An improved knowledge of wood material behavior in hot-pressing environments can provide the benefit of an increased understanding of material properties during the manufacture of wood-based composites as well as insight into the development of new processes and products which manipulate the viscoelastic nature of wood. Two specific areas where additional knowledge is needed are: the high temperature equilibrium moisture content (EMC) behavior and the moisture dependent softening behavior. EMC data was collected and desorption isotherms were generated for mature and juvenile wood of aspen, loblolly pine and yellow-poplar at 50 and 160°C. High temperature EMC behavior was found to be distinct from that at lower temperatures, and considerable differences between the isotherms for juvenile and mature wood were detected. Substantial thermal degradation was observed during desorption at 160 °C and found to be strongly influenced by relative humidity. The thermal softening behavior of wood was evaluated using dielectric thermal analysis (DETA) at moisture levels from 0 to 20 percent. Coincident in situ relaxations of hemicellulose and amorphous cellulose in the range of 20 to 200 °C were observed and found to exhibit the characteristics of a secondary (glass) transition. The moisture dependence of this transition was characterized, and differences in the observed Tg were detected between juvenile and mature wood. Time-temperature superposition was also shown to be applicable to the wood-water system. / Ph. D.

Since 2000, stripe rust, caused by the fungal pathogen (Puccinia striiformis Westend. f.sp. tritici Eriks.) has resulted in yield losses of wheat (Triticum aestivium L.) in the United States, that exceeded the combined losses of leaf rust (Puccinia triticina Eriks.) and stem rust (Puccinia gramins Pers.:Pers f. sp. Tritici Eriks. E. Henn.). The objectives of this study are to identify and map adult plant stripe rust resistance quantitative trait loci (QTL) in soft red winter (SRW) wheat that are effective against race PST-100, which is the predominant race of the pathogen in the eastern U.S. Adult plant resistance (APR) was characterized in the resistant wheat lines "USG 3555", VA00W-38, and "Coker 9553". Resistance in each of the lines was evaluated in populations derived from crosses with susceptible lines "Neuse", Pioneer Brand "26R46", and VA01W-21, respectively. On chromosomes 1AS, 4BL, and 7D of USG 3555, QTL were identified that explain on average 12.8, 73.0, and 13.6 percent of the variation for stripe rust infection type (IT), and 13.5, 72.3, and 10.5 percent of the variation for stripe rust severity. A QTL from Neuse was identified on 3A that on average explains 10.9 percent of the variation for IT and 13.0 percent of the variation for severity. On chromosomes 2AS and 4BL of VA00W-38, QTL were identified that on average explain 58.9 and 19.3 percent of the variation for stripe rust IT, and 51.9 and 12.1 percent of the variation for severity. On chromosomes 6BL and 3BL of Pioneer 26R46, QTL were identified that on average explain 8.9 and 2.1 percent of the variation for IT and 11.7 and 3.9 percent of the variation for severity. Coker 9553 possesses the QTL on 4BL that is also present in USG 3555 and VA00W-38. The SSR markers, Xgwm296, Xbarc163, and Xwmc756 were tightly linked to QTL on chromosomes 2AS, 4BL, and 6BL, respectively, and their use and development of additional diagnostic markers will facilitate the incorporation and pyramiding of stripe rust resistance QTL into SRW wheat lines via marker-assisted selection. / Ph. D.

Heat flux gages are important in applications where measurement of the transfer of energy is more important than measurement of the temperature itself. There is a need for a heat flux sensor that can perform reliably for long periods of time in high temperature and high heat flux environment. The primary objective is to design and build a heat flux sensor that is capable of operating for extended periods of time in a high heat flux and high temperature environment. A High Temperature Heat Flux Sensor (HTHFS) was made by connecting 10 brass and steel thermocouple junctions in a thermopile circuit. This gage does not have a separate thermal resistance layer making it easier to fabricate. The HTHFS was calibrated in a custom-made convection calibration facility using a commercial Heat Flux Microsensor (HFM) as the calibration standard. The measured sensitivity of the HTHFS was 20.4 ±2.0ìV/(W/cm2). The measured sensitivity value matched with the theoretically calculated value of 20.5 ìV/(W/cm2). The average sensitivity of the HTHFS prototype was one-fifth of the sensitivity of a commercially available HFM. Better ways of mounting the HTHFS in the calibration stand have been recommended for future tests on the HTHFS for better testing. The HTHFS has the potential to be made into a microsensor with thousands of junctions added together in a thermopile circuit. This could lead to a heat flux sensor that could generate large signals (~few mV) and also be capable of operating in high heat flux and high temperature conditions. / Master of Science

Temperature sensing in harsh environment is desired in many areas, such as coal gasification, aerospace, etc. Single crystal sapphire is an excellent candidate for construction of harsh environment sensors due to its superior mechanical and optical properties even at temperature beyond 1600°C. The temperature inside a coal gasifier can be as high as 1200°C. And there is dramatic temperature gradient between the inner and outer layers of the gasifier refractory. Previous work has been done at Virginia Tech's Center for Photonics Technology to design and fabricate a sapphire wafer based Fabry-Perot interferometer (FPI) sensor for temperature sensing in coal gasifiers. The sensor head is based on the use of sapphire wafer which is attached to a lead-in sapphire fiber to be applied in the ultrahigh temperature region; and the sapphire fiber is spliced to a multi-mode fused silica fiber for quality signal transmission in lower temperature areas. One of the challenges encountered by this approach is the shear force to the sapphire fiber, which is caused by the differential thermal expansion between the inner and outer layers of the gasifier refractory. This shear force may be so significant to break the sensor probe. This thesis proposed a free space based interrogation sensing system to address that problem. In this free space based interrogation sensing system, only the sensor head is placed in the inner refractory wall, while all the other parts of the system are placed in the outer refractory or outside the gasifier at the ambient room temperature. An optical frequency domain reflectometry (OFDR) based multiplexed technique is applied in the sensor design to realize temperature measurement at multiple locations along the optical path. In this work, three sapphire wafers based multiplexed temperature sensor is fabricated and calibrated in laboratory. This multiplexed high temperature sensor shows linear response in the range of 20°C ~ 1000°C, with a sensitivity of 1.602?10??/°C and a resolution of 1.3°C. / Master of Science

The thermocouple systems used for the measurement of surface temperature in high temperature applications such as advanced aerospace propulsion systems and diesel engine systems are expected to perform in rapidly fluctuating and extremely high heat fluxes corresponding to high temperatures (in excess of 1400 K) and high speed flows. Traditionally, Pt/Pt-Rh based thin film thermocouples have been used for surface temperature measurements. However, recent studies indicated several problems associated with these thermocouples at temperatures exceeding 1000 K, some of which include poor adhesion to the substrate, rhodium oxidation and reaction with the substrate at high temperatures. Therefore, there is an impending demand for thermoelectric materials that can withstand severe environments in terms of temperature and heat fluxes. In this study, thin films of titanium carbide and tantalum carbide as well as two families of conducting perovskite oxides viz., cobaltites and manganates (La(1-x)SrxCoO3, M(1-x)Cax MnO3 where, M=La,Y) were investigated for high temperature thin film thermocouple applications as alternate candidate materials. Thin films of the carbides were deposited by r.f. sputtering while the oxide thin films were deposited using pulsed laser ablation. Sapphire (1102) was used as substrate for all the thin film depositions. All the thin films were characterized for high temperature stability in terms of phase, microstructure and chemical composition using x-ray diffraction, atomic force microscopy and electron spectroscopy for chemical analysis respectively. Electrical conductivity and seebeck coefficients were measured in-situ using a custom made device. It was observed that TiC/TaC thin film thermocouples were stable up to 1373 K in vacuum and yield high and fairly stable thermocouple output. The conducting oxides were tested in air and were found to be stable up to at least 1273 K. The manganates were stable up to 1373 K. It was observed that all the oxides studied crystallize in a single phase perovskite structure. This phase is stable up to annealing temperatures of 1373 K. The predominant electrical conduction mechanism was found to be small polaron hopping. Stable and fairly high electrical conductivities as well as seebeck coefficients accompanied with phase, structure, composition and microstructure stability indicate that these materials hold excellent promise for high temperature thin film thermocouple applications. / Master of Science

Infrared sensor satellites are used to monitor the conditions in the earth's upper atmosphere. In these systems, the electronic links connecting the cryogenically cooled infrared detectors to the significantly warmer amplification electronics act as thermal bridges and, consequently, the mission lifetimes of the satellites are limited due to cryogenic evaporation. High-temperature superconductor (HTS) materials have been proposed by researchers at the National Aeronautics and Space Administration Langley's Research Center (NASA-LaRC) as an alternative to the currently used manganin wires for electrical connection. The potential for using HTS films as thermal bridges has provided the motivation for the design and the analysis of a spaceflight experiment to evaluate the performance of this superconductive technology in the space environment The initial efforts were focused on the preliminary design of the experimental system which allows for the quantitative comparison of superconductive leads with manganin leads, and on the thermal conduction modeling of the proposed system (Lee, 1994). Most of the HTS materials were indicated to be potential replacements for the manganin wires. In the continuation of this multi-year research, the objectives of this study were to evaluate the sources of heat transfer on the thermal bridges that have been neglected in the preliminary conductive model and then to develop a methodology for the estimation of the thermal conductivities of the HTS thennal bridges in space. The Joule heating created by the electrical current through the manganin wires was incorporated as a volumetric heat source into the manganin conductive model. The radiative heat source on the HTS thermal bridges was determined by performing a separate radiant interchange analysis within a high-Tc superconductor housing area. Both heat sources indicated no significant contribution on the cryogenic heat load, which validates the results obtained in the preliminary conduction model. A methodology was presented for the estimation of the thermal conductivities of the individual HTS thermal bridge materials and the effective thermal conductivities of the composite HTS thermal bridges as functions of temperature. This methodology included a sensitivity analysis and the demonstration of the estimation procedure using simulated data with added random errors. The thermal conductivities could not be estimated as functions of temperature; thus the effective thermal conductivities of the HTS thermal bridges were analyzed as constants. / Master of Science

The physical and optical properties of sapphire fiber has been investigated in an effort to create a high temperature optical fiber sensor. Sapphire fiber demonstrates high optical attenuation. This attenuation is very sensitive to injection conditions, and roughly proportional to the cube of the fiber length. The loss was found to be largely due to surface scattering, which causes the fiber to deviate from a perfect cylindrical waveguide. Because of the high optical losses (and high cost) of sapphire fiber, it is desirable to fashion a splice between the sapphire and an inexpensive, low-loss silica fiber so that sapphire is only used in the sensor head. The great physical disparities between sapphire and silica make this a challenging proposition. One solution demonstrated here is the sapphire capillary tube splice, in which the two fibers are aligned in a sapphire capillary tube and bound together with alumino-silicate glass. Sapphire fiber optical sensors cannot use standard interferometric techniques used with silica fibers because sapphire fibers are not clad, making a strongly guiding, highly multimode waveguide that introduces a great deal of modal distortion to interferometric signals. Consequently a simple intensity-based sensor was developed and tested using sapphire. More exotic intensity-based sensors are explored with their applicability to a sapphire fiber sensor head. / Master of Science

Infrared sensor satellites, which consist of cryogenic infrared sensor detectors, electrical instrumentation, and data acquisition systems, are used to monitor the conditions of the Earth's upper atmosphere in order to evaluate its present and future changes. Currently, the electrical instrumentation (connections), which act as thermal bridges between the cryogenic infrared sensor and the significantly warmer data acquisition unit of the sensor satellite system, constitute a significant portion of the heat load on the cryogen. As a part of extending the mission life of the sensor satellite system, the researchers at the National Aeronautics and Space Administration's Langley Research Center (NASA-LaRC) are evaluating the effectiveness of replacing the currently used manganin wires with high-temperature superconductive (HTS) materials as the electrical connections (thermal bridges). In conjunction with the study being conducted at NASALaRC, the proposed research is to design a space experiment to determine the thermal savings on a cryogenic subsystem when manganin leads are replaced by HTS leads -printed onto a substrate with a low thermal conductivity, and to determine the thermal conductivities of HTS materials. / Master of Science

With the increasing use of aluminum in naval vessels and the ever-present danger of fires, it is important to have a good understanding of the behavior of aluminum at elevated temperatures. The aluminum samples 5083-H116 and 6061-T651 were examined under a variety of loading conditions and temperatures. Tensile testing was completed on both materials to measure strength properties of elastic modulus, yield strength, and ultimate strength as well as reduction of area from room temperature to 500 deg C taking measurements every 50 deg C. These tests showed how much the material weakened as temperature increases. Low temperatures had a minimal effect on strength while exposure to temperatures between 200 and 300 deg C had the most significant impact. Creep testing was also completed for these materials. These tests were completed at temperatures between 200 and 400 deg C in 50 deg C increments. Stresses for these tests were in the range of 13 to 160MPa for 5083 aluminum and between 13 to 220MPa for 6061 aluminum. These tests showed a significant relationship between stress and temperature and how changes to one can cause a very different resulting behavior. In addition to the creep testing, three creep models were examined as a means of predicting creep behavior. These models included a power law, exponential, and hyperbolic-sine versions and were able to predict creep results with decent accuracy depending on the stress used in the model. / Master of Science

Particle ingestion and deposition is an issue of concern for gas turbine engines operating in harsh environments. The ingested particles accelerate the deterioration of engine components and thus reduce its service life. This effect is observed to a greater extent in aircrafts/helicopters operating in particle laden environment. Understanding the effects of particle ingestion at engine representative condition leads to improved designs for turbomachinery. Experiments have been in an Aerothermal Rig facility at Virginia Tech to study particle deposition at engine representative temperatures. The Aerothermal Rig was upgraded to achieve air temperatures of up to 1100°C at the test section. The experiments are performed using Arizona Road Dust (ARD) of 20-40 μm size range. The temperature of air and particles are around 1100°C at a constant velocity of 70 m/s. The target coupon is made of Hastelloy X, a nickel-based alloy and the angle at which the particles impact the coupon varies from 30° to 80°. The experiments were performed with different amounts of total particle injected, concentration, and coupon angle to understand their effects on deposition. Similar research was carried out in the past at the same facility to study particle deposition at temperatures up to 1050°C and 70 m/s flow velocity. However, this previous research only studied how the coupon angle affects particle deposition; other parameters such as total particle input and particle concentration were not studied. It was found that particle deposition increases significantly at higher temperatures beyond 1050°C for higher coupon angle and amount of sand injected. Results from current study also show that deposition increases with increase in total sand injected, concentration, and coupon angle for a given temperature and velocity. / Master of Science