Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 1988. / Includes bibliographical references. / Inverse methods are applied to historical hydrographic data to address two aspects of the general circulation of the Atlantic Ocean. The method allows conservation statements for mass and other properties, along with a variety of other constraints, to be combined in a dynamically consistent way to estimate the absolute velocity field and associated property transports. The method is first used to examine the exchange of mass and heat between the South Atlantic and the neighboring ocean basins. The Antarctic Circumpolar Current (ACC) carries a surplus of intermediate water into the South Atlantic through Drake Passage which is compensated by a surplus of deep and bottom water leaving the basin south of Africa. As a result, the ACC loses .25+.18x10' 5 W of heat in crossing the Atlantic. At 32*S the meridional flux of heat is .25±.19x1015 W equatorward, consistent in sign but smaller in magnitude than other recent estimates. This heat flux is carried primarily by a meridional overturning cell in which the export of 17 Sv of North Atlantic Deep Water (NADW) is balanced by an equatorward return flow equally split between the surface layers, and the intermediate and bottom water. No "leak" of warm Indian Ocean thermocline water is necessary to account for the equatorward heat flux across 32*S; in fact, a large transfer of warm water from the Indian Ocean to the Atlantic is found to be inconsistent with the present data set. Together these results demonstrate that the Atlantic as a whole acts to convert intermediate water to deep and bottom water, and thus that the global thermohaline cell associated with the formation and export of NADW is closed primarily by a "cold water path," in which deep water leaving the Atlantic ultimately returns as intermediate water entering the basin through Drake Passage. The second problem addressed concerns the circulation and property fluxes across 24*and 36*N in the subtropical North Atlantic. Conservation statements are considered for the nutrients as well as mass, and the nutrients are found to contribute significant information independent of temperature and salinity. Silicate is particularly effective in reducing the indeterminacy of circulation estimates based on mass conservation alone. In turn, the results demonstrate that accurate estimates of the chemical fluxes depend on relatively detailed knowledge of the circulation. The zonal-integral of the circulation consists of an overturning cell at both latitudes, with a net export of 19 Sv of NADW. This cell results in a poleward heat flux of 1.3±.2z10'5 W and an equatorward oxygen flux of 2900±180 kmol s-' across each latitude. The net flux of silicate is also equatorward: 138±38 kmol s-1 and 152±56 kmol s-1 across 36 0and 24*N, respectively. However, in contrast to heat and oxygen, the overturning cell is not the only important mechanism responsible for the net silicate transport. A horizontal recirculation consisting of northward flow of silica-rich deep water in the eastern basin balanced by southward flow of low silica water in the western basin results in a significant silicate flux to the north. The net equatorward flux is thus smaller than indicated by the overturning cell alone. The net flux of nitrate across 36*N is 119±35 kmol s- to the north and is indistinguishable from zero at 24*N (-8±39 kmol s-1), leading to a net divergence of nitrate between these two latitudes. Forcing the system to conserve nitrate leads to an unreasonable circulation. The dominant contribution to the nitrate flux at 36*N results from the correlation of strong northward flow and relatively high nitrate concentrations in the sub-surface waters of the Gulf Stream. The observed nitrate divergence between 24*and 36 0N, and convergence north of 36*N, can be accounted for by a shallow cell in which the northward flow of inorganic nitrogen (nitrate) in the Gulf Stream is balanced by a southward flux of dissolved organic nitrogen in the recirculation gyre. Oxidation of the dissolved organic matter during its transit of the subtropical gyre supplies the required source of regenerated nitrate to the Gulf Stream and consumes oxygen, consistent with recent observations of oxygen utilization in the Sargasso Sea. / by Stephen Rich Rintoul. / Ph.D.

Thesis (Ph.D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences and the Woods Hole Oceanographic Institution), 2000. / Vita. / Includes bibliographical references. / by Robert P. Ackert, Jr. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2012. / Cataloged from PDF version of thesis. / Includes bibliographical references. / As the only low-latitude connection between ocean basins, the Indonesian Throughflow allows the direct transmission of heat and salinity between the Pacific and Indian Oceans. Despite its potential importance, the role of the Indonesian Throughflow in global ocean circulation and regional climate is still not clear due to sparse measurements and the relative difficulty of modeling the region. The Mg/Ca and [delta]¹⁸0 of calcite of the calcitic planktic foraminifera Globigerinoides ruber (G. ruber) were used to estimate the sea surface temperature and [delta]¹⁸0 of water, an indicator of hydrologic conditions, over the past 20,000 years. I also attempted to estimate thermocline structure using the foraminifera, Pulleniatina obliquiloculata, but the Mg/Ca and [delta]¹⁸0 of calcite data yield conflicting interpretations, indicating further work on this proxy is required. The G. ruber Mg/Ca results suggest that the sea surface temperature of the outflow passages was influenced by high latitude Southern Hemisphere temperature. This connection is likely via intermediate waters that upwell in the Banda Sea. At approximately 10,000 years before present, there was a warming in the Makassar Strait. This local warming was coincident with the flooding of the Sunda Shelf, which opened a connection between the South China Sea and the Indonesian Throughflow. Regional [delta]¹⁸0 of seawater reconstructions show that during the last glacial maximum the [delta]¹⁸0 of seawater pattern was very similar to modern, but there were relatively enriched values over the equatorial IndoPacific during high latitude Northern Hemisphere cold events (Heinrich Stadial 1 and the Younger Dryas). From these results we postulate that the mean position of the Intertropical Convergence Zone was approximately the same as modern at the last glacial maximum and was likely displaced to the south during the Younger Dryas and Heinrich Stadial 1, suggesting the Intertropical Convergence Zone primarily responds to changes in the interhemispheric temperature gradient. These results shed light on the primary controls of the temperature and hydrology of Indonesian Throughflow region. / by Fern Tolley Gibbons. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2005. / Includes bibliographical references (p. 131-149). / This thesis evaluates the nature and magnitude of tropical climate variability from the Last Glacial Maximum to the present. The temporal variability of two specific tropical climate phenomena is examined. The first is the position of the Intertropical Convergence Zone (ITCZ) in the Atlantic basin, which affects sea surface temperature (SST) and precipitation patterns throughout the tropical Atlantic. The second is the strength of the Indian Monsoon, an important component of both tropical and global climate. Long-term variations in the position of the ITCZ in the Atlantic region are determined using both organic geochemical techniques and climate modeling. Upwelling in Cariaco Basin is reconstructed using chlorin steryl esters as proxies for phytoplankton community structure. We find that the diatom population was larger during the Younger Dryas cold event, indicating that upwelling was enhanced and the mean position of the ITCZ was farther south during the Younger Dryas than it is today. A climate simulation using an ocean-atmosphere general circulation model confirms these results by demonstrating that the ITCZ shifts southward in response to high-latitude cooling. The climate of the Arabian Sea region is dominated by the Indian Monsoon. / (cont.) Results from modern sediments from a suite of cores located throughout the Arabian Sea suggest that wind strength is well represented by the accumulation rate and carbon isotopic composition of terrestrially-derived plant waxes in sediments. Arabian Sea SST patterns, reconstructed from a suite of sediment cores representing four time slices utilizing the Mg/Ca SST proxy, suggest that both the summer and winter monsoons were enhanced 8,000 yr BP relative to today while the summer monsoon was weaker and the winter monsoon stronger at 15,000 and 20,000 yr. These results are confirmed by a time-series reconstruction of SST on the Oman Margin that reveals that SST at this site is sensitive to both regional and global climate processes. The results of this thesis demonstrate that tropical climate, as evaluated by a number of different proxies as well as climate models, has varied substantially over the past 20,000 years and is closely coupled to climate at high-latitudes. / by Kristina Ariel Dahl. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2004. / Includes bibliographical references (p. 188-198). / Relatively little is known about the role of eddies in controlling subduction in the eastern half of the subtropical gyre. Here, a new tool to study the eastern North Atlantic Ocean is created by combining a regional, eddy-resolving numerical model with observations to produce a state estimate of the ocean circulation. The estimate is a synthesis of a variety of in-situ observations from the Subduction Experiment, TOPEX/POSEIDON altimetry, and the MIT General Circulation Model. A novel aspect of this work is the search for an initial eddy field and eddy-scale open boundary conditions by the use of an adjoint model. The adjoint model for this region of the ocean is stable and yields useful information despite concerns about the chaotic nature of eddy-resolving models. The method is successful because the dynamics are only weakly nonlinear in the eastern region of the subtropical gyre. Therefore, no fundamental obstacle exists to constraining the model to both the large scale circulation and the eddy scale in this region of the ocean. Individual eddy trajectories can also be determined. The state estimate is consistent with observations, self-consistent with the equations of motion, and it explicitly resolves eddy-scale motions with a 1/6⁰ grid. Therefore, subduction rates, volume budgets, and buoyancy budgets are readily diagnosed in a physically interpretable context. Estimates of eddy subduction for the eastern subtropical gyre of the North Atlantic are larger than previously calculated from parameterizations in coarse-resolution models. Eddies contribute up to 40 m/yr of subduction locally. Furthermore, eddy subduction rates have typical magnitudes of 15% of the total subduction rate. To evaluate the net effect of eddies on an individual density class, / (cont.) volume budgets are diagnosed. Eddies contribute as much as 1 Sv to diapycnal flux, and hence subduction, in the density range 25.5 < [sigma] < 26.5. Eddies have a integrated impact which is sizable relative to the 2.5 Sv of diapycnal flux by the mean circulation. A combination of Eulerian and isopycnal maps suggest that the North Equatorial Current and the Azores Current are the geographical centers of eddy subduction. The findings of this thesis imply that the inability to resolve or accurately parameterize eddy subduction in climate models would lead to an accumulation of error in the structure of the main thermocline, even in the eastern subtropical gyre, which is a region of comparatively weak eddy motions. / by Geoffrey Alexander Gebbie. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2007. / Includes bibliographical references. / Basaltic ocean crust has the potential to host one of the largest endolithic communities on Earth. This portion of the biosphere, however, remains largely unexplored. In this study, we utilize molecular biological, microscopic, and geochemical tools to gain a better understanding of the geomicrobiology of the ocean crust. Specifically, we examine the phylogenetic diversity of microorganisms inhabiting basaltic lavas, the activities and abundances of these microorganisms, the spatial extent of the biosphere, and the potential effect that microbial activity has on the geochemistry of the ocean crust and overlying water column. Our study demonstrates that young, fresh volcanic lavas near mid-ocean ridges host an incredibly diverse and dense population of microorganisms dominated by Bacteria, quite distinct from the microbial communities found in surrounding deep seawater and hydrothermal vents. Furthermore, these communities may contribute to the elemental cycling of Fe, S, Mn, N, and C in this environment. The inability to definitively identify microorganisms in drill-cores of old (> 15 Ma) ocean crust, however, implies that these once prolific communities may become scarce as the crust ages and moves further away from the ridge axis. Finally, we provide evidence suggesting that these communities are fueled by oxidative alteration reactions occurring in the basaltic crust. / by Cara M. Santelli. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 1987. / Supervised by William J. Jenkins. "September 1987." / Includes bibliographical references (p. 241-250). / The isotopic evolution of helium and lead in the Earth is coupled by virtue of their common radioactive parents uranium and thorium. The isotopic signatures in oceanic volcanic rocks provide constraints on the temporal evolution of mantle source regions and volcanic magmas. He and Pb isotopes were measured in glassy basalts from young seamounts in the East Pacific, and in phenocrysts and corresponding whole rocks, respectively, from the island of St. Helena. He isotopes were also measured in glassy mid-ocean ridge basalts from the South Atlantic, previously studied for Pb isotopes by Hanan et al. (1986). A precise reconstruction of He-Pb isotope relationships in volcanic source regions is complicated by post-eruptive radiogenic ingrowth of ⁴He in non-zero age basalts, by pre-eruptive radiogenic ingrowth of ⁴He in magmas with elevated (U+Th)/He, by multi-stage fractionation processes involving (U+Th)/He, U/Pb and Th/Pb and by convective mixing in the Earth's interior. Aspects of each of these problems are addressed. (U+Th)/He ages are estimated from the isotope disequilibrium of ³He/ ⁴He between He trapped in vesicles and that dissolved in the glass phase of young alkali basalts at seamount 6 in the East Pacific. ³He/ ⁴He in the glass phase of these alkali basalts is subatmospheric, while in the vesicles it ranges between 1.2-2.5 RA (RA = atmospheric ratio). ³He/ ⁴He in vesicles (extracted by crushing in vacuo) allows a correction to be made in the dissolved phase He (by fusion of the remaining powder) for the inherited component in order to compute the radiogenic [He]. The method is applicable to rocks containing phases with different (U+Th)/He, and the results have implications for dating lavas in the age range of 0l to 106 years, and for reconstructing the temporal evolution of young volcanic systems. / (cont.) Pb, Sr and Nd isotopic variability observed at a small seamount field between 9-14'N near the East Pacific Rise covers -80% of the variability for Pacific MORB, due to small-scale heterogeneity in the underlying mantle. Tholeiites at these seamounts have He, Pb, Sr and Nd isotope compositions which are indistinguishable from MORB. Associated alkali basalts show more radiogenic He, Pb and Sr signatures. The lower ³He/⁴Heof He trapped in vesicles of these alkali basalts (1.2-2.6 RA) iS associated with low helium concentrations (< 5x10-' ccSTP/g). Evolved alkali basalts have lower ³He/⁴He (1.2-1.8 RA) than primitive alkali basalts (2.4-2.6 RA), suggesting some degree of magmatic control on inherited ³He/ ⁴He in these alkalic lavas. Collectively, the isotopic results suggest that as the lithosphere ages, material transfer from the MORB source becomes less significant because smaller degrees of melting average the chemical characteristics of heterogeneous mantle volumes less efficiently than near the ridge. Icelandites erupted at Shimada Seamount, an isolated volcano on 20 m.y. old seafloor, have Pb, Sr and Nd isotopic compositions similar to post-erosional basalts at Samoa. ³He/⁴He at Shimada ranges between 3.9-4.8 RA and helium concentrations are too large for radiogenic contamination of magma to have lowered the ³He/⁴He appreciably. These results indicate the presence of an enriched mantle component previously unidentified beneath the East Pacific. Its low ³He/⁴He may be due to the melting of domains with high (U+Th)/He which formed during accretion of the oceanic lithosphere. Alternatively, it is an inherent characteristic of the source, which contains material recycled into the mantle at subduction zones. / (cont.) The mid-ocean ridge between 12-46°S in the South Atlantic displays ³He/⁴He lower than typical MORB values. Local anomalies occur at the latitudes of off-axis islands to the east, apparently due to contamination of depleted mantle asthenosphere by hotspot materials (as previously shown for (La/Sm)N and Pb isotopes; Schilling et al., 1985; Hanan et al., 1986). He - Pb Isotopic relationships along the 12-22°S ridge segment suggest that St. Helena has ³He/4 He less than MORB. ³He/⁴He in two St. Helena rocks (extracted by in vacuo crushing of olivine and pyroxene) is 5.8 RA when the extracteTdHe contents are greater than IxI0 - 13 ccSTP/g, consistent with the He - Pb observations along the St. Helena ridge segment. ⁴He/ ³He and radiogenic Pb isotope ratios are linearly correlated for the South Atlantic ridge segment between 2-120S. Linear correlation of ⁴He/3 He - ²⁰⁶Pb/ ²⁰⁴Pb within an oceanic rock suite reflects the temporal evolution of ²⁰⁴Pb / ³He In the source. A linear correlation between volcanic suites derived from isotopically different sources (e.g., oceanic islands) may imply a coherent fractionation of (U+Th) from He and Pb during the evolutionary history of their respective mantle source regions. / by David W. Graham. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), June 1990. / "April 1990." / At scale lengths less than 100 km or so, statistical descriptions of seafloor morphology can be usefully employed to characterize processes which form and reshape abyssal hills, including ridge crest volcanism, off-axis tectonics and volcanism, mass wasting, sedimentation, and post-depositional transport. The objectives of this thesis are threefold: (1) to identify stochastic parameterizations of small-scale topography that are geologically useful, (2) to implement procedures for estimating these parameters from multibeam and side-scan sonar surveys that take into account the finite precision, resolution, and sampling of real data sets, and (3) to apply these techniques to the study of marine geological problems. The seafloor is initially modeled as a stationary, zero-mean, Gaussian random field completely specified by its two-point covariance function. An anisotropic two-point covariance function is introduced that has five free parameters describing the amplitude, orientation, characteristic width and length, and Hausdorff (fractal) dimension of seafloor topography. The general forward problem is then formulated relating this model to the statistics of an ideal multibeam echo sounder, in particular the along-track auto-covariance functions of individual beams and the cross-covariance functions between beams of arbitrary separation. Using these second moments as data functionals, we then pose the inverse problem of estimating the seafloor parameters from realistic, noisy data sets with finite sampling and beamwidth, and we solve this inverse problem by an iterative, linearized, least squares method. Resolution of this algorithm is tested against ship variables such as length of data, the orientation of ship track with respect to topographic grain, and the beamwidth. This analysis is conducted by inverting sets of synthetic data with known statistics. The mean and standard deviation of the inverted parameters can be directly compared with the input parameters and the standard errors output from the inversion. The experiments conducted in this study show that the rms seafloor height can be estimated to within -15% and anisotropic orientation to within ~5* (for a strong lineation) using very short track lengths (down to 3 characteristic lengths, or -10 to 100 km), and characteristic lengths of seafloor topography can be estimated to within -25% using fairly short track lengths (down to 5 or 6 characteristic lengths, or 10's of km to -200 kin). The number of characteristic lengths sampled by a ship track, and hence the accuracy of the estimation, is maximized when the ship track runs perpendicular to abyssal hill lineation. Using the assumed beamwidth, the measured noise values, and the seafloor parameters recovered from the inversion, Sea Beam "synthetics" are generated whose statistical character can be directly compared with raw Sea Beam data. However, these comparisons are spatially limited in the athwart ship direction. A recent SeaMARC II survey along the flanks and crest of the East Pacific Rise between 130 and 15* N included sufficient off-axis topography to permit a comparison of a complete 2-D synthetic topographic field with a region of abyssal-hill terrain that has close to 100% data coverage. Synthetic data is compared to both Sea Beam swaths and SeaMARC II survey data. These comparisons generally indicate that we are successful in characterizing the second order properties of the seafloor. They also indicate the directions we will need to take to improve our modeling, including generalization of the second-order model and characterization of higher moments. The inversion procedure is applied to a data set of 64 near-ridge Sea Beam swaths to characterize near ridge abyssal hill morphology and its relationship to ridge properties. Much of the data (27 swaths) comes from cruises to the Pacific-Cocos spreading section of the East Pacific Rise between 9* and 15* N. These data provide very good abyssal hill coverage of this well-mapped and studied ridge section and form the basis of a regional analysis of the correlation between ridge morphology and stochastic abyssal hill parameters. This regional analysis suggests a strong relationship between magma supply and the character of abyssal hills. We also have data from near the Rivera (9) and Nazca (7) spreading sections of the East Pacific Rise, the Mid-Atlantic Ridge (18), and the Indian- African Ridge (3). Though spotty, this constitutes a good initial data set for the analysis of correlations among covariance parameters and between parameters and ridge characteristics, especially spreading rate. A working hypothesis is introduced to explain the observations within a geological framework. This hypothesis contends 1) that the maximum size of abyssal hills is related to the lithosphere's ability to elastically support the load, 2) that fissuring and horst and graben formation dominate abyssal hill formation at fast spreading ridges, and 3) that volcanic edifice formation, modified by faulting driven by lithospheric necking, dominates abyssal hill formation at slow spreading ridges. To quantify abyssal hill characteristics such as vertical and lateral asymmetry and "peakiness" we must appeal to higher statistical moments than order two. A mathematical framework is introduced for the study of higher moments of a topographic field. This framework is built upon the concept that lower-order moment provide the groundwork for studying the higher-order moments. A simple 1-D parameterized model is proposed for moments up to order 4. This model includes two parameters for the third moment, describing vertical and lateral asymmetries, and one for the fourth moment, which describes the peakiness of topography. Initial methods are developed for estimating these parameters from bathymetric profiles. Results from the near ridge data set are presented and interpreted with regard to abyssal hill forming processes. / by John Anson Goff. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Biology; and the Woods Hole Oceanographic Institution), 2013. / This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections. / Cataloged from student-submitted PDF version of thesis. / Includes bibliographical references. / Seafloor digital imagery and bathymetric data are used to evaluate the volcanic characteristics of the 85°E segment of the ultraslow spreading Gakkel Ridge (9 mm yr-¹). Imagery reveals that ridges and volcanic cones in the axial valley are covered by numerous, small-volume lava flows, including a few flows fresh enough to have potentially erupted during the 1999 seismic swarm at the site. The morphology and distribution of volcaniclastic deposits observed on the seafloor at depths of ~3800 m, greater than the critical point for steam generation, are consistent with having formed by explosive discharge of magma and CO² from source vents. Microearthquakes recorded on a 200 m aperture seismometer network deployed on the Trans-Atlantic Geotraverse active mound, a seafloor massive sulfide on the Mid-Atlantic Ridge at 26°N, are used to image subsurface processes at the hydrothermal system. Over nine-months, 32,078 local microearthquakes (ML = -1) with single-phase arrivals cluster on the southwest flank of the deposit at depths <125 m. Microearthquakes characteristics are consistent with reaction-driven cracking driven by anhydrite deposition in the shallow secondary circulation system. Exit fluid temperatures recorded at diffuse vents on the mound during the microearthquake study are used to explore linkages between seismicity and venting. / by Claire Willis Pontbriand. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Science; and the Woods Hole Oceanographic Institution), 2002. / Includes bibliographical references (p. 221-243). / This thesis investigates the evolution of lithospheric deformation and crustal structure from continental margins to mid-ocean ridges. The first part (Ch. 2) examines the style of segmentation along the U.S. East Coast Margin and investigates the relationship between incipient margin structure and segmentation at the modem Mid-Atlantic Ridge. The second part (Chs. 3-5) focuses on the mechanics of faulting in extending lithosphere. In Ch. 3, I show that the incorporation of a strain-rate softening rheology in continuum models results in localized zones of high strain rate that are not imposed a priori and develop in response to the rheology and boundary conditions. I then use this approach to quantify the effects of thermal state, crustal thickness, and crustal rheology on the predicted style of extension deformation. The mechanics of fault initiation and propagation along mid-ocean ridge segments is investigated in Ch. 4. Two modes of fault development are identified: Mode C faults that initiate near the center of a segment and Mode E faults that initiate at the segment ends. Numerical results from Ch. 5 predict that over time scales longer than a typical earthquake cycle transform faults behave as zones of significant weakness. / (cont.) Furthermore, these models indicate that Mode E faults formed at the inside-corner of a ridge-transform intersection will experience preferential growth relative to faults formed at the conjugate outside-corner due to their proximity to the weak transform zone. Finally, the last part of this thesis (Ch. 6) presents a new method to quantify the relationship between the seismic velocity and composition of igneous rocks. A direct relationship is derived to relate Vp to major element composition and typical velocity-depth profiles are used to calculate compositional bounds for the lower continental, margin, and oceanic crust. / by Mark Dietrich Behn. / Ph.D.