published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

The South China Craton comprises the Yangtze Block in the northwest and Cathaysia Block in the southeast. Located in the southeastern Yangtze Block, the Jiangnan Orogen formed through the amalgamation between the Yangtze and Cathaysia Blocks. The Yangtze Block has sporadically exposed Archean rocks in the north, Paleoproterozoic to Mesoproterozoic volcano-sedimentary sequences in the southwest and widespread Neoproterozoic sedimentary sequences accompanied by syn-sedimentary igneous rocks on the western and southeastern margins. The late Paleoproterozoic to early Mesoproterozoic Dongchuan, Dahongshan and Hekou groups in the southwestern Yangtze Block formed in a series of fault-controlled, rift-related basins associated with the fragmentation of the supercontinent Columbia. These sedimentary sequences were deposited between 1742 and 1503 Ma, and recorded continuous deposition from alluvial fan and fluvial sedimentation during the initial rifting to deep marine sedimentation in a passive margin setting. Sedimentation during initial rifting received felsic detritus mainly from adjacent continents, whereas sedimentation in a passive margin basin received detritus from felsic to intermediate rocks of the Yangtze Block. Paleoproterozoic to Mesoproterozoic rift basins in the southwestern Yangtze Block are remarkably similar to those of north Australia and northwestern Laurentia in their lower part (1742-1600 Ma), but significantly different after ca. 1600 Ma. The southwestern Yangtze Block was likely connected with the north Australia and northwestern Laurentia in Columbia but drifted away from these continents after ca. 1600 Ma. Traditionally thought Mesoproterozoic sedimentary sequences in the southeastern Yangtze Block are now confirmed to be Neoproterozoic in age and include the 835-830 Ma Sibao, Fanjingshan and Lengjiaxi groups, and 831-815 Ma Shuangqiaoshan and Xikou groups. These sequences are unconformably overlain by the ~810-730 Ma Danzhou, Xiajiang, Banxi, Heshangzheng, Luokedong and Likou groups. The regional unconformity likely marked the amalgamation between the Yangtze and Cathaysia Blocks and thus occurred at ~815-810 Ma. The lower sequences (835-815 Ma) received dominant Neoproterozoic (~980-820) felsic to intermediate materials in an active tectonic setting related to continental arc and orogenic collision, whereas the upper sequences represent sedimentation in an extensional setting with input of dominant Neoproterozoic granitic to dioritic materials (~740-900 Ma). The upper parts of the Shuangqiaoshan and Xikou groups, uncomfortably underlain by lower units, are molasse-type assemblages with additional input of pre-Neoproterozoic detritus, representing accumulation of sediments in a retro-arc foreland basin associated with the formation of the Jiangnan Orogen. Stratigraphic correlation, similarly low-δ18O and tectonic affinity of igneous rocks from different continents suggest that the Yangtze Block should be placed in the periphery of Rodinia probably adjacent to northern India. Paleoproterozoic (~2480 Ma and ~2000 Ma) and Early Neoproterozoic (711-997 Ma) were the most important periods of crustal and magmatic events of the southeastern Yangtze Block, but there is a lack of significant Grenvillian magmatism. Early Neoproterozoic magmatism highlights the contribution from both juvenile materials and pre-existing old crust, whereas ~2480 Ma and ~2000 Ma events are marked by reworking of pre-existing continental crust. Magmatism at 1600-1900 Ma was dominated by reworking of pre-existing crust, whereas the 1400-1600 Ma magmatic event recorded some addition of juvenile materials. / published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

Thesis (MSc)--Stellenbosch University, 2005. / ENGLISH ABSTRACT: The northeast-trending south Central Zone (sCZ) of the Pan-African Damara belt in central Namibia is structurally characterized by kilometer-scale, northeast-trending dome structures developed in Neoproterozoic rocks of the Damara Sequence. A number of different structural models have been proposed for the formation of these domes in the literature. This study describes the structural geology of the Usakos dome. The study discusses the structural evolution of the dome within the regional framework of the cSZ that represents the high-grade metamorphic axis of the Damara Belt, characterized by voluminous Pan-African granitoids. The northeastern part of the Usakos dome is developed as an upright- to northwestverging anticlinorium containing a steep southeasterly-dipping axial planar foliation. The northeast fold trend persists into the southwestern parts of the Usakos dome. However, this southwestern core of the dome is inundated by synkinematic granitic sheets. Distinct marker horizons of the Damara Sequence outcrop as screens within the granite, preserving a ghost stratigraphy. These screens illustrate the position and orientation of second-order folds. Significantly, most of the stratigraphy of the Damara Sequence is overturned in these folds. For example, some second-order anticlines developed in the northeastern parts of the Usakos dome can be followed along their axial traces into the southwestern hinge of the dome, where they appear as synformal anticlines, i.e. synformal structures cored by older strata, plunging towards the northeast. The inverted stratigraphy and northeasterly fold plunges suggest the northeast-trending folds are refolded by second-generation, northwest-trending folds, thus, forming kilometer-scale Type-2 interference folds. The resulting fold geometries are strongly non-cylindrical, approaching southwest-closing sheath folds indicating a top-to-the-southwest material transport. Lower-order folds in this overturned domain show radial fold plunges, plunging away from the centre of the dome core, as well as a shallowly-dipping schistosity. The close spatial and temporal relationship between granite intrusion and the formation of the southwest-vergent, sheath-type folds, radial distribution of fold plunges and the subhorizontal foliation confined to the southwestern hinge of the Usakos dome are interpreted to signify the rheological weakening and ensuing collapse of the developing first-order Usakos dome immediately above the synkinematic granite intrusions. Orogenparallel, southwest-vergent sheath folds and top-to-the southwest extrusion of the southwestern parts of the Usakos dome and northwest-vergent folding and thrusting characterizing the northeastern extent of the Usakos dome are both responses to the northwest-southeast- directed contractional tectonics recorded during the main collisional phase in the Damara belt. On a regional scale, the Usakos dome represents the link between the foreland-vergent northeastern part of the sCZ and the southwest-vergent, high-grade southwestern parts of the sCZ. The results of this study illustrate how dramatic variations in structural styles may be caused by the localized and transient rheological weakening of the crust during plutonic activity. / AFRIKAANSE OPSOMMING: Die noordoos-strekkende, suidelike Sentrale Sone (sSS) van die Pan-Afrikaanse Damara gordel in sentraal Namibië word karakteriseer deur kilometer-skaal, noordoosstrekkende koepel strukture, ontwikkel in die Neoproterozoïkum gesteentes van die Damara Opeenvolging. 'n Aantal verskillende struktuur modelle is voorgestel in die literatuur vir die vorming van hierdie koepels. Hierdie ondersoek beskryf die struktuur geologie van die Usakos koepel. Die ondersoek bespreek die strukturele ontwikkeling van die koepel in die regionale konteks van die sSS, wat die hoë graadse metamorfe magmatiese as van die Damara Gordel verteenwoordig, en karakteriseer word deur omvangryke Pan-Afrikaanse granitoïede. Die noordoostelike gedeelte van die Usakos koepel is ontwikkel as 'n antiklinorium met 'n vertikale- tot noordwestelike kantelrigting. wat 'n steil hellende, suidoostelike asvlak planêre foliasie bevat. Die noordoos-strekkende plooiing kom voor tot in die suidwestelike kern van die Usakos wat ingedring is deur sinkinematiese granitiese plate. Die posisie en oriëntasie van tweede-orde plooie is afgebeeld in die graniete deur 'n skimstratigrafie wat preserveer is deur duidelike merker horisonne van die Damara Opeenvolging. Die stratigrafie van die Damara Opeenvolging is opmerklik meestal omgekeer in hierdie plooie. Byvoorbeeld, tweede-orde antikliene ontwikkel in die noordoostelike gedeelte van die Usakos koepel kan gevolg word langs hul asvlakspore tot in die suidwestelike skarnier van die koepel, waar dit voorkom as sinforme antikliene, d.w.s. sinforme strukture met ouer strata in die kern wat na die noordooste duik. Die omgekeerde stratigrafie en noordoostelike plooi duiking impliseer dat die noordoosstrekkende plooie weer geplooi is deur tweede-generasie, noordwes-strekkende plooie, wat dus aanleiding gegee het tot die vorming van kilometer-skaal, tipe-2 interferensie plooie. Die gevolglike plooi geometrieë is uitdruklik nie-silindries, en toon 'n oorgang na skede plooie met 'n sluiting na die suidweste, wat dui op 'n bokant-na-die-suidweste materiaal vervoer. Laer-orde plooie in die omgekeerde domein vertoon radiale duiking van die plooie, weg van die middelpunt van die koepel kern, sowel as 'n vlak hellende skistositeit. Die noue ruimtelike en temporele verwantskap tussen graniet intrusie en die vorming van skede-tipe plooie met 'n kantelrigting na die suidweste, die radiale verspreiding van plooi duiking, en die subhorisontale foliasie wat beperk is tot die suidwestelike skarnier van die Usakos koepel, word interpreteer as 'n aanduiding van die reologiese verswakking en die gevolglike ineenstorting van die ontwikkelende eerste-orde Usakos koepel, onmiddellik aan die bokant van die sinkinematiese graniet intrusies. Die orogeenparalleie skede plooie met kantelrigting na die suidweste en bokant-na-die-suidweste ekstrusie van die suidwestelike gedeelte van die Usakos koepel, en plooiing met kantelrigting na die noordweste en stootverskuiwing wat kenmerkend is van die noordoostelike gedeelte van die Usakos koepel, is beide 'n reaksie op die noordwessuidoos- gerigte vernouings tektoniek opgeteken gedurende die hoof botsings fase in die Damara gordel. Op 'n regionale skaal verteenwoordig die Usakos koepel die verbinding tussen die noordoostelike gedeelte van die sSS met 'n voorland kantelrigting. en die hoë graad suidwestelike gedeelte van die sSS met 'n kantelrigting na die suidweste. Die resultate van hierdie ondersoek toon aan hoe dramatiese variasies in struktuur style veroorsaak kan word deur die gelokaliseerde en kortstondige reologiese verswakking van die kors gedurende plutoniese aktiwiteit.

published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

A dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Master of Science. Johannesburg, 2017. / Massif-type anorthosites formed in the Proterozoic Eon are the most voluminous anorthosite occurrences on Earth, reaching tens of thousands of square kilometers in aerial extent. While they formed throughout the Proterozoic, most formed during a 700 Ma period between 1800 and 1100 Ma. The rocks are dominated by plagioclase (typically 70 – 95 volume %) of intermediate composition (An40-65). Olivine, orthopyroxene, clinopyroxene and Fe-Ti oxides make up the minor mafic proportion. While most researchers agree that the anorthosites formed from a high-alumina basaltic parental magma, there are disparate views on how that parental magma was generated. Whether the parental magma formed by partial melting of the lower crust, or by mantle melting, is a topic of much debate. The anorthosites commonly have crust-like isotopic signatures, but this could be produced by melting of the lower crust, or by crustal contamination of mantle-derived magmas. Many Proterozoic anorthosite complexes consist of both olivine-bearing and orthopyroxene-bearing anorthosites. This has been attributed to variable amounts of crustal contamination of mantle-derived magmas, based on evidence from isotopes and field relations. While geochemical and petrologic evidence for crustal contamination is plentiful, existing experimental work shows that a thermal divide exists for high-alumina basalts fractionating at lower crustal depths, casting doubts on whether fractionation of a mantle melt could produce anorthosite. Here I use high-pressure experiments to test whether the fractionation of high-alumina basalt can form anorthosites, and to what extent crustal contamination affects the fractionation sequence. The results are compared to new geochemical and petrologic data from the Kunene Anorthosite Complex (KAC), in Angola and Namibia. The KAC is one of the largest anorthosite complexes in the world, with an area of ~18 000 km2. The KAC (1438 – 1319 Ma) has an elongate shape and intruded into Palaeoproterozoic to Mesoproterozoic country rocks (~2200 to 1635 Ma) at the southern margin of the Congo craton. It is associated with a suite of granitoid rocks of variable composition, which are akin to the granitoids associated with nearly all Proterozoic anorthosites. The granitoids have been shown to be coeval with the anorthosites, but were from a chemically independent magma series. The most distinctive granitoids in the KAC are the Red Granites, which outcrop around the southern margins of the complex, and also cross-cut the complex in a NE-SW linear belt, dividing the complex roughly into northern and southern domains. The rocks of the KAC are highly variable in terms of mode, mineral chemistry, and texture, but there is a general trend of more olivine-bearing anorthosites north of the granite belt, and orthopyroxene-bearing anorthosites to the south. The olivine-bearing rocks (or leucotroctolites) typically contain plagioclase and cumulus and/or intercumulus olivine, with lesser interstitial orthopyroxene and/or clinopyroxene, Fe-Ti oxides, and biotite. The orthopyroxene-bearing anorthosites (or leuconorites) contain cumulus plagioclase ± cumulus orthopyroxene, and interstitial orthopyroxene, clinopyroxene, oxides and biotite. The leucotroctolites are characterized by more calcic plagioclase (An56-75), while the leuconorites contain more intermediate plagioclase (An48-56). The variability of the rocks across the complex suggests that the KAC consists of several coalesced plutons with different histories. The petrologic data and field observations in this study are consistent with the leuconorites of the complex being derived from a mantle-derived magma that experienced contamination by silica-rich rocks, crystallizing orthopyroxene rather than olivine, and less calcic plagioclase. The leucotroctolites experienced less or no contamination. To test whether the mineral dichotomy and the variations in plagioclase chemistry observed in Proterozoic anorthosites are due to variably contaminated mantle-derived magma, piston cylinder experiments were conducted on a synthetic high-alumina basalt (HAB) composition, as well as a mixture of this HAB with 30% of a Red Granite composition. Experiments were conducted at 10 kbar, to simulate the depth at which anorthosite differentiation most likely begins (based on Al-in-orthopyroxene geobarometry of highly aluminous orthopyroxene megacrysts that occur in many massifs). The uncontaminated experiments produced olivine as the first liquidus phase, followed by plagioclase (An65-68), and then by clinopyroxene, pigeonite and ilmenite at progressively lower temperatures. Residual liquids evolve towards more silica-rich compositions with decreasing temperature. The contamination experiments produced liquidus orthopyroxene, followed by plagioclase (An51-56), and then by pigeonite at lower temperatures. The experiments show that contamination of a primitive HAB magma by granitic material, most likely produced by partial melting of the lower crust during anorthosite formation, can shift the mineral assemblages of the crystallizing anorthosite from olivinebearing to orthopyroxene-bearing, and produce less calcic plagioclase than the uncontaminated HAB magma. This could explain the observation of olivine-bearing and orthopyroxene-bearing anorthosites in the KAC and many other Proterozoic anorthosites. Previous high-pressure experimental studies, using a slightly more evolved HAB composition, indicated the presence of a thermal divide, which causes liquids to evolve to more Si-poor compositions. The experimental results presented in this study however, do not show a thermal divide, indicating that small variations in experimental starting composition can cause large differences in the liquid line of descent. The results of this study indicate that partial melting of the mantle can produce anorthosite parental magmas, and that the range in mineral assemblages of the anorthosites can be accounted for by crustal contamination of a mantle-derived magma. Fractionation of the experimental starting compositions was also modeled using the MELTS algorithm. These calculations produce a close match to the experimental liquid trends. This allows for modeling of a variety of compositional and environmental variables. The MELTS modeling shows that as little as 10% contamination of HAB magma with a granitic composition may position the magma in the orthopyroxene stability field, forming orthopyroxene-bearing anorthosites. The modeling also shows that a variety of silica-rich contaminants, including granites, granodiorites and tonalities, produce similar results and liquid evolution trends, so a range of granitoid compositions may successfully produce the shift in mineral assemblages of the anorthosites. This suggests that crustal contamination of mantle-derived HAB could be a widespread process and the primary mechanism that produces the distinctive crust-like signatures in Proterozoic anorthosites. In summary, the mineralogical and chemical diversity observed in Proterozoic anorthosites can be produced by variable amounts of crustal contamination of mantle-derived, highalumina basaltic magma. The experimental results in this study combined with field observations, and geochemical and isotopic data, provide evidence for a model of massif-type anorthosite petrogenesis. Orthopyroxene-bearing rocks formed from an originally highalumina basaltic magma that experienced contamination by granitic partial melts of the lower crust, during ponding of the magma at the Moho. This process preconditioned the surrounding crust and possibly prevented further anatexis. Following emplacement of orthopyroxene-bearing anorthosites, subsequent magma pulses ponded at the Moho did not assimilate any/as much granitic material, as they were interacting with preconditioned crust, and formed olivine-bearing anorthosites. With better constraints on the parental magma composition, magma source, and crustal contamination processes, addressing aspects such as the tectonic setting and emplacement mechanisms of these massive intrusions should be prioritized. Understanding these enigmatic aspects of anorthosite petrogenesis is leading the anorthosite community towards answering the ultimate questions of why massif-type anorthosites are restricted to the Proterozoic. / XL2018

Many aspects of Proterozoic massif-type anorthosite petrogenesis have been, and remain, controversial. Mafic lower crust and depleted mantle have both been proposed as mutually exclusive sources of these near-monomineralic, temporally restricted batholiths. The debate surrounding the magma source has also led to uncertainty regarding the tectonic setting of these massifs, with a range of possibilities including convergent, divergent and anorogenic settings. The dramatic geochemical effects of crustal contamination in these massifs are well known and strong crustal signatures are evident in most, if not all, Proterozoic anorthosite massifs. The source debate, in the simplest sense, reduces to whether the ubiquitous crustal signature is derived principally from melting of a lower crust or is an effect of crustal assimilation. The origin of this crustal signature, and whether it obscures the original isotopic composition of the magmas or not, has fuelled the debate surrounding the source of the anorthosites. Using major element, trace element and isotopic compositions, as well as energyconstrained assimilation-fractional-crystallisation (EC-AFC) modelling from samples representing various stages of the polybaric crystallisation history of the magmas, including high-pressure megacrysts, anorthosites and their internal mineral phases, I remove the obfuscating effects of possible crustal contamination and probe the source of the magmas. In order to assess the effects of crustal contamination, if any, anorthosites from three massifs – the Mealy Mountains Intrusive Suite, Nain Plutonic Suite (both in eastern Canada) and Rogaland Anorthosite Province (Norway), have been analysed – all of which intrude into crust of significantly different age and chemical character. Sm-Nd geochronology of high-Al, high-pressure orthopyroxene megacrysts, as well as the comagmatic, host anorthosites, indicate that the magmatic system is long-lived, with an age difference between the megacrysts and hosts of ~110-130 million years. Isotopic compositions of primitive megacrysts qualitatively show that the magmas were derived from melting of the depleted mantle. Strong links between the isotopic offset from depleted mantle evolution and the age and composition of the surrounding crust confirm that the geochemical nature of the crustal contaminant plays a significant role in the petrogenesis of the anorthositic rocks. The geochronological indications of a long-lived magmatic system point to Proterozoic anorthosite formation in a continental magmatic arc – one of the only environments capable of supplying geographically-localised magma and heat to the base of the crust for over 100 million years. Proposed divergent or ‘anorogenic’ settings could not plausibly supply magma to the base of the crust for over 100 m.y. without initiating ocean formation or continental break-up. Anorthosite emplacement at mid-crustal levels may coincide with late- to post-orogenic events in several terranes, but evidence presented for a long-lived magmatic system is incongruent with this proposed setting. In this thesis, I propose that the petrogenesis of these intrusives must span both orogenic and post-orogenic periods. An overlap in megacryst crystallisation age with the onset of calc-alkaline orogenic magmatism in the Sveconorwegian Orogen, both occuring ~100 m.y. before anorthosite emplacement, confirms that initial magma and megacryst formation coincides with the main phase of magmatic and orogenic activity in a convergent magmatic arc. These geochronological constraints have implications for regional geodynamics in the Sveconorwegian Orogen (and the Labrador region) with the evidence providing corroboratory support for a long-lived accretionary orogen, as opposed to the widely-held view that the Sveconorwegian orogeny was predominantly collisional. Compositions of high-pressure megacrysts, anorthosites and analysis of internal isotopic disequilibrium indicates that lower crustal contamination has a significant influence on the isotopic composition of the rocks, with relatively minor contributions from the mid- to upper crust. Energy-constrained AFC modelling confirms that significant lower crustal contamination occurs during ponding of magmas at the Moho and is able to reproduce the observed isochronous isotopic compositions of the megacrysts as well as the compositions of the host anorthosites. Evidence of varying degrees of internal isotopic disequilibrium reinforces the significant role that assimilation of crust of different age and chemical nature have on the compositions of Proterozoic anorthosites. Unexpected patterns of isotopic disequilibrium show that anorthosite petrogenesis is not a “simple” case of progressive crustal contamination during polybaric ascent of viscous, partially-molten 4 magma mushes, but is more likely to involve significant differentiation and solidification at lower crust depths, followed by ascent of high-crystallinity bodies (> 50 % crystallinity) to upper crustal levels. Although the composition of the bulk continental crust is different to plagioclase-rich Proterozoic anorthosites, both are missing a mafic component. It is unclear how this missing mafic component was generated in the continental crust, because most of the evidence for these crustal differentiation processes is sequestered below or near the Moho. However, Proterozoic anorthosites, formed by viscous, plagioclase-rich mushes, entrain rare cumulate megacrysts from these depths and consequently preserve evidence of magmatic differentiation processes at the Moho. The evidence for the formation and sequestration of dense ultramafic cumulates in ponding magmas at the Moho can not only explain the missing mafic component in Proterozoic anorthosites, but also suggests that cumulate formation in crust-forming, arc environments is a significant process and should be taken into account in models dealing with evolution and differentiation of the continental crust. Sampling and petrographic and geochemical analysis of five pegmatitic segregations, or “pods”, from anorthosites of the Mealy Mountains Intrusive Suite reveal a diverse range of compositions from mafic, Fe-rich and Si-poor, to Fe-poor and Sirich felsic compositions and from monzogranite through quartz-monzodiorite and monzodiorite to Fe-P-rich gabbronorite. Each pod shows a range of noteworthy graphic, myrmekitic and symplectic textures on a variety of scales, along with distinctive mineralogical assemblages and highly-enriched trace element compositions. Derivitive minerals (e.g. apatite and zircon), high concentrations of Fe, Ti, P (and in some cases SiO2) and 10-1000 times chondrite enrichment suggest that many of the pods are highly fractionated. U-Pb zircon geochronology reveals that all the pods are the same age as the anorthositic hosts and confirms that the Mealy Mountains Intrusive Suite was emplaced between 1654 and 1628 Ma. Using the aforementioned evidence, I show that the pods represent the fluid-bearing, late-stage crystallisation products of a residual liquid in the massif anorthosite system and provide a window into the final stages of crystallisation in the anorthosite system. A range of rock types (monzonites, monzonorites, ferrodiorites and jotunites) observed in similar pod-like structures, as well as dykes and plutons, have also been documented in other Proterozoic anorthosite massifs. These have, at one time or another, controversially been interpreted as the residual liquids of anorthosite crystallisation. The observation of in-situ pods with similar compositions to all of the aforementioned rock types and displaying textures indicative of late-stage crystallisation support the notion that these associated lithologic units are comagmatic with, but residual to, the anorthosites and are not residual liquids of other crustally-derived rocks, immiscible liquids, parental magmas or cumulates. Isotopic compositions of these highly-fractionated, late-stage pods also overlap with those of anorthosites, lending further evidence to the case that upper crustal contamination plays only a minor role in developing the chemical signature of the anorthosites. With these results I propose that the nature/composition of the residual liquids of Proterozoic anorthosite magmas can vary dramatically, depending on geochemical differences in the original magma pulses and by mixing of mobilised, independently-evolved segregations of residual liquids. This process could explain why so many varied rock types associated with Proterozoic anorthosites have been suggested as residual liquids: these rocks all represent residual liquids resulting from varying degrees of differentiation, subsequent mobilisation, mixing and final solidification as plutons or dykes. Proterozoic anorthosite petrogenesis is an inherently polybaric process and so by its very nature produces a range of complicated and contradictory features which have clouded interpretation of numerous aspects of the rocks formation. In analysing crystallisation products from numerous stages of the anorthosites polybaric history, I have been able to probe the magmatic processes operating at different stages of Proterozoic anorthosite petrogenesis. In doing so I show that the magmas are derived from melting of the depleted mantle in continental-arc-like settings – two controversial aspects of Proterozoic anorthosite petrogenesis. These constraints on the source and tectonic setting will allow renewed investigation into the ultimate question surrounding Proterozoic anorthosites: why are these rock types restricted to the Proterozoic and what clues does this temporal restriction offer about Earth’s geodynamic evolution during this period? The assertion in this thesis that 5 Proterozoic anorthosites formed in arc environments dictates that subduction processes or geodynamic conditions during the Proterozoic favoured the production of voluminous masses of plagioclase, because modern-day magmatic arc terranes show no evidence of anorthosites with similar compositions. However, calcic anorthositic inclusions and xenoliths are observed in modern-day volcanic and continental arcs suggesting that anorthosites may be forming in these environments, but that conditions such as water content or style of subduction are different to the Proterozoic, producing less and compositionally different plagioclase and anorthosite. The results of this thesis shed new light on and refine the petrogenesis of Proterozoic anorthosites, but the focus of research must now shift to explaining the temporal restriction of these intrusions and the implications of this restriction for the geodynamic evolution on Earth during the Proterozoic.

Includes one folded map in pocket in back cover. / Includes bibliographical references. / iv, 214, [46] leaves, [10] leaves of plates : ill. (some col.), col. maps ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--University of Adelaide, Dept. of Geology and Geophysics, 1994

published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

Ogilvie Mountains breccia (OMB) is in Early (?) to Late Proterozoic rocks of the Coal Creek Inlier, southern Ogilvie Mountains, Yukon Territory. Host rocks are the Wernecke Supergroup (Fairchild Lake, Quartet and Gillespie Lake groups) and lower Fifteenmile group. Distribution and cross-cutting relationships of the breccia were delineated by regional mapping. OMB was classified by clast type and matrix composition. Ogilvie Mountains breccia crops out discontinuously along two east-trending belts called the Northern Breccia Belt (NBB) and the Southern Breccia Belt (SBB). The NBB extends across approximately 40 km of the map area, and the SBB is about 15 km long. Individual bodies of OMB vary from dyke- and sill-like to pod-like. The breccia belts each coincide with a regional structure. The NBB coincides with a north side down reverse fault—an inferred ruptured anticline—called the Monster fault. The SBB coincides with a north side down fault called the Fifteenmile fault. These faults, at least in part, guided ascending breccia. The age of OMB is constrained by field relationships and galena lead isotope data. It is younger than the Gillespie Lake Group, and is at least as old as the lower Fifteenmile group because it intrudes both of these units. A galena lead isotope model age for the Hart River stratiform massive sulphide deposit that is in Gillespie Lake Group rocks is 1.45 Ga. Galena from veinlets cutting a dyke that cuts OMB in lower Fifteenmile group rocks is 0.90 Ga in age. Therefore the age of OMB formation is between 1.45 and 0.90 Ga. Ogilvie Mountains breccia (OMB) has been classified into monolithic (oligomictic) and heterolithic (polymictic) lithologies. These have been further divided by major matrix components—end members are carbonate-rich, hematite-rich and chlorite-rich. Monolithic breccias with carbonate matrices dominate the NBB. Heterolithic breccias are abundant locally in the NBB, but are prevalent in the SBB. Fragments were derived mainly from the Wernecke Supergroup. In the SBB fragments from the lower Fifteenmile group are present. Uncommon mafic igneous fragments were from local dykes. OMB are generally fragment dominated. Recognized fragments are up to several 10s of metres across and grade into matrix sized grains. Hydrothermal alteration has locally overprinted OMB and introduced silica, hematite and sulphide minerals. This mineralization has received limited attention from the mineral exploration industry. Rare earth element chemistry reflects a lack of mantle or deep-seated igneous process in the formation of OMB. However, this may be only an apparent lack because flooding by a large volume of sedimentary material could obscure a REE pattern indicative of another source. The genesis of OMB is significantly similar to modern mud diapirs. It is proposed that OMB originated from pressurized, underconsolidated fine grained limey sediments (Fairchild Lake Group). These were trapped below and loaded by turbidites (Quartet Group) and younger units. Tectonics and the initiation of major faults apparently triggered movement of the pressurized fluid-rich medium. The resulting bodies of breccia are sill-like and diapir-like sedimentary intrusions. Fluid-rich phases may have caused hydrofracturing (brittle failure) of the surrounding rocks (especially in the hanging wall). Breccia intrusion would have increased the width of the passage way while encorporating more fragments. Iron- and oxygen-rich hydrothermal fluids apparently were associated with the diapirism. Presumably these fluids are responsible for the high contents of hematite and iron carbonate in fragments, and especially, in the matrix of the breccias. Exhalation of these fluids may have formed the sedimentary iron formations that are spatially associated with the breccias. / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate

The Mesoproterozoic rocks of the Bysteek and Koenap Formations of the Arribees Group are exposed within a NW-SE striking antiformal structure comprised of mafic granulites and metapelitic diatexites, and a number of marble and calc-silicate rock layers. The mafic granulites of the Bysteek Formation show a typological variety of anatectic features, including nebulitic, stromatitic mesosomes, melanosomes, quartz syenitic leucocratic vein networks and syenitic pools. Melanosomes consist of hedenbergitic to diopside-rich clinopyroxene (XMg: 0.40), anorthitic plagioclase (An90), with some quartz, minor apatite and titanite. Anatexis was caused by biotite dehydration melting and formed a melt of probably granitic composition. The leucosome composition ranges from either alkali-feldspar-granitic to plagioclase rich or granitic. This variation is interpreted as a result of variable extraction of melt from the source to granitic pools. The diatexites of the Koenap Formation are most likely of metapelitic or meta-greywacke origin. They are texturally variable but always contain high modal contents of alkali feldspar and quartz which generally form magmatic textures. Almandine-rich garnet (XMg: 0.18-0.25), cordierite (XMg: 0.71) form secondary biotite, sillimanite and magnetite during retrograde breakdown. Thermodynamic modelling of mafic granulite compositions suggests peak P-T conditions of ~865 °C and 8.6 kbar. Occasionally, garnet rich in ferric iron (XAdr: 0.55) forms by plagioclase-clinopyroxene breakdown under oxidising conditions at ~6 kilobar and ~ 800 °C. At the same stage amphibole forms in some melanosomes. P-T estimations for the diatexites based on thermodynamic modelling suggest the equilibration of the assemblage garnet, cordierite, alkali feldspar and melt at ~860 °C and 5.5 kbar. Conditions comparable to the peak pressure in the mafic granulites could not be established. However, since the diatexites and the mafic granulites are closely related in the field and no evidence of juxtaposition after the thermal peak exists, the P-T record of the diatexites might be incomplete