In this work the alkylation of 4,6-dimethylpyrimidin-2(1H)-thione with ethyl bromoalkanoates was described. It was found the reactions in the present of potassium carbonate in boiling acetonitrile gave rise to corresponding S-alkylated derivatives. Under treatment of ethyl 2-(4,6-dimethyl-2-pirimidinylthio)alkanoates with excess of hydrazine hydrate the corresponding hydrazides were prepared. Further refluxing with aromatic monocarbonylic compounds led to formation of corresponding hydrazones. By the spectral data hydrazones exist as mixtures of E/Z conformers. The purity of the synthesized compounds was controlled by thin layer chromatography. The structure was proved by 1H NMR, IR and UV spectra.

Darbo tikslas buvo skyles pernešančių organinių junginių,gebančių efektyviai tinklintis ar fotopolimerizuotis, sintezė.

The aims of the work were as follows: • synthesis of branched dimers with stable amorphous state possessing tiophenylsulphide, sulphide and hydroxygroups in the linking fragment of chromophores from aromatic and heteroaromatic alde6 hyde phenylhydrazones. A thorough study of physical and optoelectrographic properties of these charge-transporting compounds; • synthesis of new crosslinkable charge transporting molecular glasses exhibiting high charge carrier mobilities, high morphological stability; • design and synthesis of new hole transporting molecular glasses and polymers (from 9-(2,3-epoxypropyl)carbazole); • investigation of the interaction of 1(2)-aminoanthraquinone and 1- chloro-2,3-epoxypropane (CEP) with the aim to use the products for the creation of hydroxygroups possessing electron-transporting materials, having stable amorphous state.