Thesis (Ph. D.)--University of California, Berkeley, 1992. / Includes bibliographical references (leaves 136-140).

Thesis (M. Eng.(Geotechnical Engineering))--University of Pretoria, 2003. / Includes bibliographical references.

This thesis analyses the establishment of a health and safety system on the Witwatersrand gold mines in the period between the end of the South African War and the eve of World War Two. The period has been chosen, firstly, because the South African War had seriously disrupted production and the industry virtually had to start up again from scratch; secondly, because it was during this period that mine and state officials began to seriously investigate the reasons for the appalling mortality and morbidity rates on these mines; and, thirdly, because during this period some improvements did occur which were significant enough to enable the industry to warrant the lifting, in the latter part of the 1930s, of the ban on tropicals, enforced since 1913 as a result of their extremely high mortality rate. In the first thirty years of the twentieth century about 93 000 African miners died disease-related deaths and in the same period some 15000 African miners were killed in work-related deaths. In attempting to establish why so many African miners died, the thesis attempts to identify the diseases and accidents that caused these deaths and considers what attempts were made to bring mortality and morbidity rates down. Whilst the thesis is neither a history of gold mining in South Africa nor an economic history of South Africa in the period 1901 to 1939, it nevertheless, as detailed in the first chapter, places the health and safety system within the context of the wider political and economic forces that shaped the mining industry in this period. The need for a productive and efficient labour force, vital for the industry'S survival during a number of profitability crises in this period, forced the industry to reassess compound structures, nutrition and eventually the health of its work force. These issues of compounds, work and diet are discussed in chapters two, three and four. Appalling living and working conditions led to a high incidence of pulmonary diseases - TB, silicosis and pneumonia - which were the principal killers on the mines. Attempts to cure or prevent their occurrence are discussed in chapter five. Fear of disruptions to production ensured that the mining industry eventually also devoted considerable resources to accident prevention, a theme which is discussed in chapter six. The thesis concludes that the mining industry for much of this period was able to determine the pace of change; neither state officials nor African miners were able to significantly alter the tempo. In fact the industry was so successful that it was able to convince a number of government commissions in the 1940s that the migrant system had to stay, to ensure the wellbeing of the miner. This meant that despite considerable time, money and effort being spent on establishing a health and safety system on the gold mines, the mining industry was still of the opinion that the health of their workers was best served if they were sent home.

Gold exploration was conducted in northern margin, granulite-facies rocks of the Limpopo Belt. Methods used in the prospecting include drainage, soil and rock geochemistry, geophysical surveys, geological mapping, trenching and diamond drilling. These techniques successfully led to the discovery of two medium size, mesothermal gold deposits (Grid 2s and Grid 4). Objectives of this study were to (a) document the exploration methodology used; (b) describe the regional geology; (c) establish a mineral deposit model; (d) outline the methods and results of various exploration techniques; (e) outline follow-up procedures and evaluation of anomalies; and (f) discuss results of the exploration exercise and conclusions. The granulite-facies terrain comprises Charno-enderbites, mafic and felsic to intermediate metavolcanic rocks and meta-sediments. Renco Mine situated immediately east of the study area, was selected as the ore deposit model for the exploration program. Gold mineralization occurs in shear and thrust zones within an enderbite. The gold deposits are structurally controlled by a first-order, Sinistral transcrustal Mauch Shear Zone, which is parallel to a regional east-northeast penetrative foliation. The deposits are in dilation zones where the Mauch Shear (a) is intersected by a dextral east-west shear (Grid 2s), or (b) has a sinistral splay (Grid 4 and Renco). Close to these deposits, the Mauch Shear is in contact with a "greenstone belt", which is a possible source of crustal metamorphic ore fluids and gold. The Grid 2s deposit contains fine-grained, disseminated free gold, and small amounts of pyrrhotite, pyrite and chalcopyrite in quartz veins within third-order shears in K-feldspar granite. K-feldspar, sericitic, silicic, sulphidation and carbonate alteration characterizes the deposit, which has a proposed mantle-degassing model. The Grid 4 deposit is magmatic porphyry-type, with CuMo and Au in third- and fourth-order shears respectively. Mineralization comprises disseminated to semi-massive pyrrhotite, pyrite, chalcopyrite, sphalerite, bismuth, molybdenite and gold. Wall rock alteration includes biotitic, chloritic, silicic, sulphidation and carbonate. In Grid 2s, Grid 4 and Renco deposits, the alteration mineral assemblages are in three facies, which are granulite, amphibolte and greenschist. In the three deposits, the mineralization occurs with the amphibolite-facies, indicating post-peak, retrograde metamorphic conditions. / Illustrations (maps) only available in print form at Cory Library / KMBT_363 / Adobe Acrobat 9.54 Paper Capture Plug-in

Thesis (MTech (Chemical Engineering))--Cape Technikon, 2000. / The large quantities of wood chips produced at mines from damaged underground timber contain gold that cannot be completely recovered by cyanidation. A fungus that can degrade a portion of the wood matrix will allow the gold that was previously locked up, to come into contact with the cyanide solution during beneficiation, thereby improving recoveries. The fungus Phanerochaete chrysosporium produces enzymes that use the organic compounds found in lignin as substrate. Consequently, the fungus is able to selectively break down lignin, which is one of the major components of wood. Chips sampled from Vaal Reef Mine contained between 2 and 5 mg/kg gold. The main source of gold in the chips was determined to be impregnated gold-bearing ore and discrete gold particles. Direct cyanidation resulted in around 60 per cent recovery prior to biological treatment. Despite relatively high weight losses caused to the chips as a result of treatment with Phanerochaete chrysosporium gold recovery only increased 10 per cent after 4 weeks treatment compared to direct recovery without treatment.

The environmental impact of the Robinson Deep mine residue deposit in Johannesburg was assessed by evaluating the water chemistry and surface precipitates, thereby identifying the processes responsible for forming the contamination footprint. Precipitates were compared to a documented paragenetic sequence of mineral formation associated with sulphide rich mine waste. PHREEQC, a geochemical modelling tool, was utilized to predict the formation of precipitates from evaporation ponds. The chemistry of the leachate was analysed and compared to water quality standards in order to determine the possible environmental impact. The chemistry of the water emanating from the mine residue deposit reveals that an Fe-SO4 dominant chemistry persists, this is consistent with acid mine drainage environments. The most toxic cations and anions contained in the water are Fe, Al, Mn, Ca, As, Mg, Cu, Zn, Pb and SO . It is predicted that the impact of toxic metals identified in the water decreases further from the mine residue deposit due to dilution and co-precipitation with different mineral phases such as goethite. Precipitates identified include jarosite group minerals, goethite, melanterite, copiapite, Mg-copiapite, halotrichite, pickeringite, gypsum and alunogen. These secondary minerals may be used as indicator minerals of acid mine drainage. Assessment and prediction of the stage of contamination and possible environmental impact, may, therefore be pursued when comparing the indicator minerals to predicted paragenetic sequences. For example, the precipitation of melanterite is consistent with an early stage of acid mine drainage development. The presence of melanterite thus suggests that oxidation of sulphides is an ongoing process on the Robinson Deep mine residue deposit. Evaporation of water in the evaporation ponds aids in increasing the concentration, hence allowing the predominant precipitation of jarosite group minerals. Alternatively, rainfall dilutes the water allowing dissolution of minerals located on the banks of the evaporation ponds to predominate. This mechanism of precipitation and dissolution is seasonal; formation of precipitates predominates during the dry season, while dissolution is most prominent during the wet season. The development of hardpans indicates that the main mechanism of formation of the associated phases is through capillary action at the sediment surface. Leaching of Fe2+-rich water from the mine residue deposit containment area is indicated by the presence of copiapite, while jarosite and goethite formation tend to form part of a hardpan layer. Goethite is an indication of a late stage mineral predominant at lower sulphate and higher pH conditions. Results of predicted formation of precipitates by PHREEQC are not in very good agreement with actual field observations. This is mainly due to the lack of thermodynamic data for many of the sulphate minerals observed. Hence, precipitates associated with acid mine drainage may be utilized as indicator minerals. Consequently, there identification may facilitate in environmental monitoring and risk assessment. / Prof. J. M. Huizenga Prof. J. Gutzmer

A remarkable correlation between hydrothermal gold mineralisation and geological structure is discussed. The mineralisation occurs in vein quartz which occupies a fissure in Archaean greenstones of the Basement Complex in Rhodesia, It has been determined that gold which is silver-rich is typical of low-grade ore, and is associated in space with sulphides that crystallised early in paragenesis. Silver-poor gold is characteristic of highgrade ore which is concentrated along the crestal zone of anticlinal warps in the fissure. It is suggested that the local pattern of fracturing and folding is related to fundamental wrench faulting.

The gold metallogeny of Australia is predominantly confined to the Archaean and Palaeozoic Provinces. The Archaean gold occurrences are predominantly hosted in ultramafic-mafic dominated greenstone belts, with less associated tofelsic-volcanic and sedimentary sequences. Most gold occurrences are confined to shear zones or faults, and adjacent discoveries of economic laterite-hosted deposits, host rocks. Recent are presently under investigation and will supply a significant proportion of production in the future. The Proterozoic gold deposits of Australia , are confined to geosyncinal sequences, commonly turbidites (eg: Telfer), with other hydrothermal deposits associated directly to granites. An important feature of the North Australian Craton deposits, is the spatial association of most deposits to granite bodies, although a genetic link has not been established conclusively. The Roxby Downs deposit in South Australia is a unique occurrence of gold in association to copper, uranium and R.E.E. This deposit is tentatively related to intraplate alkaline-magmatism, with further work necessary. The most significant recent discovery of gold mineralization in Australia is in the Drummond Basin in Queensland. This epithermal is tentatively related to mineralization within the Georgetown Inlier. The latter mineralization is Permo-Carboniferous, in a Proterozoic (and possibly Archaean) sequence of schists. It is tentatively suggested that all the gold mineralization in northern Queensland may be related to single tectonic event, a feature which requires further study . Other mineralization in the Phanerozoic includes the turbidite-hosted metamorphogenic deposits of Victoria, the rift related deposits in New South Wales and magmatic related deposits in Queensland. The gold deposits in Australia may in the future be classified in a tectonogeological framework, similiar to the layout of this dissertation, particularly once further data becomes available on recent discoveries.

M.Sc. (Geology) / Please refer to full text to view abstract

Please read the abstract in the front matter of this document. / Dissertation (M Eng (Electrical Engineering))--University of Pretoria, 2007. / Electrical, Electronic and Computer Engineering / unrestricted