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CD containing a copy of the thesis, software and extra documentation is held with print copy. / Nuclear Magnetic Resonance (NMR) is a relatively complex technique and normally requires expensive equipment. However, with advances in computing, electronics and permanent magnet technologies, NMR is becoming more feasible as a non-invasive tool for industry. The strength of NMR is its ability to probe at the molecular level and hence gain information about molecular structure, organisation, abundance and orientation. This thesis describes the development of an instrumentation platform technology that is compact and therefore portable. It has been produced to aid the development of NMR based tools or sensors for research and industry and will lead to a series of low cost, portable NMR systems for the non-destructive testing of materials such as polymer composites, rubber, timber, bricks and concrete. The instrumentation is largely electronics based and consists of a series of modules that can be interconnected to produce a solution. The first of two main modules is called the system core. What is common to all NMR applications is the generation of precisely timed signals, the capturing of signals and the processing/display of data. This has been implemented by developing a general purpose Digital Signal Processor (DSP) based instrumentation and control module that uses a Universal Serial Bus interface to communicate with a host computer. A graphical user interface is provided by an application running under Windows® XP. The second main module is a radio frequency transceiver that has been developed using digital receiver technology. The signals, after some amplification, are digitized with a 14-bit, 62.5MH.z analogue to digital converter. The sampled signal is then mixed digitally with synthesized sine and cosine functions to generate lower frequency quadrature outputs which are then digitally filtered and decimated before being passed onto the DSP for further processing and storage. A direct digital synthesizer with an analogue output is used to generate any required excitation signals. All synthesizers have phase and frequency hopping capabilities and are phase locked to each other and the DSP. The system was designed to interface to a range of NMR probes. The type of probe is determined by the intended application and each probe has specific requirements such as the type of radio frequency power amplifier, duplexer and preamplifier needed. This results in a number of instrumentation variations and a modular instrument enclosure was used to cater for these variations. The instrument was first configured for an NMR probe called the NMR-MOUSE. Tests were performed with this probe to verify the correct operation and performance of the instrument. The instrument was then reconfigured for a new probe called the NMR-MOLE and further testing was performed. This probe was still undergoing development and had not been previously tested. Finally, a dedicated compact instrument measuring 360 x 240 x 55 mm and weighing 3.6 kg was developed for the NMR-MOUSE probe.

The thesis deals with the verification of selected internal processes and items in final accounts of the company Graziano Trasmissioni, Ltd. The theoretical basis of the thesis concerns problems with audit planning and performance. It provides an explanation of essential audit definitions, objectives and phases and a description of audit risks. It characterises methods which can be used for obtaining appropriate and sufficient audit evidence that is necessary for expressing the auditor's opinion about credibility of final accounts. The emphasis is on obtaining information with the assistance of control and substantive tests. In the practical part of the thesis, control tests are applied to a purchase and sales process. The test results should show whether the internal control mechanisms are effective or not. The substantive tests validate balances of accounts receivable and accounts payable. The specific objectives are tested and the results prove whether the account balances are misrepresented in the financial statements or not.

Made available in DSpace on 2016-04-29T14:16:35Z (GMT). No. of bitstreams: 1 Lindamar Alves Faermann.pdf: 873509 bytes, checksum: 15eeb75479bf7bdc797dd472a6f81990 (MD5) Previous issue date: 2014-09-08 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / This thesis is the result of a quantitative and qualitative research conducted by social workers who work in São José dos CamposSP. Through this study, I sought to know how the instruments and techniques are being mediated and problematizados for these professionals in their day-to-day operations. The epistemological perspective that offered the structural bases for the development of this research was Dialectical materialism. Such a perspective has helped me to build not only the investigative process, but also subsidized the analysis of their results. The survey was conducted in two stages articulated and complementary: General mapping of the instruments and techniques through the use of a questionnaire and interviews with three professionals whose practices are recognized in the city. The results obtained allowed to build some approximations about the study in screen. With regard to work instruments, it was noted that the documentation is the most widely used by professionals. As a result, appeared the home visit, interview, meeting, material resources, knowledge and language. Already in relation to techniques, centrality was identified in the use of observation, listening, group dynamics, the welcome and the Socratic maieutics. With regard to the profile of professionals, of the 45 participants, only two are male. The data show that the Group researched prevail ages between 35 and 49 years. Of the total subject, has 71 further training, with emphasis on the latsu sense. As for their income, the average wage up is low, between R 1,448 .00 to .00 2,896 R. In relation to the nature of the employer institutions, dominated by public institutions (64.4), followed by the private (28.4). The area of greater concentration is social assistance professional, after, health, sóciojurídico field, education, the business field and in last place, the social security system. The vast majority of social workers- 91.1-is serving the workday of 30 hours per week. The research draws attention to two central issues. The first relates to the impacts of the working conditions of social workers in the ownership of the tools and techniques, by virtue of the process of precariousness and bureaucratization that experience. Coupled to this process, are faced with the scrapping of policies and with meagre resources to develop its activities and meet the demands of users. The second issue is due to the absence of content and knowledge to enhance the use of the instruments and techniques in your everyday professional. In this perspective, I suggest the art as an important mediation, in order to qualify their action and instigating emancipative processes among the subjects who work. On this research built reflections, keep my thesis that, for the social worker to develop a competent work, towards the ethical-political project, it is vital to take ownership of Marxist social theory and use it in conjunction with other knowledge which allow to extend its chains of mediation, in order to build professional answers and actions connected to the present time and according to the theory which is North / Esta tese é resultado de uma pesquisa quanti-qualitativa realizada junto a assistentes sociais que trabalham em São José dos Campos/SP. Através deste estudo, busquei conhecer como os instrumentos e as técnicas vêm sendo mediados e problematizados por esses profissionais em suas intervenções cotidianas. A perspectiva epistemológica que ofereceu as bases estruturantes para o desenvolvimento desta pesquisa foi o Materialismo Dialético. Tal perspectiva ajudoume a construir não apenas o processo investigativo, mas também subsidiou a análise dos seus resultados. A pesquisa foi realizada em duas etapas articuladas e complementares: mapeamento geral dos instrumentos e das técnicas, mediante o emprego de um questionário, e entrevistas com três profissionais cujas práticas são reconhecidas na cidade. Os resultados alcançados permitiram construir algumas aproximações sobre o estudo em tela. Em relação aos instrumentos de trabalho, constatou-se que a documentação é o mais utilizado pelos profissionais. Na sequência, apareceram a visita domiciliar, a entrevista, a reunião, os recursos materiais, o conhecimento e a linguagem. Já em relação às técnicas, identificou-se centralidade no uso da observação, da escuta, da dinâmica de grupo, da acolhida e da maiêutica socrática. No tocante ao perfil dos profissionais, dos 45 participantes, apenas dois são do sexo masculino. Os dados mostram que no grupo pesquisado prevalecem as idades entre 35 e 49 anos. Do total de sujeitos, 71% possui formação complementar, com destaque para a pós-graduação latu senso. Quanto aos seus rendimentos, o salário médio levantado é baixo, entre R$ 1.448,00 a R$ 2.896,00. Em relação à natureza das instituições empregadoras, sobressaem as instituições públicas (64,4%), seguida das privadas (28,4%). A área de maior concentração profissional é a assistência social, após, a saúde, o campo sóciojurídico, a educação, o campo empresarial e, em último lugar, a previdência social. A grande maioria dos assistentes sociais 91,1% está cumprindo a jornada de trabalho de 30 horas semanais. A pesquisa chama atenção para duas questões centrais. A primeira refere-se aos impactos das condições de trabalho dos assistentes sociais no modo de apropriação dos instrumentos e das técnicas, em virtude do processo de precarização e de burocratização que vivenciam. Atrelado a esse processo, deparam-se com o sucateamento das políticas e com os parcos recursos para desenvolverem suas atividades e atenderem às demandas dos usuários. A segunda questão deve-se à ausência de conteúdos e de saberes para potencializar o uso dos instrumentos e das técnicas no seu cotidiano profissional. Nessa perspectiva, sugiro a arte como uma mediação importante, tendo em vista qualificar a sua ação e instigar processos emancipatórios junto aos sujeitos que trabalham. Diante das reflexões construídas nesta pesquisa, sustento a minha tese de que, para o assistente social desenvolver um trabalho competente, na direção do projeto ético-político, é vital apropriar-se da teoria social marxista e utilizá-la em conjunto com outros conhecimentos que possibilitem ampliar suas cadeias de mediações, tendo em vista construir ações e respostas profissionais conectadas ao tempo presente e de acordo com a teoria que tem por norte

<p>This thesis deals with the development and calibrations of sensors to measure energetic neutral atoms (ENAs) at Mars, Venus, and the Earth. ENAs are formed in charge exchange processes between energetic, singly--charged ions and a cold neutral gas. Since ENAs can travel in long straight trajectories, unaffected by electric or magnetic fields, they can be used to remotely image plasma interactions with neutral atmospheres. ENA instrument techniques have matured over the last decade and ENA images of the Earth's ring current for example, have successfully been analyzed to extract ion distributions and characterize plasma flows and currents in the inner magnetosphere.</p><p>Three different ENA sensors have been developed to image ENAs at Mars, Venus, and the Earth. Two of them, the nearly identical Neutral Particle imagers (NPIs) are on-board the Mars Express and Venus Express spacecraft as a part of the Analyzer of Space Plasmas and Energetic Atoms (ASPERA-3 and 4) instruments. The third is the Neutral Atom Detector Unit, NUADU, aboard the TC-2 spacecraft of the Double Star mission. The NPI design is based on a surface reflection technique to measure low energy (~0.3-60 keV) ENAs, while the NUADU instrument is based on a simple design with large geometrical factor and solid state detectors to measure high energy ENAs (~20-300 keV).</p><p>The calibration approach of both NPI sensors were to define the detailed response, including properties such as the angular response function and efficiency of one reference sensor direction then find the relative response of the other sensor directions. Because of the simple geometry of the NUADU instrument, the calibration strategy involved simulations to find the cutoff energy, geometrical factor and angular response. The NUADU sensor head was then calibrated to find the response to particles of different mass and energy. The NPI sensor for the Mars Express mission revealed a so-called priority effect in the sensor that lowers the angular resolution at high detector bias. During the calibration of the Venus Express NPI sensor tests were made which showed that the priority effect is a result of low amplitude (noise) pulses generated in the detector system. The conclusion is that the effect is caused by capacitive couplings between different anode sectors of the sensor. The thresholds on the preamplifiers were set higher on the Venus Express NPI, which removed the priority effect.</p><p>Two of the three ENA experiments, the Double Star NUADU instrument and the Mars Express NPI sensor, have successfully measured ENAs that are briefly described in the thesis. The first ENA measurements at Mars were performed with Mars Express. Initial results from the NPI include measurements of ENAs formed in the Martian magnetosheath and solar wind ENAs penetrating to the nightside of Mars. The first results from NUADU in Earth orbit show the expected ENA emissions from a storm time ring current. Also, together with the HENA instrument on the IMAGE spacecraft, NUADU have produced the first multi-point ENA image of the ring current.</p>

This thesis deals with the development and calibrations of sensors to measure energetic neutral atoms (ENAs) at Mars, Venus, and the Earth. ENAs are formed in charge exchange processes between energetic, singly--charged ions and a cold neutral gas. Since ENAs can travel in long straight trajectories, unaffected by electric or magnetic fields, they can be used to remotely image plasma interactions with neutral atmospheres. ENA instrument techniques have matured over the last decade and ENA images of the Earth's ring current for example, have successfully been analyzed to extract ion distributions and characterize plasma flows and currents in the inner magnetosphere. Three different ENA sensors have been developed to image ENAs at Mars, Venus, and the Earth. Two of them, the nearly identical Neutral Particle imagers (NPIs) are on-board the Mars Express and Venus Express spacecraft as a part of the Analyzer of Space Plasmas and Energetic Atoms (ASPERA-3 and 4) instruments. The third is the Neutral Atom Detector Unit, NUADU, aboard the TC-2 spacecraft of the Double Star mission. The NPI design is based on a surface reflection technique to measure low energy (~0.3-60 keV) ENAs, while the NUADU instrument is based on a simple design with large geometrical factor and solid state detectors to measure high energy ENAs (~20-300 keV). The calibration approach of both NPI sensors were to define the detailed response, including properties such as the angular response function and efficiency of one reference sensor direction then find the relative response of the other sensor directions. Because of the simple geometry of the NUADU instrument, the calibration strategy involved simulations to find the cutoff energy, geometrical factor and angular response. The NUADU sensor head was then calibrated to find the response to particles of different mass and energy. The NPI sensor for the Mars Express mission revealed a so-called priority effect in the sensor that lowers the angular resolution at high detector bias. During the calibration of the Venus Express NPI sensor tests were made which showed that the priority effect is a result of low amplitude (noise) pulses generated in the detector system. The conclusion is that the effect is caused by capacitive couplings between different anode sectors of the sensor. The thresholds on the preamplifiers were set higher on the Venus Express NPI, which removed the priority effect. Two of the three ENA experiments, the Double Star NUADU instrument and the Mars Express NPI sensor, have successfully measured ENAs that are briefly described in the thesis. The first ENA measurements at Mars were performed with Mars Express. Initial results from the NPI include measurements of ENAs formed in the Martian magnetosheath and solar wind ENAs penetrating to the nightside of Mars. The first results from NUADU in Earth orbit show the expected ENA emissions from a storm time ring current. Also, together with the HENA instrument on the IMAGE spacecraft, NUADU have produced the first multi-point ENA image of the ring current.

<p>Metalloproteins, or proteins with a metal ion cofactor, are essential for biological function of both lower and higher level organisms. These proteins provide a multitude of functions from molecular transport, such as the hemoglobin transport of oxygen, to biologically important catalytic processes. As an example case, photosystem II (PSII) is studied as a representative metalloprotein. It was chosen based on the potential impact in the energy sector due to its ability to perform water oxidation using solar based energy. Understanding mechanisms by which the Mn₄Ca cluster inside PSII, also known as the oxygen evolving complex (OEC), can store energy as redox equivalents for splitting water will be essential for future development of analogous artificial systems. By using time resolved x-ray spectroscopy, the electron structure of the metal in the protein was probed through the catalytic cycle. While the applications mentioned herein are based on PSII from spinach, the developments in time-resolved x-ray spectroscopy techniques are also applicable to other metalloproteins.</p><p></p><p>By creating a new x-ray spectrometer we were able to capture the difference in x-ray emission spectra between two compounds differing in a single metal bound ligand, i.e. Mn^IV-OH and Mn^IV=O. This both establishes the functionality of the x-ray emission spectrometer and provides useful insight into the expected changes upon an oxygen double bond formation. This change in spectroscopic signal is discussed in context of the OEC which has been hypothesized to form a Mn^IV=O state.</p><p></p><p>A new sample delivery system and further developments to the x-ray spectrometer enabled both time-resolved x-ray absorption and time-resolved x-ray emission of PSII. These experiments show the potential of synchrotron sources for time-resolved x-ray spectroscopy. From our x-ray absorption measurements we were able to follow the electronic structure changes in time using a single incident photon energy. From the kinetic traces obtained, we show possible alternative interpretations of previous results showing a delay in reduction during the final step in water oxidation. From the x-ray emission spectroscopy (XES) measurements of PSII we were able to reproduce previous results within a limited collection time and give estimates for data size requirements for metalloproteins using this spectrometer. Between the results of both these measurements, we show the improved capability for time resolved measurements at synchrotrons.</p><p>The development of x-ray free electron lasers (XFELs) has also opened many opportunities for understanding faster electronic dynamics by providing femtosecond x-ray pulse durations with ~10¹² photons per pulse. While theoretical modeling of distortions to crystallographic data have been performed, little to no work has been done to understand under what conditions such an intense pulse will have on an impact on emission spectra. Here an atomistic model was developed, and data collected, to clarify the effects of sequential ionization, i.e. two single photons absorbed by the same atom at different times during a single pulse. Experimentally we found that XFELs easily achieve flux densities that invoke a different response than is classically observed for single photon absorption and emission for Mn^II which was used as a representative case for 3d transition metals in general. We also give parameters by which the onset of this damage can be predicted and an approximation to its effect on 3d transition metals. Additionally this work guides the work of future XFEL facilities as it shows that shorter pulses, currently believed to be able to escape x-ray induced distortions to crystallography data, is not a viable method for overcoming changes in x-ray emission spectra.</p><div><br></div>

The hydrophobicity of a surface is an important property in many areas of science and engineering. This is especially the case in mineral processing, where differences in surface hydrophobicity lie at the heart of the separation process of flotation. Chemicals are used to increase and decrease the natural hydrophobicity of minerals to attain a better separation between valuable and worthless material. Polymers are often used to reduce mineral surface hydrophobicity. Decades of empirically based decision making have produced a list of effective depressants. However the detailed study of how these polymer depressants affect surface hydrophobicity and mineral recovery lags behind applied investigations. The aim of this thesis was to study the adsorption of commonly used depressants on model surfaces and to interrogate the action of these polymers in reducing surface hydrophobicity. We have modelled the degree of hydrophobicity of common minerals in order to study polymer depressants with methods not commonly used in studies of surface characterisation in flotation. The model surfaces (self-assembled monolayers, SAMs) allowed us to use the quartz crystal microbalance with dissipation monitoring (QCM-D) to study the adsorption of polymers. The QCM-D can be used to obtain adsorption isotherms, adsorption kinetics, water content of adsorbed layers, and information on the conformation of the adsorbed polymer. The results from the QCM-D were correlated with the contact angle data from the captive bubble measurements, with which we assessed the hydrophobicity of the surface before and after polymer adsorption. Three of the polymers layers were probed with dynamic dewetting studies, in order to test other modes of depressant action. Three types of polymers were studied - a polyacrylamide (Polymer-H), a polyelectrolyte CMC (carboxymethyl cellulose) and a group of dextrins (Dextrin-TY, a phenyl succinate substituted dextrin (PS Dextrin) and a styrene oxide substituted dextrin (SO Dextrin)). These polymers are commonly used or have potential to be used in the depression of talc and graphite. Polymer-H was used to investigate the hydrophobic bonding between a non-ionic polymer depressant and chemically inert and non charged surfaces by probing the influence of substrate hydrophobicity on polymer adsorption and reduction of contact angle. Three different model surfaces were used (mixed self-assembled 0.5 SAM, 0.7 SAM or single self-assembled 1.0 SAM monolayers) with advancing contact angles between 75?? and 119??. The study of Polymer-H found that the substrate hydrophobicity is an important factor in adsorption of this polymer and the change in contact angle upon adsorption depends on adsorbed amount. The effectiveness of Polymer-H to reduce surface hydrophobicity was established to correlate with its conformation and morphology. CMC was investigated to find out how a stimulus responsive polymer depressant can be used in flotation. It was established that the adsorbed amount and rate of adsorption of CMC increase with decreasing of pH or increasing of ionic strength. It was shown that the surface hydrophobicity of a CMC pre-adsorbed layer changes with the environment and these alterations are fully reversible. A switch of ionic strength (from 10-2 M KCl to 10-1 M KCl) caused partial dehydration of the adsorbed layer and a decrease of the receding contact angle by 20??. A pH switch (pH = 9 to pH = 3) resulted in a 40?? change in receding contact angle. The CMC investigation showed that the use of a stimulus responsive polymer presents opportunities for exploiting solution conditions as a means to effect a better mineral separation in flotation The adsorption of three dextrin-based polymers on a model hydrophobic surface has been characterized using the quartz crystal microbalance with dissipation monitoring (QCM-D). The three polymers (one standard dextrin and two dextrins with different aromatic group substitutions) exhibited varying affinities and capacity for adsorption on the hydrophobic substrate. The effect of the three polymers on the static contact angle of the surface was studied using captive bubble contact angle measurements. The three polymers were seen to reduce the receding contact angle by similar amounts (approximately 14 degrees) in spite of having varying adsorbed amounts and differences in adsorbed layer water content. Although no differences were observed in the ability of the polymers to reduce the static contact angle, measurements of the dewetting dynamics between a rising air bubble and the polymer covered substrate yielded stark differences between the polymers, with one polymer slowing the dewetting dynamics by an order of magnitude more than the other two polymers. The differences in dewetting behaviour correlate with the adsorbed layer characteristics determined by QCM-D. / Thesis (PhD)--University of South Australia, 2010

The combination of analytical sensitivity and selectivity provided by time-of-flight secondary ion mass spectrometry (ToF-SIMS), with advanced statistical interrogation by principal component analysis (PCA), has allowed a significant advancement in the forensic discrimination of pen, pencil and glass materials based on trace characterisation.

The hydrophobicity of a surface is an important property in many areas of science and engineering. This is especially the case in mineral processing, where differences in surface hydrophobicity lie at the heart of the separation process of flotation. Chemicals are used to increase and decrease the natural hydrophobicity of minerals to attain a better separation between valuable and worthless material. Polymers are often used to reduce mineral surface hydrophobicity. Decades of empirically based decision making have produced a list of effective depressants. However the detailed study of how these polymer depressants affect surface hydrophobicity and mineral recovery lags behind applied investigations. The aim of this thesis was to study the adsorption of commonly used depressants on model surfaces and to interrogate the action of these polymers in reducing surface hydrophobicity. We have modelled the degree of hydrophobicity of common minerals in order to study polymer depressants with methods not commonly used in studies of surface characterisation in flotation. The model surfaces (self-assembled monolayers, SAMs) allowed us to use the quartz crystal microbalance with dissipation monitoring (QCM-D) to study the adsorption of polymers. The QCM-D can be used to obtain adsorption isotherms, adsorption kinetics, water content of adsorbed layers, and information on the conformation of the adsorbed polymer. The results from the QCM-D were correlated with the contact angle data from the captive bubble measurements, with which we assessed the hydrophobicity of the surface before and after polymer adsorption. Three of the polymers layers were probed with dynamic dewetting studies, in order to test other modes of depressant action. Three types of polymers were studied - a polyacrylamide (Polymer-H), a polyelectrolyte CMC (carboxymethyl cellulose) and a group of dextrins (Dextrin-TY, a phenyl succinate substituted dextrin (PS Dextrin) and a styrene oxide substituted dextrin (SO Dextrin)). These polymers are commonly used or have potential to be used in the depression of talc and graphite. Polymer-H was used to investigate the hydrophobic bonding between a non-ionic polymer depressant and chemically inert and non charged surfaces by probing the influence of substrate hydrophobicity on polymer adsorption and reduction of contact angle. Three different model surfaces were used (mixed self-assembled 0.5 SAM, 0.7 SAM or single self-assembled 1.0 SAM monolayers) with advancing contact angles between 75?? and 119??. The study of Polymer-H found that the substrate hydrophobicity is an important factor in adsorption of this polymer and the change in contact angle upon adsorption depends on adsorbed amount. The effectiveness of Polymer-H to reduce surface hydrophobicity was established to correlate with its conformation and morphology. CMC was investigated to find out how a stimulus responsive polymer depressant can be used in flotation. It was established that the adsorbed amount and rate of adsorption of CMC increase with decreasing of pH or increasing of ionic strength. It was shown that the surface hydrophobicity of a CMC pre-adsorbed layer changes with the environment and these alterations are fully reversible. A switch of ionic strength (from 10-2 M KCl to 10-1 M KCl) caused partial dehydration of the adsorbed layer and a decrease of the receding contact angle by 20??. A pH switch (pH = 9 to pH = 3) resulted in a 40?? change in receding contact angle. The CMC investigation showed that the use of a stimulus responsive polymer presents opportunities for exploiting solution conditions as a means to effect a better mineral separation in flotation The adsorption of three dextrin-based polymers on a model hydrophobic surface has been characterized using the quartz crystal microbalance with dissipation monitoring (QCM-D). The three polymers (one standard dextrin and two dextrins with different aromatic group substitutions) exhibited varying affinities and capacity for adsorption on the hydrophobic substrate. The effect of the three polymers on the static contact angle of the surface was studied using captive bubble contact angle measurements. The three polymers were seen to reduce the receding contact angle by similar amounts (approximately 14 degrees) in spite of having varying adsorbed amounts and differences in adsorbed layer water content. Although no differences were observed in the ability of the polymers to reduce the static contact angle, measurements of the dewetting dynamics between a rising air bubble and the polymer covered substrate yielded stark differences between the polymers, with one polymer slowing the dewetting dynamics by an order of magnitude more than the other two polymers. The differences in dewetting behaviour correlate with the adsorbed layer characteristics determined by QCM-D. / Thesis (PhD)--University of South Australia, 2010