A dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in partial fulfillment of the requirements for the degree of Master of Science in Hydrogeology. July 2017. / Hydrogeological research was undertaken in the transboundary Ramotswa dolomitic aquifer to provide understanding and quantification of the processes governing recharge mechanism and rates, in order to promote efficient and sustainable groundwater resource utilization and development, as well as to improve the Ramotswa transboundary aquifer management. Hydrochemical and tracer approaches were utilized to evaluate the processes governing the recharge mechanism while the chloride mass balance approach was further applied to assess groundwater recharge rates. Results indicated that all groundwater samples contained detectable amounts of tritium highlighting the renewability of the transboundary Ramotswa aquifer resources. Two distinct water types were characterised: sub-modern waters approximately recharge prior to the 1950s and a mixture of modern and sub-modern waters of recently recharge rainfall indicative of active recharge in the area through intensive rainfall. Correlation between δ18O and δ2H, and soil Cl- indicated that groundwater recharge in the Ramotswa dolomitic aquifer takes place mainly by two flow mechanisms: a displacement of moisture through a diffuse or piston flow through permeable soils and from concentrated runoffs due to surface depressions, and a preferential flow component through fractures that outcrop at surface and riverbed infiltration along the ephemeral Notwane River. Annual groundwater recharge estimates varied from 0.4% MAP to 12% MAP and from 5% MAP to 14% MAP within the northern parts and the southern parts of the study area, respectively. Recharge estimates correlated well with the proposed mechanism of flow both in the southern and in the northern parts of the study area as well as with the previous studies conducted within the greater Ramotswa area. A way forward to ensure the long-term sustainability of the transboundary Ramotswa aquifer resources is recommended, such as to preserve and protect potential recharge areas through carefully controlled land use planning and development, and to equate abstraction rates to average recharge rates, which has to be subjected to the Limpopo Watercourse Commission. / MT2018

The main aim of the project is to investigate the feasibility of artificial recharge of the Bushmans River Mouth Aquifer in the Eastern Cape. The suggested method of recharge is through natural infiltration through a series of wetlands in the back dune area. The proposed site was the Klipfontein Vlei which is located just north of the Bushmans River Mouth. Artificial recharge is defined as augmenting the natural movement of surface water into underground formations by some method of construction, the spreading of water, or by artificially changing natural conditions. A variety of methods have been developed, including water spreading, recharging through pits and wells, and pumping to induce recharge from surface water bodies. The choice of a specific method is controlled by local topography, geology and soil conditions, and the quantity of water to be recharged and ultimate water usage. In special circumstances, land value, water quality, and climate play an important role. Artificial recharge is not a foreign concept to South Africa and this project is to test its feasibility in a back dune wetland area. Augering done in the study area revealed the dominance of sandy loam in the upper layers of the pans, loamy sand in the middle levels and the presence of some sand lenses in the lower reaches. Particle size analysis done by sieving and hydrometer test, showed a dominant 3f fraction. There was variation in modes in pan 1 from unimodal to bimodal to trimodal. Pan 2 showed no variation as all samples were unimodal and moderately well sorted. Infiltration tests were done by a double ring infiltrometer. These results showed that the infiltration rates of the pans became stable after 15 to 20 minutes, thus indicating that the soil had reached its saturation point. The resistivity surveys revealed a stepped water table. The inclination of the water is controlled by the predominately argillaceous horizons of the Bokkeveld Group. Based on the above results, it is recommended that the Klipfontein Vlei be used as an artificial recharge site.

Thesis (MSc)--Stellenbosch University, 2015. / ENGLISH ABSTRACT: Several areas in Namaqualand are affected by elevated levels of salinity; including the shallow alluvial aquifers along the Buffels River catchment. The chemistry of rainwater that recharges these aquifers has low salt-loads, but the groundwater system is very saline. The shallow alluvial aquifers are an important source of water for several communal areas along the river both for domestic and agricultural purposes. Groundwater is also used for the copper and diamond mining activities along the river. Prior to this study, the sources of salinity to the alluvial aquifers and whether salinity can be remediated has not been determined. Possible salinity sources included seawater intrusion, evaporitic salts dissolution, concentrations by evaporation, deep aquifer brines, dissolution of minerals from the aquifer geology as well as salts from anthropogenic activities (i.e. mining). The source(s) of salinity to the groundwater has been determined using the geochemical as well as the isotopic tracers. The ratios of major ions (i.e. Na/Cl) as well the oxygen (18O), hydrogen (2H), 36Cl/Cl, and 87Sr/86Sr isotopes were used in determining the possible solute sources. In addition to these, the chloride mass balance (CMB) method was used to determine the recharge rates to the alluvial aquifers. Furthermore, the groundwater age of the alluvial aquifers was determined using the tritium (3H) isotope. The groundwater samples have high 87Sr/86Sr ratios, which are in the same ranges as the 87Sr/86Sr ratios in the surrounding granitic rocks indicating water-rock interactions. The 36Cl/Cl ratios are low and indicate the dissolution of old salts. The 18O and 2H stable isotopes of groundwater show an evaporative trend with respect to the LMWL, which indicate that groundwater has been evaporated before or during infiltration. Salinity to the shallow alluvial aquifers was found to be mainly derived from the dissolution of rock mass and concentration by evaporation process. The groundwater is relatively young, but there is mixing between old water recharged prior to bomb testing and recently recharged groundwater in some boreholes. The Chloride mass balance (CMB) method assumes atmospheric chloride is the only source of chloride to the aquifers. However, there is additional chloride to these alluvial aquifers from rock mass dissolution. The estimated recharge rates by CMB method (0.1-3.4mm/a) are therefore underestimated. A simulation model was used to determine the recharge rates based on the annual precipitation that will yield the current measured chloride concentrations in the groundwater. Recharge was found to range from 1-5% of the annual precipitation, which is also low. The CMB method therefore gives significant recharge rate estimates, but they are not accurate and need to be supported by another method. / AFRIKAANSE OPSOMMING: Geen opsomming beskikbaar.

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