In recent years carbon dioxide (CO2, R-744)has moved to the foreground as an environmentally friendly alternative to commonly used CFCs and HFCs, which are being phased out due to its high ozone depleting and global warming potentials. R-744 is not only environmentally friendly but due to its unique properties, it is also ideally suited for the use in heat pump water heaters. High cycle efficiencies are achievable even at high hot water temperatures. The high cycle efficiency not only leads to energy and cost savings but also ties in with the drive for implementation of energy saving measures in South Africa. It is therefore paramount to continue development and implementation of R-744 in heat pump water heaters. Optimizing the cycle efficiency is only possible if detailed component simulation models, taking these unique properties of R-744 into account, are available. The purpose of this study therefore was to develop a detail simulation model of a concentric tube-in-tube water-to-refrigerant evaporator, as well as a fin-and-tube air-to-refrigerant evaporator model. Data from the North-West University R-744 heat pump test bench were used to verify the tube-in-tube evaporator simulation model. The discrepancies in the cooling capacity between the simulation and test bench can be attributed to the presence of lubricant in the system.The fin-and-tube model was verified by testing it against the NIST program EVAP-COND (NIST 2010). Overall there was good agreement between the results of the two programs, with EVAP-COND predicting a lower cooling capacity(6% to 14%) and and a higher pressure refrigerant pressure drop (30% to 50%). It was found that both the heat transfer correlation of Jung et al. (1989) and the pressure drop correlation of Choi et al. (1999) are able to predict the experimental values accurately and are valid for use in both the evaporator models developed. To demonstrate the use of the detail evaporator fin-and-tube model, an evaluation of the different tube geometries, commercially available in South Africa, for use with R-744 fin-and-tube evaporators was done. For a fin-and-tube evaporator it was found that the most cost effective option is to use ⅜" (10.05 mm)copper tubes and the least effective is " (12.6 mm) stainless steel tubes. / Thesis (MIng (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2013.

In recent years carbon dioxide (CO2, R-744)has moved to the foreground as an environmentally friendly alternative to commonly used CFCs and HFCs, which are being phased out due to its high ozone depleting and global warming potentials. R-744 is not only environmentally friendly but due to its unique properties, it is also ideally suited for the use in heat pump water heaters. High cycle efficiencies are achievable even at high hot water temperatures. The high cycle efficiency not only leads to energy and cost savings but also ties in with the drive for implementation of energy saving measures in South Africa. It is therefore paramount to continue development and implementation of R-744 in heat pump water heaters. Optimizing the cycle efficiency is only possible if detailed component simulation models, taking these unique properties of R-744 into account, are available. The purpose of this study therefore was to develop a detail simulation model of a concentric tube-in-tube water-to-refrigerant evaporator, as well as a fin-and-tube air-to-refrigerant evaporator model. Data from the North-West University R-744 heat pump test bench were used to verify the tube-in-tube evaporator simulation model. The discrepancies in the cooling capacity between the simulation and test bench can be attributed to the presence of lubricant in the system.The fin-and-tube model was verified by testing it against the NIST program EVAP-COND (NIST 2010). Overall there was good agreement between the results of the two programs, with EVAP-COND predicting a lower cooling capacity(6% to 14%) and and a higher pressure refrigerant pressure drop (30% to 50%). It was found that both the heat transfer correlation of Jung et al. (1989) and the pressure drop correlation of Choi et al. (1999) are able to predict the experimental values accurately and are valid for use in both the evaporator models developed. To demonstrate the use of the detail evaporator fin-and-tube model, an evaluation of the different tube geometries, commercially available in South Africa, for use with R-744 fin-and-tube evaporators was done. For a fin-and-tube evaporator it was found that the most cost effective option is to use ⅜" (10.05 mm)copper tubes and the least effective is " (12.6 mm) stainless steel tubes. / Thesis (MIng (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2013.

Taking into account the expected increase in global energy demands and increasing climate change issues, there is a pressing need to develop new environmentally sustainable energy systems. Nuclear energy will play a major role in being part of the energy mix since it offers a relatively clean, safe and reliable source of electrical energy. However, opportunities for building new generation nuclear systems will depend on their economic and safety attractiveness as well as their flexibility in design to adapt in different countries and situations. Keeping these objectives in mind, a framework for international cooperation was set forth in a charter of Generation IV International Forum (GIF) (GIF Charter, 2002) and six design concepts were selected for further development. To achieve high thermal efficiencies of up to 45 ??? 50%, the use of SuperCritical Fluids (SCFs) as working fluids in heat transfer cycles is proposed Generation IV designs. An important aspect towards development of SCF applications in novel Gen IV Nuclear Power Plant (NPP) designs is to understand the thermodynamic behavior and prediction of Heat Transfer Coefficients (HTCs) at supercritical (SC) conditions. In addition to the nuclear power industry applications; SCFs are also expected to play a vital role in a number of other important technologies such as refrigeration systems, and geothermal systems, to name a few. Given the potential for vast number of applications of SCFs in industry, the objective of this work was to gain an understanding on the behavior of SCFs and to develop a fundamental knowledge of the heat-transfer processes and correlations for SC Water and SC CO2 flowing in bare circular tubes. Experimental datasets for SC Water and SC CO2 were compiled and used to obtain a basic 1-D empirical correlation that can predict HTC in bare circular tubes during the transient phases. The accuracy of these correlations was also analyzed using statistical techniques. Limitations and applications for 1-D correlations are discussed as well. The new correlations showed promising results for HTC and Tw calculations for the reference dataset with uncertainty of about ??25% for HTC values and about ??10-15% for the calculated wall temperature.