Call number: LD2668 .T4 1962 W35

Internal solitary waves (ISW) have been detected on the interface of a stratified water column in the ocean. It is believed that ISW could affect oil drilling operations, nutrient pumping, and acoustic signal obstruction. In the ocean, the thickness of a pycnocline is finite which differs with the theoretical assumption as being a thin layer. This thesis reports the effect of an ISW propagation in various pycnocline thicknesses. Laboratory experiments were conducted in an internal wave flume (0.5¡Ñ0.7¡Ñ12m) at the National Sun Yat-sen University, Kaohsiung, Taiwan. ISW in depression or elevation type were generaled using a stratified two-layer fresh/brine water system with a total depth of 50 cm in the flume. Upon creating an ISW propagating on a flat bed or over a triangular obstacle later, several physical parameters of the ISW (i.e. wave amplitude, phase speed, characteristic wave length, and wave energy) were measured or calculated for different thicknesses of the pycnocline. The major controlling factors in the experiments included the depth ratio of the upper to lower layer H1/H2, interface displacement £b0 between the wave generating chamber and the main flume, and the thickness of the pycnocline. The thickness of the pycnocline was estimated from the result of density profile in the vertical direction in the flume, experiments under the same H1/H2 and £b was terminated when the pycnocline thickness became large enough. As the thickness of the pycnoline increased, the values of all the physical parameters (including wave amplitude, phase speed, and wave energy) under consideration decreased. Their reduction rates were more significant in the case of small interface displacement (£b0=10cm) than that with large £b0=15cm. On the other hand, the changes in the physical variables associated with a depression ISW were more significant than those in an elevation ISW.

Equipped with advanced field instruments in the past few decades, oceanographers have been able to comprehend some characteristics of the internal waves(IWs), such as the generation, propagation and energy dissipation, as well as to promote understanding in oceanography and marine ecology affected by IWs in the world ocean. Although surface gravity wave and internal wave are two of the most common natural phenomena in the ocean, the interaction between them has not been fully investigated, despite limited theoretical derivations in the literature, nor using laboratory experiments to verify the theory. A series of laboratory experiments were conducted at the National Sun Yen-sen University to study the waveform evolution of continuous IWs propagation on the flat bottom and across a trapezoidal obstacle. Surface waves were generated on a density stratified fluid system in a wave flume, from which IWs were induced indirectly to investigate their wave properties associated with their propagation . The experimental results are then used to determine the maximum depth which could be affected by surface waves in different wave conditions(wave height and period), as well as the amplitude of the IWs induced. The relationship between them are then presented in graphic form. Experiments were also conducted in uniform density and stratified fluid system with a trapezoidal obstacle. The results reveal that (1)long-period surface waves were susceptible to the interaction with the IWs in a stratified system, thus rendering wave height reduction, and (2)short-period surface waves interactions with their IWs counterparts was insignificant, hence yielded wave height similar to that in uniform density fluid system. Moreover, experiments were also conducted to study for long and short period IW propagated over pseudo slope-shelf(using trapezoidal obstacle). The results show that the variation in the IWs significantly affected the strength of internal hydraulic jump and vortices on the front slope and subsequent waveform inversion on the horizontal plateau. For IWs with short period, the horizontal distance on the plateau affected by the IWs was shirter and the total time of wave-topography interaction decreased.

This thesis is aimed at forecasting of experimental results in a lab environment, investigating often discussed external validity of laboratory experiments. We run a novel laboratory experiment in which the subject pool is asked to make predictions on results of a certain field experiment. The collected data is ana­ lyzed using different accuracy measures, arriving at several interesting results. First, the forecast among the 94 subjects is quite informative about the actual treatment effects although its accuracy substantially varies based on a type of accuracy measure and a particular treatment. Second, the average forecast is either more accurate or at least comparable to the mean individual forecast, proving the presence of "wisdom-of-crowds" effect.

abstract: Lava flow emplacement in the laboratory and on the surface of Mars was investigated. In the laboratory, the effects of unsteady effusion rates at the vent on four modes of emplacement common to lava flow propagation: resurfacing, marginal breakouts, inflation, and lava tubes was addressed. A total of 222 experiments were conducted using a programmable pump to inject dyed PEG wax into a chilled bath (~ 0° C) in tanks with a roughened base at slopes of 0, 7, 16, and 29°. The experiments were divided into four conditions, which featured increasing or decreasing eruption rates for either 10 or 50 s. The primary controls on modes of emplacement were crust formation, variability in the eruption rate, and duration of the pulsatory flow rate. Resurfacing – although a relatively minor process – is inhibited by an extensive, coherent crust. Inflation requires a competent, flexible crust. Tube formation requires a crust and intermediate to low effusion rates. On Mars, laboratory analogue experiments combined with models that use flow dimensions to estimate emplacement conditions and using high resolution image data and digital terrain models (e.g. THEMIS IR, CTX, HRSC), the eruption rates, viscosities, and yield strengths of 40 lava flows in the Tharsis Volcanic Province have been quantified. These lava flows have lengths, mean widths, and mean thicknesses of 15 – 314 km, 0.5 – 29 km, and 11 – 91 m, respectively. Flow volumes range from ~1 – 430 km3. Based on laboratory experiments, the 40 observed lava flows were erupted at 0.2 – 6.5x103 m3/s, while the Graetz number and Jeffrey’s equation when applied to 34 of 40 lava flows indicates eruption rates and viscosities of 300 – ~3.5 x 104 m3/s and ~105 – 108 Pa s, respectively. Another model which accounts for mass loss to levee formation was applied to a subset of flows, n = 13, and suggests eruption rates and viscosities of ~30 – ~1.2 x 103 m3/s and 4.5 x 106 – ~3 x 107 Pa s, respectively. Emplacement times range from days to centuries indicating the necessity for long-term subsurface conduits capable of delivering enormous volumes of lava to the surface. / Dissertation/Thesis / Chapter 4 - Mars Lava Flow Data and Calculations / Chapter 2 - Experimental Data / Chapter 3 - Experimental Data / Doctoral Dissertation Geological Sciences 2020

Call number: LD2668 .R4 1967 L43

La recherche et la détection de molécules organique à la surface de Mars est l’un des objectifs des missions martiennes actuelles (MSL, Mars Science Laboratory) et futures (ExoMars 2020). Plusieurs sources de matière organique peuvent être considérées telles que les sources abiotiques (milieu interplanétaire, hydrothermalisme, synthèses atmosphériques…) mais également les sources biotiques telles qu’une potentielle activité biologique martienne passée. A ce titre, le rover Curiosity de la mission MSL a permis la détection de composés organiques d’origine martienne chlorés et soufrés, bien que ces molécules ne soient pas liées à une quelconque activité biologique ou bien ne reflètent pas la diversité moléculaire de sources abiotiques avérées telles que le milieu interplanétaire. L’une des hypothèses pour expliquer cette faible diversité consiste à considérer que l’environnement martien n’est pas favorable à la préservation de la matière organique. Afin de comprendre l’évolution des molécules organiques à la surface de Mars et donc de guider et aider les interprétations des analyses menées in situ, j’ai travaillé sur deux expériences de simulation simulant certains paramètres de la surface de Mars (rayonnement UV, pression, température, composition minérale). La première, MOMIE (Mars Organic Matter Irradiation and Evolution), est une simulation de laboratoire mise en place au LISA (Créteil, France). La seconde est l’expérience PSS (Photochemistry on the Space Station), mise en place sur la plateforme EXPOSE R2 sur la Station Spatiale Internationale (ISS) en orbite basse terrestre, utilisant directement le flux de photons UV du Soleil filtré.J’ai étudié l’évolution de quatre molécules organiques susceptibles d’être présentes sur Mars, pures ou en présence de phases minérales analogues martiennes : la glycine (un acide aminé), l’adénine et l’uracile (deux bases azotées), et le chrysène (un hydrocarbure aromatique polycyclique). La glycine, l’adénine et le chrysène se dégradent en surface directe de Mars avec des rendements quantiques de photodissociation ϕ200-280 compris entre 6,4 ± 1,4 x 10-6 et 2,3 ± 1,0 x 10-3 molécule.photon-1. L’uracile forme des photoproduits plus stables, selon un rendement de production élevé de 1,64 ± 1,43 x 10-1 molécule.photon-1. Quatre dimères d’uracile ont pu être identifiés comme des photoproduits. Pour finir, l’ajout de phases minérales amorphe et riche en fer ou bien de perchlorates accélère la dégradation ou l’évolution des molécules organiques / Organic molecule detection at Mars is one of the main goals of the current and future Mars exploration space missions, Mars Science Laboratory (MSL, NASA) and ExoMars 2020 (ESA). Several organic sources exist : abiotic sources (interplantary medium, hydrothermalism and atmospheric synthesis) but also biotic sources such as potential past biological activity. Curiosity from the MSL mission detected chlorinated and sulfur organic compounds. However these compounds can not be linked to any biological activity and do not represent the meteoritical organic diversity.The main hypothesis to explain the low diversity of detected organic compounds at Mars is that the martian environment degrade organic matter. In order to understand organic molecule evolution at the Martian surface and be able to guide and help interpret in situ analysis, I worked on two experimental simulations mimicking some of the martian environmental conditions (UV radiation, pressure, temperature and mineral composition). MOMIE, for Mars Organic Matter Irradiation at Mars, is a laboratory experiment set up at the LISA laboratory (Créteil, France). PSS, for Photochemistry on the Space Station, has been set up on the International Space Station (ISS) in low Earth orbit, using directly filtered UV photons from the Sun.I studied the evolution of four organic molecules likely to be present at Mars with ou without a mineral phase : glycine (an amino acid), adenine and uracil (two nucleobases), and chrysene (a polycyclic aromatic hydrocarbon). Glycine, adenine and chrysene are degraded at Mars surface with quantum efficiencies of photodecomposition from 6,4 ± 1,4 x 10-6 to 2,3 ± 1,0 x 10-3 molecule.photon-1. Uracil evolve into more stable photoproducts with a production efficiency of 1,64 ± 1,43 x 10-1 molécule.photon-1. Four uracil dimers have been identified as uracil photoproducts. Finally, the studied mineral phases, an amorphous iron-rich phase and perchlorates, accelerate organics evolution or degradation

Un protocole d’altération de lubrifiants par NO2 en laboratoire a été développé pour étudier les effets de la nitroxydation sur les additifs et la base hydrocarbonée de lubrifiants moteur et comprendre leurs mécanismes d’altération. Des structures de produits d’altération et des voies de transformation ont pu être proposées ainsi que les facteurs contrôlant les cinétiques de dégradation des additifs. Les interactions entre les constituants de lubrifiants tant au niveau des cinétiques de dégradation que des structures des produits de dégradation ont ainsi été identifiées, notamment à partir d’un plan d’expériences. L’évolution des lubrifiants simulée en laboratoire n’est pas directement superposable à celle observée avec des essais moteur, un certain nombre de produits d’altération n’ayant pas été détectés en essais moteur. En revanche, les interactions contrôlant les cinétiques de dégradation des additifs sont proches dans les cas des expériences de laboratoire et des essais moteur. / An alteration laboratory protocol of lubricants by NO2 has been developed in order to investigate the effects of nitroxidation on base oil and additives from engine lubricants, and to understand the different mechanisms involved. The structure of alteration products and their transformation pathways have been proposed, as well as the factors that control the degradation kinetics of the additives. Interactions between lubricant constituents have been identified at the degradation kinetic level as well as the level of the alteration products formed, notably by means of an experimental design. The fate of lubricants in the laboratory experiments does not exactly match that observed in the case of engine tests, notably regarding the absence of formation of some degradation products. However, the interactions controlling the degradation kinetics of lubricant additives are close between laboratory experiments and engine tests.

In case of exceptional floods induced by the failure of a dam, huge amounts of sediments may be eroded. This results in large-scale modifications of the valley morphology and may drastically increase the resulting damages. The objective of the research is to advance the understanding of sediment transport under dam-break flows. For such highly erosive and transient floods, it is crucial to account explicitly for sediment inertia, and therefore traditional “clear-water” modelling approaches are largely inappropriate. The present approach relies on a two-layer idealisation of the flow behaviour. Separating a clear-water flow region from the underlying sediment bed, the transported sediments are confined in a flow layer of finite thickness, endowed with its proper inertia, density and velocity. The thesis also pinpoints granular dilatancy as an essential mechanism of interaction between the layers. When passing from a solid-like to a fluid-like behaviour as they are entrained by the flow, the eroded sediment grains dilate along the vertical, and this generates vertical exchanges of mass and momentum that should be accounted for. The thesis proceeds first with experimental investigations. Laboratory dam-break waves are reproduced in a dedicated flume, exploring different bed configurations and sediment densities. Imaging observations are used to support the proposed phenomenological description of the flow. Within a shallow-water framework, theoretical and numerical endeavours are then developed to investigate the implications on the flow dynamics of the two essential contributions of the proposed description, i.e. the two-layer flow behaviour, and the effects of granular dilatancy.

While shoaling from deepwater in a stratified ocean, an interfacial solitary wave (ISW) may experience waveform inversion on a continental margin. Although many oceanographers have believed that the inversion from depression to elevation may commence at the turning point where the upper and bottom layers are equal in depth, this phenomenon has not been fully verified in field observations nor in a laboratory. In this study, a series of laboratory experiments and numerical modeling were conducted on the evolution of an ISW of depression across uniform slope joining a horizontal plateau which resembles pseudo slope-shelf topography, in order to clarify this fascinating phenomenon and the variations of wave properties associated with the process. In the laboratory experiments, a depression ISW was produced by a collapse mechanism in a stratified two-layer fluid system within a steel-framed wave flume (12 m long, 0.7 m high by 0.5 m wide) at the National Sun Yat-sen University in Taiwan. The fluid density in the upper (fresh) and bottom (brine) layers was 996 and 1030 kg/m3, respectively. A series of experiments were conducted upon varying the magnitude of the most important physical factors (i.e., nominal thickness of pycnocline, depth ratio between upper and bottom layer, front gradient and shape of pseudo slope-shelf), from which the results are now discussed in four separate chapters in this thesis. Present laboratory results indicate that the process of waveform inversion took place after an ISW had experienced internal run-down, hydraulic jump, vortex motion and surge-up on the front slope, prior to its propagation onto the plateau. Moreover, the fundamental wave period of leading wave on the plateau was significantly smaller than that in the preceding sections on the front slope and the incident stage earlier, thus representing frequency downshift. Amongst the factors involved, the depth ratio between the upper and bottom layer was the most significant one for waveform inversion. Only when the upper layer was thicker than the bottom layer on the plateau of pseudo slope-shelf, waveform inversion could occur, besides the length of the plateau. On the other hand, the front gradient and shape of pseudo slope-shelf also affected the magnitude of the transmitted wave over the plateau as the wave across this specific topography. In the case of a steeper front gradient, waveform inversion became insignificant due to stronger wave reflection and intense energy dissipation caused by turbulent mixing while a depression ISW propagated over a slope-shelf; particularly against a submerged vertical cliff. As a depression ISW across pseudo slope-shelf with short plateau, intense wave breaking might occur again with vortex motion at its rear end as the newly inversed waveform reentering deep water. In this region, the upper layer was smaller than the bottom layer, hence it could not support the continuous existence of an ISW in elevation. Again, energy dissipation occurred due to turbulent mixing beyond the rear end of a short plateau. Finally, a different mode of ISW appeared within pycnocline, while its nominal thickness was larger than the amplitude of the incident wave. In addition to the laboratory investigations, numerical model was also adopted to study the variations in the flow field as an ISW propagated over a pseudo slope-shelf, in order to complement the experimental results. The results of numerical modeling revealed that the horizontal velocity in the bottom layer increased when the wave encountered the front slope, even if the depth of upper layer was thinner than that of the bottom layer on the plateau. Consequently, the velocity in the upper layer became less than that in the bottom layer when the former was thicker than that of the latter on the plateau. On the other hand, the vertical velocity within the self-generated vortex switched direction as waveform inversion commenced after the wave across the shoulder of pseudo slope-shelf where the local depth of the upper layer was larger than that of bottom part. Overall, the significance of the four pertinent factors (i.e., nominal thickness of pycnocline, water depth ratio, front slope, and plateau length) that affected a depression ISW across pseudo slope-shelf is discussed in detail in this thesis, as well as the variation of flow field calculated by the numerical mode presented.