[Introduction] During 1965 the author, in looking for a project for a thesis to be submitted for the degree of Master of Science in Geology, decided to map a suitable region in order to gain experience in geological field work. The exact nature of the region itself was of no great importance, but since this study was to be conducted through Rhodes University, it was decided that an area, as near to Grahamstown as possible, would be the most suitable. With this in view, the geologist in charge of the Grahamstown Office of the Geological Survey was invited to suggest an area suitable for study, and if possible, to obtain financial assistance. He indicated the region which has been mapped and which will eventually form part of the proposed sheet 143. It is immediately adjacent to, and to the west of the 1:125,000 sheet 136 of Grahamstown completed by Mountain in 1940.

During 1963 an area was mapped around Sidbury, 23 miles south- west of Grahamstown. The object of the survey was to examine stratigraphic problems, which included the nature of a large occurrence of shale south of Alicedale in a region previously mapped as Witteberg, and the relationship between Silcrete and Calcrete. During the invest igation evidence of the existence of two, possibly three , major thrust-faults and of extensive overfolding to the south was discovered. There is reason to believe, that movement on the Zuurberg Fault was initiated in pre-Cretaceous times, and renewed in the early Cretaceous. The Silcrete is shown to be related to the pattern of presentday drainage. Stone implements found embedded in the Calcrete suggest that it is of Recent age.

The Cape Supergroup (Sequence) comprises three groups, embracing a total of twenty-three formations, with a maximum combined thickness of approximately 8 km. The Table Mountain Group consists of medium-grained (occasionally fine- or coarse-grained), "clean", ultra-quartzose sandstone plus subordinate fine-grained, "dirty", subfeldspathic to feldspathic sandstone, mudrock, and rhythmitite. Average total thickness is about 3000 m. The Bokkeveld Group is composed of mudrock, rhythmitite and subordinate subfeldspathic to feldspathic sandstone (generally fine-grained and "dirty"), with a maximum total thickness of over 3000 m. The Witteberg Group comprises fine- to medium-grained ultra-quartzose sandstone, icaceous streaky rhythmitite, mudrock, and one thin diamictite unit; total thickness is about 1700 m. The strata belonging to the Cape Supergroup appear to have been largely deposited under marine conditions in environments ranging from outer shelf to beach. Deltaic deposits are,however, common in the upper part of the Bokkeveld Group and the Witteberg Group, while the main sandstone units in the upper third of the Table Mountain Group may have accumulated on a coastal alluvial plain. Deposition took place in a basin elongated in an east-west direction, with the palaeoslope inclined towards the south. Palaeocurrents were generally directed down the palaeoslope, but westerly 1 transport directions parallel to the palaeostrike and presumed shoreline are present in both the Table Mountain and Witteberg Groups. I The sedimentary rocks o~ the Karoo Sequence are subdivided into two groups (containing a total of eleven formations) and four ungrouped formations. Using the maximum thicknesses of the individual formations, a combined total thickness of about 12 km can be calculated. The sequence commences with the Dwyka Tillite, a 700-m-thick diamictite unit. The overlying Ecca Group consists of "varved" rhythmitite, dark, massive, fine- to very fine-grained ultra-lithofeldspathic sandstone and subordinate mudrock with a total thickness of 2000 - 3000 m. The Beaufort Group is composed of thick mudstone layers alternating with thinner fine-grained ultra-lithofeldspathic, lithofeldspathic and lithic sandstones, with the exception of the Katberg Formation which consists largely of sandstone. Fining-upward cycles are ubiquitous, while red mudstone is com~on, especially in the upper half of the group. A maximum thickness of about 6000 m was obtained in the East London area. The Molteno Formation Consists of up to 600 m of alternating fine- to coarse-grained sublithic sandstones (frequently pebbly) and grey mudstones, generally forming finingupward cycles. The Elliot Formation (up to 500 m thick) consists of red and grey mUdstones and subordinate fine-grained lithofeldspathic sandstones arranged in fining-upward cycles. The bulk of the Clarens Sandstone consists of very fine-grained massive (occasionally cross-bedded) sandstone, with a maximum thickness of 300 m. The Drakensberg Group, consisting of up to 1200 m of basalt with some pyroclastic intercalations near the base, caps the Karoo sedimentary succession. The deposition of the Dwyka Tillite by glacier action coincided with a major change from the generally shallow marine conditions which characterised the sedimentation of the Cape Supergroup (with the source area located on the craton to the north of the basin) to a deep linear trough receiving clastic sediments from a source area situated south and south-east of the basin. The Ecca Group,the lower half of which is characterised by the presence of "proximal" turbidite sandstones, records the gradual infilling of this basin, with deltaic conditions developing in the upper part of the group in the western half of the study area (i.e. in the Waterford Formation). The overlying strata were virtually all deposited under fluviatile conditions, the chief exceptions being a stratigraphic interval within the lower half of the Beaufort Group which appears to have formed in a large body of water, a~d the aeolian Clarens Sandstone. The fluviatile sediments were all deposite1 by rivers flowin~ towards the north and nort~-west, while the Clarens Sandstone was laid down by winds blowing from the west. The Ecca and Beaufort Group sandstones are characterised by a high rock fragment content with "felsit ic" gra ins being a prc;>minent constituent. This, together with the relative abundance of quartzfeldspar porphyry pebbles in the Katberg Sandstone unit (Beaufort Group) near East London, indicates that volcanic material probably formed a prominent part of the post-Dwyka Karoo provenance.

The aim of the research focuses on characterizing heavy mineral assemblages and interpretation of the provenance of the Ecca Group of in the Eastern Cape Province, South Africa. In South Africa, the Ecca Group outcrops extensively in the Main Karoo Basin. Mudstone, siltstone, sandstone, minor conglomerate and coal are the major constituent lithologies within the group. For descriptive purposes, the Ecca is categorized into three different geographical areas: the southern area, the western and northwestern area and the northeastern area. Six of the sixteen geological formations, namely the Prince Albert, Whitehill, Collingham, Ripon, Fort Brown, Waterford and Koonap Formations are present in the study area and are best exposed in road cuttings. For purposes of comparison, the underlying Witteberg Group, the Dwyka (which has Formation status here), and the overlying Koonap Formation of the Beaufort Group, are included in the study. This study is motivated by the relatively little information that is available on the heavy minerals of the Ecca Group, and that research of this nature had not been undertaken in the study area before. Another contributing motivation was to determine whether heavy mineral assemblages could be used to identify formations of the Ecca Group and for correlating between different localities in accordance with studies done elsewhere. Additionally, diagnostic heavy mineral assemblages could aid with stratigraphic selection of future boreholes in the Ecca Group. Heavy minerals are natural provenance tracers because of their stable nature and hydrodynamic behaviour. They are both non-opaque and opaque, with apatite, epidote, garnet, rutile, staurolite, tourmaline and zircon being good examples of non-opaque grains while ilmenite and magnetite are the most common opaques. Heavies are either derived from stable minor accessory minerals or from abundant but unstable mafic components of the host rock. They are very useful in interpreting the provenance due to the fact that some minerals are diagnostic of certain source rocks. However, sediments are exposed to several factors (conditions) such as weathering, erosion, breakage due to abrasion, mixing and recycling during transportation from the source to the depositional area. This implies that there are parameters other than the parent lithology that determine their final composition.

A number of outcrops of the Witteberg Group and lowermost Karoo Supergroup rocks were studied in the area south of the Darlington Dam, Jansenville District, with the aim of documenting structural characteristics of the area. All lithologies are folded with fold styles varying from gentle to near isoclinal (based on interlimb angle). Fold axes are either sub-horizontal or plunging at gentle to moderate angles whereas axial planes dip gently to vertically (predominantly steep to sub-vertical). Folds verge predominantly towards the north but where southward verging they are associated with faulting or strongly folded areas. Folds plunge gently to the east-southeast and west-northwest. The area consists of a large anticlinorium with both first and second order folds occurring. Eastwest striking faults occur in the study area and are classified as normal, reverse and thrust faults. A study of the joint sets shows that there are four dominant joint directions, namely 18o, 33o, 97o and 107o (in order from least to most important). An interpretation of the tectonic history is presented in which the relationships between faults and folds show that faults formed during and after folding. Folding, and reverse and thrust faulting, occurred during the compressional events that formed the Cape Fold Belt, whereas the normal faults formed during the relaxation of these compressional forces or during the break-up of Gondwana.

The Ecca Group of Karoo Supergroup is a sedimentary rock sequence that deposited between the Late Carboniferous (Dwyka Group) and the Late Permian-Middle Triassic (Beaufort Group). The Ecca Group investigated in this study is situated in the Eastern Cape Province of South Africa and it comprises mainly of shales, mudstones, siltstones and sandstones. The Ecca Group sequence contains considerable carbon content and suitable thickness to make it an ideal target for shale gas exploration. Previous studies put more emphasis on the geology and stratigraphy of the Ecca Group, this study revised the stratigraphy, and put new insight on the petrography, depositional processes, sedimentary facies, provenance, paleoweathering, tectonic setting, subsidence rates and history, electrical resistivity, source rock characteristics and diagenesis of the potentially feasible sandstone and mudrock reservoir rocks of the Ecca Group. Based on the lithological features, sedimentary structures and facies characteristics, the stratigraphy of the Prince Albert, Whitehill, Collingham and Fort Brown Formations of the Ecca Group is now subdivided into two informal members each, i.e. Lower Member and Upper Member. Furthermore, the Ripon Formation is now subdivided into three informal members. Each member has been asigned a lithological name. The grain size parameters show that most of the Ecca Group sandstones are very fine to fine grained, poorly to moderately well sorted, mostly near-symmetrical and mesokurtic in grain-size distribution. The linear discriminant function analysis is dominantly indicative of turbidity current deposits under deep marine environment for Prince Albert, Whitehill and Collingham Formations, shallow marine environment for Ripon Formation, while the Fort Brown Formation is lacustrine-deltaic deposits. Modal composition analysis and petrography studies revealed that the detrital components of the sandstones are dominated by monocrystalline quartz, feldspar and lithic fragments. The sandstones are compositionally and texturally immature and can be classified as feldspathic wacke and lithic wacke. The provenance analysis revealed plutonic and metamorphic terrains as the main source rocks with minor debris derived from recycled sedimentary rocks. The detrital modal compositions of these sandstones are related to back arc to island and continental margin of tectonic setting. Based on the detailed sedimentological analyses of outcrop and borehole data, fourteen lithofacies were identified and seven facies associations (FAs) were recognised. The facies associations are: FA 1: Shale and mudstones intercalated with siltstones, FA 2: Carbonaceous shale, mudstone with subordinate chert and sandstone, FA 3: Mudstones rhythmite with thin bedded mudstone and lenticular siltstone, FA 4: Greyish medium bedded sandstone intercalated with laminated mudstone, FA 5: Dark-grey medium to thick bedded mudstone and siltstone, FA 6: Thin to medium bedded sandstone alternated with thin bedded carbonaceous mudstone, and FA 7: Varved mudstone rhythmite intercalated with siltstone and minor sandstone. Sedimentological characteristics of the identified facies associations indicate four deposition environments, namely, deep marine basin, turbidite, shallow marine and lacustrine environments, which constitute a gradually regression sequence as a result of sea-level dropping and shallowing of the basin during the developmental processes. Geochemical analysis of the Ecca mudrocks and sandstones revealed that the rocks are of quartzose sedimentary provenance, suggesting that they were derived from a cratonic interior or recycled orogen. The petrography and geochemistry of the sandstones indicated that the source areas are composed of plutonic and metamorphic rocks with a minor component from sedimentary rocks. The geochemical diagrams and indices of weathering suggested that the granitic source rocks underwent moderate to high degree of chemical weathering. The tectonic setting discrimination diagrams support passive continental margin setting of the provenance.

A traverse through the Balfour Formation was chosen in the area around the towns of Fort Beaufort and Alice in the Eastern Cape Province. The main objectives of the study were to map the lithological variations within the Balfour Formation and to distinguish it from the underlying Middleton Formation and the overlying Katberg Formation. A combined desktop, field and laboratory approach was used in this study. Aerial photographs, satellite images and digital topographical maps formed the basis of the desktop work. After desktop mapping, a number of field traverses were measured through the study area. Sedimentary structures were observed, photomosaics were done, stratigraphic sections were measured and samples were collected for thin sectioning, heavy mineral separation and major, trace and REE analysis. Sedimentological development of the Balfour Formation has been outlined in relation to its provenance during the Late Permian. Lithological variation of the Balfour Formation is characterised by alternating sandstone-dominated and mudstone-dominated members. Arenaceous Oudeberg and Barberskrans Members are contain facies ranging from intraformational conglomerates (Gmm), massive sandstones (Sm & Ss), horizontally laminated sandstones (Sh), planar and trough cross-bedded sandstones (Sp, Sl & St), trough cross-laminated sandstones (Sr) and fine-grained sediments (Fm & Fl), whereas the mudstone dominated members are characterised by the facies Fm and Fl. Lithofacies together with bedforms observed in the Balfour Formation were used in architecturalelement analysis. Sandstone–rich members are dominated by channel fill elements such as LS, DA, SB, LA and CH, whereas the fine-grained component consists of mainly, FF iii element. The mudstone-dominated members contain FF, CS and LV elements, with LA, SB and CH in the subordinate sandstones. Petrography, geochemistry and palaeocurrent analysis indicated that the source of the Balfour Formation was to the south-east and the rocks had a transitional/dissected magmatic arc signature. This led to the postulation of the Karoo Basin to have developed in a retro-arc foreland basin where there was supralithospheric loading in the Cape Fold Belt due to a compressional regime initiated by the subduction of Palaeo-Pacific plate underneath the Gondwana plate. The tectonic loading was episodic with eight major paroxysms affecting the Karoo Supergroup. The Balfour Formation coincides with the fourth paroxysm, this paroxysm in turn consists of two third-order paroxysm that initiated the deposition of the Oudeberg and Barberskrans Members in low sinuosity streams. Each paroxysm was followed by a period of quiescence and these resulted in the deposition of the Daggaboersnek, Elandsberg and Palingkloof Members in meandering streams. Depositional environments were determined mainly from the sedimentary structures and 3D architecture of the rock types. Sandstone rich members were formed by seasonal and ephemeral high energy low sinuous streams whereas the fine-grained rich members were formed by ephemeral meandering streams. Palaeoclimates have been equated to the present temperate climates; they were semi-arid becoming arid towards the top of the Balfour Formation. This has been determined geochemistry (CIA), sedimentary structures and other rock properties like colour.

Detailed field mapping (Map, Appendix B) has been conducted in and around the boundaries of a 14x18km, volcanic complex 35km northeast of Molteno in the Eastern Cape Province, South Africa. The structure is interpreted as a subsidence structure, and is filled with two volcaniclastic breccias, numerous lava flows, a number of sedimentary facies, and lies on a base of Clarens Formation overlying Elliot Formation rocks. This is an important study because 'widespread, voluminous fields of basaltic breccias are very rare (see Hanson and Elliot, 1996) and this is the first time that this type of volcanic complex and its deposits have been described. Detailed analyses of the two volcaniclastic breccias revealed changes in colour, clast types, clast sizes, and degree of alteration over relatively short distances both vertically and laterally within a single breccia unit. The variation in clast sizes implies a lack of sorting of the breccias. The lower of the two volcaniclastic breccias fills the subsidence structure, and outcrops between the Stormberg sedimentary sequence and the overlying Drakensberg basalts and was produced from phreatomagmatic eruptions signalling the start of the break-up of Gondwanaland in the mid-Jurassic. The upper volcaniclastic breccia is interbedded with the flood basalts and is separated from the lower breccia by up to 100m of lava flows in places, it is finer-grained than the lower volcaniclastic breccia, and it extends over 10km south, and over 100km north from the volcanic complex. The upper breccia is inferred to have been transported from outside the study area, from a source presumably similar to the subsidence structure in the volcanic complex. The pyroclastic material forming the upper breccia was transported to the subsidence structure as a laharic debris flow, based on its poorly sorted, unwelded and matrix-supported appearance. However, both breccias are unlikely to have been derived from epiclastic reworking of lava flows as they contain glass shards which are atypical of those derived from the autoclastic component of lava flows. The breccias are therefore not "secondary" lahars. There is also no evidence of any palaeotopographic highs from which the breccias could have been derived as gravity-driven flows. Based on the occurrence of three, 1m thick lacustrine deposits, localised peperite, fluvial reworking of sandstone and breccia in an outcrop to the south of the subsidence structure, and channel-lags encountered only in the upper units of the Clarens Formation and only within the subsidence structure, the palaeoenvironment inferred for the subsidence structure is one of wet sediment, possibly a shallow lake, in a topographic depression fed by small streams. Magmatic intrusions below the subsidence structure heated the water-laden, partly consolidated Clarens Formation sandstones, causing the circulation of pore fluid which resulted in the precipitation of minerals forming pisoliths in the sandstones. Intruding magma mixed, nonexplosively, with the wet, unconsolidated sediments near the base of the Clarens Formation (at approximately 100m below the surface), forming fluidal peperite by a process of sediment fluidisation where magma replaces wet sediment and cools slowly enough to prevent the magma fracturing brittly. Formation of fluidal peperite may have been a precursor to the development of FCIs (Fuel Coolant Interactions) (Busby-Spera and White, 1987). The breccias may represent the products of FCIs and may be the erupted equivalents of the peperites, suggesting a possible genetic link between the two. The peperites may have given way to FCI eruptions due to a number of factors including the drying out of the sediments and/or an increase in the volume of intruded magma below the subsidence structure which may have resulted in a more explosive interaction between sediment and magma. Phreatic activity fragmented and erupted the Clarens Formation sandstone, and stream flows reworked the angular sandstone fragments, pisoliths and sand grains into channelised deposits. With an increase in magmatic activity below the subsidence structure, phreatic activity became phreatomagmatic. The wet, partly consolidated Clarens Formation, and underlying, fully consolidated Elliot Formation sediments were erupted and fragmented. Clasts and individual grains of these sediments were redeposited with juvenile and non-juvenile basaltic material probably by a combination of back fall, where clasts erupted into the air fell directly back into the structure, and backflow where material was erupted out of the structure, but immediately flowed back in as lahars. This material formed the lower volcaniclastic breccia. A fault plane is identified along the southwestern margin of the subsidence structure, and is believed to continue up the western margin to the northwestern corner. A large dolerite body has intruded along the inferred fault plane on the western margin of the structure, and may be related to the formation of the lower volcaniclastic breccia, either directly through fluidisation of wet sediment during its intrusion, or as a dyke extending upwards from a network of sill-like intrusions below the subsidence structure. Geochemical analysis of the Drakensberg basalt lava flows by Mitchell (1980) and Masokwane (1997) revealed four distinct basalt types; the Moshesh's Ford, the Tafelkop, the Roodehoek, and the Vaalkop basalts. Basalt clasts sampled from the lower volcaniclastic breccia were shown to belong to the Moshesh's Ford basalt type which does not outcrop in situ within the subsidence structure. This implies that the Moshesh's Ford basalts were emplaced prior to the formation of the lower volcaniclastic breccia, and may have acted as a "cap-rock" over the system, allowing pressure from the vaporised fluids, heated by intruding basalt, to build up. The Moshesh's Ford basalt type was erupted prior to the resultant phreatomagmatic events forming the lower volcaniclastic breccia.

Palaeoenvironmental reconstruction of the late Pleistocene and Holocene geological periods for central and southern Africa has been hampered by the erratic distribution of suitable sites, incomplete and inaccurately dated sequences and the limited nature of published data. One geomorphological feature which has supplied valuable evidence for fluctuations in past environmental conditions, is the vlei or dambo. The type-site of these waterlogged features is in south central Africa, but similar features have been described on other continents. The clastic and organic sediments contained within these features are affected by, and therefore reflect to some degree, the environment under which they were formed. The characteristics of the sediments supply information as to their transport and mechanisms of deposition. From these processes, the environmental conditions at the time of vlei formation can be inferred. The environmental history of the Eastern Cape region has been considerably neglected, and is far less well understood than other countries such as Malawi, Zambia and Zimbabwe. A study site in the Winterberg Range (Eastern Cape) was selected which permitted the comparison of two vleis, the objective being to establish an accurate late Pleistocene sediment chronology for the entire plateau area. Radiocarbon dates from organic layers indicate that these sediments span the last 12 000 years BP, suggesting that organic accumulation at this site began at roughly the same time as at sites further afield. The vlei sediments are analysed in terms of their morphology, particle slze distribution, and other physical and chemical characteristics. These data facilitate the construction of detailed stratigraphic diagrams and a chronological summary of sediment accumulation, from which the period and governing processes of vlei development under changing environments may be described. It is found that the Winterberg vleis contain sediments which respond to changes in the prevailing environment. This makes these sediments useful indices from which to trace such changes during the late Pleistocene and Holocene times. These features are found to be similar in many respects to those described elsewhere in Southern Africa. The study attempts to provide greater understanding of contemporary vlei processes and emphasises the necessity of their preservation, as finite and valuable resources, by future generations

Nodules within the lower Bokkeveld shales often contain well-preserved invertebrate fossil material. The aim of this study was to describe some characteristics seen at various scales (macro-, micro- and ultra -) within nodules that might contribute to an understanding of aspects of nodule formation and the reasons for the excellent preservation of the fossil material within these nodules. Detailed, high quality macro-photographs were taken of sliced and whole nodule surfaces and a catalogue was produced to tentatively identify fossils present and illustrate the variations seen within nodules. Selected nodules were then subjected to petrographic, ultra-structural (SEM) and some chemical (EDS, XRD & XRF) analysis to investigate the possible reasons for these variations. The chemical results have indicated that nodules are enriched with quartz compared to the surrounding shale. Quartz is also the dominant mineral replacing trilobite carapace material within nodules, while trilobite material within shales is replaced with equal proportions of hematite, biotite and quartz. It appears that the higher resistance of quartz to weathering is the dominant factor leading to the preservation of both nodules within the shales and trilobite material within the nodules examined. A comparison with some Western Cape nodules highlighted possible variations in overall nodule chemical composition along strike. Western Cape nodules are predominantly composed of apatite whereas the Cockscomb nodules are mainly composed of quartz. This quartz-apatite compositional variation in nodules occurring within a single formation has been reported from nodules found in the Armorican Massif of France which are very similar in a number of respects to the Bokkeveld nodules described in this study. Based on various features of the fossils present and the structure of nodules they were probably formed during early diagenesis within an epeiric marine deposit greatly affected by sea level fluctuations.