No description available.

The Kuboos-Bremen Igneous Province comprises a linear zone of alkaline complexes that intrude Proterozoic and Pan-African rocks and trends in a northeast direction from the northwest of the Cape Province in South Africa into southern Namibia. Of the three most southerly complexes in Namibia. two comprise silicate rocks ranging from nepheline syenite to alkali-granite and are called the Grootpenseiland and Marinkas Kwela Complexes (GPC and MKC). The Marinkas Kwela Carbonatite Complex is the third and most northerly of the complexes. Isotopic age determinations on a number of rock types from both the silicate complexes yield ages around 520Ma and are consistent with published Pan-African ages for the Province. Each silicate complex shows a migrating locus of intrusion from Siundersaturated rocks in the southwest to Si-oversaturated rocks in the northeast. The complexes overlap in outcrop. The rocks are moderately to highly felsiC and none reflects primary magma compositions. The Si-undersaturated rocks from both complexes include side-wall cumulates formed from magmas that fractionated alkali-feldspar, clinopyroxene and amphibole. Foyaites also occur in the MKC and have a compositional range reflecting alkali-feldspar fractionation and, probably, some interaction with dolomite country rocks. Major and trace element data suggest that critically saturated alkali syenites occurring in both complexes evolved via protracted feldspar fractionation, and that critically saturated alkali-feldspar syenite occurring only in the GPC is a cumulate. The two rock types cannot be related genetically. Of the SI-oversaturated rocks in both complexes, those in the compositional range monzonite to granite were intruded before alkali-granites. Compositional diversity amongst the former reflects fractionation of feldspar and of mafic phases, but that process cannot genetically link the rocks to the alkali-granites. Isotopic compositions of Sr and Nd indicate that the silicate magmas were derived from an upper mantle source region characterised by low time-integrated Rb/Sr ratios and high time-Integrated Sm/Nd ratios, However, the evidence of Sr and 0 isotopic data is that the Si-oversaturated melts possibly interacted with a crustal component. presumably the Proterowlc rocks of the Namaqua Metamorphic Province. This interaction may explain the occurrence of apparently co-genetic rock series that evolved on opposite sides of the feldspar join in Petrogeny's Residua System. The Marinkas Kwela Carbonatite Complex was emplaced before the final intrusive phases of the MKC and exhibits unusually pronounced late-stage enrichment in manganese. The earliest intrusive rocks in the complex were nepheline syenites which were fenitised by later intrusions of sôvites. Although the commonly occurring magmatic sequence of sôvite-beforsite-ferrocarbonatite is observed at Marinkas Kwela, sôvites do not appear to have been parental to beforsites. Removal of apatite and early crystallisation of magnetite distinguish magnetite-rich beforsite from co-genetic apatite-rich beforsite. Two further magmatic sequences. the first from apatite-rich beforsite through ferrocarbonatite to Mn-rich ferrocarbonatite (high Fe/Mn) and the second from magnetite-rich beforsite to Mn-rich ferrocarbonatite (low Fe/Mn). reflect fractionation of dolomite and of dolomite+magnetite respectively.

The Ice River igneous complex, exposed in the southern part of Yoho National Park in the Field area, British Columbia, is an asymmetrical laccolith made up of several varieties of undersaturated alkaline igneous rooks. Nepheline- sodalite syenite and urtite, two of the major types, are described. Several theories on the origin of undersaturated alkaline igneous rocks are discussed and it is concluded that Daly’s limestone syntexis theory best explains the origin of the Ice River complex. In the vicinity of Garnet Mountain and Aquila Ridge, the north-west extension of the laccolith has contact metasomatised enclosing limestone and limestone inclusions. The mineralogy and petrology of several extensive skarn zones which carry pyrochlore and radioactive minerals are described. The concentration of certain elements in alkaline igneous rooks is considered and the, addition of Na, K, Cb, Zr and others to Ice River limestone is described. / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate

Twenty Four samples of xenoliths and country rocks from the 1961 lava flow of Calbuco volcano have been studied. Fourteen samples have been analyzed for major elements and P, Ni, Ba, Cr, V, Zr, Sc, Y, and Sr. Five of these samples were further analyzed for Sm, Nd, Sr, and Pb isotope ratios. Seventeen samples were studied under the microscope and three samples were analyzed by microprobe for their pyroxene compositions. Based on petrographic studies xenoliths were divided into three groups. Fine grained xenoliths (groups I and II) probably formed from metamorphosed MORB-like basalts, whereas coarse grained xenoliths (group III) were apparently derived from cumulate minerals that crystallized from the Calbuco magma. The fine grained xenoliths were probably entrained in magma at intermediate levels of the crust, near the stability limit of amphibole to form pyroxene and plagioclase. In the coarse grained xenoliths amphibole that formed at depth dehydrated as the xenoliths were brought to the surface. The country rocks are apparently unrelated to the xenoliths.

Thesis (M.S.)--University of Rhode Island, 1974. / Includes bibliographical references.

Thesis (M. Phil.)--University of Hong Kong, 2005. / Title proper from title frame. Also available in printed format.

No description available.

The first part of this dissertation deals with the timing of Mesozoic igneous activity in southern Cordillera of North America and its tectonic implications. A representative section in Santa Rita Mountains is dated using the zircon U-Th-Pb isotopic method. The oldest unit, the lower member of the Mt. Wrightson Formation, is concordantly dated at 210 ± 3 Ma. Initial basaltic andesite to andesite volcanism was followed by deposition of redbeds and associated volcanic rocks that are dated at 200 Ma. Felsic volcanism and eolian sand deposition may have spanned from 190 to 170 Ma. The Piper Gulch Granodiorite, representing the earliest Mesozoic intrusive equivalent, gives concordant dates of 188 ± 2 Ma. A second cycle of andesite and rhyolitic volcanism and sedimentation is dated at 151 ± 5 Ma using the whole-rock Rb-Sr isotopic method. The Hovatter Volcanics in the Little Harquahala Mountains, southwestern Arizona is dated at 165 Ma. Whole-rock Rb-Sr isotopic method on the same rocks gives a coherent reset isochron of 70 ± 3 Ma (Appendix III). A new stratigraphic correlation is proposed based on the dating data. Tectonic models proposed by previous workers to account for what seemed to be the lack of Triassic volcanic rocks are not necessary. This part of the Cordillera was an uplifted arc terrane during the Early Mesozoic (Appendix II) and may have provided volcanic detritus to the Late Triassic Chinle Formation in the Colorado Plateau. The second part of the dissertation deals with magma evolution and crust modification during arc magmatism. Rocks in southeastern Arizona have ƭ(N)(d) values of -3.4 to -6.4, while rocks to the west have ƭ(N)(d) values ranging from -8.5 to -9.2. An ƭ(N)(d) value of +2 for a Jurassic basalt indicates the presence of depleted mantle under the arc. Using lower crust and mantle end-members, 20 to 40% mantle input is estimated. This seems to argue for continuous growth model of the continental crust. Combined REE and isotopic data indicate that assimilation of lower crust by mantle melts followed by fractional crystallization took place. Detailed study indicates that the lower crust along sites of arc magmatism gets progressively hybridized by the mantle, becoming more mantle-like with time.

Equilibrium properties of the MgO-Al₂O₃-SiO₂ (MAS) system are modeled using techniques from statistical and quantum mechanics. The fundamental structural units in this model are the closed shell ions: Mg²⁺, Al³⁺, Si⁴⁺, and O²⁻. The equilibrium properties of the MAS system are determined by the interactions among these ions and by the environment (i.e. temperature and pressure). The interactions are modeled using coulombic, dispersion, and repulsive forces. Two parameters appearing in the repulsive terms for each cation-oxygen interaction are fitted from properties of quartz, corundum, and periclase crystals. The effects of the environment on the liquid and solid compositions found in this system are calculated using a Monte Carlo technique involving the generation of a Markov chain of configurations; each configuration being a "snapshot" of the particles in the liquid or solid material being studied. The properties of the material are derived from averaging appropriate quantities over all the configurations. Enthalpies of formation, heat capacities, and volumes of seven compositions in the MAS system have been calculated using this method. All are within three percent of the corresponding experimental values. Radial distribution functions for these runs show the competition among the cations for the common anion, oxygen, under charge and mass balance constraints. The electronic structure of several molecular clusters in the MAS system are examined using ab initio linear combinations of atomic orbitals (LCAO) techniques. The assumptions used in LCAO calculations are examined and a small, balanced basis set for the MAS system is presented. The Mg-, Al-, and Si-O interactions are all found to be highly ionic using this basic set. Using a first principles technique, the two body effective pair potentials assumed for the Monte Carlo calculations were shown to be physically reasonable.

Six alkalinity and oxidation classes of fresh igneous rocks were correlated with trace elements in rock chip samples from temporally and spatially associated ore deposits. Learning vector quantization and back-propagation artificial neural networks correctly classified 100 percent of whole rock oxides and 99 percent of mineralized samples; discriminant analysis correctly classified 96 and 83 percent, respectively. The high degree of correlation between chemistries of igneous rocks and related mineralization implies genetic links between magmatic processes or sources and the ore deposits studied. The petrochemical classification was evaluated by assigning 43 deposits to classes defined on eight variation diagrams, training neural networks to classify analyses of 569 igneous and 887 mineralized samples, and testing the networks on their ability to classify new data. Whole rock analyses were obtained from mining districts in which trace element geochemistry was also available. Half the data was eliminated using five alteration filter graphs. The K₂O and Fe₂O₃/FeO versus SiO₂ diagrams and iron mineralogy best defined alkalinity and oxidation classes. Neural networks trained with 90, 80, 70, or 50 percent of the samples correctly classified 81 to 100 percent of randomly withheld data. SiO₂/K₂O ratios of alkali-calcic igneous rocks are 14-20 and of calc-alkalic 20-30. Fe₂O₃/FeO ratios are >0.8 with abundant magnetite and sphene for oxidized, 0.5-1.2 with magnetite, sphene, and rare ilmenite for weakly oxidized, and <0.6 with ilmenite only in reduced subclasses. Lead-zinc-silver deposits as at Tombstone and Tintic are related to oxidized alkali-calcic igneous rocks. Polymetallic lead-zinc-copper-tin-silver deposits, such as Santa Eulalia and Tempiute, Nevada, are associated with weakly oxidized alkali-calcic rocks. Tin-silver deposits of Llallagua and Potosi are correlated with reduced alkali-calcic intrusives. Porphyry copper deposits as at Ray and Sierrita are connected with oxidized calc-alkalic plutons. Gold-rich porphyry copper deposits, such as Copper Canyon and Morenci are linked to weakly oxidized calc-alkalic plutons. Disseminated gold deposits, such as Chimney Creek, Nevada, are temporally and chemically correlated with reduced calc-alkalic igneous rocks, although physical connections between plutons and Carlin-type deposits remain unconfirmed. Magma series classification and neural networks have profound applications and implications to exploration, alteration and zoning studies, and metallogenesis.