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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
41

Use Of Aluminium Dross For Slag Treatment In Secondary Steelmaking To Decrease Amount Of Reducible Oxides In Ladle Furnace

Aydemir, Onur 01 January 2007 (has links) (PDF)
In this study it was aimed to analyse refining processes such as decreasing reducible oxide content of ladle slag with affecting parameters in low carbon aluminum killed grades and for the research Erdemir low carbon steel grades 7112K and 7110K are selected. There was a negative correlation between reducible oxide amount in ladle slag and desulphurization capacity of ladle slag with metal-slag reaction and steel internal cleanliness. To refine these properties of slag, aluminium dross, which was aluminium production discard and has a metallic content around %30-35 was used and after ladle treatment operation, decrease in reducible oxides such as FetO, MnO, SiO2, P2O5 was analysed. After the study it was observed that 653 kg. of converter slag leaked during tapping of steel and SiO2 ve P2O5 content of ladle slag had negligible change after ladle treatment. According to the results, it is observed that initial %10-12 (FetO + MnO) content was reduced to % 4.5-5.0 (FetO + MnO) after ladle treatment with use of aluminium dross. Beside of this, in order to see the effect of this slag reduction on steel cleanliness, low carbon aluminium killed grades were compared with ultra-low carbon aluminium killed grades having (FetO + MnO) content of %16-17 in slag. It was seen that reoxidation of aluminium (loss of dissolved aluminium) during continuous casting for ULC (ultra-low carbon) gradesis 144 ppm but for LC grades it was 94 ppm and it was being expected that ULC steel group would have higher inclusion content after casting.
42

The effect of ladle vacuum treatment on inclusion characteristics for tool steels

Steneholm, Karin January 2005 (has links)
No description available.
43

Thermodynamic Studies of the Fe-Pt System and “FeO”-Containing Slags for Application Towards Ladle Refining

Fredriksson, Patrik January 2003 (has links)
<p>In the present work, the thermodynamic activites of ironoxide, denoted as "FeO" in the slag systems Al<sub>2</sub>O<sub>3</sub>-"FeO", CaO-"FeO", "FeO"-SiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>-"FeO"-SiO<sub>2</sub>, CaO-"FeO"-SiO<sub>2</sub>and "FeO"-MgO-SiO<sub>2</sub>were investigated by employing the gasequilibration technique at steelmaking temperatures. Thestrategy was to expose the molten slag mixtures kept inplatinum crucibles for an oxygen potential, determined by aCO/CO<sub>2</sub>-ratio. A part of the iron reduced from the "FeO"in the slag phase was dissolved into the Pt crucible.</p><p>In order to obtain the activites of "FeO", chemical analysisof the quenched slag samples together with thermodynamicinformation of the binary metallic system Fe-Pt is required.Careful experimental work was carried out by employing asolid-state galvanic cell technique as well as calorimetricmeasurements in the temperature ranges of 1073-1273 K and300-1988 K respectively. The outcome of these experiments wasincorporated along with previous studies into a CALPHAD-type ofthermodynamic assessment performed with the Thermo-Calc™software. The proposed equilibrium diagram enabledextrapolation to higher temperatures.</p><p>The experimentally obtained activites of "FeO" in thepresent work, along with earlier investigations were assessedwith the KTH slag model, THERMOSLAG©. New binaryparameters were evolved and incorporated in THERMOSLAG©.The present model calculations are compared with othercommercially available software such as F*A*C*T™andThermo-Calc™. The validity of the modified model wasinvestigated by measurements carried out in case of Al<sub>2</sub>O<sub>3</sub>-"FeO"-SiO<sub>2</sub>, CaO-"FeO"-SiO<sub>2</sub>and "FeO"-MgO-SiO<sub>2</sub>ternary slags. The potential of the model tocompute the activities in the case of multicomponent slags wasdemonstrated.</p><p>A correlation between the activity of a metallic oxide in aternary slag system and the sulphide capacity of the slag wasinvestigated by using the solubility of sulphur in the binarysystems CaO-SiO<sub>2</sub>and Al<sub>2</sub>O<sub>3</sub>-CaO along with the sulphide capacity of the Al<sub>2</sub>O<sub>3</sub>-CaO-SiO<sub>2</sub>system. The estimated values of the activitieswere found to be in good agreement with the measured values.This correlation also gives the possibility to elucidate theapplicability of Henry's law to the activity of a metallicsulphide and to determine the order in the affinity of a cationto sulphur between two metallic oxides in a slag.</p><p>Model calculations were performed with THERMOSLAG<sup>©</sup>, by using plant data from the ladle refiningprocess at OVAKO Steel, Hofors, Sweden. It was found thatoxygen estimations in the metal from the "FeO" analyses ofslags, obtained by conventional sampling and analysis methodwere less reliable. Reliable estimation of the oxygen levelsutilising the sulphur partition between the slag and the metalwere carried out using THERMOSLAG© software.</p><p><b>Keywords:</b>Thermodynamics, Activity, Galvanic cell,Calorimetry, Gas equilibration technique, Iron-platinum alloys,FeO, Slags, Modelling, Ladle</p>
44

SCALE MODEL EXPERIMENTS AND NUMERICAL STUDY ON A STEEL TEEMING PROCESS

Singh, Pavan Kumar 01 January 2004 (has links)
During the teeming process of molten steel from a ladle, a bathtub-type vortex may be formed in the ladle. The vortex entrains undesired slag on the surface into the tundish, lowering the quality. The formation of such vortices has been studied using two different scale models. Since the kinematic viscosity of water is similar to that of molten steel, the molten steel was simulated by water in the experiments. The Particle Image Velocimetry (PIV) technique was used to measure water flow patterns. Results show that the initial tangential velocity of water is responsible for the vortex formation. The effects of Reynolds and Froude numbers on the vortex formation were investigated and Froude number was found to be the dominant pi-number. A Computational Fluid Dynamics (CFD) modeling was also conducted to simulate the vortex formation with good agreement with the experiments.
45

Viscosidade efetiva de escórias e parâmetro cinético de agitação aplicados na limpeza inclusionária de aços especiais durante desgaseificação a vácuo

Rocha, Vinicius Cardoso da January 2016 (has links)
Há uma demanda por competitividade entre as indústrias de aços, a fim de alcançar a excelência definida pelo termo clean steel. O processo de desgaseificação a vácuo (VD) ocorre durante o Refino Secundário de aços especiais. Sua principal função é remover gases indesejáveis, especialmente o hidrogênio. Entretanto, durante este processo, o fenômeno de flotação e a absorção de inclusões são reportados. O objetivo do presente trabalho foi estudar a viscosidade de escórias e a capacidade da estação de desgaseificação a vácuo do tipo tanque na limpeza de aços sob uma perspectiva industrial. Para realizar este objetivo, foram coletadas amostras de escória e aço antes e após a etapa de vácuo. Os resultados em limpeza de aço foram relacionados à energia de agitação durante o tratamento a vácuo (associada a um parâmetro cinético - βs) e ao efeito da viscosidade de escórias. É possível observar um decréscimo expressivo na população de inclusões entre as condições antes e após tratamento de desgaseificação a vácuo. A remoção de inclusões durante o vácuo atinge 64, 75 e 78% para as faixas de diâmetro de 2,5-5, 5-15 e ≥ 15 μm, respectivamente. Após o processo de desgaseificação, a composição das inclusões não-metálicas aproxima-se da composição química da escória. O processo de agitação na estação de desgaseificação a vácuo promove uma diminuição significativa na densidade de inclusões na faixa de diâmetro de 2,5-15 μm. Além disso, ao aumentar a intensidade do parâmetro cinético, a composição química de inclusões não-metálicas foi afetada e o teor de enxofre presente no aço líquido foi reduzido. Quanto às viscosidades efetiva das escórias, conclui-se que, para valores mais baixos (0,20 Pa.s) aumenta-se a capacidade da escória na remoção de inclusões, enquanto que valores mais altos (> 0,40 Pa.s) aparentaram ser prejudiciais à limpeza do aço. / There is a demand in competitiveness within the steel industry towards achieving excellence defined by clean steel term. The process of vacuum degassing (VD) occurs during the secondary refining of special steels. Its main function is to remove undesirable gases, primarily hydrogen. However, during this process, flotation phenomenon and inclusions absorption are reported. The aim of the present work was to study the slag viscosity and vacuum degassing (tank type) capacity in steel cleanliness from an industry perspective. To achieve this objective, slag and steel samples were taken before and after vacuum stage. The results in steel cleanliness were related to the stirring energy of the vacuum station (associated to a kinetic parameter – βs) and to the effect of slag viscosity. It is possible to observe an expressive decrease in the population of inclusions between the conditions before and after vacuum degassing treatment. The removal of inclusions during the vacuum stage reaches 64, 75 and 78% in the diameter ranges of 2,5-5, 5-15 and ≥ 15 μm, respectively. After the degassing process, the composition of non-metallic inclusions seemed to approach the slags’ chemical compositions. The stirring process in the vacuum degassing station promotes a significant decrease in the inclusion density with 2,5-15 μm diameter range. Also, by increasing the kinetic parameter intensity, the composition of non-metallic inclusions was affected. The sulfur content present in liquid steel was reduced. Regarding the effective viscosities of slags, it was concluded that lower values (0,20 Pa.s) increased slag capacity in inclusion removal, whereas higher values (> 0,40 Pa.s) was detrimental to steel cleanliness.
46

Estudo dos mecanismos de degradação de placa Al2O3-ZrO2-C de válvula gaveta em panela de aciaria

Sousa, Bruna Berti de January 2017 (has links)
O trabalho disserta sobre a investigação dos mecanismos de degradação da placa refratária utilizada no sistema de válvula gaveta, o qual controla o fluxo de aço líquido da panela da aciaria para o distribuidor. As placas estudadas eram do tipo Al2O3-ZrO2-C. Na investigação foram caracterizadas e analisadas placas novas e usadas. Também foi feito teste de corrosão estático para avaliação da interação química das placas com a escória proveniente do processo de refino secundário. Além disso, foi feito experimento em laboratório para avaliar o desgaste das placas devido a presença de resquícios de escória entre as placas no processo de abertura da válvula. Tal experimento foi realizado nos moldes do teste de resistência de argamassa usado por Leroy (EQUIPE DE FURNAS, 1997). Para tanto foram usadas técnicas de caracterização como Microscopia Eletrônica de Varredura (MEV), Espectroscopia de Dispersão em Energia (EDS), Fluorescência de raios x (FRX) e Difração de raios x (DRX). Por meio de análises foi possível propor explicações para os mecanismos de degradação, como a corrosão devido ao contato com a escória e a formação de desgaste em forma de lingueta devido ao uso de válvula semiaberta Principalmente, a partir dos experimentos realizados foi possível identificar um mecanismo de degradação ainda não abordado na literatura: o desgaste do material das placas ocasionado pela abertura da válvula gaveta quando as placas estão ligadas por escória solidificada. Devido à falta de metodologia específica para abordar esse tema, adotou-se um método usado para avaliar a resistência de cimetos e argamassas na investigação sobre a influência da adesão da escória na degradação das placas. Tal método, chamado de tração direta (L.A.Farias, 2016), mostrou uma degradação intensa das placas. A reação química entre a placa aluminosa e a escória é a responsável pela adesão entre as duas placas e a escória. A adesão por escória mostrou que pode ser tão resistente quanto a ligação entre as partículas do refratário, que teve partículas retiradas no teste de tração direta. Assim, conclui-se que a interação química entre a placa e a escória, aliada a movimentação de abre e fecha do conjunto de placas quando a escória já solidificou, são mecanismos importantes na degradação das placas Al2O3-ZrO2-C de válvula gaveta. / This master’s dissertation investigates the deterioration of one of the parts that make up the sliding gate system of a steelmaking ladle. This part controls the liquid steel flow from the ladle to the tundish. These parts are called plates and may be made of different refractory ceramic materials. However, the plates used in this study are made of Al2O3-ZrO2-C. New parts and after service parts were analyzed. A static corrosion test was performed to analyze the chemical interaction between the refractory plates and the slag derived from steelmaking refining process. A laboratory experiment was carried out to evaluate wear due to remnants of slag between the sliding gate plates during the opening and closing of the gate. Such experiment was performed based on Mortar Resistance test used by Leroy. To analyze the materials, characterization techniques such as Scan Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), X-ray fluorescence (XRF), and X-ray diffraction were used. Based on the results of these analyses, a series of deterioration mechanisms were presented, such as the corrosion due to slag contact, and intensification of wear due to the use of semi-open valve. Mainly, from the performed experiments it was possible to identify a deterioration mechanism, that has not been discussed in literature yet This wear mechanism happens when the sliding gate plates are bonded by solidified slag, which is caused by opened valves, and leads to the extraction of particles from the surface of the plates. Due the lack of methodology to evaluate this kind of deterioration mechanism, a methodology based on mortar testing was developed. This method, called direct tensile test (L.A.Farias, 2016), showed intense deterioration. The chemical reaction between aluminum oxide refractory plate and the slag is responsible for the adhesion between plates and slag. This adhesion may be as strong as adhesion between the particles of the refractory, since refactory particles were removed in the test. Thus, it was concluded that the chemical interaction between refractory plate and slag, alied to the opening and closing mechanism are important in the deterioration of the Al2O3-ZrO2-C plates of the slide gate of the ladle.
47

Viscosidade efetiva de escórias e parâmetro cinético de agitação aplicados na limpeza inclusionária de aços especiais durante desgaseificação a vácuo

Rocha, Vinicius Cardoso da January 2016 (has links)
Há uma demanda por competitividade entre as indústrias de aços, a fim de alcançar a excelência definida pelo termo clean steel. O processo de desgaseificação a vácuo (VD) ocorre durante o Refino Secundário de aços especiais. Sua principal função é remover gases indesejáveis, especialmente o hidrogênio. Entretanto, durante este processo, o fenômeno de flotação e a absorção de inclusões são reportados. O objetivo do presente trabalho foi estudar a viscosidade de escórias e a capacidade da estação de desgaseificação a vácuo do tipo tanque na limpeza de aços sob uma perspectiva industrial. Para realizar este objetivo, foram coletadas amostras de escória e aço antes e após a etapa de vácuo. Os resultados em limpeza de aço foram relacionados à energia de agitação durante o tratamento a vácuo (associada a um parâmetro cinético - βs) e ao efeito da viscosidade de escórias. É possível observar um decréscimo expressivo na população de inclusões entre as condições antes e após tratamento de desgaseificação a vácuo. A remoção de inclusões durante o vácuo atinge 64, 75 e 78% para as faixas de diâmetro de 2,5-5, 5-15 e ≥ 15 μm, respectivamente. Após o processo de desgaseificação, a composição das inclusões não-metálicas aproxima-se da composição química da escória. O processo de agitação na estação de desgaseificação a vácuo promove uma diminuição significativa na densidade de inclusões na faixa de diâmetro de 2,5-15 μm. Além disso, ao aumentar a intensidade do parâmetro cinético, a composição química de inclusões não-metálicas foi afetada e o teor de enxofre presente no aço líquido foi reduzido. Quanto às viscosidades efetiva das escórias, conclui-se que, para valores mais baixos (0,20 Pa.s) aumenta-se a capacidade da escória na remoção de inclusões, enquanto que valores mais altos (> 0,40 Pa.s) aparentaram ser prejudiciais à limpeza do aço. / There is a demand in competitiveness within the steel industry towards achieving excellence defined by clean steel term. The process of vacuum degassing (VD) occurs during the secondary refining of special steels. Its main function is to remove undesirable gases, primarily hydrogen. However, during this process, flotation phenomenon and inclusions absorption are reported. The aim of the present work was to study the slag viscosity and vacuum degassing (tank type) capacity in steel cleanliness from an industry perspective. To achieve this objective, slag and steel samples were taken before and after vacuum stage. The results in steel cleanliness were related to the stirring energy of the vacuum station (associated to a kinetic parameter – βs) and to the effect of slag viscosity. It is possible to observe an expressive decrease in the population of inclusions between the conditions before and after vacuum degassing treatment. The removal of inclusions during the vacuum stage reaches 64, 75 and 78% in the diameter ranges of 2,5-5, 5-15 and ≥ 15 μm, respectively. After the degassing process, the composition of non-metallic inclusions seemed to approach the slags’ chemical compositions. The stirring process in the vacuum degassing station promotes a significant decrease in the inclusion density with 2,5-15 μm diameter range. Also, by increasing the kinetic parameter intensity, the composition of non-metallic inclusions was affected. The sulfur content present in liquid steel was reduced. Regarding the effective viscosities of slags, it was concluded that lower values (0,20 Pa.s) increased slag capacity in inclusion removal, whereas higher values (> 0,40 Pa.s) was detrimental to steel cleanliness.
48

Estudo dos mecanismos de degradação de placa Al2O3-ZrO2-C de válvula gaveta em panela de aciaria

Sousa, Bruna Berti de January 2017 (has links)
O trabalho disserta sobre a investigação dos mecanismos de degradação da placa refratária utilizada no sistema de válvula gaveta, o qual controla o fluxo de aço líquido da panela da aciaria para o distribuidor. As placas estudadas eram do tipo Al2O3-ZrO2-C. Na investigação foram caracterizadas e analisadas placas novas e usadas. Também foi feito teste de corrosão estático para avaliação da interação química das placas com a escória proveniente do processo de refino secundário. Além disso, foi feito experimento em laboratório para avaliar o desgaste das placas devido a presença de resquícios de escória entre as placas no processo de abertura da válvula. Tal experimento foi realizado nos moldes do teste de resistência de argamassa usado por Leroy (EQUIPE DE FURNAS, 1997). Para tanto foram usadas técnicas de caracterização como Microscopia Eletrônica de Varredura (MEV), Espectroscopia de Dispersão em Energia (EDS), Fluorescência de raios x (FRX) e Difração de raios x (DRX). Por meio de análises foi possível propor explicações para os mecanismos de degradação, como a corrosão devido ao contato com a escória e a formação de desgaste em forma de lingueta devido ao uso de válvula semiaberta Principalmente, a partir dos experimentos realizados foi possível identificar um mecanismo de degradação ainda não abordado na literatura: o desgaste do material das placas ocasionado pela abertura da válvula gaveta quando as placas estão ligadas por escória solidificada. Devido à falta de metodologia específica para abordar esse tema, adotou-se um método usado para avaliar a resistência de cimetos e argamassas na investigação sobre a influência da adesão da escória na degradação das placas. Tal método, chamado de tração direta (L.A.Farias, 2016), mostrou uma degradação intensa das placas. A reação química entre a placa aluminosa e a escória é a responsável pela adesão entre as duas placas e a escória. A adesão por escória mostrou que pode ser tão resistente quanto a ligação entre as partículas do refratário, que teve partículas retiradas no teste de tração direta. Assim, conclui-se que a interação química entre a placa e a escória, aliada a movimentação de abre e fecha do conjunto de placas quando a escória já solidificou, são mecanismos importantes na degradação das placas Al2O3-ZrO2-C de válvula gaveta. / This master’s dissertation investigates the deterioration of one of the parts that make up the sliding gate system of a steelmaking ladle. This part controls the liquid steel flow from the ladle to the tundish. These parts are called plates and may be made of different refractory ceramic materials. However, the plates used in this study are made of Al2O3-ZrO2-C. New parts and after service parts were analyzed. A static corrosion test was performed to analyze the chemical interaction between the refractory plates and the slag derived from steelmaking refining process. A laboratory experiment was carried out to evaluate wear due to remnants of slag between the sliding gate plates during the opening and closing of the gate. Such experiment was performed based on Mortar Resistance test used by Leroy. To analyze the materials, characterization techniques such as Scan Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), X-ray fluorescence (XRF), and X-ray diffraction were used. Based on the results of these analyses, a series of deterioration mechanisms were presented, such as the corrosion due to slag contact, and intensification of wear due to the use of semi-open valve. Mainly, from the performed experiments it was possible to identify a deterioration mechanism, that has not been discussed in literature yet This wear mechanism happens when the sliding gate plates are bonded by solidified slag, which is caused by opened valves, and leads to the extraction of particles from the surface of the plates. Due the lack of methodology to evaluate this kind of deterioration mechanism, a methodology based on mortar testing was developed. This method, called direct tensile test (L.A.Farias, 2016), showed intense deterioration. The chemical reaction between aluminum oxide refractory plate and the slag is responsible for the adhesion between plates and slag. This adhesion may be as strong as adhesion between the particles of the refractory, since refactory particles were removed in the test. Thus, it was concluded that the chemical interaction between refractory plate and slag, alied to the opening and closing mechanism are important in the deterioration of the Al2O3-ZrO2-C plates of the slide gate of the ladle.
49

Étude numérique du dépôt turbulent de particules non-browniennes en suspension dans un liquide : application aux inclusions dans l’acier liquide / Numerical study on turbulent deposition of non-Brownian particles suspended in a liquid phase : application to inclusions in liquid steel

Xayasenh, Arunvady 20 December 2013 (has links)
Nous étudions par simulation numérique le transport et le dépôt turbulent d’inclusions d’oxydes métalliques (de l’ordre de 10 µm de diamètre) en suspension dans l’acier liquide. Deux surfaces de dépôt sont envisagées : l’interface acier liquide/paroi solide et l’interface métal liquide/laitier. Dans les deux cas, nous nous focalisons sur la couche limite adjacente à l’interface. Le comportement des inclusions en suspension est examiné à l’aide d’un suivi lagrangien où le poids, la poussée d’Archimède, la force d’accélération en volume, la force de masse ajoutée et la force de traînée sont prises en compte dans l’équation de la dynamique. Dans le cas de la paroi solide, nous nous appuyons sur une représentation schématique de l’écoulement du métal liquide dans la sous-couche visqueuse et dans la zone tampon, où les structures turbulentes qui apportent le liquide à la paroi (sweeps) ou l’éjectent (bursts) sont décrites analytiquement (modèle d’Ahmadi). Les simulations numériques montrent que les mécanismes principaux de dépôt des inclusions sont la sédimentation et dans une moindre mesure l’interception directe. Notons cependant que la contribution de l’interception directe croît avec l’intensité turbulente de l’écoulement et peut devenir prépondérante pour les vitesses de frottement les plus élevées (au-delà de 0,1 m.s-1). Les effets inertiels ont, quant à eux, une contribution négligeable sur le dépôt des inclusions (contrairement au cas des aérosols). Enfin, la prise en compte des interactions hydrodynamiques entre les inclusions et la paroi solide conduit à une diminution significative de la vitesse de dépôt des inclusions. Dans le cas de l’interface acier liquide/laitier, l’écoulement du métal liquide est calculé par simulation numérique directe (DNS) à l’échelle de la couche de surface. La turbulence, générée à distance de l’interface par un forçage aléatoire, diffuse vers l’interface métal liquide/laitier modélisée comme une surface libre indéformable. L’évolution des inclusions en suspension est obtenue par un suivi lagrangien à l’aide d’un couplage one-way. Le nombre de Reynolds de surface des simulations varie de 68 à 235. Le diamètre des inclusions varie de 10-5m à 5.10-5m et le rapport entre la densité des inclusions et la densité du métal varie de 0,5 (inclusions d’alumine) à 1 (inclusions fictives). Il apparaît que le dépôt des inclusions d’alumine est contrôlé par la sédimentation. En l’absence d’effet gravitaire, le dépôt d’inclusions est contrôlé par l’interception directe et dépend fortement du nombre de Reynolds de surface. Dans ce dernier cas, nous montrons que la vitesse de dépôt adimensionnée par la vitesse de Kolmogorov de surface est proportionnelle au diamètre des inclusions adimensionné par la longueur de Kolmogorov de surface. La prise en compte des interactions hydrodynamiques entre les inclusions et la surface libre conduit à une diminution de moitié de la contribution de l’interception directe mais affecte peu la contribution gravitationnelle. En outre, en l’absence d’effet gravitaire, la linéarité entre la vitesse de dépôt adimensionnée et le diamètre des inclusions adimensionné est conservée. / The deposition of metallic oxide inclusions (of about 10 µm in diameter) suspended in liquid steel is studied by numerical simulation. Two types of deposition surface are investigated, i.e., the liquid steel/solid wall interface and the liquid steel/liquid slag interface. In both cases, we focus on the boundary layer adjacent to the interface. The inclusion behavior is examined thanks to Lagrangian particle tracking: Newton’s second law governing inclusion motion includes the buoyancy force, the pressure gradient force, the added mass force and the steady drag force.For the liquid steel/solid wall interface, the inclusion behavior is analyzed in the buffer layer and in the viscous layer. These layers are described according to Ahmadi’s model, which provides a kinematic representation of the turbulent structures responsible for deposition, i.e., the sweeps and the bursts of liquid. The numerical simulations show that the deposition is mainly controlled by sedimentation. However, since the direct interception contribution increases with the turbulence intensity, direct interception becomes dominant for the highest values of the friction velocity (greater than 0.1 m.s-1). When the hydrodynamic interactions between the inclusions and the solid surface are taken into account, the deposition velocity is significantly reduced. Finally, it should be noted that the inertial forces have a negligible effect on the inclusion deposition velocity. For the liquid steel/liquid slag interface, the inclusion turbulent deposition is investigated using direct numerical simulation of the liquid flow combined with Lagrangian particle tracking under conditions of one-way coupling. The interface is modeled as a non-deformable free-slip surface. Unsheared turbulence is generated by random forcing in a finite-height region parallel to the free-slip surface. In between, the turbulence diffuses toward the free surface. The Reynolds number at the interface varies from 68 to 235. The inclusion diameter varies from 10-5m to 5.10-5m and the particle to liquid density ratio from 0.5 (alumina inclusions) to 1 (fictitious inclusions). It appears that the deposition of alumina inclusions is controlled by sedimentation whereas direct interception is the only deposition mechanism for non-buoyant inclusions. In the latter case, the deposition velocity strongly depends on the surface Reynolds number. It is shown that the deposition velocity made dimensionless by the free surface characteristic velocity scales as the inclusion diameter made dimensionless by the Kolmogorov length scale calculated at the free surface. When the hydrodynamic interactions between the inclusions and the free surface are taken into account, the direct interception contribution of the deposition velocity is significantly reduced (about half of the value without hydrodynamic retardation) but the scaling law is conserved.
50

Análise multivariada dos principais fatores que afetam o desgaste (vida) do revestimento refratário das panelas de transporte de aço na Aciaria da Usina de Cubatão-Usiminas. / Multivariate analysis of the main factors that affecting the wear (life) of refractories\'steel ladle transport in the Cubatão-Usiminas\' Steelmaking plant.

Ronaldo Adriano Alvarenga Borges 15 July 2016 (has links)
O aumento da demanda por aços cada vez mais exigentes, em termos de composição química e limpidez interna, faz com que as condições de refino nas aciarias sejam cada vez mais severas. Ao mesmo tempo, o aumento dos tempos de tratamento do aço, aliado às outras variáveis operacionais como quantidades e tipos de adições químicas, etc. fazem com que haja um aumento no tempo de contato entre o revestimento refratário das panelas de transporte de aço e escórias com conseqüente redução do desempenho (vida) de tais revestimentos refratários. Apesar dos esforços no intuito de redução de custos com redução de consumos de refratários, é cada vez maior a pressão sobre os custos de produção e de segurança operacional. Neste sentido, a construção de modelos de previsão de vida em função de tais variáveis é de extrema importância para a gestão de processos e contratos, estabilidade operacional e segurança. Além disso, os estudos de post-mortem podem contribuir no sentido de compreensão física e química de tais fenômenos e mecanismos de desgaste, contribuindo assim para a validação de tais modelos determinísticos. Neste estudo, buscou-se verificar quais variáveis operacionais influem no desempenho (vida) das panelas através de correlações estatísticas. O modelamento levou em consideração os dados de 6 meses de operação da aciaria de uma usina integrada com capacidade de 4,5 Mt/ano. O estudo post-mortem realizado em uma das panelas, após o final de sua campanha, mostrou-se eficiente na validação de tais correlações e no entendimento físico e químico dos possíveis fenômenos e mecanismos de desgaste. As análises mostraram que as variáveis que impactam a vida das panelas de aço são a temperatura de vazamento do aço, temperatura do aço na panela pós vazamento, quantidade de aço chapas grossas (CG) produzido, rota de tratamento dessulfurado, tempo de panela cheia, participação do forno panela no refino secundário, condições da panela, carga de aço na panela, adições de nefelina, escória sintética, fios de cálcio silício (CaSi) e ferro alumínio cálcio (FeAlCa), ligas de manganês e tempos de tratamento no refino secundário. O estudo de post-mortem de amostras de refratário da linha de escória extraída de uma das panelas revelou que o principal mecanismo de desgaste desta região é a corrosão química pela escória que é facilitada pelas adições de nefelina. / The increased demand for increasingly demanding steels, in terms of chemical composition and internal sanity, makes the conditions of refining in steelmaking plants are increasingly stringent and select. At the same time, increasing metallurgical treatment times, combined with the various other operating variables such as the quantities and types of chemical additions, etc. makes that there is an increase in contact time between the refractory coating of steel transport ladles and slag with a consequent reduction in performance (life) of such refractory linings. Despite efforts in order to reduce costs with a reduction of refractory consumption, it is increasing the pressure on the costs of production and operational safety. In this sense, the construction of life prediction models according to such variables is extremely important for cost reduction, process management and procurement, operational stability and safety. Moreover, post-mortem studies can contribute towards chemical and physical understanding of such phenomena and wear mechanisms, thus contributing to the validation of such deterministic models. In this study, we sought to determine which operating variables really influence the performance (life) of the ladles through statistics correlations. The modeling took into account data from 6 months of operation of an integrated steelmaking plant with capacity of 4.5 Mt / year. The study post-mortem conducted on some ladles, after the end of their campaigns, was effective in the validation of such correlations and in the physical and chemical understanding of possible phenomena and wear mechanisms. The analysis showed that the variables that impact in the life of steel\'s ladles are the steel taping temperature, the steel taping temperature in the ladle after taping, amount of produced plate mill (CG) steel, desulfurized treatment route, ladle full time, participation of the ladle furnace in the secondary refining, ladle conditions, steel load in the ladle, nepheline additions, synthetic slag, calcium silicon (CaSi) and iron aluminium calcium (FeAlCa) wires, manganese alloys and treatment times in the secondary refining. The post-mortem study of slagline\'s refractory samples extracted from ladles in operation revealed that the main wear mechanism in this region is the chemical corrosion by slag and is facilitated by additions of nepheline.

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