriction in fracture height and fracture width in wellbore part. / text

This dissertation presents an experimental investigation of fluid flow, proppant settling and horizontal proppant transport in hydraulic fractures. The work is divided into two major sections: investigation of proppant settling in polymer-free surfactant-based viscoelastic (VES) fluids and development of a new method of proppant injection, referred to as Alternate-Slug fracturing. VES fluid systems have been used to eliminate polymer-based damage and to efficiently transport proppant into the fracture. Current models and correlations neglect the important influence of fracture walls and fluid elasticity on proppant settling. Experimental data is presented to show that elastic effects can increase or decrease the settling velocity of particles, even in the creeping flow regime. Experimental data shows that significant drag reduction occurs at low Weissenberg number, followed by a transition to drag enhancement at higher Weissenberg numbers. A new correlation is presented for the sphere settling velocity in unbounded viscoelastic fluids as a function of the fluid rheology and the proppant properties. The wall factors for sphere settling velocities in viscoelastic fluids confined between solid parallel plates (fracture walls) are calculated from experimental measurements made on these fluids over a range of Weissenberg numbers. Results indicate that elasticity reduces the retardation effect of the confining walls and this reduction is more pronounced at higher ratios of the particle diameter to spacing between the walls. Shear thinning behavior of fluids is also observed to reduce the retardation effect of the confining walls. A new empirical correlation for wall factors for spheres settling in a viscoelastic fluid confined between two parallel walls is presented. An experimental study on proppant placement using a new method of fracturing referred to as Alternate-Slug fracturing is presented. This method involves alternate injection of low viscosity and high viscosity fluids into the fracture, with proppant pumped in the low viscosity fluid. Experiments are conducted in Hele-Shaw cells to study the growth of viscous fingers over a wide range of viscosity ratios. Data is presented to show that the viscous finger velocities and mixing zone velocities increase with viscosity ratio up to viscosity ratios of about 350 and the trend is consistent with Koval’s theory. However, at higher viscosity ratios the mixing zone velocity values plateau signifying no further effect of viscosity contrast on the growth of fingers and mixing zone. The plateau in the velocities at high viscosity ratios is caused by an increase in the thickness of the displacing fluid and a reduction in the thin film of the displaced fluid on the walls of the Hele-Shaw cell. Fluid elasticity is observed to retard the growth of fingers and leads to growth of multiple thin fingers as compared to a single thick dominant finger in less elastic fluids. Observations show the shielding effect is reduced by fluid elasticity. Elastic effects are observed to reduce the thickness of thin film of displaced fluid on the walls of Hele-Shaw cell. The dominant wave number for the growth of instabilities is observed to be higher in more elastic fluids. At the onset of instability, the interface breaks down into a greater number of fingers in more elastic fluids. Experiments are performed in simulated fractures (slot cells) to show the proppant distribution using alternate-slug fracturing. Observations show alternate-slug fracturing ensures deeper placement of proppant through two primary mechanisms: (a) proppant transport in viscous fingers formed by the low viscosity fluid and (b) an increase in drag force in the polymer slug leading to better entrainment and displacement of any proppant banks that may have formed. The method offers advantages of lower polymer costs, lower pumping horsepower, smaller fracture widths, better control of fluid leak-off and less gel damage compared to conventional gel fracs. / text

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Diagnostic ultrasound (US) is safer, quicker and cheaper than other diagnostic imaging modalities. Over the past two decades, the applications of US imaging has been widened due to the development of injectable, compressible and encapsulated microbubbles (MBs) that provide an opportunity to improve conventional echocardiographic imaging, blood flow assessment and molecular imaging. The encapsulating material is manufactured by different biocompatible materials such as proteins, lipids or polymers. In current research, researchers modify the encapsulated shell with the help of advanced molecular chemistry techniques to load them with dyes (for fluorescent imaging), nanoparticles and radioisotopes (for multimodal imaging) or functional ligands or therapeutic gases (for local drug delivery). The echogenicity and the radial oscillation of MBs is the result of their compressibility, which undoubtedly varies with the encapsulated shell characteristics such as rigidity or elasticity. In this thesis, we present acoustic properties of novel type of polyvinyl alcohol (PVA)-shelled microbubble (PVA-MB) that was further modified with superparamagnetic iron oxide nanoparticles (SPIONs) to work as a dual-modal contrast agent for magnetic resonance (MR) imaging along with US imaging. Apparently, the shell modification changes their mechanical characteristics, which affects their acoustic properties. The overall objective of the thesis is to investigate the acoustic properties of modified and unmodified PVA-MBs at different ultrasound parameters. The acoustic and mechanical characterization of SPIONs modified PVA-MBs revealed that the acoustical response depends on the SPION inclusion strategy. However they retain the same structural characteristics after the modification. The modified MBs with SPIONs included on the surface of the PVA shell exhibit a soft-shelled behavior and produce a higher echogenicity than the MBs with the SPIONs inside the PVA shell. The fracturing mechanism of the unmodified PVA-MBs was identified to be different from the other fracturing mechanisms of conventional MBs. With the interaction of high-pressure bursts, the air gas core is squeezed out through small punctures in the PVA shell. During the fracturing, the PVA-MBs exhibit asymmetric (other modes) oscillations, resulting in sub- and ultra-harmonic generation. Exploiting the US imaging at the other modes of the oscillation of the PVA-MBs would provide an opportunity to visualize very low concentrations of (down to single) PVA-MBs. We further introduced the PVA-MBs along with particles mimicking red blood cells in an acoustic standing-wave field to observe the acoustic radiation force effect. We observed that the compressible PVA-MBs drawn toward pressure antinode while the solid blood phantoms moved toward the pressure node. This acoustic separation method (acoustophoresis) could be an efficient tool for studying the bioclearance of the PVA-MBs in the body, either by collecting blood samples (in-vitro) or by using the extracorporeal medical procedure (ex-vivo) at different organs. Overall, this work contributes significant feedback for chemists (to optimize the nanoparticle inclusion) and imaging groups (to develop new imaging sequences), and the positive findings pave new paths and provide triggers to engage in further research. / <p>QC 20150827</p> / 3MiCRON

Hydrate Ridge is a peanut shape bathymetric high located about 80 km west of Newport, Oregon on the Pacific continental margin, within the Cascadia subduction zone’s accretionary wedge. The ridge's two topographic highs (S. and N. Hydrate Ridge) are characterized by gas vents and seeps that were observed with previous ODP initiatives. In 2008, we acquired a 3D seismic reflection data set using the P-Cable acquisition system to characterize the subsurface fluid migration pathways that feed the seafloor vent at S. Hydrate Ridge. The new high-resolution data reveal a complex 3D structure of localized faulting within the gas hydrate stability zone (GHSZ). We interpret two groups of fault-related migration pathways. The first group is defined by regularly- and widely-spaced (100-150 m) faults that extend greater than 300ms TWT (~ 250 m) below seafloor and coincide with the regional thrust fault orientations of the Oregon margin. The deep extent of these faults makes them potential conduits for deeply sourced methane and may include thermogenic methane, which was found with shallow drilling during ODP Leg 204. As a fluid pathway these faults may complement the previously identified sand-rich, gas-filled stratigraphic horizon, Horizon A, which is a major gas migration pathway to the summit of S. Hydrate Ridge. The second group of faults is characterized by irregularly but closely spaced (~ 50 m), shallow fractures (extending < 160ms TWT below seafloor, ~ 115 m) found almost exclusively in the GHSZ directly beneath the seafloor vent at the summit of S. Hydrate Ridge. These faults form a closely-spaced network of fractures that provide multiple migration pathways for free gas entering the GHSZ to migrate vertically to the seafloor. We speculate that the faults are the product of hydraulic fracturing due to near-lithostatic gas pressures at the base of the GHSZ. These fractures may fill with hydrate and develop a lower permeability, which will lead to a buildup of gas pressures below the GHSZ. This may lead to a vertical propagation of new fractures to release the overpressure, which results in the high concentration of shallow fractures within the GHSZ seen in the 2008 data. / text

The thesis research examined localized socio-environmental perceptions related to amplified fresh water requirements for hydraulic fracturing and subsequent flowback disposal activities. These requirements are associated with increasing shale gas development in the Duvernay formation, located within the Kaybob region of West-central Alberta, Canada. Fresh water refers to surface and groundwater with a total dissolved solids concentration of less than 4,000 ppm. Through recourse to a mixed methods approach, combined with triangulation as a method of further validation, the research demonstrates that there exists a public sensitivity related to fresh water use in the Kaybob region. This sensitivity arises from increasing development activities in the Duvernay shale gas formation. The thesis presents conclusions and recommendations whereby industry may address stakeholder concerns, and provides advice for future research.