ALVES, Ana paula Melo. Vermiculitas tratadas quimicamente na obten??o de s?lidos microporosos como precursores para h?bridos inorg?nico-org?nicos com aplica??es adsortivas. 2009. 124 f. Tese (Doutorado em Quimica) - Centro de Ci?ncias Exatas e da Natureza, Universidade Federal da Para?ba, Jo?o Pessoa, PB, 2009. / Submitted by Sonia Leite (sonia@geologia.ufrn.br) on 2010-09-27T16:18:21Z No. of bitstreams: 2 2000Tese_AnaPaulaMAlves.pdf: 2643720 bytes, checksum: 1e6e5bae6c1a2fb7113b073819b6445a (MD5) license_rdf: 19710 bytes, checksum: aa65da15f424ff71c620a992a187295c (MD5) / Rejected by clediane guedes(clediane@bczm.ufrn.br), reason: ALVES dever? est? em mai?sculo on 2010-09-27T18:01:29Z (GMT) / Submitted by Sonia Leite (sonia@geologia.ufrn.br) on 2010-09-27T18:28:33Z No. of bitstreams: 2 2000Tese_AnaPaulaMAlves.pdf: 2643720 bytes, checksum: 1e6e5bae6c1a2fb7113b073819b6445a (MD5) license_rdf: 19710 bytes, checksum: aa65da15f424ff71c620a992a187295c (MD5) / Approved for entry into archive by clediane guedes(clediane@bczm.ufrn.br) on 2010-09-30T12:05:26Z (GMT) No. of bitstreams: 2 2000Tese_AnaPaulaMAlves.pdf: 2643720 bytes, checksum: 1e6e5bae6c1a2fb7113b073819b6445a (MD5) license_rdf: 19710 bytes, checksum: aa65da15f424ff71c620a992a187295c (MD5) / Made available in DSpace on 2010-09-30T12:05:26Z (GMT). No. of bitstreams: 2 2000Tese_AnaPaulaMAlves.pdf: 2643720 bytes, checksum: 1e6e5bae6c1a2fb7113b073819b6445a (MD5) license_rdf: 19710 bytes, checksum: aa65da15f424ff71c620a992a187295c (MD5) / A lixivia??o seletiva de argilominerais ? um m?todo importante na prepara??o de silicatos porosos constituindo-se em uma rota simples, efetiva e de baixo custo. Neste estudo a vermiculita foi submetida a tratamento ?cido com acido n?trico nas concentra??es 1, 2, 3 e 4 mol dm-3, originando os s?lidos precursores denominados VacX (x=1 a 4), respectivamente. As matrizes ativadas e a vermiculita reagiram covalentemente com os organosilanos aminopropil-, propiletilenodiamino-,propildietilenotriamino- e glicid?xipropiltrimetoxissilano (GPTS) atrav?s dos grupos metoxilas do silano e as hidroxilas da superf?cie das matrizes. O h?brido Vac3G, derivado da silaniza??o do Vac3 com GPTS, sofreu rea??es subseq?entes com as diaminas etil, propil, butildiamina e 2-aminopiridina, possibilitando a entrada de novos centros b?sicos. Os diversos s?lidos foram caracterizados por an?lise qu?mica, espectroscopia na regi?o do IV, DRX, RMN 29Si e 27Al, MEV, volume de poro e ?rea superficial. A lixivia??o da vermiculita s?dica originou s?lidos porosos reestruturados com elevadas ?reas superficiais cujos valores foram 133, 334, 673 e 575 m2 g-1 para os s?lidos Vac1, Vac2, Vac3 e Vac4,respectivamente. Independentemente do s?lido, observou-se que ? medida que a lixivia??o se torna mais acentuada, houve um aumento na reatividade das matrizes ativadas em rela??o ? vermiculita original, sendo a matriz Vac3 a mais reativa diante das rea??es aqui propostas. Todos os s?lidos modificados apresentaram altos teores de grupos org?nicos incorporados. A s?rie de vermiculitas modificadas com o grupo aminopropil foi utilizada para a adsor??o de c?tions divalentes de cobre e n?quel em solu??o aquosa, mostrando maior afinidade para os ?ons de Ni2+(aq) do que para Cu2+(aq) como ilustrado pelos valores Nf de 2,97 e 1,23 mmol g-1, respectivamente. Os s?lidos porosos argilosos derivados de tratamento ?cido da vermiculita s?o substratos potenciais para imobiliza??o de silanos apresentando importantes aplica??es como adosrventes para esp?cies poluentes como metais pesados. ABSTRACT: The selective leaching of clay minerals is an important method in the preparation of porous silicates presenting as a simple, effective and low cost route. In this study, vermiculite was submitted to acid treatment at concentrations 1, 2, 3, and 4 mol dm-3, resulting the precursor solids named as VacX (x=1 a 4), respectively. The lixiviated matrices and vermiculite reacted covalently with the organosilanes aminepropyl-, propyletilenediamine-, ropyldietilenetriamine- and glycidoxypropyltrimethoxisilane (GPTS). The hybrid Vac3G, derived from silanization reaction between Vac3 and GPTS, was submitted to subsequent reactions with ethyl, propyl, butyldiamines and 2- aminepiridine resulting in the entrance of new basic centres. The products were characterized by chemical analysis, infrared spectroscopy, X-ray diffraction, 29Si and 27Al NMR in solid state, SEM, and pore volume and surface area determination. The lixiviation of sodic vermiculite originated the restructured porous solids with high superficial area showing the values133, 334, 673 e 575 m2 g-1 for VacX where X = 1,2,3,4, respectively. These solids and sodic vermiculite reacted covalently with each organosilane through methoxyl groups of silane and the hydroxyl surface of matrices. Independently of solid, it was observed that the lixiviation favored the reactivity of activated matrices compared with sodic vermiculite, showing the Vac3 as more reactive comparing with others solids. All modified solids presented high nitrogen content showing the values of 6,31 %. The set of modified vermiculites containing aminepropyl group was applied as adsorbent for divalent cations as copper and nickel in aqueous solution. These solid showed highest affinity for Ni2+ than Cu2+ ions as illustrated by Nf values of 2,97 and 1,23 mmol g-1, respectively. Clay porous solids obtained of leaching treatment of vermiculite are potential substrates for grafting of silanes showing important applications as adsorbents for contaminant species as heavy metals