Dissertation Submitted to the University of the Witwatersrand in the Fulfilment of the Master’s Degree in Geology (Hydrogeology) Faculty of Science University of the Witwatersrand Date: May 2017 / The state of water quality in the Swartkops River catchment in the Uitenhage area, Eastern Cape Province, South Africa, continues to be degraded by anthropogenic activities, which include municipal waste water, industrial waste and agricultural runoff. The study area consists of two aquifers (Swartkops and Coega) that are separated by the fault (Coega fault). In the study area there are two main rivers, namely: Swartkops River and Coega River, which are situated in the Swartkops Aquifer and Coega Aquifer, respectively. Most of the degrading anthropogenic activities are situated in the vicinity of the Swartkops River. The focus of the study was on the pollution of the stream water and aquifer (groundwater), with particular emphasis on the groundwater management. The study objectives were to establish the relationship between groundwater levels and surface topography using Bayesian interpolation method and groundwater and surface water interaction using environmental isotope and hydrogeochemical techniques. The bacteriological assessment was also conducted to determine if hydraulic connections exist between groundwater and the polluted streams. The results of the Bayesian Interpolation Method indicated that there was a strong relationship between the groundwater level elevation and surface topography with the correlation coefficient of 0.9953. The results also indicated that the fault is permeable; hence it did not have influence on groundwater circulation; however, groundwater does not flow from Swartkops River to Coega Aquifer due to groundwater flow gradient. The environmental isotope results indicated that both Swartkops Aquifer and Swartkops River were characterised by heavy isotopes signatures, which indicated the correlation between the two water components. The results further showed that the Swartkops River was recharging the Swartkops aquifer. However, no correlation was established between Swartkops River and Coega aquifer due to flow gradient. Although the flow gradient allows the flow of groundwater from Coega Aquifer to Swartkops Aquifer, Coega aquifer is a Government Water Controlled Area, which could have a very low to none impact on the other aquifer. Piper diagram and stiff diagrams indicated one water type found in the Swartkops and Coega aquifers, which was: Na-Cl type. The water in the Coega aquifer indicated high salinity in the chemical properties, which was typical old marine water derived from deep groundwater source. It was noted that the electrical conductivity values in the Waste Water Treatment Work were closest to those of the Swartkops River and Aquifer, which was in central to those of Coega Aquifer. The bacterial analysis results indicated that during the wet season most of the bacterial counts were high as compared to dry season. It was noted; however, that during the wet season the bacterial counts appeared similar in both aquifers. It is unlikely that the similarities emanated from the interaction of the two aquifers as the analysis of the results indicated that the bacterial counts found in the Coega Aquifer emanated from the farming activities. The study concluded that the fault act as a pathway for migration of groundwater flow. It was established that the groundwater only flows from Coega Aquifer to Swartkops Aquifer due to difference in the hydraulic gradient. / MT 2017

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Hydrogeologists have faced serious challenges worldwide in the characterization of fractured rock aquifers due to the heterogeneous nature of the imbedded geology. The bulk flow parameters in the Karoo strata in South Africa are specifically uncertain since most models are based on homogenous block systems. As part of a WRC research project, entitled “Measurement of the bulk flow and transport characteristics of selected fractured rock aquifer systems in South Africa”, this study focuses on the characterization, borehole drilling, flow parameter measurements and groundwater quality assessment of the Balfour Formation in the Beaufort Group of the Karoo Supergroup in the Eastern Cape, South Africa, which is seriously heterogeneous in deposition and has also been largely neglected as drilling targets for groundwater. The Balfour Formation comprises mostly mudstone, shale and sandstone, formed in a braided and meandering river system. In addition to the heterogeneous deposition, the flow pathways in this aquifer system are not fully understood due to lack of actual measurement data. The methods used in this study include field mapping, site characterization, borehole drilling, and pumping and tracer testing in order to obtain the borehole yield, aquifer transmissivity, storativity and groundwater flow velocity. In addition, the groundwater chemistry was also studied to determine quality for use and possible connectivity with the nearby Tyume River and to determine potential sources of groundwater contamination. The results obtained include: 1) The study area is predominantly mudstone/shale with thin layers and lenses of siltstone and sandstone, which are interbedded; 2) Two boreholes were successfully drilled, which had yields in excess of 10 l/s in four water levels (at 7, 22, 54 and 65 m); 3) The estimated average transmissivity is 246 m 2/day according to the recovery test; 4) The estimated seepage velocity is 120 m/day according to tracer tests in the aquifer between the two boreholes which are 5 m apart; and 5) The water chemical type is the combination of HCO3-, Cl-and SO42- , which is distinguishable from that of the Tyume river; 6) There is no evidence for groundwater recharge to the deep aquifers from the Tyume river, based on the differences of the water chemistry; 7) The elements Ca, Cl, Na and C are distributed more than 90% as free ion species in BH2 borehole water; and 8) The groundwater in BH2 borehole is undersaturated (negative SI) with respect to some minerals (for example: anhydrite, fluorite, gypsum and halite), oversaturated (positive SI) with respect to some minerals (for example: aragonite, calcite and dolomite). It is concluded that there is a great potential to obtain drilling targets for high yielding boreholes in the sedimentary rocks of the Balfour Formation in the Karoo Supergroup.