Gold-black has emerged as a popular absorptive coating for thermal radiation detectors in aerospace applications. The performance and accuracy of thermal radiation detectors largely depends on the surface optical properties of the absorptive coating. If the absorptivity of the layer is directional or wavelength dependent, then so will be the detector gain itself. This motivates our interest in the manufacture, physical characterization, and study of the wavelength and polarization sensitivity of the directional spectral absorptivity of gold-black. A first-principle model based on lossy antenna theory is presented to predict the polarization dependent directional spectral absorptivity of gold-black in the visible and near infrared. Results for normal spectral absorptivity are in good agreement with measurements reported in the literature. However, suitable experimental data were not available to validate the theory for directional spectral absorptivity. Therefore, an experimental campaign to fabricate and measure the directional spectral behavior of gold-black had to be undertaken to validate the first-principle model. New in-plane bidirectional reflectance distribution function (BRDF) measurements for two thicknesses (~4 μm and ~8 μm) of gold-black laid down on a gold mirror substrate are reported in the visible (532 nm) and near-infrared (800 and 850 nm) for p- and s-polarizations. The investigation is then extended to a three-layer sample, which is shown to exhibit off-specular reflectivity. Described are processes for laying down gold-black coatings and for measuring their in-plane BRDF as a function of thickness, wavelength, and polarization state. A novel method for retrieving the directional absorptivity from in-plane BRDF measurements is presented. The influence of polarization on directional absorptivity is shown to follow our earlier theory except at large incident zenith angles, where an unanticipated mirage effect is observed. / Doctor of Philosophy / Instruments called thermal radiation detectors play an important role in monitoring the global climate from space. Gold-black is often used as an absorptive coating to enhance the performance of these instruments. Users need to know how gold-black coatings influence instrument performance. In general, coating properties depend on the wavelength and direction of incident radiation, as well as on an optical phenomenon called polarization. This dissertation investigates the relationship between the creation of gold-black coatings and their performance. A physical model is postulated for predicting the optical behavior of gold-black in the visible and near infrared. The model produces results that are in good agreement with measurements reported in the literature. However, suitable directional measurements were not available to validate the theory. Therefore, an experimental campaign was mounted to fabricate gold-black coatings and measure their optical behavior in order to validate the mathematical model. We observed the optical behavior of several of our gold-black samples of various thickness and over a range of wavelengths. We also studied a three-layer sample which was found to exhibit an unexpected behavior called off-specular reflectivity. Described are processes for creating gold-black coatings and for measuring and explaining their optical performance. During the course of this investigation an unanticipated mirage effect was observed for the first time.

The work presented here addresses an important topic in thermal radiation detection when gold-black is used as an absorber. Sought is a model to simulate the absorption of thermal radiation by gold-black. Fractal geometry is created to simulate the topology of gold-black. Then electrical circuits based on the topology are identified that capture the physics of the interaction between the gold-black material and incident electro-magnetic radiation. Parameters of the model are then adjusted so results obtained are comparable to absorption data from the literature. Potential next-generation radiometric instruments will likely involve thermal radiation detectors using gold-black as an absorbing medium. A model that accurately simulates gold-black absorption will be an important tool in their design. / Master of Science

High sensitivity uncooled microbolometers are necessary to meet the needs of the next generation of infrared detectors, which seek low power consumption and production cost without sacrificing performance. Presented here is the design, fabrication, and characterization of a microbolometer with responsivity enhanced by novel highly absorptive coatings. The device utilizes a gold-doped vanadium oxide film in a standard air bridge design. Performance estimations are calculated from current theory, and efforts to maximize signal to noise ratio are shown and evaluated. Most notably, presented are the experimental results and analysis from the integration of two different absorptive coatings: a patterned gold black film and a plasmonic resonant structure. Infrared-absorbing gold black was selectively patterned onto the active surfaces of the detector. Patterning by metal lift-off relies on protection of the fragile gold black with an evaporated oxide, which preserves gold black's near unity absorptance. This patterned gold black also survives the dry-etch removal of the sacrificial polyimide used to fabricate the air-bridge bolometers. Infrared responsivity is improved 70% for mid-wave IR and 22% for long-wave IR. The increase in the thermal time constant caused by the additional mass of gold black is a modest 15%. However, this film is sensitive to thermal processing; experimental results indicate a decrease in absorptance upon device heating. Sub-wavelength resonant structures designed for long-wave infrared (LWIR) absorption have also been investigated. Dispersion of the dielectric refractive index provides for multiple overlapping resonances that span the 8-12 ?m LWIR wavelength band, a broader range than can be achieved using the usual resonance quarter-wave cavity engineered into the air-bridge structures. Experimental measurements show an increase in responsivity of 96% for mid-wave IR and 48% for long-wave IR, while thermal response time only increases by 16% due to the increased heat capacity. The resonant structures are not as susceptible to thermal processing as are the gold black films. This work suggests that plasmonic resonant structures can be an ideal method to improve detector performance for microbolometers.

Earth radiation budget instruments are devices designed to study global climate change. These instruments use telescopes embarked on low-earth-orbit satellites to measure Earth emitted and reflected solar radiation. Radiation is sensed as temperature changes caused by radiation absorbed during scans of the earth on a delicate gold-black coated detector. This work is part of a larger effort to develop an end-to-end dynamic electro-thermal model, based on first-principles, for the next generation of earth radiation budget instruments, the Radiation Budget Instrument (RBI). A primary objective of this effort is to develop a numerical model of the detector to be used on RBI. Specifically, the sensor model converts radiation arriving at the detector, collimated and focused through telescopes, into sensible heat; thereby producing a voltage. A mathematical model characterizing this sensor is developed. Using a MATLAB algorithm, an implicit finite-volume scheme is implemented to determine the model solution. Model parameters are tuned to replicate experimental data using a robust parameter estimation scheme. With these model parameters defined, the electro-thermal sensor model can be used, in conjunction with the remaining components of the end-to-end model, to provide insight for future interpretation of data produced by the RBI. / Master of Science / Earth radiation budget instruments are devices designed to study global climate change. These instruments use telescopes embarked on low-earth-orbit satellites to measure radiation exiting the atmosphere of the Earth. As the atmospheric science community works to design and develop the next generation of these instruments, a need for a model capable of simulating operating performance has arisen. This work is part of a larger effort to develop a complete model for the next generation of Earth radiation budget instruments, the Radiation Budget Instrument (RBI). A primary objective of this effort is to develop a model of a detector to be used on the RBI. The modelling techniques used to characterize the detector are presented in this work. Once the model has been developed, optimal model parameters are determined to tune the model. With these model parameters defined, the detector model can be used, in conjunction with the remaining pieces of the overall end-to-end model, to provide insight for future interpretation of data produced by the RBI.

Gold black porous coatings were thermally evaporated in the chamber backfilled with inert gas pressure and their optical properties were studied in near-far-IR wavelengths. The porosities of coatings were found to be extremely high around ~ 99%. Different approaches of effective medium theories such as Maxwell-Garnett, Bruggeman, Landau-Lifshitz-Looyenga and Bergman Formalism were utilized to calculate refractive index (n) and extinction coefficient (k). The aging induced changes on electrical and optical properties were studied in regular laboratory conditions using transmission electron microscopy, Fourier transform infrared spectroscopy, and fore-probe electrical measurements. A significant decrease in electrical resistance in as deposited coating was found to be consistent with changes in the granular structure with aging at room temperature. Electrical relaxation model was applied to calculate structural relaxation time in the coatings prepared with different porosities. Interestingly, with aging, absorptance of the coatings improved, which is explained using conductivity form of Bergman Formulism. Underlying aim of this work was to utilize gold blacks to improve sensitivity in un-cooled IR sensors consist of pixel arrays. To achieve this, fragile gold blacks were patterned on sub-mm length scale areas using both stenciling and conventional photolithography. Infrared spectral imaging with sub-micron spatial resolution revealed the spatial distribution of absorption across the gold black patterns produced with both the methods. Initial experiments on VOx-Au bolometers showed that, gold black improved the responsivity by 42%. This work successfully establishes promising role of gold black coatings in commercial un-cooled infrared detectors.