Ce travail de thèse consiste en l’étude de la mise en forme topologique de la lumière et de la matière et s’articule autour de deux axes de recherche. Le premier concerne la mise en forme topologique de la lumière à partir d’interfaces spin-orbite à base de cristaux liquides. En l’occurrence, nous montrons dans ce manuscrit que différents systèmes de défauts topologiques naturels permettent de générer des vortex optiques par interaction spin-orbite de la lumière, de manière efficace, accordable en longueur d’onde et reconfigurable en temps réel et donnant accès à des charges topologiques diverses. Tout ceci nous a permis de travailler à des échelles microscopiques et de manière spatialement contrôlée. Ces avancées ouvrent la voie au contrôle de l’état orbital de la lumière sur une large bande spectrale.Le second axe concerne la mise en forme topologique d’un film de cristal liquide cholestérique dans le cadre du stockage de l’information de nature topologique. Nous avons démontré la possibilité de générer une grande diversité de défauts topologiques métastables, de manière contrôlée et reconfigurable, à la fois dans le temps et dans l’espace. Nous avons développé une approche permettant de réduire drastiquement le coût énergétique d’écriture de ces défauts. Nous avons également montré qu’il était possible d’obtenir un nouveau type de mémoire réinscriptible contrôlé par le degré de liberté «spin» du photon. / The enclosed work deals with the study of the topological shaping of light and matter and will bedivided into two categories of research. The first focuses on the topological shaping of light from liquid-crystal based spin-orbit interfaces. In particular, we show in this manuscript, that different systems based on the use of natural topological defects behave as highly efficient natural optical spin-orbit encoders, for distinct topological charges, at the micron scale and with spatial control.The operating wave length and operation mode of such interfaces can be tuned in real-time using low voltage electric fields. This breakthrough opens the path to the ultra-broadband control of the light’sorbital state. The second category concerns the topological shaping of a cholesteric liquid crystal film in context of mass data storage. We show the potential to generate metastable topological mi-crostructures in a controlled and reconfigurable way, both in time and space and with a low energy cost. We also demonstrated a new, unique type of rewritable memory, controlled by the«spin»ofthe laser-generated incident photon

<p>In modern gas turbines parts of combustion chamber and turbine section are under heavy heat load, for example, the rotor inlet temperature is far higher than the melting point of the rotor blade material. These high temperatures causes thermal stresses in the material, therefore it is very important to cool the components for safe operation and to achieve desired component life. But on the other hand the cooling reduces the turbine efficiency, for that reason it is vital to understand and optimize the cooling technique.</p><p>In this project Thermochromic Liquid Crystals (TLCs) are used to measure distribution of heat transfer coefficient over a scaled up combustor liner section. TLCs change their color with the variation of temperature in a particular temperature range. The color-temperature change relation of a TLC is sharp and precise; therefore TLCs are used to measure surface temperature by painting the TLC over a test surface. This method is called Liquid Crystal Thermography (LCT). LCT is getting popular in industry due to its high-resolution results, repeatability and ease of use.</p><p>Test model in present study consists of two plates, target plate and impingement plate. Cooling of the target plate is achieved by impingement of air coming through holes in the impingement plate. The downstream surface of the impingement plate is then cooled by cross flow and re-impingement of the coolant air.</p><p>Heat transfer on the target plate is not uniform; areas under the jet which are called stagnation points have high heat transfer as compare to the areas away from the center of jet. It is almost the same situation for the impingement plate but the location of stagnation point is different. A transient technique is used to measure this non-uniform heat transfer distribution. It is assumed that the plates are semi-infinitely thick and there is no lateral heat transfer in the plates. To fulfill the assumptions a calculated time limit is followed and the test plates are made of Plexiglas which has very low thermal conductivity.</p><p>The transient technique requires a step-change in the mainstream temperature of the test section. However, in practical a delayed increase in mainstream temperature is attained. This issue is dealt by applying Duhamel’s theorem on the step-change heat transfer equation. MATLAB is used to get the Hue data of the recorded video frames and calculate the time taken for each pixel to reach a predefined surface temperature. Having all temperatures and time values the heat transfer equation is iteratively solved to get the value of heat transfer coefficient of each and every pixel of the test surface.</p><p>In total fifteen tests are conducted with different Reynolds number and different jet-to-target plate distances. It is concluded that for both the target and impingement plates, a high Reynolds number provides better overall heat transfer and increase in jet-to-target distance</p><p>decreases the overall heat transfer.</p>

Multi-scale ordering of the components is of utmost importance for the preparation of any functional system. This is particularly interesting for the assembly of plamonic nanoparticles which show drastic differences in their optical properties compared to the individual counterparts, giving rise to the unique opportunity to perform enhanced spectroscopies, sensing, and transporting optical information below the diffraction limitation of light. The control over ordering of nanoscale materials is therefore of paramount importance. Template based bottom up approaches such as using nematic liquid crystals promise a long range, reversible ordering of nanomaterials. It also promises active control over plasmonic properties of metal nanoparticles due to the electric field induced reorientation of liquid crystals, resulting in a change of the local refractive index. This thesis discusses the possibility of ordering anisotropic metal nanoparticles and performing active modulaton of the plasmonics response using a nematic liquid crystals. While long polymer chains can be solvated and aligned in liquid crystal solvents, anisotropic metal nanoparticles could not be dissolved in the nematic liquid crystal phase because of their poor solubility. Here, I show that appropriate surface functionalization can increase the otherwise low solubility of plasmonic nanoparticles in a nematic liquid crystal matrix. I also show that it is possible to reversibly modulate the polarized scattering of individual gold nanorods through an electric field induced phase transition of the liquid crystal. In this thesis, I also studied the motion of a molecular machine, commonly known as nanocars, over different solid surface. I show that individual nanocars, which consist of four carborane wheels attached to an aromatic backbone chassis, can move up to several micrometers over a glass surface at ambient temperature. Their movement is consistent with the rolling of the carborane wheels and can be controlled by tuning the interaction between the surface and the wheels.

In modern gas turbines parts of combustion chamber and turbine section are under heavy heat load, for example, the rotor inlet temperature is far higher than the melting point of the rotor blade material. These high temperatures causes thermal stresses in the material, therefore it is very important to cool the components for safe operation and to achieve desired component life. But on the other hand the cooling reduces the turbine efficiency, for that reason it is vital to understand and optimize the cooling technique. In this project Thermochromic Liquid Crystals (TLCs) are used to measure distribution of heat transfer coefficient over a scaled up combustor liner section. TLCs change their color with the variation of temperature in a particular temperature range. The color-temperature change relation of a TLC is sharp and precise; therefore TLCs are used to measure surface temperature by painting the TLC over a test surface. This method is called Liquid Crystal Thermography (LCT). LCT is getting popular in industry due to its high-resolution results, repeatability and ease of use. Test model in present study consists of two plates, target plate and impingement plate. Cooling of the target plate is achieved by impingement of air coming through holes in the impingement plate. The downstream surface of the impingement plate is then cooled by cross flow and re-impingement of the coolant air. Heat transfer on the target plate is not uniform; areas under the jet which are called stagnation points have high heat transfer as compare to the areas away from the center of jet. It is almost the same situation for the impingement plate but the location of stagnation point is different. A transient technique is used to measure this non-uniform heat transfer distribution. It is assumed that the plates are semi-infinitely thick and there is no lateral heat transfer in the plates. To fulfill the assumptions a calculated time limit is followed and the test plates are made of Plexiglas which has very low thermal conductivity. The transient technique requires a step-change in the mainstream temperature of the test section. However, in practical a delayed increase in mainstream temperature is attained. This issue is dealt by applying Duhamel’s theorem on the step-change heat transfer equation. MATLAB is used to get the Hue data of the recorded video frames and calculate the time taken for each pixel to reach a predefined surface temperature. Having all temperatures and time values the heat transfer equation is iteratively solved to get the value of heat transfer coefficient of each and every pixel of the test surface. In total fifteen tests are conducted with different Reynolds number and different jet-to-target plate distances. It is concluded that for both the target and impingement plates, a high Reynolds number provides better overall heat transfer and increase in jet-to-target distance decreases the overall heat transfer.

In this research, the polarization converters were manufactured by impinging intensity-gradient-distribution laser on DDLC (dye-doped liquid crystal) samples, which the gradient distributed light intensity was produced by applying linear variable ND filter. The performances of these polarization converters were demonstrated, which can convert a linear polarized incident light into a circular polarized light or an elliptic polarized light. The influence of cell gap and beam size of probe beam on the DDLC polarization converter has been discussed.

We take the electron deficient heterocyclic hexaazatriphenylene (HAT) as our central core and readily synthesized by the condensation of hexaketo- cyclohexane with the respective 1,2-bis-alk-oxy-4,5-diaminobenzene. We use the polarised optical microscopy (POM) and differential scanning calorimetry (DSC) to study the mesophase range.These mesophases are identified as columnar phases by diffraction (XRD).

In this study, the phase grating was investigated by using electro-optical characteristics of blue phase liquid crystals(BPLCs) such as fast-response and optically isotropic etc. The BPLC units was affected by distribution of periodically electric field and then changed the cubic structure into others, when applying voltage in etched electrode of grating pattern. A linearly polarized light is incident upon the sample and experience the periodic difference of index, and diffraction effect was generated. In order to find out the best conditions of these liquid crystals device, we discussed different factor such as angle of linearly polarized light, operating temperature of grating, cooling rate and electrode structure.

The specific heat Cp has been showed at various temperatures in the literature, which shows a sharp increase labeled as the lambda-transition at the critical temperature. This transition has been observed previously among the phases of solid-nematic-isotropic liquid in p-azoxyanisole (PAA) and anisaldazine (AAD), and among the phases of solid-smectic-cholesteric-isotropic liquid in cholesteryl myristate (CM). In this thesis work, we analyze the experimental data for the temperature dependence of Cp and the thermal expansion alpha_p and also pressure dependence of alpha_p by a power-law formula. From the analysis of pressure dependence of alpha_p, we calculate the temperature dependencies of specific heat Cp and of the isothermal compressibility kappa_T for the phase transitions considered in PAA, AAD and CM. Our calculations for the temperature dependence of the p and kappa_T can be compared with the experimental data when available in the literature. Polarization, tilt angle and the dielectric constant have been reported in the literature at various temperatures close to the solid-smectic C*-smectic A-isotropic liquid transition in the ferroelectric liquid crystals of A7 and C7. The mean field model with the free energy expanded in terms of the order parameters (polarization and tilt angle) has been reported in the literature previously. In this thesis work, we apply the mean field model first time by fitting the expressions derived for the temperature dependence of the polarization, tilt angle and the dielectric constant to the experimental data for A7 and C7 from the literature. Since the mean field model studied here describes adequately the observed behaviour of A7 and C7, the expressions for the temperature dependence of the polarization, tilt angle and the dielectric constant which we derive, can also be applied to some other ferroelectric liquid crystals to explain their observed behaviour.

Thermal behavior and molecular packing of a series of £\-helical poly(L-glutamates), with n-alkyl side chain of various lengths (m(number of carbons in the alkyl group) = 1, 2, 6, 12,18), were studied by means of differential scanning calorimetry, polarizing light microscopy and X-ray diffraction. For polymers of m = 1 and 2, There is a pseudohexagonal structure below ca. 130 oC and above this temperature the stable phase is the hexagonal columnar phase. There exists a layered structure in the polymer of m = 6, as well as a solvent induced hexagonal columnar structure which formed during solution casting process. In the polymer of m = 12, a layered structure was formed in the temperature range between 20 to 255 oC. However, for longer side chain, m = 18, tendency of crystallization of alkyl long side chain forced the backbone to pack into layer structure. There are two distinct melting temperature at ca. 60 oC, and the enthalpy are ca. 53 and 19 J/g, which corresponding to the melting of hexagonal and monoclinic side chain crystallines. The polymers with longer side chain (m = 6, 12 and 18) tend to be lyotropic liquid crystalline phase within lamellar inter-rod distance of 1.25 nm in solution state, and the structure will remain after drying. However, the inter-rod distance will collapse at the temperature above ca. 200 ¢J and will not recover after cooling.

The objective of this thesis is to design RF circuits using silicon-germanium (SiGe) heterojunction bipolar transistors (HBTs) for communication system. The packaging effect for the SiGe chip using liquid crystal polymer (LCP) is presented and methodology to derive the model for the package is discussed. Chapter 1, we discuss the overview and benefits of SiGe HBT technology in high frequency circuit design. Chapter 2 presents the methodology of the low noise amplifier (LNA) design and discusses the trade-off between the noise and gain matching. The technique for achieving simultaneous noise and gain matching for the LNA is also presented. Chapter 3 presents an L-band cascaded feedback SiGe low noise amplifier (LNA) design for use in Global Position System (GPS) receivers. Implemented in a 200 GHz SiGe BiCMOS technology, the LNA occupies 1 x 1 millimeter square (including the bondpads). The SiGe LNA exhibits a gain greater than 23 dB from 1.1 to 2.0 GHz, and a noise figure of 2.7 to 3.3 dB from 1.2 to 2.4 GHz. At 1.575 GHz, the 1-dB compression point (P1dB) is 1.73 dBm, with an input third-order intercept point (IIP3) of -3.98 dBm. Lastly, Chapter 4 covers the packaging techniques for the SiGe monolithic integrated circuit (MMIC). We present the modeling of a liquid crystal polymer (LCP) package for use with an X-band SiGe HBT Low Noise Amplifier (LNA). The package consists of a 2 mil LCP laminated over an embedded SiGe LNA, with vias in the LCP serving as interconnects to the LNA bondpads. An accurate model for the packaging interconnects has been developed and verified by comparing to measurement results, and can be used in chip/package co-design.