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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Surface modification and chromophore attachment via ionic assembly and covalent fixation

Hubbell, Christopher 09 January 2009 (has links)
A reactive-ionic functional group was incorporated into the structure of fiber finishes and colorants to provide high-yield add-on and permanency. The reactive-ionic group consists of a moderately strained, cyclic ammonium group which undergoes ionic assembly on the surface of negatively charged substrates. The ionic bond is then converted to a covalent bond at elevated temperatures via a ring-opening reaction. A reactive-ionic alkyl (wax) finish was prepared from octadecanol and N-phenyl pyrrolidine then applied to a glass slide to provide a permanent, hydrophobic surface with an average contact angle increase of approximately 40°. A reactive-ionic fluorinated finish was prepared from 1H,1H,2H,2H-perfluoro-1-octanol and N-phenyl pyrrolidine and after application served as a permanent, non-wetting, anti-stain finish for nylon carpet. A reactive-ionic chromophore (dye) was prepared from C.I. Disperse Red 1 and quinuclidine. The reactive-ionic dye was applied to cellophane and nylon films and bleached cotton, nylon and silk fabrics. The percent exhaustion for a 1% owf dyeing of silk fabric was measured to be 98% using visible light absorbance spectrophotometry. K/S values obtained from reflectance spectrophotometric measurements of a 1% owf dyeing of nylon 6,6 fabric showed a 6% color loss after solvent extraction, indicating that the dyeing was indeed permanent.

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