Submitted by Igor Matos (igoryure.rm@gmail.com) on 2017-01-31T14:38:14Z No. of bitstreams: 1 DISS_2015_Jennifer Cardoso Farias Almada.pdf: 5724861 bytes, checksum: 75d76d597050375391c29d0a04f80995 (MD5) / Approved for entry into archive by Jordan (jordanbiblio@gmail.com) on 2017-01-31T15:18:18Z (GMT) No. of bitstreams: 1 DISS_2015_Jennifer Cardoso Farias Almada.pdf: 5724861 bytes, checksum: 75d76d597050375391c29d0a04f80995 (MD5) / Made available in DSpace on 2017-01-31T15:18:18Z (GMT). No. of bitstreams: 1 DISS_2015_Jennifer Cardoso Farias Almada.pdf: 5724861 bytes, checksum: 75d76d597050375391c29d0a04f80995 (MD5) Previous issue date: 2015-08-28 / CAPES / Os estágios do período pós-cosilisional do Ciclo Brasialiano/Panafricano na região de Cocalinho, porção leste do estado de Mato Grosso, divisa com o estado de Goiás, é marcado por corpos graníticos intrusivos associados a rochas máficas e ultramáficas. O Plutão Itacaiu é um corpo extenso e alongado segundo um trend regional, na direção NE/SW. É caracterizado por um magmatismo expressivo de natureza alcalina e composição que varia de monzo a álcali-feldspato-granitos. Este extenso corpo é definido por três fácies petrográficas denominadas de Fácies Biotita-Granito, Fácies RiebeckitaBiotita-Granito e Fácies Biotita-Granito Porfirítico. Os granitóides imprimem evidências de processos deformacionais decorrentes de duas fases de deformação, representada principalmente pelo desenvolvimento da foliação penetrativa marcada pela orientação preferencial dos minerais placóides, com direção NE e mergulho para SE, variando de baixo a alto ângulo, e foliação milonítica decorrente do cisalhamento de característica transcorrente. A composição química permitiu classificar essas rochas como granitos do tipo-A, gerados em ambiente de arco magmático e intra-placa pós-colisional. Dados geocronológicos U/Pb extraídas de cristais de zircão indicaram idade de cristalização variando de 806.6±4.0 a 582.9±6.3 Ma, consistentes com aquelas registradas para o Arco Magmático de Goiás. Idades modelo TDM= 0.97 a 1.08 Ga, mostram valores positivo εNd(T) = +4.39, +4.31,+3.69. Os valores positivos de εNd sugerem um empobrecimento do magma que deu origem aos granitóides em ETR leves. O valor negativo de εNd indica origem a partir de fusão parcial de crosta continental Paleoproterozóica. As rochas máficas-ultramáficas ocorrem alinhadas aproximadamente a leste-oeste, com variáveis níveis de alteração. Definem um magmatismo toleítico a cálcio-alcalino, metaluminoso, de caráter intermediário a ultrabásico. Os estudos isotópicos sugerem caráter juvenil do magma parental, devido aos valores positivos de εNd(T). As idades modelo variam de TDM = 0,71 a 1,44Ga e estão relacionadas a outras unidades de rochas juvenis do Arco Magmático de Goiás / Post-collisional stages of the Brasiliano/Pan-African Cycle in the region of Cocalinho on eastern Mato Grosso, bordering the State of Goiás, are represented by granitic intrusive bodies associated with mafic and ultramafic rocks. The Itacaiu Pluto is an NE-SWelongated body conform to the regional trend. It is characterized by a expressive magmatism of alkaline nature and composition ranging from monzo the alkali-feldspargranites. This extensive body is defined by three petrographic facies termed biotitegranite Facies, riebeckite-biotite-granite Facies and biotite-granite porphyry Facies. The granitoids show evidence of deformational processes resulting two-phase of deformation, represented mainly by development of penetrative foliation marked by the preferred orientation of minerals placoid, with direction NE and dip to SE, ranging from low to high angle, and mylonitic foliation resultant by strike-slip shear. The chemical composition allowed to classify the rocks as granite type-A, generated in magmatic arc environment and intra-plate post-collisional. Geochronological data U / Pb extracted in zircon crystals indicated crystallization age ranging from 806.6 ± 4.0 to 582.9 ± 6.3 Ma, consistent with those recorded for the Goiás Magmatic Arc. model ages TDM= 0.97 to 1.8 Ga, show positive values of εNd(T) = +4.39, +4.31,+3.69. Positive values of εNd suggest impoverishment of the magma that gave rise to the granitoids in LREE. The negative value of εNd indicates origin from partial melting of continental crust Paleoproterozoic. The rocks mafic-ultramafic occur aligned approximately east-west, with varying degrees of alteration. Define a tholeiitic to calcium-alkaline magmatism, metaluminous, of character intermediate to ultrabasic. The Isotopic studies suggest juvenile character of the parental, magma due to positive values εNd(T). The model ages ranging from TDM = 0.71 to 1,44 Ga and are related to other units of juvenile rocks of the Goiás Magmatic Arc.

Submitted by Simone Souza (simonecgsouza@hotmail.com) on 2017-11-06T16:06:43Z No. of bitstreams: 1 DISS_2014_ Regiane Ferreira de Oliveira.pdf: 6027017 bytes, checksum: f165c49fb24857b10d67f0c0b49ba85f (MD5) / Approved for entry into archive by Jordan (jordanbiblio@gmail.com) on 2018-02-02T15:10:33Z (GMT) No. of bitstreams: 1 DISS_2014_ Regiane Ferreira de Oliveira.pdf: 6027017 bytes, checksum: f165c49fb24857b10d67f0c0b49ba85f (MD5) / Made available in DSpace on 2018-02-02T15:10:33Z (GMT). No. of bitstreams: 1 DISS_2014_ Regiane Ferreira de Oliveira.pdf: 6027017 bytes, checksum: f165c49fb24857b10d67f0c0b49ba85f (MD5) Previous issue date: 2014-03-21 / Este trabalho apresenta os resultados de estudos geológicos e petrográficos realizados na região do Distrito de Noroagro – município de Comodoro no Estado de Mato Grosso com enfoque na geoquímica e geocronologia Sm e Nd de diques e “plugs máficos”, intrudidos nas rochas do Granito Rio Piolho e do Complexo Rio Galera. Os diques estudados situam-se no sudoeste do Cráton Amazônico na província Rondoniana San – Ignacio, especificamente nos domínios da Faixa Alto Guaporé. Petrograficamente, as rochas apresentam como aspectos macroscópicos feições estruturais características de rochas maciças de granulação fina a media variando de máficas a ultramáficas e cor cinza- esverdeada a preta. Apresentam texturas inequigranulares e composição gabroica ou peridotítica, constituídas, essencialmente, por minerais máficas (piroxênios e anfibólios) e plagioclásio por vezes alterados por processos de saussuritização. Opticamente, são rochas holocristalinas, textura ofítica a cumulática (peridotitos) onde os piroxênios representam à fase cumulus e os plagioclásios a fase inter-cumulus. Dados geoquímicos enfatizam que o magmatismo é do tipo toleítico, de natureza subalcalina, estando a totalidade das rochas no campo dos Basaltos de Fundo Oceânico – OFB (Ocean Floor Basalts), sendo que duas amostras apresentam assinatura de arco de ilhas. Datações de Sm- Nd indicaram idades de 1,24 , 1,27 e 1,57 (Ga) e apresentam ɛ Nd (t)a entre +6,27e + 6,50 para os gabros +5,80 para metapiroxênito. Os valores positivos de ɛ Nd (t)a juntamente com a razão 87Sr/86Sr de 0,704 para litotipo metagabro confirma que as rochas máficas –ultramáficas da região da Fazendas Maringá e Imaculada são derivadas de manto empobrecido / This works presents the results of Geological studies and petrographics realized in the Noroagro District, Comodoro municipality of Mato Grosso State focused on Geochemistry and Sm/Nd geochronology of dykes and maphic plugs emplaced in Rio Piolho Granite and Rio Galera Complex. The studied dykes is located in southwest of Amazonian Craton, Rondonian-San Ignácio Province, specifically in the Alto Guaporé Belt. Petrographically the rocks exhibit macroscopic strutural feature characteristics of massiveslightelly oriented rocks, fine to médium grain ranging of mafic to utramafic composition and greenhish – gray to black color. They presets inequigranular textures and gabbroic or peridotite composition, consisting essentially of mafic minerals (pyroxene and amphibole) and sometimes altered plagioclase and its partial saussuritization process. Optically Show holocrystalline granular rocks, with cumulate and ophitic texture ( peridotites) where pyroxene representes the cumulus crystal phase and the plagioclase inter-cumulus phase. Geochemical data emphasize that the magmatism is tholeiitic with sub-alkaline nature, being all of the rocks in the field of Ocean Floor Basalts (OFB) and two samples representes signatures island arc. Geochoronological Sm-Nd data indicated ages of 1,24 ,1,27 and 1,57 (Ga) and Show ɛ Nd (t)a between + 6,27 and +6,50 for gabbro and +5,80 for pyroxenite. The positive ɛ Nd (t)a values together with razão 87Sr/86Sr ratio of 0,704 for metagabbro suggests for the mafic- ultramafic rocks of region of Maringa and Imaculada Farm are derived of depleted mantle.

Diploma thesis - Kateřina Schlöglová - 2011 1/2 English abstract Granulites of the Rychleby Mts. represent relics of high-pressure eclogite-facies metamorphic rocks that are scattered in various crustal and mantle segments of the Variscan orogen in central Europe. These rocks may provide important insights into early stages of Variscan plate convergence and burial as well as exhumation mechanisms. We use mineral assemblages and chemistry to reconstruct the pressure-temperature paths, mechanisms of melting, and conditions of mineral preservation of high-pressure granulites, as well as whole- rock geochemistry to aid in interpretation of granulite precursors and their geodynamic setting. The mafic granulites consist of garnet, omphacite, two feldspars, and quartz with accessory rutile and zircon. The peak assemblage was partly replaced by pargasitic amphibole and biotite. Garnet grains are zoned from Grs36Py10Alm54 (core) to Grs20Py38Alm42 (rim), and host inclusions of phengite, omphacite, unmixed feldspars, kyanite, and rutile. Omphacite composition varies from Di44Hd14Jd42 (inclusions in garnet) through Di63Hd20Jd17 (porphyroblasts) and Di63Hd24Jd13 (symplectitic intergrowths with plagioclase). Reintegrated composition of the feldspar porphyroblasts is Or43Ab53An04. The felsic granulite variety is composed...

Determining mafic mineral composition of asteroid bodies is a topic reviewed by M.J. Gaffey et al. (2002). The iterative procedure discussed can be implemented as an algorithm, and such efforts revealed weaknesses that are examined in this work. We seek to illustrate the limits of this method and graphically determine its predictions. There are boundaries in the formulae given where the equations break down. In ranges where mafic mixtures are predicted, a method is illustrated that allows a decoupling of these mixtures into the constituents.

Variscan dike swarms associated with the Central Bohemian Plutonic Complex (CBPC) at the boundary between the Teplá-Barrandian and Moldanubian Units of the Bohemian Massif represent one of the most interesting geological phenomena. Frequency of dykes and their chemical variability do not have any comparable analogy in the whole European Variscides. This work is focused on the study of dyke rocks in the NE periphery of CBPC in geologically very complicated area with intrusions of predominantly deformed granitoids, contact metamorphosed sediments and magmatic rocks of "Islet Zone" with different protolith ages (forming remnants of the original roof of CBPC), deformed basic rocks of uncertain origin and age. The area extends up to the western boundary of the northernmost part of the Moldanubian high-grade metamorphic complex, the boundary itself being also tectonically problematic. Several localities with dyke rocks under study are situated in the area east of Senohraby (SE of Prague), on the northern side (right coast) of the Sázava river, and extend up to the area of Stříbrná Skalice. This area is rich in dykes of gabbro to diorite porphyry accompanied in some places with tonalite (rarely quartz diorite) porphyry and more rarely with amphibole lamprophyres (spessartite). Significantly younger dykes...

A técnica da Distribuição do Tamanho de Cristais - DTC (Crystal Size Distribution - CSD), que relaciona a densidade de cristais com a distribuição do tamanho, foi aplicada à população de plagioclásio de diques máficos do Enxame de Cabo Frio - Búzios (RJ). Os diques possuem larguras variáveis, de alguns centímetros a 20 metros, e orientação em torno de N45E. A textura dos diques é geralmente fina, localmente microporfirítica e intergranular no centro dos diques mais largos. Bordas resfriadas de alguns centímetros de largura são frequentes nos contatos com as rochas metamórficas encaixantes. Foram estudados dois diques na Praia das Conchas com espessura de 0,8m e 8,2m e, um outro na Praia da Lagoinha, com 2m de largura. As amostras foram coletadas junto às margens (~10 cm do contato) e no centro dos diques. O tamanho médio dos cristais de plagioclásio varia de 0,07 a 0,13 mm na borda dos diques mais finos (<= 2 m de largura) e de 0,09 a 0,20 mm na borda do dique mais largo. No centro do dique de Lagoinha e no dique largo de Praia das Conchas o tamanho de plagioclásio é da ordem de 0,19 ± 0,02 mm e 0,60 ± 0,07 mm, respectivamente. As DTCs nas bordas dos diques, independentemente de sua largura, mostraram um padrão tipicamente encurvado, e que tem sido atribuído na literatura como evidência para misturas de magmas com populações de cristais de tamanhos distintos. No entanto, no centro do dique largo (8,2m) de Praia das Conchas, a DTC é log-linear consistente com uma cristalização magmática simples. A química mineral mostrou que os cristais maiores (precoces) de plagioclásio apresentam um teor mais elevado em An (bytownita-labradorita) que os cristais menores (tardios) da matriz (labradorita-andesina). Além disso, a olivina é mais rica em Fo na borda que no centro do dique e, respectivamente, o piroxênio mais enriquecido em Ca. Esses resultados indicam que as margens resfriadas são mais máficas que o centro sugerindo uma evolução química normal com o resfriamento do magma. Portanto, as DTCs encurvadas provavelmente refletem taxas de cristalização heterogêneas possivelmente induzidas pela despressurização durante a ascensão do magma basáltico seguida de rápido resfriamento. O padrão da DTC log-linear no centro do dique de 8,2m de largura é atribuído ao maior tempo de residência do magma que favoreceria os processos de difusão química e re-equilíbrio textural. Os cálculos da taxa de resfriamento utilizando a inclinação da DTC permitiram estimar que o centro do dique largo da Praia das Conchas estaria completamente cristalizado (~ 900 °C) em torno de 73 dias. O estudo da Orientação Preferencial de Forma (OPF) de plagioclásio mostrou que a petrotrama tende a isotrópica nas margens dos diques com largura menor que 2 metros, o que poderia refletir uma rápida cristalização de plagioclásio por despressurização. Quando a trama é localmente definida, como no dique largo da Praia das Conchas, a lineação de plagioclásio é subhorizontal sugerindo que o fluxo magmático moveu-se predominantemente na lateral do dique. / The method of Crystal Size Distribution (CSD), which relates crystal density with size distribution, has been applied on the plagioclase population of the Mafic Dyke Swarm of Cabo Frio-Búzios (RJ). The dykes are NE-trending with widths from a few centimetres to 20m. The texture is generally fine grained and locally microporphyritic and intergranular at the center of the larger dykes. Chilled margins of a few centimetres in width are common at contacts with the metamorphic basement. Two dykes of 0.8m and 8.2m in width of the Conchas Beach and another of 2m in width at the Lagoinha Beach have been studied. Samples were collected at the margins (~10cm from the contact) and at the center of the dykes. The average characteristic size of the plagioclase crystals varies from 0.07 to 0.13mm at the margins of the narrow dykes (<=2m of width) and from 0.09 to 0.20mm at the margins of the large dyke. At the center of the Lagoinha and Conchas dykes the plagioclase size varies from 0.19 ±0.02mm and 0.60±0.07mm respectively. The CSDs at the dyke margins, irrespective of the dyke width, are typically concave-up, and in literature such patterns have been attributed as evidence of magma mixing with distinct crystal populations. However, at the center of the largest dyke (8.2m) of Conchas Beach, the CSD is log-linear, consistent with simple steady-state crystallization pattern. The mineral chemistry shows that the plagioclase phenocrysts have a high An content (bytownite-labradorite) than the groundmass grains (labradorite-andesine). At the margins olivine is richer in Fo than at the center, and respectively, pyroxene is richer in Ca. These results indicate that the chilled margin is more mafic than the center suggesting a normal chemical evolution in a cooling magma. Nevertheless, the concave-up CSDs probably depict heterogeneous crystallization rates possibly induced by depressurization during the ascent of the basaltic magma followed by rapid cooling. The log-linear CSD pattern at the center of the Conchas dyke (8.2m width) is attributed to a higher residence time of the magma which favors the processes of chemical diffusion and textural re-equilibration. The calculated cooling rates using the CSD slope enables us to estimate that the larger dyke of Conchas would be completely crystallized (at ~900oC) in 73 days. The study of the Shape Preferred Orientation (SPO) in plagioclase shows an isotropic petrofabric at the margins of the dykes <=2m, which could reflect a rapid crystallization of plagioclase by depressurization. When the fabric is defined, as in the larger Conchas Beach dyke, the plagioclase lineation is subhorizontal, suggesting that the magma flow was predominantly lateral to the dyke plane.

The rheology and strength of the lower crust play a key role in lithosphere dynamics, influencing the orogenic cycle and how plate tectonics work. Despite their geological importance, the processes that cause weakening of the lower crust and strain localization are still poorly understood. Through microstructural analysis of naturally deformed samples, this PhD aims to investigate how weakening and strain localization occurs in the mafic continental lower crust. Mafic granulites are analysed from two unrelated continental lower crustal shear zones which share comparable mineralogical assemblages and high-grade deformation conditions (T > 700 °C and P > 6 Kbar): the Seiland Igneous Province in northern Norway (case-study 1) and the Finero mafic complex in the Italian Southern Alps (case-study 2). Case-study 1 investigates a metagabbroic dyke embedded in a lower crustal metasedimentary shear zone undergoing partial melting. Shearing of the dyke was accompanied by infiltration of felsic melt from the adjacent partially molten metapelites. Findings of case-study 1 show that weakening of dry and strong mafic rocks can result from melt infiltration from nearby partially molten metasediments. The infiltrated melt triggers melt-rock reactions and nucleation of a fine-grained (< 10 µm average grain size) polyphase matrix. This fine-grained mixture deforms by diffusion creep, causing significant rheological weakening. Case-study 2 investigates a lower crustal shear zone in a compositionally-layered mafic complex made of amphibole-rich and amphibole-poor metagabbros. Findings of case-study 2 show that during prograde metamorphism (T > 800 °C), the presence of amphibole undergoing dehydration melting reactions is key to weakening and strain localization. Dehydration of amphibole generates fine-grained symplectic intergrowths of pyroxene + plagioclase. These reaction products form an interconnected network of fine-grained (< 20 µm average grain size) polyphase material that deforms by diffusion creep, causing strain partitioning and localization in amphibole-rich layers. Those layers without amphibole fail to produce an interconnected network of fine grained material. In this layers, plagioclase deforms by dislocation creep, and pyroxene by microfracturing and neocrystallization. Overall, this PhD research highlights that weakening and strain localization in the mafic lower crust is governed by high-T mineral and chemical reactions that drastically reduce grain size and trigger diffusion creep.

Fundação Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro / Nesta dissertação foram estudas rochas máficas dos complexos alcalinos de Morro de São João, Rio Bonito, Tanguá, Gericinó-Mendanha, Morro Redondo, Itatiaia e Passa Quatro. Essas rochas ocorrem na forma de diques e/ou sills. As amostras coletadas foram classificadas como lamprófiros, fonolitos, gabros e diabásios alcalinos. A análise geoquímica permitiu identificar um trend fortemente insaturado e um trend moderadamente alcalino para os complexos estudados. O primeiro é caracterizado por foiditos e fonolitos como membros parentais e mais evoluídos, respectivamente, enquanto o segundo tem basaltos alcalinos como membros parentais e traquitos como os mais evoluídos. Todas as amostras plotam no campo da série alcalina, sendo majoritariamente miaskíticas, sódicas ou potássicas. Adicionalmente, o estudo geoquímico indicou que os complexos alcalinos representam câmaras magmáticas distintas, onde diferentes processos evolutivos tiveram lugar. As modelagens apontaram dois processos de diferenciação distintos nos complexos estudados. Os complexos alcalinos de Morro de São João, Morro Redondo, Gericinó-Mendanha e Itatiaia estariam relacionados a processos de cristalização fracionada. Por outro lado, o Complexo Alcalino de Passa Quatro teria sido diferenciado por processos de cristalização fracionada com esvaziamento e posterior reabastecimento da câmara magmática (RTF). De um modo geral, esses modelos indicaram a presença de mais do que uma série magmática nos complexos estudados e a não cogeneticidade entre as séries agpaíticas e miaskíticas. A discriminação de fontes foi feita com base na análise dos elementos terras raras das amostras parentais de cada um dos complexos (gabro em Morro de São João e lamprófiro nos demais). No entanto, este procedimento não foi aplicado para o Complexo Alcalino de Morro Redondo, uma vez que todas as suas amostras apresentaram valores de MgO muito abaixo do típico para líquidos parentais. O líquido parental do Complexo Alcalino do Gericinó-Mendanha apresentou razões de La/Yb e La/Nb, maior e menor que a unidade, respectivamente, típicas de derivação a partir fontes férteis. Os líquidos parentais dos outros complexos alcalinos tiveram suas razões La/Yb e La/Nb maiores que a unidade, típicas de derivação a partir de fontes enriquecidas. Os modelos desenvolvidos revelaram que os líquidos parentais de cada um dos complexos estudados estariam relacionados a fontes lherzolíticas com granada residual. Além disso, a fusão parcial destas fontes teria ocorrido num intervalo de 1 a 7% dentro da zona da granada. Finalmente, as modelagens petrogenéticas elaboradas permitiram a proposição de um cenário geodinâmico, envolvendo a descompressão adiabática do manto litosférico e sublitosférico anomalamente aquecidos. As características geoquímicas dos líquidos parentais parecem ter sido controladas essencialmente pela mistura desses dois tipos de fontes. / Mafic rocks from the Morro de São João, Rio Bonito, Tanguá, Gericinó-Mendanha, Morro Redondo, Itatiaia and Passa Quatro alkaline complexes were studied based on field, petrographic and lithogeochemical data. The mafic rocks are mostly alkaline lamprophyres and alkaline gabbro (in Morro de São João). The complexes show both strongly undersaturated and mildly alkaline evolutionary trends, having foidites and alkaline basalts as parental compositions. Trachytes and phonolites are the most common evolved rocks. Geochemical modelling has show that miaskitic and agpaitic series are unlikely to be related by fractional crystallization. Enriched mantle sources predominate although a fertile mantle source seems to be related with the Gericinó-Mendanha complex. Parental compositions are related to small amounts of partial melting (1-7%) of garnet lherzolite within the garnet stability field in the mantle. Simple geodynamic models indicate that the alkaline complexes are related to the adiabatic decompression of anomalously hot (~1570C) mantle although unrelated to lithospheric translation over a fixed hotspot or mantle plume. Parental compositions are likely to be strongly controled by mixing of distinctive lithospheric mantle sources and a more homogeneous sublithospheric mantle. The lithospheric components seem to be related with the accreted terranes during the Gondwana amalgamation in Early Proterozoic times.

Cette thèse a pour but d'améliorer notre compréhension des processus d'altération des roches mafiques silicatées, de la spéciation des éléments et de leur migration dans le milieu boréal (bassin versant de la mer Blanche, Nord-Ouest de la Russie). Les objectifs principales du travail sont i) de caractériser et décrire les mécanismes responsables de l'altération chimique et de la formation des minéraux dans la zone subarctique, ii) évaluer le rôle de la lithologie (environnement granitique versus basaltique) dans la spéciation des éléments traces (ET) et la formation des colloïdes organo-minéraux dans les eaux de surface des bassins versants boréaux des hautes latitudes, et iii) révéler la dépendance de la spéciation des ET en fonction du pH de la solution pour prédire des changements éventuels dans la bioaccumulation des éléments dans les eaux naturelles à cause de leur acidification. L'originalité de cette thèse est de combiner, pour la première fois sur les mêmes objets naturels, les techniques physico-chimique, minéralogique et isotopique afin de mieux comprendre les facteurs qui contrôlent les cycles biogéochimiques des éléments dans les régions subarctiques.

No description available.