<p>When the amorphous silicon (a-Si) dangling bonds are bonded to hydrogen the concentration of the dangling bond is decreased. The resulting film is called hydrogenated amorphous silicon (a-Si:H). The reduction in the dangling bonds concentration improves the optoelectrical properties of the film. The improved properties of a-Si:H makes it possible to manufacture electronic devices including a solar cell. A solar cell device based on the hydrogenated amorphous silicon (a-Si:H) was fabricated using the Hot-Wire Chemical Vapour Deposition (HWCVD). When an n-i-p solar cell configuration is grown, the norm is that the p-doped layer is deposited from a mixture of silane (SiH4) gas with diborane (B2H6). The boron atoms from diborane bonds to the silicon atoms and because of the number of the valance electrons, the grown film becomes a p-type film. Aluminium is a group 3B element and has the same valence electrons as boron, hence it will also produce a p-type film when it bonds with silicon. In this study the p-doped layer is grown from the co-deposition of a-Si:H from SiH4 with aluminium evaporation resulting in a crystallized, p-doped thin film. When this thin film is used in the n-i-p cell configuration, the device shows photo-voltaic activity. The intrinsic layer and the n-type layers for the solar cell were grown from SiH4 gas and Phosphine (PH3) gas diluted in SiH4 respectively. The individual layers of the solar cell device were characterized for both their optical and electrical properties. This was done using a variety of experimental techniques. The analyzed results from the characterization techniques showed the films to be of device quality standard. The analysed results of the ptype layer grown from aluminium showed the film to be successfully crystallized and doped. A fully functional solar cell was fabricated from these layers and the cell showed photovoltaic activity.<br /> &nbsp / </p>

<p>This study reports on the changes in the structural properties of a tungsten-filament when exposed to a methane / hydrogen ambient for different durations at various filament-temperatures.</p>

<p>The overall aim of this project is to study the heat transfer inside the reaction chamber of the Hot-Wire Chemical Vapor Deposition (HWCVD) system with a commercial software package FLUENT6.3 / it is one of the most popular Computational Fluid Dynamics solvers for complex flows ranging from incompressible to mildly compressible to even highly compressible flows. The wealth of physical models in FLUENT allows us to accurately predict laminar and turbulent flows, various modes of heat transfer, chemical reactions, multiphase flows and other phenomena with complete mesh flexibility and solution-based mesh adaptation. In this study the 3-D HWCVD geometry was measured and created in GAMBIT which then generates a mesh model of the reaction chamber for the calculation in FLUENT. The gas flow in this study was characterized as the steady and incompressible fluid flow due to the small Mach number and assumptions made to simplify the complexity of the physical geometry. This thesis illustrates the setups and solutions of the 3-D geometry and the chemically reacting laminar and turbulent gas flow, wall surface reaction and heat transfer in the HWCVD deposition chamber.</p>

<p>When the amorphous silicon (a-Si) dangling bonds are bonded to hydrogen the concentration of the dangling bond is decreased. The resulting film is called hydrogenated amorphous silicon (a-Si:H). The reduction in the dangling bonds concentration improves the optoelectrical properties of the film. The improved properties of a-Si:H makes it possible to manufacture electronic devices including a solar cell. A solar cell device based on the hydrogenated amorphous silicon (a-Si:H) was fabricated using the Hot-Wire Chemical Vapour Deposition (HWCVD). When an n-i-p solar cell configuration is grown, the norm is that the p-doped layer is deposited from a mixture of silane (SiH4) gas with diborane (B2H6). The boron atoms from diborane bonds to the silicon atoms and because of the number of the valance electrons, the grown film becomes a p-type film. Aluminium is a group 3B element and has the same valence electrons as boron, hence it will also produce a p-type film when it bonds with silicon. In this study the p-doped layer is grown from the co-deposition of a-Si:H from SiH4 with aluminium evaporation resulting in a crystallized, p-doped thin film. When this thin film is used in the n-i-p cell configuration, the device shows photo-voltaic activity. The intrinsic layer and the n-type layers for the solar cell were grown from SiH4 gas and Phosphine (PH3) gas diluted in SiH4 respectively. The individual layers of the solar cell device were characterized for both their optical and electrical properties. This was done using a variety of experimental techniques. The analyzed results from the characterization techniques showed the films to be of device quality standard. The analysed results of the ptype layer grown from aluminium showed the film to be successfully crystallized and doped. A fully functional solar cell was fabricated from these layers and the cell showed photovoltaic activity.<br /> &nbsp / </p>

The longitudinal fluctuations at a point in the core of air flowing through a 15 cm. diameter pipe at a mean centerline velocity of 13.4 and 29.5 m/sec. were measured with a hot-wire anemometer. This signal, after analog to digital conversion, was stored in the form of digital samples on an ICT computer drum storage device. This method of data recording includes the effect of all eddy frequencies from DC upwards and the presence of large, slow eddies in the longitudinal direction became apparent in the subsequent autocorrelations. The longitudinal dispersion of a tracer material injected on the axis of the pipe was measured over short distances with pulses of approx. 20 msecs. duration of radioactive Krypton-85, detected at two downstream stations by small surface-barrier radiation detectors. By varying the separation of these two stations, an asymptotic mixing coefficient was established which was very much greater than the corresponding transverse mixing coefficient measured by other workers. The method proposed by Philip (4) for the prediction of the Lagrangian time autocorrelation from the Eulerian velocity measurements was examined with the correlation data of Baldwin and the data obtained in this investigation. The method applied to the unfiltered correlation data in the present measurements in a non-isotropic field to predict a longitudinal turbulent Peclet no. was found to predict a value in the region measured experimentally. When the present velocity data was filtered to remove the low-frequency components and give a turbulence intensity equal to that measured in a radial direction in previous dispersion measurements, the mixing coefficient predicted with Philip's method was found to agree very well with the transverse mixing coefficient reported in these investigations. A value is also suggested for the longitudinal Peclet number in the absence of the low frequency fluctuations. / Thesis (Ph.D.)-University of Natal, Durban, 1970.

It has been debated that among all the renewable energy alternatives, only solar energy offers sufficient resources to meet energy demands. Silicon thin film solar cells are at the frontier of commercial solar technology. Hot wire chemical vapour deposition (HWCVD) is the technique of choice for silicon thin film deposition due to the absence of ion bombardment and its independence toward geometry or electromagnetic properties of the substrate, as seen by plasma enhanced chemical vapour deposition (PECVD). With the implementation of nanostructures in a multi-band gap tandem solar cell, considerable improvement has been achieved over the single junction solar cells. Defect assisted tunnelling processes at the junctions between individual solar cells in a tandem structure solar cell largely affect the efficiency of these solar cells. In this contribution, the investigation toward the improvement of silicon thin films for tandem solar cell application is initiated. This study reports on the effects of hydrogen dilution and deposition time on six silicon thin films deposited at six specific deposition regimes. The thin film properties are investigated via X-Ray diffraction analysis, Raman spectroscopy, Fourier transform infra-red spectroscopy, elastic recoil detection analysis, scanning and transmission electron microscopy and UV-visible spectroscopy. This investigation revealed the dominating etching effect of atomic hydrogen with the increase in hydrogen dilution and a bonded hydrogen content (CH) exceeding 10 at.% for each of the six thin films. The optically determined void volume fraction and static refractive index remain constant, for each thin film, with the change in CH. A new deposition procedure, utilising the deposition conditions of the previously investigated thin films, is performed by HWCVD to deposit two silicon thin films. This deposition procedure involved either increasing (protocol 1) or decreasing (protocol 2) hydrogen dilution during deposition. Structural and optical variation with depth was observed for the dynamically deposited silicon thin films, with nano-voids existing across the entire cross section and bond angle variations which are indicative of good structural order. The optical absorption curves differ for the two silicon thin films whereas the optical density remains constant for both. / >Magister Scientiae - MSc

This thesis is motivated by the necessity to understand the flow structure of turbulent flows in bends encountered in many technical applications such as heat exchangers, nuclear reactors and internal combustion engines. Flows in bends are characterised by strong secondary motions in terms of counter-rotating vortices (Dean cells) set up by a centrifugal instability. Specifically the thesis deals with turbulent flows in 90° curved pipes of circular cross-section with and without an additional motion, swirling or pulsatile, superposed on the primary flow.  The aim of the present thesis is to study these complex flows in detail by using time-resolved stereoscopic particle image velocimetry to obtain the three-dimensional velocity field, with complementary hot-wire anemometry and laser Doppler velocimetry measurements. In order to analyse the vortical flow field proper orthogonal decomposition (POD) is used. The so called ``swirl-switching'' is identified and it is shown that the vortices instantaneously, ``rock'' between three states, viz. a pair of symmetric vortices or a dominant clockwise or counter-clockwise Dean cell. The most energetic mode exhibits a single cell spanning the whole cross-section and ``rolling'' (counter-)clockwise in time. However, when a honeycomb is mounted at the inlet of the bend, the Dean vortices break down and there is strong indication that the ``swirl-switching'' is hindered. When a swirling motion is superimposed on the incoming flow, the Dean vortices show a tendency to merge into a single cell with increasing swirl intensity. POD analysis show vortices which closely resemble the Dean cells, indicating that these structures co-exist with the swirling motion. In highly pulsating turbulent flow at the exit of a curved pipe, the vortical pattern is diminished or even eliminated during the acceleration phase and then re-established during the deceleration. In order to investigate the effect of pulsations and curvature on the performance of a turbocharger turbine, highly pulsating turbulent flow through a sharp bend is fed into the turbine. Time-resolved pressure and mass-flow rate measurements show that the hysteresis loop in the pressure-ratio-mass-flow plane, may differ significantly between straight and curved inlets, however the mean operating point is only slightly affected. / <p>QC 20140523</p>

This document addresses problems encountered when establishing the very low air-flow speeds required for experimental investigations of the mechanisms of low-Reynolds-number boundary-layer turbulence. Small-scale motions in the near-wall region are important features of turbulent boundary-layer dynamics, and, if these features are to be resolved by measurements in air with conventionally-sized hot-wire probes, a well-behaved canonical turbulent boundary layer must be developed at free stream flow speeds no higher than 4 m/s. However, at such low speeds, the turbulent boundary layers developed on the walls of a wind tunnel are very susceptible to perturbation by non-turbulent time-dependent flow structures which originate upstream from the test section in the laminar flow at the inlet and in the contraction. Four different non-turbulent flow structures have been identified. The first is a result of quasi-two-dimensional separation of the laminar boundary-layer from the surfaces of the wind-tunnel contraction. Potential flow simulations show that susceptibility to this form of separation is reduced by increasing the degree of axisymmetry in the cross-section geometry and by decreasing the streamwise curvature of the concave surfaces. The second source of time-dependence in the laminar boundary-layer flow is an array of weak streamwise vortices produced by Goertler instability. The Goertler vortices can be removed by boundary-layer suction at the contraction exit. The third form of flow perturbation, revealed by visualisation experiments with streamers, is a weak large-scale forced-vortex swirl produced by random spatial fluctuations of temperature at the wind-tunnel inlet. This can be prevented by thorough mixing of the inlet flow; for example, a centrifugal blower installed at the inlet reduces the amplitude of temperature nonuniformity by a factor of about forty and so prevents buoyancy-driven swirl. When subjected to weak pressure gradients near the start of a wind-tunnel contraction, Goertler vortices in laminar wall layers can develop into three-dimensional separations with strong counter-rotating trailing vortices. These trailing vortices are the fourth source of unsteady flow in the test-section. They can be suppressed by a series of appropriately located screens which remove the low-speed-streak precursors of the three-dimensional separations. Elimination of the above four contaminating secondary flows permits the development of a steady uniform downstream flow and well-behaved turbulent wall layers. Measurements of velocity in the turbulent boundary layer of the test-section have been obtained by hot-wire anemometry. When a hot-wire probe is located within the viscous sublayer, heat transfer from the hot-wire filament to the wall produces significant errors in the measurements of both the mean and the fluctuating velocity components. This error is known as wall-proximity effect and two successful methods are developed for removing it from the hot-wire signal. The first method is based on the observation that, if all experimental parameters except flow speed and distance from the wall are fixed, the velocity error may be expressed nondimensionally as a function of only one parameter, in the form DeltaU^+=f(y^+). The second method, which also accommodates the effect of changing the hot-wire overheat ratio, is based on a dimensional analyis of heat transfer to the wall. Velocity measurements in the turbulent boundary layer at the mid-plane of a nearly square test-section duct have established that, when the boundary-layer thickness is less than one quarter of the duct height, mean-velocity characteristics are indistinguishable from those of a two-dimensional flat-plate boundary layer. In thicker mid-plane boundary layers, the mean-velocity characteristics are affected by stress-induced secondary flow and by lateral constriction of the boundary-layer wake region. A significant difference between flat-plate and duct boundary layers is also observed in momentum-balance calculations. The momentum-integral equation for a duct requires definitions of momentumd and displacement thickness which are different from those given for flat-plate boundary layers. Momentum-thickness growth rates predicted by the momentum-integral equation for a duct agree closely with measurements of the newly defined duct momentum thickness. Such agreement cannot be obtained in terms of standard flat-plate momentum thickness. In duct boundary layers with Reynolds numbers Re_theta between 400 and 2600, similarity in the wake-region distributions of streamwise turbulence statistics has been obtained by normalising distance from the wall with the flat-plate momentum thickness, theta_2. This result indicates that, in contrast with the mean velocity characteristics, the structure of mid-plane turbulence does not depend on the proportion of duct cross-section occupied by boundary layers and is essentially the same as in a flat-plate boundary layer. For Reynolds numbers less than 400, both wall-region and wake-region similarity fail because near-wall turbulence events interact strongly with the free stream flow and because large scale turbulence motions are directly influenced by the wall. In these conditions, which exist in both duct and flat-plate turbulent boundary layers, there is no distinct near-wall or wake region, and the behaviour of turbulence throughout the boundary layer depends on both wall variables and on outer region variables simultaneously. / Thesis (Ph.D.)--School of Mechanical Engineering, 1998.

>Magister Scientiae - MSc / This study reports on the effects of hydrogen dilution and deposition time on six silicon thin films deposited at six specific deposition regimes. The thin film properties are investigated via X-Ray diffraction analysis, raman spectroscopy, fourier transform infra-red spectroscopy, elastic recoil detection analysis, scanning and transmission electron microscopy and UV-visible spectroscopy. This investigation revealed the dominating etching effect of atomic hydrogen with the increase in hydrogen dilution and a bonded hydrogen content (CH) exceeding 10 at.% for each of the six thin films. The optically determined void volume fraction and static refractive index remain constant, for each thin film, with the change in CH

Made available in DSpace on 2014-06-11T19:23:39Z (GMT). No. of bitstreams: 0 Previous issue date: 2005-12-16Bitstream added on 2014-06-13T19:06:57Z : No. of bitstreams: 1 eguti_cca_me_ilha.pdf: 4013696 bytes, checksum: 9efc5c11950fccddb62667186e778ef2 (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Anemômetros de fio quente são sensíveis instrumentos capazes de medir variações de velocidade nos mais diversos tipos de escoamentos, sejam eles gasosos ou líquidos. Um delicado filamento metálico é aquecido por uma corrente elétrica a qual gera calor por efeito Joule e transfere parte dessa energia para o escoamento incidente, sendo esta troca de calor proporcional a velocidade do fluído, definindo assim o princípio básico de funcionamento da anemometria de fio quente. Quando este filamento é montado num circuito tipo ponte de Wheatstone, pode-se relacionar a troca de calor no filamento através da variação de sua resistência elétrica fazendo o uso de circuitos eletrônicos especiais. Este trabalho aborda os conceitos básicos da anemometria de fio quente, seus circuitos de controle principais e seus modos de operação, mostrando diferentes métodos para calibração de sondas de fio quente em escoamentos gasosos, além de apresentar uma metodologia completa para construção de um sistema básico de anemômetro de fio quente de temperatura constante. Dois dispositivos foram construídos e testados sendo avaliados quanto ao seu funcionamento e sua resposta em freqüência. / Hot wire anemometers are sensitive instruments capable of measuring fluctuation of speed in many fluid flows, gaseous or liquid. A delicate metallic filament is heated by an electric current (Joule effect) and cooled by incident flow, this heat exchange is proportional of the fluid speed, defining the basic phenomenon of hot-wire anemometry. When this filament is mounted on an arm of Wheatstone bridge, the heat lost by the filament can be related its electric resistance when special electronic circuits are used. This work presents the concepts of hot-wire anemometry, its main control circuits and its operation mode, showing the basic methods for hot wire calibration with gaseous flows, besides presenting a complete methodology for construction of a basic constant temperature hot-wire anemometer system, based on the tests of two experimental circuits which are evaluated by electronic tests and its frequency response.