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River networks act as a link between components of the terrestrial landscape, such as soils and groundwater, with the atmosphere and oceans, and are now believed to contribute significantly to global budgets of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O). The idea of rivers being an inert conduit for carbon and nitrogen to reach the coast has been challenged recently, with considerable processing of carbon and nitrogen occurring in both the water column and bed sediments in the various aquatic components that make up a river network, including lakes, streams, rivers and estuaries. Although understanding of the cycling of carbon and nitrogen has improved markedly in the last 20 years, there is still much uncertainty regarding the production and emission of greenhouse gases (GHGs) linked to this processing across river catchments and few studies have quantified GHG fluxes from source to sea. Therefore this study aimed to a) understand the spatial and temporal saturations and fluxes of GHGs from both the freshwater River Tay catchment (Scotland) and the River Tay estuary, and b) understand what controls the production of GHGs within both a freshwater lake and across multiple sites in the freshwater river using laboratory incubations of sediment. Hotspots of in-stream production and emission were evident both in the freshwater catchment and the estuary, with significant temporal and spatial variability in saturation and emission (density) for CH4, CO2 and N2O. CH4 emission densities, across the freshwater river sites, ranged from 1720 to 15500 μg C m-2 d-1 with a freshwater catchment wide mean of 4640 μg C m-2 d-1, and in general decreased from upland to lowland sites along the main river stem, with notable peaks of emission in a lowland tributary and at the outflow of a lowland loch. This corresponds well with the main drivers of spatial variability which include allochthonous inputs from gas rich soil waters and in-situ production in fine grained organic rich sediments. CH4 production was observed to be higher in the lowland tributaries (R. Isla 4500 μg C m-2 d- 1) compared to main-stem river sites both in the lowland river (129 μg C m-2 d-1) and upland river which displayed an uptake of CH4 (-1210 μg C m-2 d-1). The main driver of spatial variability in CH4 production rates was the quality of the sediment, as production was higher in fine grained sediments rich in carbon compared to sand and gravels with a low carbon content. CH4 production also varied seasonally, with temperature and seasonal variation in sediment quality as the predominant driving factors. CO2 emission densities across the freshwater catchment ranged from 517 to 2550 mg C m-2 d-1 with a catchment mean flux density of 1500 mg C m-2 d-1. Flux densities on the whole increased along the main river stem from upland sites to lowland sites, with higher fluxes in lowland tributaries. Seasonally, CO2 flux density was highest in late summer and autumn and lowest in winter at most sites, highlighting the importance in seasonal environmental controls such as temperature, light, and substrate availability. Production rates in the sediment increased from upland to lowland sites with highest production rates evident in the lowland tributaries, and in autumn sediment samples. N2O emission density also showed considerable spatial and seasonal variation across the catchment with flux densities ranging from 176 to 1850 μg N m-2 d-1 with a mean flux of 780 μg N m-2 d-1. Mean fluxes were highest in the lowland tributaries and lowest in the upland river with sediment experiments finding similar spatial variation in N2O production. On the whole, in-stream N2O production and emission across the freshwater catchment was driven by increases in nutrient concentration (NO3 -, NH4 +) which in turn was related to the proportion of agricultural landuse. The saturation and emission of GHGs also varied substantially both spatially and temporally in the River Tay estuary, with a mean emission density of 2790 μg CH4-C m-2 d-1, 990 mg CO2-C m-2 d-1 and 162 μg N2O-N m-2 d-1. The spatial variability of GHG concentrations and emission densities in the estuary were predominantly controlled by the balance between lateral inputs (from tidal flushing of surrounding intertidal areas), in-situ microbial production/consumption (both in the water column and bed sediments) and physical mixing/loss processes. Although emission densities of CH4, CO2 and N2O appear low compared to the freshwater river, this is because the estuary is emitting large quantities of gas in the middle and outer estuary, for example net annual emission of N2O increased from 84.7 kg N2O-N yr-1 in the upper freshwater section of the estuary to 888 kg N2O-N yr-1 in the middle estuary section, then decreased to 309 kg N2O-N yr-1 in the saltwater lower estuary. Overall, this study has shown that both dissolved and aerial fluxes of GHGs vary markedly both spatially and temporal from source to sea in a temperate river catchment, with hotspots of in-stream production and emission across the river catchment. The catchment (river, lake and estuary) was a smaller source of CO2, CH4 and N2O emission (total emission and by area) compared to other highly polluted aquatic systems both in the UK and globally.

In recent decades the knowledge of nitrous oxide (N2O) emissions after the application of nitrogen (N) fertilizers in agriculture soil has improved. However the understanding of emissions of N2O from Canadian organic agricultural systems has not been developed. The Glenlea Long Term Crop Rotation is the longest running organic conventional comparison study in western Canada and was used here to compare N2O emissions between the systems. In organic cropping systems forage legumes such as alfalfa are incorporated into the soil as an N source. The amount of N2O that is emitted after the incorporation and during the subsequent crop is not well known. The wheat and legume phases (alfalfa (Medicago sativa) in organic system and soybean (Glycine max L.) in the conventional) of the rotation were monitored for N2O. In 2014, 2015, and spring 2016 (data still being analysed) emissions of N2O were monitored using the vented static chambers method as well, soil conditions (temperature, moisture, inorganic N and extractable carbon) and yields were measured. Typical N2O emissions from spring applied urea were observed after application in the conventional system however no emission episode was seen after the fall alfalfa plough down or during spring thaw in the organic system. Greater NO3- accumulation was observed in the organic treatments however low emissions were observed. The organic system resulted in lower yields for both years, but still resulted in lower emissions per amount of grain produced (yield-scaled emissions) than the conventional system. This study adds to the knowledge that N2O emissions from organic systems do differ from conventional however yields need to be improve to fully exploit the benefits. / February 2017

Nitrous oxide (N2O) is a potent greenhouse gas (GHG) which is released naturally into the atmosphere as a by-product of the microbial processes of nitrification and denitrification. Agricultural activities are believed to account for up to 80% of anthropogenic N2O emissions at a global scale; however, these estimates are prone to large uncertainties due to the large temporal and spatial variability associated with flux measurements. This thesis contains five studies which aimed to improve the ability to measure and predict N2O emissions from agricultural activities. A closed loop dynamic chamber was developed using a quantum cascade laser (QCL). This method provided high precision chamber measurements of N2O flux from soils with a detection limit below 4 μg N2O-N m-2 h-1. Using the dynamic chamber method allowed for a detailed investigation of uncertainties in individual measurements including contributions from regression fitting, temperature and pressure. The lack of negative fluxes measured that were outwith the detection limits of the methodology (0.3% of all measurements) highlighted that the uptake of N2O reported in some previous literature is likely to have been the result of detection limits of measurement methods applied. Spatial variability of N2O flux was investigated at the plot, field and farm scale. Fluxes were measured from a grassland field plot before and after a tillage event. These measurements highlighted the large spatially variability present in N2O fluxes from agricultural soils. Fluxes varied by up to three orders of magnitude over distances less than 5 metres after the tillage event. A field scale experiment carried out on grazed grassland investigated relationships between soil properties and N2O flux. This study found that N2O emissions correlated strongly with available nitrogen content in the soil and that animal waste was likely responsible for the spatial variability of N2O flux observed at the field scale. A farm scale inventory of N2O emissions was carried out investigating several large point sources of N2O and emissions from the wider field coverage. The inventory estimates that nitrogen fertiliser application is the single largest N2O source from the livestock farm accounting for 49% of annual emissions.

Ongoing conversion of forests in Sumatra to agricultural lands might affect the biodiversity of soil fauna, such as termites, and emissions of nitrous oxide (N2O), methane (CH4) and carbon dioxide (CO2). To assess the impact of such forest conversions, this study was conducted in Jambi, Sumatra in an undisturbed forest (FR), a disturbed forest (DF), a one year old rubber plantation (RB1), a twenty year old rubber plantation (RB20) and an oil palm plantation (OP). The plantations belonged to smallholders and were not usually fertilized. The effect of fertilizer was assessed by applying N fertilizer and taking a series of intensive measurements. The N2O, CH4 and CO2 fluxes were measured using static chamber methods and termite species richness was assessed using a standard semi quantitative transect method. Forest conversion to smallholder plantations did not significantly affect the N2O, CH4 and CO2 fluxes, but the diversity and relative abundance of termites was decreased. this implies that the ecosystem services regulated by termites might decline. The application of N fertilizer at the conventional rate (141 kg N ha-1 y-1), with an emission factor of 3.1 % in the oil palm plantation, increased N2O emissions to twice as high as that in the undisturbed forest. The annual N2O and CH4 fluxes from termites amounted to 0.14, 0.21, 0.88, 2.47 and -0.56 kg ha-1 y-1 N2O-N and 0.85, 1.65, 3.80, 0.97 and 2.30 kg ha-1 y-1 CH4-C in the FR, DF, RB1, RB20 and OP, respectively. Further research is needed to understand the interannual variability of the N2O, CH4 and CO2 fluxes from soils and termites. Understanding the key drivers and underlying processes which regulate them would help to control the biodiversity loss and the change of N2O, CH4 and CO2 fluxes from soils and termites.

One strategy to manage pig slurry is centrifugation and composting of the solids fraction to produce a value added product to distribute manure nutrients further from productions sites. This study determined turned windrow composting was suitable for processing slurry solids throughout winter. It was also the first attempt at combining automated chambers and a Fourier Transform Infrared spectroscopy analyzer to measure multiple gases during the composting process; the system proved capable but captured fluxes better if conducted in an area sheltered from wind. Straw and woodshavings were shown suitable as bulking materials for composting slurry solids, however, the lack of porosity provided by woodshavings created anaerobic conditions that doubled the greenhouse gas emissions compared to those of straw, 1,126 kg CO2-equivalent Mg-1 compared to 526 kg CO2-equivalent Mg-1. Either bulking material produced compost of quality for use in agricultural or soil blending applications and was free of manure pathogens. / May 2016

O objetivo geral deste trabalho foi avaliar o efeito de diferentes alturas de ambientes protegidos e de diferentes níveis de sombreamento no cultivo de bromélias das espécies Aechmea fasciata e Guzmania lingulata. O experimento foi conduzido no período de 03 de abril de 2001 a 3 de abril de 2002, em dois ambientes protegidos, instalados, no sentido leste -oeste, na área experimental do Núcleo de Pesquisa em Ambiência (NUPEA), junto ao Departamento de Engenharia Rural, da Escola Superior de Agricultura "Luiz de Queiroz", Universidade de São Paulo, em Piracicaba, SP. Ambos os ambientes protegidos possuíam dimensões de 6,4m de largura por 17,5m de comprimento, com alturas diferenciadas, de 3,0m e de 3,5m. Esses ambientes possuíam cobertura plástica de polietileno de baixa densidade (PEBD), com 150m de espessura. A avaliação dos níveis de sombreamento aplicados às plantas no interior dos ambientes foi viabilizada pelo uso de telas de polipropileno de cor preta que proporcionaram sombreamentos de 18, 40, 60 e 80%. As mudas utilizadas no experimento foram obtidas através de micropropagação, e transplantadas para os vasos plásticos com uma idade aproximada de 90 dias em condições ex vitro. Avalio-se nos ambientes protegidos com diferentes alturas, a temperatura do ar, a umidade relativa, a temperatura de globo negro, a carga térmica radiante e a intensidade luminosa. Essa avaliação foi realizada pela leitura direta nos seguintes instrumentos: psicrômetros, termômetro de globo negro, anemômetro e luxímetro digital. Foram ainda realizadas coletas de dados de temperatura do ar, de umidade relativa e de radiação solar global, através de uma estação meteorológica automática. O desenvolvimento das plantas, sob os diferentes níveis de sombreamento e as diferentes alturas dos ambientes, foi avaliado através do número de folhas, da altura das plantas, da largura das folhas e do diâmetro da roseta. Nas condições em que foi conduzido o experimento, concluiu-se que não houve diferença significativa nos ambientes com diferentes alturas, quando relacionou-se a umidade relativa do ar, a temperatura do ar, a temperatura de globo negro, a carga térmica de radiação, a luminosidade e a radiação solar global. A A. fasciata, submetida aos vários níveis de sombreamento, mostrou um melhor desenvolvimento sob as telas de 40%, enquanto que para G. lingulata as telas de 60 e 80% de sombreamento proporcionaram desenvolvimento semelhante das plantas. / The objective of this research was to evaluate the effect of different greenhouses heights and levels of shading on the growth of Aechmea fasciata and Guzmania lingulata (Bromeliaceae). The experiment was done from march 26'th of 2001 to april third of 2002, in two greenhouses, built in east-west orientation, at the experimental area of Nucleos of Environment Research - NUPEA, Rural Engineering Department, "Luiz de Queiroz" College of Agriculture, University of São Paulo, Piracicaba, Brazil. Greenhouses measured: 6.4m in width, 17.5m in length and heights of 3.0m and 3.5m. They were covered with 150m thick low density polyethylene (PEBD). Black polypropylene cloth providing shading of 18%, 40%, 60%, and 80% was used. The plants used in the experiment were obtained through micropropagation and transplanted to plastic pots at approximately 90 days after ex vitro culture. The air temperature, the relative humidity, the black globe temperature, the radiant thermal load, and light intensity were evaluated inside the greenhouses. These evaluations were carried out through the direct reading from the following instruments: psycrometers, black globe thermometer, anemometer and digital luximeter. Air temperature, relative humidity and global solar radiation were also obtained through sensors connected to an automatic meteorological station. The development of the plants under different levels of shading and different heights was evaluated according to the number of leaves, height of plants, width of leaves, and the diameter of the rosette. Under the conditions used for the experiment, it can be concluded that the 3.5m high greenhouse showed lower air relative humidity when compared to the 3.0m high greenhouse. Plants of A. fasciata growing under different levels of shading had a better development under 40% cloths, while G. lingulata showed a more vigorous grouth under 60% and 80% of shading.