Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Mathematics, 1979. / Bibliography: leaves 58-59. / by Boris A. Kupershmidt. / Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Mathematics, 1979.

In this dissertation we report on the application of the Liouville Operator Resolvent technique (LRM) to two hamiltonians used to model highly correlated systems: Falicov-Kimball and Anderson Lattice. We calculate specific heats, magnetic susceptibilities, thermal averages of physical operators, and energy bands. We demonstrate that the LRM is a viable method for investigating many body problems. For the Falicov-Kimball, an exact calculation of the atomic limit shows no sharp metal-insulator transition. A truncation approximation for the full hamiltonian has a smooth evolution from the atomic limit with the opening of a band for the conduction electrons. No phase transition was observed. A bose space calculation using the proper boson norm indicates that the conduction band induces a correlation between localized electrons on nearest-neighbor sites. It is not known if this effect is real or a by-product of the approximation. We applied the LRM to the Anderson Lattice and several of its limiting cases. In the limit of no hybridization, for both the symmetric and asymmetric (mixed-valence) parameter sets, we found that the thermodynamics could be described as competition between closely-lying energy levels. The effects that dominate are those that minimize the thermal average of the hamiltonian. A simple model is presented in which only hybridization between two localized orbitals is allowed. It shows that hybridization can give rise to mixed valence phenomena as the temperature approaches zero. For the full Anderson Lattice hybridization causes relatively small shifts in the occupation numbers of the localized and conduction electrons. However, these shifts can have dramatic effects on the physical properties as demonstrated by the magnetic susceptibilities. Band structures of the eigenenergies of the Liouville operator, for both parameter sets, reveal that low-lying excitations associated with some of the basis vector operators may split out from the fermi level and become significant at low temperatures. In addition, we report on progress toward extending the calculation to bose space using a commutator norm. / Ph. D. / incomplete_metadata

In this work, we investigate the spectrum of the non-relativistic Krönig-Penney Hamiltonian H_α= -d²/dx² +αΣ_m∈Zδ(-(2m+1)π) perturbed by a short-range potential λW and the spectrum of its relativistic counterpart obtained by replacing the Schrödinger Hamiltonian H_α with its relativistic analogue H̅_α. The interesting feature of both spectra is that they have gaps and that bound states may occur in such gaps as a consequence of the presence of the short-range potential representing the impurity. Such bound states, often called "impurity states" in the solid state physics literature. are important with regard to the conductivity properties of solids We show the existence of such bound states of H_α + λW in each sufficiently remote gap of its essential spectrum if the integral of W is different from zero and the 1 + 𝛅-moment of W is finite for some 𝛅 > 0. Furthermore, if the potential has a constant sign we prove that there is only one bound state in each sufficiently remote gap. We shall see that in the relativistic case one may have more than one bound state in each remote gap under the same assumptions on W. Nevertheless, we shall see that such additional bound states cannot appear in the range of energies of solid state physics. / Ph. D.

In this paper we derive the eigenfunctions to the Hamiltonian operator associated with the Harmonic Oscillator, and show that they are given by the Hermite functions. Then we prove that the Hermite functions form an orthonormal basis in the underlying Hilbert space. We also classify the inverse to the Hamiltonian operator as a Schatten-von Neumann operator. Finally, we derive the fundamental solution to the Schrödinger Equation corresponding to the Harmonic Oscillator using Mehler’s formula.