Nonpoint source (NPS) pollution is possibly the greatest form of contamination to our nation's waters. Nutrient pollutants, such as nitrate and ammonium, often enter aquatic ecosystems through surface and subsurface hydrological transport that drain agricultural watersheds. The over-abundance of nitrogen within these watersheds is easily transported to receiving stream and rivers, and result in aquatic ecosystem degradation. In response to the problem of nutrient loading to aquatic ecosystems, ecosystems scientists and federal and state governments have recommended the use of streamside management zones (SMZ) to reduce the amount of NPS pollutants. A small agricultural watershed in southwestern North Carolina was utilized to quantify subsurface transport of nitrate and ammonium to a naturally developing riparian area along Cartoogechaye Creek. Vertical and lateral transport of nitrate and ammonium were measured along three transect perpendicular to the stream. Transects were instrumented with time domain reflectometry (TDR) and porous cup tension lysimeters to monitor soil water and nutrient flux through the pasture and riparian area located at the base of the watershed. The HYDRUS 2-D flow and transport model was used to predict and simulate subsurface flow. Predicted flow was coupled with observed field nutrient data to quantify nutrient flux as a function of slope location. HYDRUS 2-D was capable of simulating subsurface flow (saturated and unsaturated) as a function of observed soil physical properties (bulk density, saturated hydraulic conductivity, particle size distribution, water retention characteristics) and climatic data (precipitation, air temperature, wind speed, etc.). The riparian area was effective in reducing the amount of nonpoint source pollution to a naturally developing riparian area from an agricultural watershed. Dramatic decreases in both NO3- -N and NH4+ -N in upland pasture water were observed within the riparian area. Seasonal percent reductions of NO3- from the pasture to riparian area in subsurface water within the study watershed are as follows: summer (2002) = 456%; fall (2002) = 116%; winter (2003) = 29%; spring = 9%, pasture and riparian, respectively. / Master of Science

京都大学 / 新制・課程博士 / 博士(工学) / 甲第25247号 / 工博第5206号 / 新制||工||1994(附属図書館) / 京都大学大学院工学研究科社会基盤工学専攻 / (主査)教授 佐山 敬洋, 教授 田中 賢治, 教授 市川 温 / 学位規則第4条第1項該当 / Doctor of Agricultural Science / Kyoto University / DFAM

Thesis (MScAgric)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: Hillslope hydrology represents a complex system with several interacting processes influencing the movement of water through the landscape. The Western Cape area of South Africa is expected to be impacted on by a change in climate and the importance of water management that will increase in the future. Climate, especially precipitation, is the driving factor behind the hydrological system and there are currently no predictions as to what the impact will be on the hydrological conditions. The main objective of the study is to understand the hydrological responses along a hillslope and secondly to determine the effect of climate change on the hydrology by using hydrological models. The studied system is situated on the Langgewens Experimental Farm, north of Malmesbury in the Swartland region of the Western Cape. Six sites in a range of vegetation, land use and expected soil types along a toposequence were investigated. All sites are rain fed areas with natural vegetation, seasonal or long-term shrubs. Through monitoring different components of the hydrological cycle, including rainfall, overland flow, infiltration, soil water content, base flow and water table depth at the different sites, the movement of water through the landscape can be defined. Hillslope hydrological processes at different positions on the hillslope were investigated. The baseline data obtained during this process was used in hydrological modelling for the different positions on the hillslope to determine the accuracy of model predictions. Expected future climatic conditions were emulated in this model to determine the possible effect of a change in climate on the hydrological system. The research confirmed the complex interaction between different processes within the hydrological system. At each point along the toposequence different components of the hydrological cycle contributed on a different scale to the hydrological system. Soil properties were the most significant factor influencing water movement through the landscape, directly impacting infiltration, overland flow, lateral water flow and deep percolation. This resulted in water table fluctuations through the seasons as the contribution of different components towards the hydrological cycle changed. By comparing soil water content measurements through the season with modelled water content levels, accurate hydrological models were created for different measuring points in the landscape. By using forecasted climate data of two different weather generators, accurate estimations of expected soil water content were possible. This indicated that droughts will occur on a regular basis in the future. This research made it possible to understand water movement through the landscape at hillslope level and contributed towards future water management plans by estimating future soil water content levels based on current predictions. / AFRIKAANSE OPSOMMING: Heuwelhang hidrologie omskryf die proses van water beweging deur die landskap en dit word deur verskeie prosesse beinvloed. Onder huidige toestande word verwag dat die Weskaap provinsie van Suid-Afrika warmer en droëer sal word in die toekoms as gevolg van klimaatsverandering. Dit sal die noodsaaklikheid van effektiewe waterbestuur verhoog in die toekoms. Klimaat, en in besonder reënval, is die dryfkrag agter die hidrologiese sisteem en huidiglik is daar geen aanduiding van wat die effek van klimaatsverandering op die hidrologiese sisteem gaan wees nie. Die eerste doel van die studie is om die heuwelhang se hidrologiese sisteem te ontleed en tweedens om die impak van klimaatsverandering op die hidrologiese sisteem te bepaal deur gebruik te maak van hidrologiese modelle. Die studie area is geleë op die Langgewens Proefplaas, noord van Malmesbury in die Swartland distrik van die Weskaap. Ses verskillende posisies is op die heuwelhang geselekteer op grond van posisie in die landskap, plantegroei, landgebruik en verwagte grondvorms. Al die studiepunte ontvang slegs water deur reën en die landgebruik wissel ten opsigte van natuurlike plantegroei, en eenjarige- of meerjarige gewasse wat gevestig is. Deur verskillende komponente van die hidrologiese sisteem te monitor, insluitend reënval, oppervlak afloop, infiltrasie, grond water inhoud, laterale water vloei en die diepte van die watertafel, kan die beweging van water deur die landskap gedefinieër word. Die data wat versamel is gedurende die proses word gebruik om die akkuraatheid van die hidrologiese modelle se resultate te bepaal. Tesame met vooruitgeskatte klimaatdata kan die modelle gebruik word om die impak van klimaatsverandering op grondwater toestande vas te stel. Die navorsing toon die komplekse interaksie tussen verskillende prosesse in die hidrologiese sisteem. By elke punt in die landskap dra verskillende komponente op verskillende skale by tot die hidrologiese sisteem. Grondeienskappe het die meeste invloed op die verskillende komponente van die hidrologiese sisteem en beïnvloed die infiltrasie, oppervlak afloop, laterale water vloei en diep dreinering. Soos die verskillende komponente se bydrae tot die hidrologiese sisteem verander, vind daar fluktuasies in die diepte van die water tafel plaas. Deur die vergelyking van gemete grondwaterinhoud teen hidrologiese model voorspelde grondwaterinhoude, is akkurate hidrologiese modelle opgestel vir verskillende punte in die landskap. Deur gebruik te maak van twee moontlike verwagte klimaat toestande, is gevind dat droogtes op ‘n roetine basis in die toekoms sal voorkom. Die navorsing maak dit moontlik om die beweging van water deur die landskap te verstaan en dra by tot die opstelling van toekomstige waterbestuur planne. Dit word moontlik gemaak deur die vooruitskatting van grondwater inhoude gebasseer op verwagte klimaatsveranderinge en huidige grondwater toestande. / Water Research Commission

abstract: Ponderosa pine forests are a dominant land cover type in semiarid montane areas. Water supplies in major rivers of the southwestern United States depend on ponderosa pine forests since these ecosystems: (1) receive a significant amount of rainfall and snowfall, (2) intercept precipitation and transpire water, and (3) indirectly influence runoff by impacting the infiltration rate. However, the hydrologic patterns in these ecosystems with strong seasonality are poorly understood. In this study, we used a distributed hydrologic model evaluated against field observations to improve our understandings on spatial controls of hydrologic patterns, appropriate model resolution to simulate ponderosa pine ecosystems and hydrologic responses in the context of contrasting winter to summer transitions. Our modeling effort is focused on the hydrologic responses during the North American Monsoon (NAM), winter and spring periods. In Chapter 2, we utilized a distributed model explore the spatial controls on simulated soil moisture and temporal evolution of these spatial controls as a function of seasonal wetness. Our findings indicate that vegetation and topographic curvature are spatial controls. Vegetation controlled patterns during dry summer period switch to fine-scale terrain curvature controlled patterns during persistently wet NAM period. Thus, a climatic threshold involving rainfall and weather conditions during the NAM is identified when high rainfall amount (such as 146 mm rain in August, 1997) activates lateral flux of soil moisture and frequent cloudy cover (such as 42% cloud cover during daytime of August, 1997) lowers evapotranspiration. In Chapter 3, we investigate the impacts of model coarsening on simulated soil moisture patterns during the NAM. Results indicate that model aggregation quickly eradicates curvature features and its spatial control on hydrologic patterns. A threshold resolution of ~10% of the original terrain is identified through analyses of homogeneity indices, correlation coefficients and spatial errors beyond which the fidelity of simulated soil moisture is no longer reliable. Based on spatial error analyses, we detected that the concave areas (~28% of hillslope) are very sensitive to model coarsening and root mean square error (RMSE) is higher than residual soil moisture content (~0.07 m3/m3 soil moisture) for concave areas. Thus, concave areas need to be sampled for capturing appropriate hillslope response for this hillslope. In Chapter 4, we investigate the impacts of contrasting winter to summer transitions on hillslope hydrologic responses. We use a distributed hydrologic model to generate a consistent set of high-resolution hydrologic estimates. Our model is evaluated against the snow depth, soil moisture and runoff observations over two water years yielding reliable spatial distributions during the winter to summer transitions. We find that a wet winter followed by a dry summer promotes evapotranspiration losses (spatial averaged ~193 mm spring ET and ~ 600 mm summer ET) that dry the soil and disconnect lateral fluxes in the forested hillslope, leading to soil moisture patterns resembling vegetation patches. Conversely, a dry winter prior to a wet summer results in soil moisture increases due to high rainfall and low ET during the spring (spatially averaged 78 mm ET and 232 mm rainfall) and summer period (spatially averaged 147 mm ET and 247 mm rainfall) which promote lateral connectivity and soil moisture patterns with the signature of terrain curvature. An opposing temporal switch between infiltration and saturation excess runoff is also identified. These contrasting responses indicate that the inverse relation has significant consequences on hillslope water availability and its spatial distribution with implications on other ecohydrological processes including vegetation phenology, groundwater recharge and geomorphic development. Results from this work have implications on the design of hillslope experiments, the resolution of hillslope scale models, and the prediction of hydrologic conditions in ponderosa pine ecosystems. In addition, our findings can be used to select future hillslope sites for detailed ecohydrological investigations. Further, the proposed methodology can be useful for predicting responses to climate and land cover changes that are anticipated for the southwestern United States. / Dissertation/Thesis / Ph.D. Geological Sciences 2012

The Sub artic regions are becoming increasingly important due to the effects of climate change. In northern Sweden, thawing of permafrost has led to significant increases in annual minimum flows in several catchments. This has led to studies of groundwater flow, responses to precipitation and runoff, and subsurface connectivity of springs on slopes. However, there remains a limited understanding of the interplay between surface flow and subsurface flow in the hillslopes of subarctic region. There is a need to better understand the flow pathways and connectivity of groundwater flows within the slopes. This study aims to analyze the interactions between surface flow and subsurface flow on an Sub artic mountainside. Utilizing tracer experiments and a hydrological model, the complex dynamics governing water movement within this intricate system have been studied.  Tracer experiments affirmed the hydraulic connection between hillslope and spring. The spring's response to tracer injection hinted at dominant preferential flow paths within the regolith layer's base. Nonetheless, only 40% mass recovery raised queries about factors affecting the flow in the hillslope. Thus, in this project, a model was developed using Advanced Terrestrial Simulator (ATS) to examine the dominant flow processes and evaluate the influence of various hydrogeology parameters and fluid flow properties on tracer movement. The results highlight the dominance of subsurface flows occurring close to the surface. The parameter sensitivity analysis conducted in the study showed that roughness coefficient and permeability significantly influenced specific pathways and directions that water, and tracers took as they moved through the hillslope's subsurface layers and regolith.  However, the model has limitations, such as neglecting the lateral variations of the subsurface material, seasonal freeze-thaw processes and the simplified representation of the slope and catchment. The results of this study show the need for utilizing more field-based methodologies and further refinement of the modeling approach to improve our understanding of hydrologic processes in high latitude areas.

Les transferts latéraux de produits phytosanitaires en proche surface constituent une voie potentielle de contamination des eaux de surface dans certains contextes agro pédo climatique. L'objectif de cette thèse est d'apporter des éléments de connaissance et de compréhension de ces transferts. Un site viticole, dans le Nord Beaujolais, a ainsi été instrumenté avec une tranchée d'interception des écoulements latéraux, un canal Venturi et un réseau piézométrique. Cette instrumentation a ensuite été utilisée pour suivre les transferts latéraux et le ruissellement de produits phytosanitaires sur deux années viticoles. Enfin, une expérimentation de traçage in situ a été menée puis modélisée. Les résultats montrent une relation de seuil entre les volumes évènementiels d'écoulements latéraux captés, le degré de connectivité du versant, les volumes pluviométriques évènementiels, et l'humidité initiale du sol. La dynamique de transfert latéral des pesticides en proche surface s'est avérée très variable à l'échelle de l'évènement, mais en accord avec les propriétés physico chimiques des substances. À l'échelle de l'ensemble des évènements, les concentrations de ces produits dans l'écoulement latéral suivent une décroissance exponentielle temporelle. À l'échelle annuelle, la saisonnalité de l'écoulement latéral et du ruissellement semble expliquer la saisonnalité observée des transferts. L'expérimentation de traçage a permis d'identifier une composante préférentielle de l'écoulement latéral et une composante matricielle. La composante préférentielle a engendré des flux de substance significatifs et de concentrations élevées, mais fugaces. La composante matricielle a généré un flux de faible concentration, mais continu et de longue durée, qui a impliqué une contribution finale plus élevée que la composante préférentielle. Des liens explicatifs entre les propriétés des substances et ces composantes du transfert latéral ont pu être soulignés / Subsurface lateral flow may stand for a risky pathway in several agro pedo climatic contexts: in this way, the aim of this thesis work is to improve our understanding of pesticide transfer and dynamics by this pathway. A farmed vine plot, located on a hillslope in the Nord Beaujolais, was instrumented with a trench, a Venturi flume and a shallow groundwater well network. The instrumentation was used during two farming years to continuously monitor pesticide transfers in both subsurface lateral flows and surface runoff at a fine temporal resolution. Lastly, an in situ tracing experiment was conducted and modeled. Hydrological results highlighted a threshold relationship between subsurface lateral flow volumes measured in the trench, the degree of lateral connectivity of the hillslope, rainfall amounts and initial soil water content. The dynamics of these transfers was very variable at the event scale, and in agreement with the physico chemical properties of the substances. Considering all subsurface lateral flow events, pesticides concentrations were described using a decreasing exponential function depending on the time interval between a given event and the last application of the considered pesticides, and their physico chemical properties. At the year scale, the seasonality of pesticide transfers seemed related with the seasonality of subsurface lateral flow and surface runoff. The tracing experiment highlighted two components in subsurface lateral flow: a matrix related one and a preferential related flow component. The preferential component implied short, highly concentrated and significant lateral fluxes. Matrix related component produced continuous and slightly concentrated fluxes over a long period, and was responsible for a bigger part of the total transfer than the preferential component. Links between substance properties and transfer components were highlighted

Our understanding of subsurface flow depends on assumptions of how event characteristics and spatial scale affect the relationships between subsurface water velocity, discharge, water table dynamics, and runoff response. In this thesis, three chapters explore some of these patterns for a hillslope and small watershed in coastal British Columbia. In the first chapter, tracers were applied under natural and steady state conditions to determine the relationship between lateral tracer velocities and various hillslope and event characteristics; such as hillslope subsurface flow, rainfall intensity, water table level, hillslope length, and antecedent condition. The results showed that preferential flow made up a large percentage of the subsurface flow from the gauged hillslope. Flow velocities as measured by tracers were affected by slope length and boundary conditions. The flow velocity was most closely related to the rainfall intensity, and changes in flow velocity were large compared to the changes in the water table. In the second chapter, the preferential flow features that transmitted water during steady state were investigated by staining the soil with a food dye solution and excavating the soil. These data were used to explore the link between the topographical factors (slope and contributing area), the network of preferential features and soil properties. The contributing area appeared to be an indicator of the size of the preferential features and their connectivity. In the final manuscript chapter, water table level and stream discharge measurements were used to determine if areas within a watershed with runoff dominated by preferential flow could be grouped based on the observable physical information such as slope, contributing area, distance to stream, and vegetation. Preferential flow made the water table responses dynamic and thus, distinct zones could not be identified. Models of the water table – runoff were not able to predict the water table response for other sites with similar physical characteristics. Even though there was high variability in the results, the patterns and relationships revealed in this thesis conform to existing conceptual models of hillslope subsurface preferential flow. These patterns and relationships may be useful in developing or validating numerical models.

Our understanding of subsurface flow depends on assumptions of how event characteristics and spatial scale affect the relationships between subsurface water velocity, discharge, water table dynamics, and runoff response. In this thesis, three chapters explore some of these patterns for a hillslope and small watershed in coastal British Columbia. In the first chapter, tracers were applied under natural and steady state conditions to determine the relationship between lateral tracer velocities and various hillslope and event characteristics; such as hillslope subsurface flow, rainfall intensity, water table level, hillslope length, and antecedent condition. The results showed that preferential flow made up a large percentage of the subsurface flow from the gauged hillslope. Flow velocities as measured by tracers were affected by slope length and boundary conditions. The flow velocity was most closely related to the rainfall intensity, and changes in flow velocity were large compared to the changes in the water table. In the second chapter, the preferential flow features that transmitted water during steady state were investigated by staining the soil with a food dye solution and excavating the soil. These data were used to explore the link between the topographical factors (slope and contributing area), the network of preferential features and soil properties. The contributing area appeared to be an indicator of the size of the preferential features and their connectivity. In the final manuscript chapter, water table level and stream discharge measurements were used to determine if areas within a watershed with runoff dominated by preferential flow could be grouped based on the observable physical information such as slope, contributing area, distance to stream, and vegetation. Preferential flow made the water table responses dynamic and thus, distinct zones could not be identified. Models of the water table – runoff were not able to predict the water table response for other sites with similar physical characteristics. Even though there was high variability in the results, the patterns and relationships revealed in this thesis conform to existing conceptual models of hillslope subsurface preferential flow. These patterns and relationships may be useful in developing or validating numerical models.

Our understanding of subsurface flow depends on assumptions of how event characteristics and spatial scale affect the relationships between subsurface water velocity, discharge, water table dynamics, and runoff response. In this thesis, three chapters explore some of these patterns for a hillslope and small watershed in coastal British Columbia. In the first chapter, tracers were applied under natural and steady state conditions to determine the relationship between lateral tracer velocities and various hillslope and event characteristics; such as hillslope subsurface flow, rainfall intensity, water table level, hillslope length, and antecedent condition. The results showed that preferential flow made up a large percentage of the subsurface flow from the gauged hillslope. Flow velocities as measured by tracers were affected by slope length and boundary conditions. The flow velocity was most closely related to the rainfall intensity, and changes in flow velocity were large compared to the changes in the water table. In the second chapter, the preferential flow features that transmitted water during steady state were investigated by staining the soil with a food dye solution and excavating the soil. These data were used to explore the link between the topographical factors (slope and contributing area), the network of preferential features and soil properties. The contributing area appeared to be an indicator of the size of the preferential features and their connectivity. In the final manuscript chapter, water table level and stream discharge measurements were used to determine if areas within a watershed with runoff dominated by preferential flow could be grouped based on the observable physical information such as slope, contributing area, distance to stream, and vegetation. Preferential flow made the water table responses dynamic and thus, distinct zones could not be identified. Models of the water table – runoff were not able to predict the water table response for other sites with similar physical characteristics. Even though there was high variability in the results, the patterns and relationships revealed in this thesis conform to existing conceptual models of hillslope subsurface preferential flow. These patterns and relationships may be useful in developing or validating numerical models. / Forestry, Faculty of / Graduate

Ziel der Arbeit ist es, ein genaueres Prozessverständnis zur Abflussbildung an Hängen auf der Basis der räumlichen Verbreitung periglazialer Deckschichten zu erhalten. Das Untersuchungsgebiet ist ein 6 ha großes, forstlich bewirtschaftetes Quelleinzugsgebiet im Osterzgebirge. Das anstehende Gestein ist Gneis. Der oberflächennahe Untergrund ist aus zwei- und dreigliedrigen Deckschichten zusammengesetzt. Auf der Punkt-, Hang- und Kleineinzugsgebietsskala werden hydrometrische, hydrochemische und geoelektrische Methoden sowie Färbeversuche eingesetzt, um auf die dominierenden Abflussbildungsprozesse schließen zu können. Aus der Synthese der Teilergebnisse werden drei typische Prozessabläufe in Abhängigkeit von der Gebietsvorfeuchte abgeleitet. Diese verdeutlichen, dass bei geringer Vorfeuchte Sättigungsoberflächenabfluss im Quellsumpf vorherrscht, bei mittlerer bis hoher Vorfeuchte dagegen Zwischenabfluss der dominierende Abflussprozess ist. Die Abflusswirksamkeit der Niederschläge steigt zudem mit zunehmender Vorfeuchte nichtlinear an. Es wird herausgestellt, dass die hydraulisch anisotropen Eigenschaften der Basislage entscheidend die oberflächennahen Fließwege des Wassers beeinflussen. Sie besitzt durch ihre hohe Lagerungsdichte einerseits vertikal wasserstauende Eigenschaften. Andererseits kann Wasser, begünstigt durch das dominant sandige Substrat und das hangparallel eingeregelte Bodenskelett innerhalb der Schicht bevorzugt lateral geleitet werden. Die gewonnenen Erkenntnisse verdeutlichen die Bedeutung der Eigenschaften der periglazialen Deckschichten für die Abflussbildung an Mittelgebirgshängen. / The aim of this study is to contribute to the understanding of runoff processes on slopes based on the spatial distribution of periglacial cover beds. The study area is a 6 ha large forested spring catchment in the Eastern Ore Mountains, Saxony. Bedrock is gneiss overlain by periglacial cover beds comprising two or three layers. On plot, hillslope and small-catchment scales hydrometrical, hydrochemical and geoelectrical methods as well as tracer experiments are used to determine the constitutive runoff processes. From the synthesis of partial results, three pre-moisture controlled process cycles are derived. With low pre-moisture, saturation overland flow dominates in the spring bog. In contrast, with medium or high pre-moisture interflow occurs. Besides, with rising pre-moisture runoff coefficients increase in a non-linear manner. It is emphasised that the hydraulic anisotropic structure of the Basal Layer is the major control factor for subsurface water-flow paths. On the one hand, this layer acts as an aquitard for seeping water because of its high bulk density. On the other hand, water within the layer is able to flow laterally because of the sandy texture and the coarse clasts oriented parallel to the slope. These findings highlight the importance of relic periglacial cover beds for runoff generation in subdued mountains.