No description available.

Landfills are considered to be one of the major sources of anthropogenic methane (CH4) emissions in the environment. A landfill biocover system optimizes environmental conditions for biotic CH4 consumption that controls the fugitive and residual emissions from landfills. A compost material has more oxidation potential in comparison to any other material due to its high porosity, organic content, free flux for gases and water holding capacity. Thermal, hydraulic, bio – chemical and mechanical (THMCB) properties are important factors that can significantly affect the performance of biocover material with regards to CH4 oxidation potential as well as structural stability. Technical data on the thermal, hydraulic and mechanical (THM) properties of compost based biocover materials are quite limited. Hence, a detailed experimental program has been carried out at the University of Ottawa to study the THM properties and behaviour of compost biocover material by conducting experimental tests on small compost samples as well as by performing column experiments. The test results indicate that lower water content (dry of optimum for compaction curve) shows more free air space (FAS) in comparison to higher water content. The compost has almost the same shear strength for various initial water contents and dry unit weights; however, it settles and swells more at higher water content than lower water content per mechanical test results. The thermal and hydraulic properties of compost are a function of the compaction degree in addition to various other parameters. It is also found that the THM properties of compost are strongly coupled and the degree of saturation greatly affects the FAS.

Landfills are considered to be one of the major sources of anthropogenic methane (CH4) emissions in the environment. A landfill biocover system optimizes environmental conditions for biotic CH4 consumption that controls the fugitive and residual emissions from landfills. A compost material has more oxidation potential in comparison to any other material due to its high porosity, organic content, free flux for gases and water holding capacity. Thermal, hydraulic, bio – chemical and mechanical (THMCB) properties are important factors that can significantly affect the performance of biocover material with regards to CH4 oxidation potential as well as structural stability. Technical data on the thermal, hydraulic and mechanical (THM) properties of compost based biocover materials are quite limited. Hence, a detailed experimental program has been carried out at the University of Ottawa to study the THM properties and behaviour of compost biocover material by conducting experimental tests on small compost samples as well as by performing column experiments. The test results indicate that lower water content (dry of optimum for compaction curve) shows more free air space (FAS) in comparison to higher water content. The compost has almost the same shear strength for various initial water contents and dry unit weights; however, it settles and swells more at higher water content than lower water content per mechanical test results. The thermal and hydraulic properties of compost are a function of the compaction degree in addition to various other parameters. It is also found that the THM properties of compost are strongly coupled and the degree of saturation greatly affects the FAS.

Landfills are considered to be one of the major sources of anthropogenic methane (CH4) emissions in the environment. A landfill biocover system optimizes environmental conditions for biotic CH4 consumption that controls the fugitive and residual emissions from landfills. A compost material has more oxidation potential in comparison to any other material due to its high porosity, organic content, free flux for gases and water holding capacity. Thermal, hydraulic, bio – chemical and mechanical (THMCB) properties are important factors that can significantly affect the performance of biocover material with regards to CH4 oxidation potential as well as structural stability. Technical data on the thermal, hydraulic and mechanical (THM) properties of compost based biocover materials are quite limited. Hence, a detailed experimental program has been carried out at the University of Ottawa to study the THM properties and behaviour of compost biocover material by conducting experimental tests on small compost samples as well as by performing column experiments. The test results indicate that lower water content (dry of optimum for compaction curve) shows more free air space (FAS) in comparison to higher water content. The compost has almost the same shear strength for various initial water contents and dry unit weights; however, it settles and swells more at higher water content than lower water content per mechanical test results. The thermal and hydraulic properties of compost are a function of the compaction degree in addition to various other parameters. It is also found that the THM properties of compost are strongly coupled and the degree of saturation greatly affects the FAS.

Landfills are considered to be one of the major sources of anthropogenic methane (CH4) emissions in the environment. A landfill biocover system optimizes environmental conditions for biotic CH4 consumption that controls the fugitive and residual emissions from landfills. A compost material has more oxidation potential in comparison to any other material due to its high porosity, organic content, free flux for gases and water holding capacity. Thermal, hydraulic, bio – chemical and mechanical (THMCB) properties are important factors that can significantly affect the performance of biocover material with regards to CH4 oxidation potential as well as structural stability. Technical data on the thermal, hydraulic and mechanical (THM) properties of compost based biocover materials are quite limited. Hence, a detailed experimental program has been carried out at the University of Ottawa to study the THM properties and behaviour of compost biocover material by conducting experimental tests on small compost samples as well as by performing column experiments. The test results indicate that lower water content (dry of optimum for compaction curve) shows more free air space (FAS) in comparison to higher water content. The compost has almost the same shear strength for various initial water contents and dry unit weights; however, it settles and swells more at higher water content than lower water content per mechanical test results. The thermal and hydraulic properties of compost are a function of the compaction degree in addition to various other parameters. It is also found that the THM properties of compost are strongly coupled and the degree of saturation greatly affects the FAS.

The development of ideas on deinstitutionalization of mental patients has a much longer history in the United States than is commonly acknowledged. Evidence of intense discussion on the rights of the mentally disturbed, curative as opposed to control measures in their treatment, and the drawbacks of congregating the afflicted in large institutions can be found as early as the middle of the 19th century. This discussion was provoked by dissemination of knowledge about the oldest community care program of all: the colony of mental patients in Gheel, Belgium. Based on document analysis of publications in the American Journal of Insanity from 1844 to 1921, this study attempts to trace how this discussion resulted in the first wave of deinstitutionalization in the American mental health care system, and the successful implementation of the alternative of hospital treatment. My study further documents how the development of this program was inhibited by the need of psychiatry to attain professional legitimation. In its struggle to acquire public respect and occupational authority, the profession focused on somatic explanations of disease that could justify categorization of psychiatry as a branch of medical science. While this claim was not decisively supported by laboratory findings, or the ability to cure patients, psychiatry put forward genetic explanations of mental disorder. This took the profession to the extreme of the eugenics movement, and eventually positioned it as an institution of social control instead of medical authority. Having thus failed to achieve the ultimate professional legitimation in the medical field, psychiatry was exposed to a new wave of criticism in the 1960s, which led to the second wave of deinstitutionalization. History repeated itself with the same outcome. In the absence of overall support within psychiatric circles, and a lack of appreciation of family care as a viable alternative to hospital treatment among social scientists, deinstitutionalization could not but fail again. The contribution of the study lies in the areas of deinstitutionalization, professionalization of expert labor, and the social construction of mental illness and deviance.

Neste trabalho foi estabelecido um sistema padrão primário para raios X de energias baixas (10 kV a 50 kV), utilizando uma câmara de ionização de ar livre de cilindros concêntricos da marca Victoreen (modelo 481-5) no Laboratório de Calibração de Instrumentos (LCI) do Instituto de Pesquisas Energéticas e Nucleares (IPEN/CNEN-SP). Para isso foi desenvolvido um novo protocolo de alinhamento da câmara de ionização no sistema de radiação e foi feita uma modificação no suporte dos micrômetros utilizados para o movimento dos cilindros internos. Os resultados obtidos nos testes de estabilidade e de caracterização ficaram dentro dos limites estabelecidos pelas normas IEC 61674 e IEC 60731. Foram determinados também os fatores de correção para atenuação de fótons no ar, transmissão e espalhamento no diafragma, espalhamento e fluorescência, e recombinação iônica. Esses valores foram comparados com os valores obtidos pelo laboratório padrão primário alemão,Physikalisch-Technische Bundesanstalt (PTB), mostrando boa concordância. Por último, foi determinado o valor absoluto da grandeza taxa de kerma no ar para as qualidades padronizadas de mamografia de feixes diretos WMV28 e WMV35 e feixes atenuados WMH28 e WMH35; os resultados são compatíveis, com diferença máxima de 3,8% com os valores obtidos utilizando o sistema padrão secundário do LCI. / In this work a primary standard system was established for low energy X-rays (10 kV to 50 kV), using a free air ionization chamber with concentric cylinders, Victoreen (Model 481-5), at the Calibration Laboratory of Instruments (LCI) of the Instituto de Pesquisas Energéticas e Nucleares (IPEN/CNEN-SP). For this, a new ionization chamber alignment protocol was developed for the radiation system and a modification on the micrometer housing used for the movement of the internal cylinders was made. The results obtained for the stability and characterization tests showed to be within the limits established by the standards IEC 61674 and IEC 60731. The correction factors for photon attenuation in the air, transmission and scattering in the diaphragm, scattering and fluorescence and ion recombination were also determined. These values were compared with those obtained by the German primary standard laboratory, Physikalisch-Technische Bundesanstalt (PTB), showing good agreement. Finally, the absolute values of the quantity air kerma rate for the standard qualities direct beams MWV28 and WMV35 and the attenuated beams WMH28 and WMH35 were determined; the results are in agreement, with a maximum difference of 3,8% with the values obtained using the secondary standard system of LCI.

Neste trabalho foi estabelecido um sistema padrão primário para raios X de energias baixas (10 kV a 50 kV), utilizando uma câmara de ionização de ar livre de cilindros concêntricos da marca Victoreen (modelo 481-5) no Laboratório de Calibração de Instrumentos (LCI) do Instituto de Pesquisas Energéticas e Nucleares (IPEN/CNEN-SP). Para isso foi desenvolvido um novo protocolo de alinhamento da câmara de ionização no sistema de radiação e foi feita uma modificação no suporte dos micrômetros utilizados para o movimento dos cilindros internos. Os resultados obtidos nos testes de estabilidade e de caracterização ficaram dentro dos limites estabelecidos pelas normas IEC 61674 e IEC 60731. Foram determinados também os fatores de correção para atenuação de fótons no ar, transmissão e espalhamento no diafragma, espalhamento e fluorescência, e recombinação iônica. Esses valores foram comparados com os valores obtidos pelo laboratório padrão primário alemão,Physikalisch-Technische Bundesanstalt (PTB), mostrando boa concordância. Por último, foi determinado o valor absoluto da grandeza taxa de kerma no ar para as qualidades padronizadas de mamografia de feixes diretos WMV28 e WMV35 e feixes atenuados WMH28 e WMH35; os resultados são compatíveis, com diferença máxima de 3,8% com os valores obtidos utilizando o sistema padrão secundário do LCI. / In this work a primary standard system was established for low energy X-rays (10 kV to 50 kV), using a free air ionization chamber with concentric cylinders, Victoreen (Model 481-5), at the Calibration Laboratory of Instruments (LCI) of the Instituto de Pesquisas Energéticas e Nucleares (IPEN/CNEN-SP). For this, a new ionization chamber alignment protocol was developed for the radiation system and a modification on the micrometer housing used for the movement of the internal cylinders was made. The results obtained for the stability and characterization tests showed to be within the limits established by the standards IEC 61674 and IEC 60731. The correction factors for photon attenuation in the air, transmission and scattering in the diaphragm, scattering and fluorescence and ion recombination were also determined. These values were compared with those obtained by the German primary standard laboratory, Physikalisch-Technische Bundesanstalt (PTB), showing good agreement. Finally, the absolute values of the quantity air kerma rate for the standard qualities direct beams MWV28 and WMV35 and the attenuated beams WMH28 and WMH35 were determined; the results are in agreement, with a maximum difference of 3,8% with the values obtained using the secondary standard system of LCI.

Thermosonic ball bonding is the most popular method used to create electrical interconnects between integrated circuits (ICs) and substrates in the microelectronics industry. Traditionally gold (Au) wire is used, however with industry demands for lower costs and higher performance, novel wire materials are being considered. Some of these wire materials include Cu, insulated, and coated wires. The most promising of which being Cu wire. Some of the main issues with these wire materials is their performance in the electrical flame off (EFO) step of the wire bonding process. In the EFO step a ball called the free air ball (FAB) is formed on the end of the wire. The quality of the FAB is essential for reliable and strong ball bonds. In Cu wire bonding the hardness of the FAB and oxidation are the main issues. A hard FAB requires larger bonding forces and US levels to make the bond which increases the likelihood of damage to the IC. Excessive oxidation acts as a contaminant at the bond interface and can also influence the shape of the FAB. Shielding gases are required to reduce oxidation and improve FAB quality. This thesis focuses on the EFO process and the influence of EFO parameters and shielding gases on Au and Cu FABs. The primary focus of this thesis is to provide a better understanding of the EFO process in order to expedite the introduction of novel wire materials into industry. Several different experiments are performed on an automated thermosonic wire bonder with 25 µm Au and Cu wires to investigate the EFO process during ball bonding. The effects of EFO parameters on the hardness and work hardening of FABs and the effects of shielding gas type and flow rates on the quality of the FABs are determined. The EFO discharge characteristics in different shielding gases is also studied to better understand how the composition of the atmosphere the FAB is formed in influences the energy input via the EFO electrical discharge. Using the online deformability method and Vickers microhardness testing it is found that the EFO current (IEFO) and EFO time (tEFO) have a large influence on the hardness and work hardening of Au and Cu FABs. A harder FAB produced with a large IEFO and low tEFO will work harden less during deformation. The bonded ball will be softer than that of a FAB produced with a lower IEFO and higher tEFO. The online deformability method is found to be twice as precise as the Vickers microhardness test. An online method for characterizing the quality of FABs is developed and used to identify shielding gas flow rates that produce defective FABs. The EFO process for an Au wire and two Cu wire materials is investigated in flow rates of 0.2-1.0 l/min of forming gas (5 % H2 + 95 % N2) and N2 gas. All three of the most common FAB defects are identified with this online method. It is found that good quality FABs cannot be produced above flow rates of 0.7 l/min and that H2 in the shielding gas adds a thermal component to the EFO process. It is recommended that the gas flow rate be optimized for each new wire type used. The EFO discharge power is measured to be 12 % higher in a N2 gas atmosphere than in a forming gas atmosphere. The lower ionization potential of the forming gas leads to a higher degree of ionization and therefore lower resistance across the discharge gap. It was found that the discharge power does not determine the energy transferred to the wire anode because the Au FAB produced in forming gas has a 6 % larger diameter than that of the FABs produced in N2 gas. Other factors that effect the voltage of the EFO discharge include the controlled EFO current, the discharge gap, and the wire anode material.

Thermosonic ball bonding is the most popular method used to create electrical interconnects between integrated circuits (ICs) and substrates in the microelectronics industry. Traditionally gold (Au) wire is used, however with industry demands for lower costs and higher performance, novel wire materials are being considered. Some of these wire materials include Cu, insulated, and coated wires. The most promising of which being Cu wire. Some of the main issues with these wire materials is their performance in the electrical flame off (EFO) step of the wire bonding process. In the EFO step a ball called the free air ball (FAB) is formed on the end of the wire. The quality of the FAB is essential for reliable and strong ball bonds. In Cu wire bonding the hardness of the FAB and oxidation are the main issues. A hard FAB requires larger bonding forces and US levels to make the bond which increases the likelihood of damage to the IC. Excessive oxidation acts as a contaminant at the bond interface and can also influence the shape of the FAB. Shielding gases are required to reduce oxidation and improve FAB quality. This thesis focuses on the EFO process and the influence of EFO parameters and shielding gases on Au and Cu FABs. The primary focus of this thesis is to provide a better understanding of the EFO process in order to expedite the introduction of novel wire materials into industry. Several different experiments are performed on an automated thermosonic wire bonder with 25 µm Au and Cu wires to investigate the EFO process during ball bonding. The effects of EFO parameters on the hardness and work hardening of FABs and the effects of shielding gas type and flow rates on the quality of the FABs are determined. The EFO discharge characteristics in different shielding gases is also studied to better understand how the composition of the atmosphere the FAB is formed in influences the energy input via the EFO electrical discharge. Using the online deformability method and Vickers microhardness testing it is found that the EFO current (IEFO) and EFO time (tEFO) have a large influence on the hardness and work hardening of Au and Cu FABs. A harder FAB produced with a large IEFO and low tEFO will work harden less during deformation. The bonded ball will be softer than that of a FAB produced with a lower IEFO and higher tEFO. The online deformability method is found to be twice as precise as the Vickers microhardness test. An online method for characterizing the quality of FABs is developed and used to identify shielding gas flow rates that produce defective FABs. The EFO process for an Au wire and two Cu wire materials is investigated in flow rates of 0.2-1.0 l/min of forming gas (5 % H2 + 95 % N2) and N2 gas. All three of the most common FAB defects are identified with this online method. It is found that good quality FABs cannot be produced above flow rates of 0.7 l/min and that H2 in the shielding gas adds a thermal component to the EFO process. It is recommended that the gas flow rate be optimized for each new wire type used. The EFO discharge power is measured to be 12 % higher in a N2 gas atmosphere than in a forming gas atmosphere. The lower ionization potential of the forming gas leads to a higher degree of ionization and therefore lower resistance across the discharge gap. It was found that the discharge power does not determine the energy transferred to the wire anode because the Au FAB produced in forming gas has a 6 % larger diameter than that of the FABs produced in N2 gas. Other factors that effect the voltage of the EFO discharge include the controlled EFO current, the discharge gap, and the wire anode material.