Millimeter wave studies of molecules in circumstellar envelopes and a planetary nebula have been conducted. Using the Submillimeter Telescope (SMT) of the Arizona Radio Observatory (ARO) on Mt. Graham, a comparative spectral survey from 215-285 GHz was carried out of the carbon-rich asymptotic giant branch star IRC +10216 and the oxygen-rich supergiant VY Canis Majoris. A total of 858 emission lines were observed in both objects, arising from 40 different molecules. In VY Canis Majoris, AlO, AlOH, and PO were detected for the first time in interstellar space. In IRC +10216, PH3 was detected for the first time beyond the solar system, and C3O, and CH2NH were found for the first time in a circumstellar envelope. Additionally, in the evolved planetary nebula, the Helix, H2CO, C2H, and cyclic-C3H2 were observed using the SMT and the Kitt Peak 12 m telescopes. The presence of these three molecules in the Helix suggests that relatively complex chemistry occurs in planetary nebulae, despite the harsh ultraviolet field. Overall, the research on molecules in circumstellar and planetary nebulae furthers our understanding of the nature of the material that is fed back into the interstellar medium from evolved stars. Besides telescope work, laboratory research was also conducted - the rotational spectrum of ZnCl was measured and its bond length and rotational constants were determined. Lastly, in partial fulfillment of a graduate certificate in entrepreneurial chemistry, the commercial applications of terahertz spectroscopy were explored through literature research.

The object of this dissertation is to provide an observational study of the effects of interstellar magnetic fields on star-formation regions. This is part of a long-standing research project that uses the techniques of radio astronomy to measure magnetic field strengths in the interstellar medium of our galaxy. Interstellar magnetic fields are believed to play a crucial role in the star-formation process therefore a comprehensive study of magnetic fields is necessary in understanding the origins of stars. These projects use observational data obtained from the Very Large Array (VLA) in Socorro, NM. The data reveal interstellar magnetic field strengths via the Zeeman effect in radio frequency spectral lines. This information provides an estimate of the magnetic energy in star-forming interstellar clouds in the Galaxy, and comparisons can be made with these energies and the energies of self-gravitation and internal motions. From these comparisons, a better understanding of the role of magnetic fields in the origins of stars will emerge. The regions observed include the giant molecular clouds and star-forming regions of Cygnus X and NGC 6334. NGC 6334 A is a compact HII region at the center of what is believed to be a large, rotating molecular torus (based on studies by Kramer et al. (1997)). This is a continuing study based on initial measurements of the HI and OH Zeeman effect (Sarma et al. (2000)). The current study includes OH observations performed by the VLA at a higher spatial resolution than previously published data, and allows for a better analysis of the spatial variations of the magnetic field. A new model of the region is also developed based on OH opacity studies, dust continuum maps, radio spectral lines, and infrared (IR) maps. The VLA has been used to study the Zeeman effect in the 21cm HI line seen in absorption against radio sources in the Cygnus-X region. These sources are mostly galactic nebulae or HII regions, and are bright and compact in this region of the spectrum. HI absorption lines are strong against these regions and the VLA is capable of detecting the weak Zeeman effect within them.

Herschel and JCMT surveys of nearby star-forming regions have provided excellent images of cold dust emission across several wavelengths with unprecedented dynamic range and resolutions. Here we present spectral emissivity index and temperature maps of dust in the star-forming clumps of the Perseus molecular cloud determined from fitting SEDs to the combined Herschel and JCMT observations in the 160 μm, 250 μm, 350 μm, 500 μm, and 850 μm bands, employing the technique developed by Sadavoy et al. (2013). In NGC1333, the most complex and active star-forming clump in Perseus, we demonstrate that CO line contamination in the JCMT SCUBA-2 850 μm band is typically insignificant. The derived spectral emissivity index, β, and dust temperature, T, ranges between 0.8 - 3.0 and 7 - 50 K, respectively. Throughout Perseus, we see indications of heating from B stars and embedded protostars, and smooth β variations on the smaller scales. The distribution of β values seen in each clump differs from one clump to another, and is in general different from the diffuse ISM values (i.e., ~2), suggesting that dust grain evolution is significant in star-forming clumps. We also found coincidences between low β regions and local temperature peaks as well as locations of outflows, which may provide hints to the origins of these low β value grains, and dust grain evolution in star-forming clumps in general. / Graduate / mcychen@uvic.ca

Kinetic data is presented for a variety of ion-neutral reactions which are relevant to the atmosphere of Titan and to the chemistry occurring in interstellar clouds. The data were recorded with a Selected Ion Flow Tube (SIFT) operating at room temperature (294 ± 4 K) and at a pressure of 0.46 Torr. Results of the recent Cassini-Huygens mission to Saturn and Titan have identified several species in the atmosphere of Titan not predicted by pre-Cassini models of the atmosphere. In order to determine the fate of three of these species (methylenimine, propionitrile and cyanodiacetylene) in Titan's ionosphere, their reactivity with the principal ions in Titan's upper ionosphere has been examined. As expected, collision rate proton transfer reactions dominate the chemistry with association channels also observed with many of the hydrocarbon ions. The results of the Cassini mission also identified several individual reactions as being of potential importance to models of Titan's atmosphere and this chemistry has also been examined. The above studies are also relevant to the interstellar medium where each of the neutral reactants have also been detected. The results of some proton transfer equilibrium studies are also presented. The gas phase basicities of propyne and acetylene have been determined to be 681 kJ mol⁻¹ and 617.4 kJ mol⁻¹ respectively. Their relative proton affinities can be estimated from these values. A combined experimental/theoretical study of the proton affinity of cyanodiacetylene (HC₅N) has enabled this value to be estimated at 770 ± 20 kJ mol⁻¹. Details of an attempt to complete the first laboratory measurement of the crucial reaction between H₃⁺ and atomic carbon are presented. The generation of atomic carbon in sufficient quantities for reaction in the SIFT was not possible with the microwave discharge source used. Other generation methods have also been explored with the laser photolysis of carbon suboxide expected to provide a possible solution to the problems encountered. The results of an investigation into the applicability of lithium ions (Li⁺) to SIFT-MS are presented. The lithium ions associated with each of the twenty-one neutral analytes examined to form pseudo-molecular ions. The association reactions were rapid (k ~ 10⁻⁹ cm³ s⁻¹) for large hydrocarbons but were much slower for smaller analytes (k < 10⁻¹¹ cm³ s⁻¹). In order to clarify some unusual experimental observations, the effect of water molecules on the observed chemistry has been examined in detail. The measured chemistry has important consequences for the applicability of Li⁺ to SIFT-MS where the presence and detection of an identifiable ion of the analyte is essential. Details of new SIFT operating software which can be run on a modern computer are given. Mass spectra and kinetic data recorded with the new software are also presented.

Thesis (PhD) -- University of Western Sydney, Nepean, 1999. / "A thesis submitted for the degree of Doctor of Philosophy at the University of Western Sydney Nepean" "July, 1999" Bibliography : p. 177-185.

Thesis (Ph.D.)--University of Western Sydney, 2001. / "A thesis submitted for the degree of Doctor of Philosophy at the University of Western Sydney." Includes appendices. Bibliography : p. 137-142.

Thesis (Ph. D.)--University of Adelaide, Dept. of Chemistry, 2002. / Appendix inside back cover. "June 2002." Includes bibliographical references (leaves 157-168).

Thesis (Ph. D.)--Ohio State University, 2008. / Title from first page of PDF file. Includes bibliographical references (p. 195-199).

Thesis (Ph. D.)--University of Chicago, Dept. of Astronomy and Astrophysics, Jun. 2003. / Includes bibliographical references (p. 168-171). Also available on the Internet.

El siguiente análisis es solo una aproximación a algunos aspectos de la novela, podríamos abordarla desde muchas perspectivas, aplicar la teoría de los mundos posibles, analizarla como perteneciente a la estética barroca, relacionarla con teorías sobre el lenguaje humano, etc. Ahora haremos una lectura, básicamente, sobre las ideas de la estética de la fragmentación y de la intersticialidad, planteadas por Myrna Solotorevsky y el profesor Francisco Aguilera, que atañen tanto al aspecto ficcional como fictivo de la novela. Concentrándonos además en los temas del lenguaje, éste como creador de mundos, como elemento constituyente del ser humano, y del tiempo, del tiempo fundido, más bien del no-tiempo, del lugar en que el tiempo no existe, del no lugar, fundamentales en la novela; y en motivos como los de la máscara, el viaje, el viaje al averno, la pérdida del paraíso, etc. Considerando sin duda los intertextos o contratextos bíblicos que son los grandes guías en nuestra lectura, que son parte ineludible de la estructura que es la novela. Incluso refiriéndonos rápidamente a los intertextos de obras plásticas clásicas.