Thesis (M.S.)--Virginia Polytechnic Institute and State University, 1990. / Vita. Abstract. Includes bibliographical references (leaves 60-61). Also available via the Internet.

Thesis (M.S.)--Florida State University, 2003. / Advisor: Dr. Farrukh S. Alvi, Florida State University, FAMU-FSU College of Engineering, Dept. of Mechanical Engineering. Title and description from dissertation home page (Aug. 27, 2004). Includes bibliographical references.

A numerical model has been developed for investigating boundary layer transition control for a three-dimensional flat plate boundary layer. Control of a periodically forced boundary layer in an incompressible fluid is studied using surface heating techniques. The spatially evolving boundary layer is simulated. The Navier-Stokes and energy equations are integrated using a fully implicit finite difference/spectral method. The Navier-Stokes equations are in vorticity-velocity form and are coupled with the energy equation through the viscosity dependence on temperature. Both passive and active methods of control by surface heating are investigated. In passive methods of control, wall heating is employed to alter the stability characteristics of the mean flow. Both uniform and nonuniform surface temperature distributions are studied. In the active control investigations, temperature perturbations are introduced locally along finite heater strips to directly attenuate the instability waves in the flow. A feedback control loop is employed in which a downstream sensor is used to monitor wall shear stress fluctuations. Passive control of small amplitude two-dimensional Tollmien-Schlichting waves and three-dimensional oblique waves are numerically simulated with both uniform and nonuniform passive heating applied. Strong reductions in both amplitude levels and amplification rates are achieved. Active control of small amplitude two-dimensional and three-dimensional disturbances is also numerically simulated. With proper phase control, in phase reinforcement and out of phase attenuation is demonstrated. A receptivity study is performed to study how localized temperature perturbations are generated into Tollmien-Schlichting waves. It is shown that narrow heater strips are more receptive in that they maximize the amplitude level of the disturbances in the flow. It is also found that the local temperature fluctuations cause mainly a strong normal gradient in spanwise vorticity. Control of the early stages of the nonlinear breakdown process is also investigated. Uniform passive control is applied to both the fundamental and sub-harmonic routes to turbulence. A strong reduction in amplitude levels and growth rates results. In particular, the three-dimensional growth rates are significantly reduced below the uncontrolled levels. Active control of the fundamental breakdown process is also numerically simulated. Control is achieved using either a two-dimensional or three-dimensional control input.

A variety of functional thin films can be produced using the layer-by-layer assembly technique. In this work, assemblies of anionic clay and cationic polymer were studied with regard to film growth and gas barrier properties. A simple, yet flexible robotic dipping system, for the preparation of these thin films, was built. The robot alternately dips a substrate into aqueous mixtures with rinsing and drying in between. Thin films of sodium montmorillonite clay and cationic polymer were grown and studied on poly(ethylene terephthalate) film or a silicon wafer. After 30 clay polymer bilayers were deposited, the resulting transparent film had an oxygen transmission rate (OTR) below 0.005 cm3/m2/day/atm. This low OTR, which is unprecedented for a clay-filled polymer composite, is believed to be due to a ?brick wall? nanostructure comprised of completely exfoliated clay bricks in polymeric ?mortar?. The growth of polymer and clay assemblies is then shown to be controlled by altering the pH of polyethylenimine (PEI). Growth, oxygen permeability, and mechanical behavior of clay-PEI assemblies were studied as a function of pH in an effort to tailor the behavior of these thin films. Thicker deposition at high pH resulted in reduced oxygen permeability and lower modulus, which highlights the tailorability of this system.

A variety of materials were used to fabricate nanocoatings using layer-by-layer (LbL) assembly to reduce the flammability of cotton fabric. The most effective brominated flame retardants have raised concerns related to their toxicity and environmental impact, which has created a need for alternative flame retardant chemistries and approaches. Polymer nanocomposites typically exhibit reduced mass loss and heat release rates, along with anti-dripping behavior, all of which are believed to be due to the formation of a barrier surface layer. Despite these benefits, the viscosity and modulus of the final polymeric material is often altered, making industrial processing difficult. These challenges inspired the use of LbL assembly to create densely layered nanocomposites in an effort to produce more flame-retardant coatings. Laponite and montmorillonite (MMT) clay were paired with branched poly(ethylenimine) to create thin film assemblies that can be tailored by changing pH and concentration of aqueous deposition mixtures. Both films can be grown linearly as a function of layers deposited, and they contained at least 70 wt percent of clay. When applying these films to cotton fabric, the individual fibers are uniformly coated and the fabric has significant char left after burning. MMT-coated fabric exhibits reduced total heat release, suggesting a protective ceramic surface layer is created. Small molecule, POSS-based LbL thin films were also successfully deposited on cotton fabric. With less than 8 wt percent added to the total fabric weight, more than 12 wt percent char remained after microscale combustion calorimetry. Furthermore, afterglow time was reduced and the fabric weave structure and shape of the individual fibers were highly preserved following vertical flame testing. A silica-like sheath was formed after burning that protected the fibers. Finally, the first intumescent LbL assembly was deposited on cotton fabric. SEM images show significant bubble formation on fibers, coated with a 0.5 wt percent PAAm/1 wt percent PSP coating after burning. In several instances, a direct flame on the fabric was extinguished. The peak HRR and THR of coated fabric has 30 percent and 65 percent reduction, respectively, compared to the uncoated control fabric. These anti-flammable nanocoatings provide a relatively environmentally-friendly alternative for protecting fabrics, such as cotton, and lay the groundwork for rendering many other complex substrates (e.g., foam) flame-retardant without altering their processing and desirable mechanical behavior.

The mixing layer (ML) heights inferred from radiosondes, wind profilers, airborne lidar, airborne microwave temperature profiler (MTP), and in-situ aircraft data were compared during the Texas 2000 Air Quality Study in the Houston area. The comparisons and resulting good agreement between the separate instruments allowed for the spatial and temporal evolution of the ML height distribution to be determined across the Houston area on September 1, 2000. A benchmark method was created for determining ML heights from radiosonde data. The ML heights determined using this method were compared to ML heights determined using wind profiler data. The airborne lidar and MTP heights were also compared to the wind profiler heights. This was the first time the MTP was used for estimating ML heights. Because of this, the MTP heights were also compared to the ML heights determined by in-situ aircraft data. There was good agreement between the ML estimates when the instruments were co-located. The comparisons between the benchmark method and the wind profilers were independent of the quality of the profiler heights. The statistics for lidar and the wind profilers were better for the inland profiler comparisons. Even so, the results for coastal profilers were similar to the other comparisons. The results between the MTP and the wind profilers were comparable with the results found between the other instruments, and better, in that the statistics were similar for the both the inland and coastal profilers. The results between the MTP and in-situ aircraft data provided additional support for the use of MTP for determining ML heights. The combination of the inland and coastal wind profilers with the airborne instruments provided adequate information for the spatial and temporal evolution of the ML height to be determined across the Houston area on September 1, 2000. By analyzing the ML height distribution, major features were evident. These features included the shallow ML heights associated with the marine air from Galveston Bay and the Gulf of Mexico, and the sharp gradient of increasing ML heights north of Houston associated with the variation in the inversion depth found on this day.

Layer-by-layer (LbL) assembly was used to produce highly conductive thin films with carbon black (CB) and polyelectrolytes. The effects of sonication and pHadjustment of the deposition mixtures on the conductivity and transparency of deposited films were studied. Drying temperature was also evaluated with regard to thin film resistance. Sonication and oven drying at 70oC produced films with the lowest sheet resistance (~ 1500 Ω/sq), which corresponds to a bulk resistivity of 0.2 Ω⋠cm for a 14- bilayer film that is 1.3 μm thick. Increasing the pH of the PAA-stabilized mixture and decreasing the pH of the PEI-stabilized mixture resulted in films with 70% transparency due to thinner deposition from increased polymer charge density. Varying the number of bilayers allows both sheet resistance and optical transparency to be tailored over a broad range. Variation of deposition mixture composition led to further reduction of sheet resistance per bilayer. A 14 bilayer film, made from mixtures of 0.25wt% carbon black in 0.05wt% PAA and plain 0.1wt% PEI, was found to have a sheet resistance of approximately 325 Ω/sq. Bulk resistivity was not improved due to the film being 8 μm thick, but this combination of small thickness and low resistance is an order of magnitude better than carbon black filled composites made via traditional melt or solution processing. Applications for this technology lie in the areas of flexible electronics, electrostatic charge dissipation, and electromagnetic interference shielding.

Thesis (Ph. D.)--Virginia Polytechnic Institute and State University, 1993. / Vita. Abstract. Includes bibliographical references (leaves 70-74). Also available via the Internet.

Thesis (Ph. D.)--Stanford University, 1978. / "Printed in 2003 by digital xerographic process on acid-free paper"--P. after T.p. Includes abstract (p. iv). Includes bibliographical references (p. 213-217). Also issued in print.

Thesis (Ph. D.)--Stanford University, 1978. / "Printed in 2003 by digital xerographic process on acid-free paper"--P. after T.p. Includes abstract (p. iv). eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (p. 213-217).