A preliminary study shows that Submarine Groundwater Discharge (SGD) exists around Taiwan even though groundwater overdrawing is serious. Only five of the 20 sites studied did not record any SGD signal. Two nearly fresh SGD samples were obtained, providing strong and direct evidence for the existence of SGD in Taiwan. SGD is the submarine seepage of all fluids from coastal sediments into the overlying coastal areas. It has been well documented that SGD may contribute much nutrients to the coasts (Burnett et al.,2001, 2003; Church, 1996; Taniguchi et al., 2002; Zhang and Satake, 2002). Because of its difficulty in measurement, there are few reports on the characteristics of groundwater seepage, such as the flow rate and the water chemistry. In Taiwan, the only report was published in the Japanese journal Geochemistry (Chen et al. , 2005 ). In this study, samples were collected monthly from May, 2004 to June, 2006 at Xiziwan and Caishan in Kaohsiung. A flux chamber was also used in the observation of the SGD seepage rates. Further, samples were collected from 20 different places around Taiwan. The SGD collecting device, the SGD-Flux chamber and the Lee type seepage meter (Zhang et al., 2005) were used in this study, the latter being the first time used to explore the SGD flux in Taiwan. Salinity, dissolved oxygen saturation (%), nutrients (NO3, NO2, PO4, SiO2, NH3), total alkalinity, pH and major ions were analyzed. We averaged all seepage rate data at Xiziwan and Caishan to estimated the SGD seepage rate at about 1.32¡Ó1.57 L/m2/hr. The average concentrations of inorganic nitrogen (NO3+NO2+NH3), PO4 and SiO2 are, respectively, 48.6¡Ó86.3 (n=85), 0.78¡Ó1.26 (n=110) and 55.1¡Ó39.8

Στην παρούσα διπλωματική εργασία πραγματοποιήθηκε επεξεργασία και ανάλυση δεδομένων που συλλέχθηκαν κατά την περίοδο μελέτης της περιοχής της Στούπας στην Νοτιοανατολική Μεσσηνία, στον όρμο της Καλόγριας, με απώτερο στόχο την διερεύνηση του φαινομένου των υποθαλάσσιων εκροών υπογείων υδάτων. / --

In this thesis, the response of uranium minerals and poorly crystalline phases to changes in geochemical conditions through geological time has been assessed in order to understand the mobility of natural uranium in the fracture network of a proposed site for a spent nuclear fuel repository in Forsmark, Sweden. Identification and characterization of solid phase uranium have been performed through electron microprobe analysis and optical petrography (Article I). The identified uraninite, haiweeite, and uranophane crystals have been dated using U-Pb and Pb-Pb isotope ratios obtained from secondary ion mass spectrometry and laser ablation-inductively coupled plasma-mass spectrometry (Article II). The mobility of uranium in current Forsmark groundwaters and fracture system has been modelled using the PHREEQC geochemical program and Ra and Rn isotope systematics (Article IV). The rate of submarine groundwater discharge (SGD) from the Forsmark coast to Öregrundsgrepen has also been modelled using Ra isotopes (Article V). Results from these studies support a geologically early (~1200 Ma) oxidation of U(IV) to U(VI). It is further suggested that the old U(VI) minerals present in the bedrock are soluble at the pe values and alkalinities observed in the Forsmark groundwaters. At pe &lt; −4.6 and alkalinity &lt; 60 mg/L, U(VI) can be reduced to U(IV) and deposited in the fracture network. Although a non-negligible rate of SGD has been observed, this cannot be attributed to the discharge of deep (&gt;200 m.b.s.l.) Forsmark groundwaters on the basis of current data. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 2: Manuscript. Paper 3: In press. Paper 4: Manuscript. Paper 5: Manuscript.</p>

For this dissertation I studied phosphorus (P) sorption dynamics in the shallow groundwater of the southern Everglades. In particular, I examined how the ambient water type governs soluble reactive P (SRP) availability through adsorption/desorption reactions with the aquifer matrix. Chapter 2 investigated how P sorption dynamics of the mangrove root zone sediment are affected by high bicarbonate brackish groundwater compared to both fresh groundwater and saltwater. The results from chapter 2 show that the sediment exhibited exceptionally low sorption efficiency in the high bicarbonate brackish water, which would allow ambient water SRP concentration to be maintained at a higher level. Chapter 3 is a detailed analysis of how P sorption dynamics in two bedrock samples are affected by incremental increases in saltwater content in a freshwater-saltwater transition zone. The results of chapter 3 indicate that a sorption edge occurs at 3 mM Cl- concentration. In water exceeding this Cl- concentration, SRP would be expected to desorb from the bedrock due to a sharp decrease in sorption efficiency between the freshwater saltwater. These results suggest that SRP is active in the ion exchange front of saltwater intrusion, with a rapid increase in SRP availability expected at the leading edge of saltwater intrusion. A landward incursion of 3 mM Cl- concentration water would be expected to raise ambient SRP concentration along the affected aquifer zone, in turn increasing SRP availability in the ecosystem where the transitional waters discharge to the surface. Chapter 4 investigates the kinetics SRP release accompanying saltwater intrusion using a column of carbonate aquifer solids and alternating inflow between fresh groundwater and saltwater. The results show an immediate and high magnitude increase in SRP concentration when saltwater flows into the column. The combined results of this dissertation show that, in the southern Everglades and possibly other carbonate coastlines as well, water type strongly controls P sorption behavior of the sediment and bedrock, and may have a direct influence on the local ecology through increased P availability. A fundamental understanding of the abiotic exchange mechanisms between SRP and the aquifer solids can aid in the successful management and protection of this unique and important ecosystem.

No description available.

The dissertation is comprised of three manuscripts presenting rare earth element (REE) and neodymium (Nd) isotopic analyses for the groundwaters, surface waters, sediments, and bedrocks of two estuaries along the eastern coast of the United States: Indian River Lagoon, Florida, and Pettaquamscutt Estuary, Rhode Island. This research was performed to understand the behavior of REEs in subterranean estuaries, the REE SGD fluxes, and the Nd isotopic composition of SGD. The selection of these sites offers contrasting geology (carbonate/sand matrix aquifer versus glacial till aquifer sourced from granitoids) and contrasting subterranean estuary structure. In the first site, the flux of REEs to the Indian River Lagoon, FL is comprised of a nearshore source of terrestrial SGD displaying a HREE-enriched fractionation pattern, and LREE- and MREE-enriched sources that originate from the reductive dissolution of Fe (III) oxide/hydroxides in the subterranean estuary and transported by bioirrigation to the overlying lagoon. The εNd(0) value the Indian River Lagoon groundwater is much more radiogenic than those of the surface water and sediments which could be due to the use of fertilizers in adjacent communities. The surface waters Nd isotopic composition appears to be a mixture of weathering of the Anastasia Formation and dissolution of eolian-transported Saharan Dust. In contrast at the second site, phosphate minerals control the surface and groundwaters of the Pettaquamscutt estuary, RI. The weathering of apatite and precipitation of secondary REE phosphate minerals most likely produce the MREE-enriched fractionation patterns of the Pettaquamscutt groundwaters. The further precipitation of the secondary REE phosphates in the surface waters of the Pettaquamscutt yields HREE-enriched fractionation patterns. The radiogenic Nd isotopic ratios of the Pettaquamscutt waters relative to the bedrock further suggest that apatite is the source of REEs. The Nd flux of SGD for both sites is roughly equal to the respective river fluxes; however, the Nd flux of SGD to the Pettaquamscutt is approximately 3 times greater than the SGD flux to the Indian River Lagoon. More research is needed in both environments to evaluate the impact of SGD on the Nd isotopic budget of the oceans. / acase@tulane.edu

High latitude mountain environments are experiencing disproportionately adverse effects in a currently changing climate. The Gulf of Alaska (GoA) region is an exemplar of this. Dramatic shifts are occurring in the region’s freshwater reservoirs as glaciers retreat more with each passing year. Research in the region places much focus on observing and predicting climate driven shifts in glacier mass balance, surface discharge, and associated nutrient fluxes to the ocean. On the other hand, coastal groundwater discharge (CGD) is given very little attention. Global and near-global estimates of CGD indicate variable results spanning an order of magnitude. Focusing on regionally specific processes may provide more reliable estimates of CGD and allow isolation of CGD hotspots. This is of particular importance in the GoA region where complex topography, geology, and climate are coupled with recharge derived from rain, snow, and ice. I estimate CGD to the GoA with a water balance that integrates high temporal and spatial resolution recharge inputs and distinguishes between high conductivity surficial deposit and bedrock catchments. I find that CGD contributes nearly 3% of the total freshwater flux to the GoA, equivalent to a mean annual flux of 20.8 km3, and that CGD has been increasing by 0.5%/year over the past 4 decades. Although freshwater discharge to the GOA is well-constrained, the importance of fresh CGD to the GoA has, thus far, been overlooked.

Submarine Groundwater Discharge (SGD) through seafloor sediments is gaining recognition as an important component of coastal water quality. Stratigraphic features creating geologic heterogeneity, such as incised paleochannels, may influence preferential pathways for SGD. The central Mississippi Sound is underlain by paleochannels that were incised into Pleistocene sediments while the area was subaerially exposed during the last glacial maximum and are now buried by transgressive Holocene deposits. In this thesis, newly collected chirp, previously published seismic reflection, and sediment core data are used to characterize the three-dimensional structure of the Holocene-Pleistocene contact. Results indicate that Pleistocene paleochannels cross-cut the study area, exhibiting depths from 7.3–23.4 m, widths from 0.2–2.5 km, infilling with higher acoustic impedance fluvial sediments, and burial by transgressive Holocene sediments. Results suggest that this shallow subsurface stratigraphy may mediate locations of SGD and aid in predicting SGD pathways and associated contaminant loading into the coastal ocean.

Der Zustrom von Grundwasser zu Seen (lacustrine groundwater discharge, LGD) kann signifikante Auswirkungen auf Qualität und Quantität des Seewassers haben. Viele Ansätze zur Identifikation und Quantifizierung von LGD basieren auf Temperaturunterschieden zwischen Grund- und Seewasser und der Messung des damit einhergehenden Wärmetransports. Ziel der Doktorarbeit ist es, Signalfortpflanzung und -ausbreitung des Grundwasserzustroms von der Punktskala an der Sediment-Wasser-Grenzfläche über den Wasserkörper bis zur Grenzfläche Wasseroberfläche-Atmosphäre zu untersuchen. Getestet wird die Hypothese, dass das im Verhältnis zum Umgebungswasser wärmere und daher leichtere Grundwasser in der kalten Wassersäule aufsteigt und die Detektion von LGD an der Wasseroberfläche mit thermalen Infrarot Aufnahmen (TIR) erlaubt. Zunächst wird mit der hierarchical patch dynamics ein Konzept entwickelt, das eine angemessene Kombination multipler Techniken zur Erfassung von Wärme- und Wasserflüssen anbietet (Kap. 2). Dabei werden verschiedene räumliche Skalen und ökohydrologische Grenzflächen abgedeckt. Darauf basierend werden in einem Mesokosmos-Experiment unterschiedliche LGD-Raten durch den Zustrom von warmem Wasser am Grund eines Outdoor-Pools simuliert (Kap. 3 und 4). Ein Glasfaserkabel (fibre-optic distributed temperature sensing, FO-DTS) wird in verschiedenen Tiefen installiert, um das Wärmesignal des Grundwasserzustroms unter verschiedenen Bedingungen zu verfolgen. Mit einer TIR-Kamera wird die Temperatur des Oberflächenwassers aufgezeichnet. Die Aufnahmen werden mit FO-DTS-Temperaturen von 2 cm unter der Wasseroberfläche validiert. Die Anwendung von TIR und FO-DTS ermöglicht die Detektion von LGD in der Wassersäule und an der Grenzfläche Wasseroberfläche-Atmosphäre. Wolkenbedeckung und der Tagesgang der Netto-Strahlung kontrollieren den Auftrieb von LGD und die Zuverlässigkeit der TIR-Ergebnisse. Die besten Ergebnisse werden bei Bewölkung und nachts erzielt. / Lacustrine groundwater discharge (LGD) can have significant impacts on lake water quantity and quality. There is a need to understand LGD mechanisms and to improve measurement methods for LGD. Approaches to identify and quantify LGD are based on significant temperature differences between GW and lake water. The main goal of this PhD thesis is to trace heat signal propagation of LGD from the point scale at the sediment-water interface across the overlying water body to the water surface-atmosphere interface. The PhD thesis tests the hypothesis that the positive buoyancy of warm GW causes upwelling across the cold water column and allows detection of LGD at the water surface by thermal infrared imaging (TIR). First, a general conceptual framework is developed based on hierarchical patch dynamics (HPD). It guides researchers on adequately combining multiple heat tracing techniques to identify and quantify heat and water exchange over several spatial scales and ecohydrological interfaces (Chapter 2). Second, the conceptual framework is used for the design of a mesocosm experiment (Chapters 3 and 4). Different LGD rates were simulated by injecting relatively warm water at the bottom of an outdoor mesocosm. A fiber optic distributed temperature sensing (FO-DTS) cable was installed in a 3D setup in the water column to trace the heat signal of the simulated LGD under different weather conditions and over entire diurnal cycles. Finally, a TIR camera was mounted 4 meters above the mesocosm to monitor water surface temperatures. TIR images were validated using FO-DTS temperature data 2 cm below the water surface (Chapter 4). The positive buoyancy of relatively warm LGD allows the detection of GW across the water column and at the water surface-atmosphere interface by FO-DTS and TIR. Cloud cover and diurnal cycle of net radiation strongly control the upwelling of simulated LGD and the reliability of TIR for detection of LGD at the water surface-atmosphere interface. Optimal results are obtained under overcast conditions and during night.

The feasibility of predicting porewater salinity based on calibrated surface electromagnetic methods is discussed in a coastal wetland on the southern banks of Tampa Bay in West-Central Florida. This study utilizes a new method to float commercial land based electromagnetic (EM) instruments in shallow marine waters of less than 1.5 meters. The floating EM-31 (Geonics, Ltd.) effectively sensed the magnitude and lateral extent of high and low salinity porewaters within mangrove lined ditches and ponds. Resistivity and EM geophysical methods are merged with direct sampling data to calibrate layers in electromagnetic models to infer shallow (<30m) groundwater salinity patterns. Initial marine resistivity surveys are necessary to discriminate between equivalent EM model solutions for seafloor conductivities beneath shallow (0.1-1.5m) marine (~30 ppt) waters. Using formation factors computed from nearby resistivity surveys, porewater conductivity predictions based on surface EM-31 and EM-34 measurements are successful at distinguishing overall porewater salinity trends. At the Tampa Bay study site, the most distinctive terrain conductivity anomalies are associated with mangroves bordering marine waters. Highly elevated porewater conductivities are found within 5m of the mangrove trunks, falling sharply off within 10m, presumably due to saltwater exclusion by mangrove roots. Modeling indicates the shallow water EM-31 measurements probably lack the resolution necessary to image more subtle porewater conductivity variations, such as those expected in association with diffuse submarine groundwater discharge. However, the technique has potential application for locating high contrast zones of freshwater discharge and other salinity anomalies in shallow and nearshore areas not accessible to conventional marine resistivity or land-based arrays, and hence may be useful for interdisciplinary studies of coastal wetland ecosystems.