The importance of the Musgrave Province in continental reconstructions of Proterozoic Australia is only beginning to be appreciated. The Mesoproterozoic Musgrave Province sits in a geographically central location within Australia and is bounded by older and more isotopically evolved regions including the Gawler Craton of South Australia and Arunta Region of the Northern Territory. Understanding the crustal growth and deformation mechanisms involved in the formation of the Musgrave Province, and also the nature of the basement that separates these tectonic elements, allows for greater insight into defining the timing and processes responsible for the amalgamation of Proterozoic Australia. The ca. 1.60-1.54 Ga Musgravian Gneiss preserves geochemical and isotopic signatures related to ongoing arc-magmatism in an active margin between the North Australian and South Australian Cratons (NAC and SAC). Characteristic geochemical patterns of the Musgravian Gneiss include negative anomalies in Nb, Ti, and Y, and are accompanied by steep LREE patterns. Also characteristic of the Musgravian Gneiss is its juvenile Nd isotopic composition (ɛNd1.55 values from -1.2 to +0.9). The juvenile isotopic signature of the Musgravian Gneiss separates it from the bounding comparitively isotopically evolved terranes of the Arunta Region and Gawler Craton. The geochemical and isotopic signatures of these early Mesoproterozoic felsic rocks have similarities with island arc systems involving residual Ti-bearing minerals and garnet. Circa 1.40 Ga metasedimentary rocks of the eastern Musgrave Province also record vital evidence for determining Australia.s location and fit within a global plate reconstruction context during the late Mesoproterozoic. U-Pb detrital zircon and Sm-Nd isotopic data from these metasedimentary rocks suggests a component of derivation from sources outside of the presently exposed Australian crust. Best fit matches come from rocks originating from eastern Laurentia. Detrital zircon ages range from Palaeoproterozoic to late Mesoproterozoic, constraining the maximum depositional age of the metasediments to approximately 1.40 Ga, similar to that of the Belt Supergroup in western Laurentia. The 1.49-1.36 Ga detrital zircons in the Musgrave metasediments are interpreted to have been derived from the voluminous A-type suites of Laurentia, as this time period represents a “magmatic gap” in Australia, with an extreme paucity of sources this age recognized. The metasedimentary rocks exhibit a range of Nd isotopic signatures, with ɛNd(1.4 Ga) values ranging from -5.1 to 0.9, inconsistent with complete derivation from Australian sources, which are more isotopically evolved. The isotopically juvenile ca. 1.60-1.54 Ga Musgravian Gneiss is also an excellent candidate for the source of the abundant ca. 1.6-1.54 Ga detrital zircons within the lower sequences of the Belt Supergroup. If these interpretations are correct, they support a palaeogeographic reconstruction involving proximity of Australia and Laurentia during the pre-Rodinia Mesoproterozoic. This also increases the prospectivity of the eastern Musgrave Province to host a metamorphised equivalent of the massive Pb-Zn-Ag Sullivan deposit. The geochemical and isotopic signatures recorded in mafic-ultramafic rocks can divulge important information regarding the state of the sub continental lithospheric mantle (SCLM). The voluminous cumulate mafic-ultramafic rocks of the ca. 1.08 Ga Giles Complex record geochemical and Nd-Sr isotopic compositions consistent with an enriched parental magma. Traverses across three layered intrusions, the Kalka, Ewarara, and Gosse Pile were geochemically and isotopically analysed. Whole rock samples display variably depleted to enriched LREE patterns when normalised to chondrite ((La/Sm)N = 0.43-4.72). Clinopyroxene separates display similar depleted to enriched LREE patterns ((La/Sm)N = 0.37-7.33) relative to a chondritic source. The cumulate rocks display isotopically evolved signatures (ɛNd ~-1.0 to .5.0 and ɛSr ~19.0 to 85.0). Using simple bulk mixing and AFC equations, the Nd-Sr data of the more radiogenic samples can be modelled by addition of ~10% average Musgrave crust to a primitive picritic source, without need for an enriched mantle signature. Shallow decompressional melting of an asthenospheric plume source beneath thinned Musgravian lithosphere is envisaged as a source for the parental picritic magma. A model involving early crustal contamination within feeder zones is favoured, and consequently explorers looking for Ni-Cu-Co sulphides should concentrate on locating these feeder zones. Few absolute age constraints exist for the timing of the intracratonic Petermann Orogeny of the Musgrave Province. The Petermann Orogeny is responsible for much of the lithospheric architecture we see today within the Musgrave Province, uplifting and exhuming large parts along crustal scale E-W trending fault/shear systems. Isotopic and geochemical analysis of a suite of stratigraphic units within the Neoproterozoic to Cambrian Officer Basin to the immediate south indicate the development of a foreland architecture at ca. 600 Ma. An excursion in ɛNd values towards increasingly less negative values at this time is interpreted as representing a large influx of Musgrave derived sediments. Understanding the nature of the basement separating the SAC from the NAC and WAC is vital in constructing models of the amalgamation of Proterozoic Australia. This region is poorly understood as it is overlain by the thick sedimentary cover of the Officer Basin. However, the Coompana Block is one place where basement is shallow enough to be intersected in drillcore. The previously geochronologically, geochemically, and isotopically uncharacterised granitic gneiss of the Coompana Block represents an important period of within-plate magmatism during a time of relative magmatic quiescence in the Australian Proterozoic. U-Pb LA-ICPMS dating of magmatic zircons provides an age of ca. 1.50 Ga, interpreted as the crystallisation age of the granite protolith. The samples have distinctive A-type chemistry characterised by high contents of Zr, Nb, Y, Ga, LREE with low Mg#, Sr, CaO and HREE. ɛNd values are high with respect to surrounding exposed crust of the Musgrave Province and Gawler Craton, and range from +1.2 to +3.3 at 1.5 Ga. The tectonic environment into which the granite was emplaced is also unclear, however one possibility is emplacement within an extensional environment represented by interlayered basalts and arenaceous sediments of the Coompana Block. Regardless, the granitic gneiss intersected in Mallabie 1 represents magmatic activity during the “Australian magmatic gap” of ca. 1.52-1.35 Ga, and is a possible source for detrital ca. 1.50 zircons found within sedimentary rocks of Tasmania and Antarctica, and metasedimentary rocks of the eastern Musgrave Province. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1261003 / Thesis(PhD)-- University of Adelaide, School of Earth and Environmental Sciences, 2006

The importance of the Musgrave Province in continental reconstructions of Proterozoic Australia is only beginning to be appreciated. The Mesoproterozoic Musgrave Province sits in a geographically central location within Australia and is bounded by older and more isotopically evolved regions including the Gawler Craton of South Australia and Arunta Region of the Northern Territory. Understanding the crustal growth and deformation mechanisms involved in the formation of the Musgrave Province, and also the nature of the basement that separates these tectonic elements, allows for greater insight into defining the timing and processes responsible for the amalgamation of Proterozoic Australia. The ca. 1.60-1.54 Ga Musgravian Gneiss preserves geochemical and isotopic signatures related to ongoing arc-magmatism in an active margin between the North Australian and South Australian Cratons (NAC and SAC). Characteristic geochemical patterns of the Musgravian Gneiss include negative anomalies in Nb, Ti, and Y, and are accompanied by steep LREE patterns. Also characteristic of the Musgravian Gneiss is its juvenile Nd isotopic composition (ɛNd1.55 values from -1.2 to +0.9). The juvenile isotopic signature of the Musgravian Gneiss separates it from the bounding comparitively isotopically evolved terranes of the Arunta Region and Gawler Craton. The geochemical and isotopic signatures of these early Mesoproterozoic felsic rocks have similarities with island arc systems involving residual Ti-bearing minerals and garnet. Circa 1.40 Ga metasedimentary rocks of the eastern Musgrave Province also record vital evidence for determining Australia.s location and fit within a global plate reconstruction context during the late Mesoproterozoic. U-Pb detrital zircon and Sm-Nd isotopic data from these metasedimentary rocks suggests a component of derivation from sources outside of the presently exposed Australian crust. Best fit matches come from rocks originating from eastern Laurentia. Detrital zircon ages range from Palaeoproterozoic to late Mesoproterozoic, constraining the maximum depositional age of the metasediments to approximately 1.40 Ga, similar to that of the Belt Supergroup in western Laurentia. The 1.49-1.36 Ga detrital zircons in the Musgrave metasediments are interpreted to have been derived from the voluminous A-type suites of Laurentia, as this time period represents a “magmatic gap” in Australia, with an extreme paucity of sources this age recognized. The metasedimentary rocks exhibit a range of Nd isotopic signatures, with ɛNd(1.4 Ga) values ranging from -5.1 to 0.9, inconsistent with complete derivation from Australian sources, which are more isotopically evolved. The isotopically juvenile ca. 1.60-1.54 Ga Musgravian Gneiss is also an excellent candidate for the source of the abundant ca. 1.6-1.54 Ga detrital zircons within the lower sequences of the Belt Supergroup. If these interpretations are correct, they support a palaeogeographic reconstruction involving proximity of Australia and Laurentia during the pre-Rodinia Mesoproterozoic. This also increases the prospectivity of the eastern Musgrave Province to host a metamorphised equivalent of the massive Pb-Zn-Ag Sullivan deposit. The geochemical and isotopic signatures recorded in mafic-ultramafic rocks can divulge important information regarding the state of the sub continental lithospheric mantle (SCLM). The voluminous cumulate mafic-ultramafic rocks of the ca. 1.08 Ga Giles Complex record geochemical and Nd-Sr isotopic compositions consistent with an enriched parental magma. Traverses across three layered intrusions, the Kalka, Ewarara, and Gosse Pile were geochemically and isotopically analysed. Whole rock samples display variably depleted to enriched LREE patterns when normalised to chondrite ((La/Sm)N = 0.43-4.72). Clinopyroxene separates display similar depleted to enriched LREE patterns ((La/Sm)N = 0.37-7.33) relative to a chondritic source. The cumulate rocks display isotopically evolved signatures (ɛNd ~-1.0 to .5.0 and ɛSr ~19.0 to 85.0). Using simple bulk mixing and AFC equations, the Nd-Sr data of the more radiogenic samples can be modelled by addition of ~10% average Musgrave crust to a primitive picritic source, without need for an enriched mantle signature. Shallow decompressional melting of an asthenospheric plume source beneath thinned Musgravian lithosphere is envisaged as a source for the parental picritic magma. A model involving early crustal contamination within feeder zones is favoured, and consequently explorers looking for Ni-Cu-Co sulphides should concentrate on locating these feeder zones. Few absolute age constraints exist for the timing of the intracratonic Petermann Orogeny of the Musgrave Province. The Petermann Orogeny is responsible for much of the lithospheric architecture we see today within the Musgrave Province, uplifting and exhuming large parts along crustal scale E-W trending fault/shear systems. Isotopic and geochemical analysis of a suite of stratigraphic units within the Neoproterozoic to Cambrian Officer Basin to the immediate south indicate the development of a foreland architecture at ca. 600 Ma. An excursion in ɛNd values towards increasingly less negative values at this time is interpreted as representing a large influx of Musgrave derived sediments. Understanding the nature of the basement separating the SAC from the NAC and WAC is vital in constructing models of the amalgamation of Proterozoic Australia. This region is poorly understood as it is overlain by the thick sedimentary cover of the Officer Basin. However, the Coompana Block is one place where basement is shallow enough to be intersected in drillcore. The previously geochronologically, geochemically, and isotopically uncharacterised granitic gneiss of the Coompana Block represents an important period of within-plate magmatism during a time of relative magmatic quiescence in the Australian Proterozoic. U-Pb LA-ICPMS dating of magmatic zircons provides an age of ca. 1.50 Ga, interpreted as the crystallisation age of the granite protolith. The samples have distinctive A-type chemistry characterised by high contents of Zr, Nb, Y, Ga, LREE with low Mg#, Sr, CaO and HREE. ɛNd values are high with respect to surrounding exposed crust of the Musgrave Province and Gawler Craton, and range from +1.2 to +3.3 at 1.5 Ga. The tectonic environment into which the granite was emplaced is also unclear, however one possibility is emplacement within an extensional environment represented by interlayered basalts and arenaceous sediments of the Coompana Block. Regardless, the granitic gneiss intersected in Mallabie 1 represents magmatic activity during the “Australian magmatic gap” of ca. 1.52-1.35 Ga, and is a possible source for detrital ca. 1.50 zircons found within sedimentary rocks of Tasmania and Antarctica, and metasedimentary rocks of the eastern Musgrave Province. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1261003 / Thesis(PhD)-- University of Adelaide, School of Earth and Environmental Sciences, 2006

Over the last two decades, gold occurrences in the Palaeoproterozoic Pine Creek Orogen (PCO) have been cited as type-examples of high-temperature contact-metamorphic or thermal-aureole deposits associated with granitoid magmatism. Furthermore, spatial relationships between these gold occurrences and the granitoids have led to inclusion of these deposits in the intrusion-related gold deposit group. Research on the characteristics, distribution and timing of these gold deposits tests these classifications and supports an alternative interpretation. The deposits display many similarities to well-described ‘turbidite-hosted’ orogenic gold deposits described from several Palaeozoic orogens. As in most ‘turbidite-hosted’ orogenic deposits, the gold mineralisation is dominantly epigenetic, sediment-hosted (typically greywacke and siltstone) and fold-controlled. Most gold is hosted by concordant or discordant veins, with limited alteration halos in host rocks, except where they occur in silicate-facies BIF or other Fe-rich rocks. The domal culminations of major doubly-plunging anticlines, and/or fold-limb thrust-faults, are important structural controls at the camp- and deposit-scales. Many deposits are sited in parts of the lithostratigraphy where there is significant competency and/or chemical contrast between units or sequences. In particular, the complex interdigitated stratigraphy of euxinic and transitional high-energy sedimentary rocks of the c.1900-1880Ma South Alligator Group is important for the localisation of gold deposits. The distribution of deposits is influenced further by the location and shape of granitoids and their associated contact-metamorphic aureole. Approximately 90% of gold deposits lie within the ∼2.5km wide contact-aureole, and most of these are concentrated in, and just beyond, the biotite-albite-epidote zone (0.5-1.0km from granitoid), with few deposits located in the inner hornblende-hornfels zone. At the deposit scale, gold is commonly associated with arsenopyrite-loellengite and pyrite, native-Bi and Bi-bearing minerals, and is confined to a variety of extensional quartz-sulphide ± carbonate veins. Such veins formed typically at 180-320°?C and ∼1kbar from low- to moderate salinity, two-phase aqueous fluids. Isotopic studies of the deposits are equivocal in terms of the source of hydrothermal fluid. Most δD and δ18O values fall within the range defined for contact-metamorphic and magmatic fluids, and sulphur isotopes indicate that the fluids are within the range of most regional sources. Significantly, lead isotope ratios show that the goldbearing fluid does not have a felsic magmatic-source signature, but instead suggest a homogenous regional-scale lead source. Excluding a few outliers, the relative uniformity of deposit characteristics, including host rocks, structural style, alteration, sulphide paragenesis and fluid P-T-X conditions, suggests that most deposits represent a continuum of broadly coeval mineralisation that formed under similar geological conditions

[Truncated abstract] Banded iron formations of the ~27702405 Ma Hamersley Province of Western Australia were locally upgraded to high-grade hematite ore during the Early Palaeoproterozoic by a combination of hypogene and supergene processes after the initial rise of atmospheric oxygen. Ore genesis was associated with the stratigraphic break between Lower and Upper Wyloo Groups of the Ashburton Province, and has been variously linked to the Ophthalmian orogeny, late-orogenic extensional collapse, and anorogenic continental extension. Small spot PbPb dating of in situ baddeleyite by SHRIMP (sensitive highresolution ion-microprobe) has resolved the ages of two key suites of mafic intrusions constraining for the first time the tectonic evolution of the Ashburton Province and the age and setting of iron-ore formation. Mafic sills dated at 2208 ± 10 Ma were folded during the Ophthalmian orogeny and then cut by the unconformity at the base of the Lower Wyloo Group. A mafic dyke swarm that intrudes the Lower Wyloo Group and has close genetic relationship to iron ore is 2008 ± 16 Ma, slightly younger than a new syneruptive 2031 ± 6 Ma zircon age for the Lower Wyloo Group. These new ages constrain the Ophthalmian orogeny to the period <2210 to >2030 Ma, before Lower Wyloo Group extension, sedimentation, and flood-basalt volcanism. The ~2010 Ma dykes present a new maximum age for iron-ore genesis and deposition of the Upper Wyloo Group, thereby linking ore genesis to a ~21002000 Ma period of continental extension similarly recorded by Palaeoproterozoic terrains worldwide well after the initial oxidation of the atmosphere at ~2320 Ma. The Lower Wyloo Group contains, in ascending order, the fluvial to shallow-marine Beasley River Quartzite, the predominantly subaqueously emplaced Cheela Springs flood basalt and the Wooly Dolomite, a shelf-ramp carbonate succession. Field observations point to high subsidence of the sequence, rather than the mainly subaerial to shallow marine depositional environment-interpretation described by earlier workers. Abundant hydro-volcanic breccias, including hyaloclastite, peperite and fluidal-clast breccia all indicate quench-fragmentation processes caused by interaction of lava with water, and support the mainly subaqueous emplacement of the flood basalt which is also indicated by interlayered BIF-like chert/mudstones and below-wave-base turbiditic mass-flows.

published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

[Truncated abstract] The realization in 1999 that the authigenic phosphate, xenotime, could be used in geochronological studies to place age constraints on burial events that affected sedimentary basins has opened numerous opportunities for establishing timeframes for sedimentary basin analysis. Since then, the mineral has been used to place new and novel age constraints on diagenesis, metamorphism, and hydrothermal alteration and mineralization events. Whilst these studies were successful, they identified many complexities in xenotime growth and were restricted to specific areas or single basins: they do not convey, demonstrate or explore the immense variety of geological applications in which xenotime may provide unique geochronological constraints. This thesis explores the nature of authigenic xenotime, utilizing studies in three different Proterozoic sedimentary basins: two in Australia, southwestern Australia and the Northern Territory, and the third in the United States of America. The thesis includes a number of discrete studies demonstrating different aspects of xenotime growth, elucidated from detailed petrography, geochronology and geochemistry of authigenic xenotime. An integrated textural, geochemical and geochronological study of authigenic xenotime from the Mt Barren Group, SW Australia, establishes an absolute timescale on some of the many processes involved during the diagenesis of siliciclastic units. ... positions and trends and broadly confirm the chemical discrimination criteria established for an Archaean basin. However, the Proterozoic data are shifted to lower Gd-Dy values and extend beyond the original field outlines, causing more overlap between fields intended to discriminate xenotimes of different origin. The plots were revised to encompass the new data. This study has significantly extended our knowledge of the nature of authigenic xenotime. It was found that xenotime may form in (meta)sediments in response to a large number of post-depositional processes, including early- and latediagenesis, (multiple) basinal hydrothermal events and low-grade metamorphism. A combination of detailed petrography and in situ geochronology provides the best avenue to decipher complex growth histories in xenotime. With further development, it is likely that xenotime geochemistry will also prove diagnostic of origin and can be incorporated into the interpretation of age data. The number of potential applications for xenotime geochronology has been expanded by this study.

Ce travail retrace l’évolution de la suture panafricaine le long de l’axe Anti-Atlas, Hoggar occidental, Gourma, depuis l’activité tectono-magmatique néoprotérozoïque pré-panafricaine jusqu’à l’activité magmatique anorogénique cénozoïque via l’étude de quatre massifs basiques-ultrabasiques disposés à la périphérie du craton ouest-africain.<p><p>Le massif d’Amalaoulaou (Gourma, Mali) est interprété comme la racine d’un arc intra-océanique ayant enregistré la mise en place de magmas basiques (unité des métagabbros) à un stade immature de l’évolution de l’arc (subduction naissante) vers 800-790 Ma. Les gabbros quartziques (~720 Ma) et les gabbros à hornblende de l’unité supérieure ont des signatures de magmas d’arc plus franche, témoins d’une source mantellique plus enrichie par l’apport de la plaque océanique plongeante. Les métagabbros sont ensuite affectés par une recristallisation et localement par une anatexie en conditions du faciès granulitique. De nombreuses veines leucocrates se développent à ce stade, ce sont principalement des anorthosites et des tonalites (mises en place vers 660 Ma) provenant de la fusion partielle des métagabbros (850°C-1000°C, P>10 kbar). Cette fusion génère également des résidus denses à grenat-clinopyroxène-rutile, associations fréquemment présentes dans les racines d’arcs plus récents et reflétant la maturation de l’arc. L’arc d’Amalaoulaou est ensuite exhumé et charrié sur le craton ouest-africain dans des conditions de basse température et moyenne pression (550°C, 6-9 kbar), probablement au même moment que l’exhumation des éclogites du Gourma (~620 Ma).<p><p>L ‘épisode de subduction océanique est suivi par la subduction continentale dans le Gourma et le Hoggar occidental. Les éclogites/amphibolites de Tiléouine et Tin Zebbane (Hoggar occidental) sont des métabasaltes tholéiitiques enrichis et alcalins intracontinentaux ayant plongé à 60 km de profondeur (600°C, 17 kbar) lors de la subduction d’une partie du terrane du Tassendjanet. Même si la nature géochimique du protolithe est encore reconnaissable, ces métabasaltes ont subi une différenciation chimique lors de la recristallisation à haute pression par interaction avec les fluides issus de la déshydratation des métasédiments. L’exhumation (615-600 Ma) se fait relativement lentement, ce qui induit un rééquilibrage thermique (750°C, ~10 kbar) avant l’exhumation à basse température (660 °C, 7-8 kbar) précédant de peu voire synchrone à la phase collisionnelle.<p><p>L’intrusion basique-ultrabasique de Tiléouine marque la fin de la collision panafricaine dans le Hoggar occidental (600-590 Ma). C’est une ancienne chambre magmatique différenciée, mise en place entre 10 et 20 km de profondeur, et montrant une évolution magmatique depuis des cumulats ultramafiques riches en olivine, spinelle et pyroxène vers des gabbros riches en plagioclase. Le magma parental est d’affinité tholéiitique enrichie et tire probablement sa source de la lithosphère sous-continentale. La mise en place de cette intrusion est contemporaine d’un contexte tectonique transtensif induisant un amincissement lithosphérique au niveau du Tassendjanet.<p><p>Cette suture péri-cratonique est réactivée au Cénozoïque, lors de la convergence Afrique-Europe, ce qui se marque par la mise en place de laves alcalines, notamment dans l'Est de l’Anti-Atlas marocain (Saghro :10-3 Ma). Les néphélinites du Saghro sont issues de faibles taux de fusion partielle d’une source mantellique contenant un composant HIMU et localisée à la limite asthénosphère/lithosphère (70-100 km sous l’Anti-Atlas). La cristallisation fractionnée de ces magmas génère des phonolites, par fractionnement de feldspath, néphéline, apatite et sphène, principalement. L’étape finale de différenciation se marque par la formation de phases peu communes comme la hainite et la lorenzenite. Ces magmas se sont mis en place à la faveur de fentes de tension et de fractures ouvertes ayant la même orientation que la contrainte principale au Mio-Pliocène.<p> / Doctorat en Sciences / info:eu-repo/semantics/nonPublished

The subject of BIF genesis, particularly their environmental conditions and ocean chemistry at the time of deposition and their evolution through time, has been a subject of much contentiousness, generating a wealth of proposed genetic models and constant refinements thereof over the years. The prevailing paradigm within the various schools of thought, is the widespread and generally agreed upon depositional and diagenetic model(s) which advocate for BIF deposition under anoxic marine conditions. According to the prevailing models, the primary depositional environment would have involved a seawater column whereby soluble Fe²⁺ expelled by hydrothermal activity mixed with free O₂ from the shallow photic zone produced by eukaryotes, forming a high valence iron oxy-hydroxide precursor such as FeOOH or Fe(OH)₃. An alternative biological mechanism producing similar ferric precursors would have been in the form of photo-ferrotrophy, whereby oxidation of ferrous iron to the ferric form took place in the absence of biological O₂ production. Irrespective of the exact mode of primary iron precipitation (which remains contentious to date), the precipitated ferric oxy-hydroxide precursor would have reacted with co-precipitated organic matter, thus acting as a suitable electron acceptor for organic carbon remineralisation through Dissimilatory Iron Reduction (DIR), as also observed in many modern anoxic diagenetic environments. DIR-dominated diagenetic models imply a predominantly diagenetic influence in BIF mineralogy and genesis, and use as key evidence the low δ¹³C values relative to the seawater bicarbonate value of ~0 ‰, which is also thought to have been the dissolved bicarbonate isotope composition in the early Precambrian oceans. The carbon for diagenetic carbonate formation would thus have been sourced through a combination of two end-member sources: pore-fluid bicarbonate at ~0 ‰ and particulate organic carbon at circa -28 ‰, resulting in the intermediate δ¹³C values observed in BIFs today. This study targets 65 drillcore samples of the upper Kuruman and Griquatown BIF from the lower Transvaal Supergroup in the Hotazel area, Northern Cape, South Africa, and sets out to explore key aspects in BIF carbonate petrography and geochemistry that are pertinent to current debates surrounding their interpretation with regard to primary versus diagenetic processes. The focus here rests on applications of carbonate (mainly siderite and ankerite) petrography, mineral chemistry, bulk and mineral-specific carbon isotopes and speciation analyses, with a view to obtaining valuable new insights into BIF carbonates as potential records of ocean chemistry for their bulk carbonate-carbon isotope signature. Evaluation of the present results is done in light of pre-existing, widely accepted diagenetic models against a proposed water-column model for the origin of the carbonate species in BIF. The latter utilises a combination of geochemical attributes of the studied carbonates, including the conspicuous Mn enrichment and stratigraphic variability in Mn/Fe ratio of the Griquatown BIF recorded solely in the carbonate fraction of the rocks. Additionally, the carbon isotope signatures of the Griquatown BIF samples are brought into the discussion and provide insights into the potential causes and mechanisms that may have controlled these signatures in a diagenetic versus primary sedimentary environment. Ultimately, implications of the combined observations, findings and arguments presented in this thesis are presented and discussed with particular respect to the redox evolution and carbon cycle of the ocean system prior to the Great Oxidation Event (GOE). A crucial conclusion reached is that, by contrast to previously-proposed models, diagenesis cannot singularly be the major contributing factor in BIF genesis at least with respect to the carbonate fraction in BIF, as it does not readily explain the carbon isotope and mineral-chemical signatures of carbonates in the Griquatown and uppermost Kuruman BIFs. It is proposed instead that these signatures may well record water-column processes of carbon, manganese and iron cycling, and that carbonate formation in the water column and its subsequent transfer to the precursor BIF sediment constitutes a faithful record of such processes. Corollary to that interpretation is the suggestion that the evidently increasing Mn abundance in the carbonate fraction of the Griquatown BIF up-section would point to a chemically evolving depositional basin with time, from being mainly ferruginous as expressed by Mn-poor BIFs in the lower stratigraphic sections (i.e. Kuruman BF) to more manganiferous as recorded in the upper Griquatown BIF, culminating in the deposition of the abnormally enriched in Mn Hotazel BIF at the stratigraphic top of the Transvaal Supergroup. The Paleoproterozoic ocean must therefore have been characterised by long-term active cycling of organic carbon in the water column in the form of an ancient biological pump, albeit with Fe(III) and subsequently Mn(III,IV) oxy-hydroxides being the key electron acceptors within the water column. The highly reproducible stratigraphic isotope profiles for bulk δ¹³C from similar sections further afield over distances up to 20 km, further corroborate unabatedly that bulk carbonate carbon isotope signatures record water column carbon cycling processes rather than widely-proposed anaerobic diagenetic processes.

The Paleoproterozoic Transvaal Supergroup in the Northern Cape Province of South Africa is host to high-grade BIF-hosted hematite iron-ore deposits and is the country’s most important source of iron to date. Previous work has failed to provide a robust and all-inclusive genetic model for such deposits in the Transvaal Supergroup; in particular, the role of hydrothermal processes in ore-genesis has not been adequately clarified. Recent studies by the author have produced evidence for hydrothermal alteration in shales (Olifantshoek Supergroup) stratigraphically overlying the iron-ore intervals; this has highlighted the need to reassess current ore-forming models which place residual supergene processes at the core of oregenesis. This thesis focuses on providing new insights into the processes responsible for the genesis of hematite iron ores in the Maremane anticline through the use of newly available exploration drill-core material from the centre of the anticline. The study involved standard mineralogical investigations using transmitted/reflected light microscopy as well as instrumental techniques (XRD, EPMA); and the employment of traditional whole-rock geochemical analysis on samples collected from two boreholes drilled in the centre of the Maremane anticline, Northern Cape Province. Rare earth element analysis (via ICP-MS) and oxygen isotope data from hematite separates complement the whole-rock data. Iron-ore mineralisation examined in this thesis is typified by the dominance of Fe-oxide (as hematite), which reaches whole-rock abundances of up to 98 wt. % Fe₂O₃. Textural and whole-rock geochemical variations in the ores likely reflect a variable protolith, from BIF to Fe-bearing shale. A standard supergene model invoking immobility and residual enrichment of iron is called into question on the basis of the relative degrees of enrichment recorded in the ores with respect to other, traditionally immobile elements during chemical weathering, such as Al₂O₃ and TiO₂. Furthermore, the apparently conservative behaviour of REE in the Fe ore (i.e. low-grade and high-grade iron ore) further emphasises the variable protolith theory. Hydrothermally-induced ferruginisation is suggested to post-date the deposition of the post-Transvaal Olifantshoek shales, and is likely to be linked to a sub-surface transgressive hydrothermal event which indiscriminately transforms both shale and BIF into Fe-ore. A revised, hydrothermal model for the formation of BIF-hosted high-grade hematite iron ore deposits in the central part of the Maremane anticline is proposed, and some ideas of the author for further follow-up research are presented.