No description available.

No description available.

No description available.

Placer gold is frequently reported to assay at overall higher values of fineness than the gold in the rock from which it was liberated. A related phenomenon is the historical discovery of many extremely large gold nuggets (up to 28 lbs) in the southeastern United States that have no apparent source rock. Placer gold grains from the southeastem United States have been examined and found to frequently exhibit the development of nearly pure to pure gold rims around their borders. These gold rims are suggested as a possible cause of the high fineness placer deposits. Formation of very thick rims may also be the cause of the large nuggets. Formation of these gold-enriched rims by the often attributed mechanism of simple silver leaching is disputed on the basis of ineffective mechanisms for the removal of silver from the alloy. Diffusion of silver through the gold at low temperatures proceeds far too slowly to produce the chemical gradients observed in the placer gold grains. Comparison of the complexation capacities of 41 ligands with subsequent modelling of expected complex concentrations in natural stream and stream sediment waters indicates CN⁻ and S² as the most likely functional ligands for the transport and redeposition of supergene gold. Electrolytic refining of placer Au-Ag grains is also a process for forming gold-enriched rims that can operate together with secondary enrichment to produce the observed phenomena. / Master of Science

Placer ore minerals are commonly intergrown with "relict" phases that coexisted with the ore mineral in the original lode deposit. Studying these relict phases can yield important information about the nature, and formation of the lode deposit. This type of study can be useful in areas with poor exposure, areas that are remote, or areas where discretion is important. Analysis of the heavy mineral suite of stream sediments from the Brush Creek area shows no correlation between the heavy minerals and the gold. However, analysis of the relict phases intergrown with the gold grains yields important results. Placer gold grains recovered from streams draining the Brush Creek deposit, in southwestern Virginia, contain relict quartz, orthoclase, ilmenite and mica. Textures, and fluid inclusion composition and character in the relict quartz, indicate that the gold mineralization post dated the mylonitization associated with the Fries ductile deformation zone, which hosts the gold mineralization. The relict orthoclase is interpreted to be adularia, which is common in low-temperature, hydrothermal environments. The intergrowth textures of the gold and ilmenite show that the ilmenite was present in the country rocks prior to gold mineralization, and was not, therefore, cogenetic with the gold. The relict mica was not positively identified, but is believed to be chlorite, which is consistent with the proposed low temperature mineralization. The textures of the relict phases indicate that gold mineralization occurs in late, brittle fractures, with little or no significant alteration. The study of the relict phases intergrown with the alluvial gold grains has yielded information that otherwise could only have been obtained by more advanced, but also much more expensive, exploration techniques. / Master of Science