Universiẗat, Diss., 2001--Osnabrück.

Techn. Universiẗat, Diss., 2003--Dresden.

Techn. Universiẗat, Diss., 2005--Dresden.

Thesis (Habilitationsschrift)--Friedrich-Alexander-Universität Erlangen-Nürnberg. / Includes bibliographical references (p. 225-232).

Regensburg, Universiẗat, Diss., 2003.

Freie Universiẗat, Diss., 2003--Berlin. / Erscheinungsjahr an der Haupttitelstelle: 2003. Dateiformat: zip, Dateien im PDF-Format.

Universiẗat, Diss., 2001--Kiel.

Techn. Universiẗat, Diss., 2004--Darmstadt.

Techn. University, Diss., 2004--Dresden.

Two trigonal tritopic ligands with different conformational degree of freedom: conformationally labile H3tcbpa (tris((4-carboxyl)phenylduryl)amine) and conformationally obstructed H3hmbqa (4,4′,4′′-(4,4,8,8,12,12-hexamethyl-8,12-dihydro-4H-benzo[9,1]quino-lizino[3,4,5,6,7-defg]acridine-2,6,10-triyl)tribenzoic acid) are assembled with square-planar paddle-wheel nodes with the aim of selective engineering of the frameworks with tbo and pto underlying net topologies. In the case of H3tcbpa, both topological types were obtained forming non-interpenetrated MOFs namely DUT-63 (tbo) and DUT-64 (pto). Whereas synthesis of DUT-63 proceeds under typical conditions, formation of DUT-64 requires an additional topology directing reagent (topological modifier). Solvothermal treatment of the conformationally hindered H3hmbqa ligand with the Cu-salt results exclusively in DUT-77 material, based on the single pto net. The possibility to insert the salen based metallated pillar ligand into networks with pto topology post-synthetically results in DUT-78 and DUT-79 materials (both ith-d) and opens new horizons for post-synthetic insertion of catalytically active metals within the above-mentioned topological type of frameworks.