In order to develop high speed photo-electronic device, first, we grew one layer of GaN by MOPVE to decline lattice mismatch. Then we used PA-MBE to grow AlxGa1-xN/GaN heterostructure III-V semiconductor. Via changing the content of aluminum, we can confer the characteristic of these samples. In these samples, we controlled the content of aluminum by changing the vapor of aluminum. And then we used X-ray diffraction, SEM, AFM, low temperature Hall measurement and SdH to study the characteristic of these samples. Throughout X-ray diffraction, the aluminum content x are 1.76%, 2.3%, 14.33%, 22.03% and 37.26%. Due to (004) AlGaN Rocking Curve F.W.H.M. are only 300 arcsec, the quality of the five samples are extraordinary. In addition, SEM and AFM measurement indicate that this series samples¡¦ interface are very smooth, and the roughest sample is only 2nm. It can make sure that samples were grown in mode of two-dimensional (2D). With low temperature Hall measurement, we can find out the Coulomb scattering which is from the defect are very small in the sample A, B, C, D. And the mobility of this series samples are very high, the highest mobility is sample A at 8K which is 19593 cm2/Vs. We can observe the oscillation of the sample C, D obviously in SdH measurement indicate that the 2DEG is confined in the potential well.

Aluminum doped zinc oxide AZO has been studied for 20 years. It can improve thin films¡¦ thermal stability and transparency in visible range .However AZO is not as good as ITO in conductivity and transparency, that¡¦s why the application of AZO is only limited in few fields. This is because the nature limit of ZnO. Because part of doped Al forms Al2O3 instead of sits on Zn sites, that enhances light and carriers scattering and suppresses the optical transparency and electric conductivity. This study is plane to take advantage of amorphous properties, that may be achieved try grown films at liquid Nitrogen temperature, in which the distribution of Al and Zn will be very uniform and the solubility of Al will be high. ZnO:Al thin films is grown on glass substrates at low temperature by Radio frequency magnetron sputtering system. Low-temperature deposition is done in order to deposit amorphous thin films (ceramic targets ZnO contained 2wt.% Al2O3). The Al3+ in place of Zn2+ should be uniformly distributed in the thin films because of amorphous structure. It expects to find the best deposition condition under a fixed target-to-substrate distance (10cm) by varying growth, such as the deposition mode, PF plasma power and working pressure. AFM, XRD (grazing incident x-ray diffraction) and N&K analyzer were used to measure the thin surface morphology, structure, thickness and transmittance, respectively. The colors of the thin films are very different dependent on the modes of deposition. The low sputtering rate by lower RF power and high working pressure is the key to successfully grow amorphous ZnO:Al films. The amorphous ZnO:Al thin films (a-5) are deposited under 100W of RF power and 50mTorr of working pressure. The transmittance of the assembly of ZnO:Al thin films/glass substrate is the same as glass substrates which inducates the transmittance of films is far above 90%. However, the amorphous ZnO:Al thin films are poor conductor . We also tried to improve it by the post-annealing of ZnO:Al thin films in 2% hydrogen atmosphere. It is found to be not successful.

Thesis (Ph. D.)--University of Missouri-Columbia, 2000. / Typescript. Vita. Includes bibliographical references (leaves 80-84). Also available on the Internet.

Thesis (Ph. D.)--University of Missouri-Columbia, 1996. / Typescript. Vita. Includes bibliographical references (leaves 201-208). Also available on the Internet.

This thesis presents the design and construction of a low temperature differential (LTD) Stirling engine for electric power generation. The target energy sources were geothermal, industrial waste heat or solar heated water. These sources would supply a source temperature of around 90 °C. Assuming that the sink is kept at around 20 °C, the engine was designed based on a temperature difference of approximately 70 °C. The initial design and basic structure of the engine was completed in a previous project utilising first order design methods. The goal was to develop a low cost prototype engine capable of producing up to 500W electrical output power. A novel gamma type engine was proposed utilising a rotary reciprocating displacer and industrial steam piping to form a low cost pressurised chamber. This project concentrated on advancing the design and construction towards completion with particular emphasis on the electrical control, measurement/instrumentation components, and gas flow through the regenerator. At the completion of this project the displacer piston actuation system has been redesigned. In order to achieve the displacer’s specified 2 ㎐ actuation, both the displacer’s structure and the actuation system were altered. The displacer’s aluminium shell and foam centre were removed and replaced with a pine superstructure coated in depron foam, reducing the moment of inertia from 0.4488 ㎏ ∙ ㎡ to 0.0984 ㎏ ∙ ㎡. A secondary motor was added to the actuation system to increase the actuation power. The gearing ratio was also altered from 10:1 to 2:1 to increase the peak displacer speed. The regenerator was designed and built to suit the unusual wedge shape requirements of the original design. A ribbed structure was conceived to allow fluid flow to be manipulated within separate sections, producing an even pressure drop over varying regenerator lengths. Simulations were run to optimise both the number of sections and the mass of wire wool to be placed in each segment. The final regenerator design has axial ribs placed at radii of 93, 134, 192, 276 and 392mm, creating four sections. These sections are filled with 0.68, 0.97, 1.40 and 1.90kg of #0 mild steel wire wool. As Stirling engines are not self-starting the generator was required to be run as a motor when starting the Stirling engine. To achieve bidirectional flow of current within the starter motor/generator control system, a field oriented control (FOC) inverter from Texas Instruments was purchased and set up to run the 1kW, 3 phase, permanent magnet generator in both motor and generation modes. This will allow the Stirling engine to be brought up to speed with the generator operating as a motor and then switch to generation mode when the motoring current falls below a set limit. Both pressure and temperature measurement systems were developed, constructed and tested in order to collect information about the performance of the engine under operation. Three pressure transducer circuits were designed and constructed with measurement ranges of 10 ㎪, ±0.99 ㎪ and ±6.66 ㎪. These circuits were integrated with a PiocLog1012 analog to digital converter and PicoLog recording software. Eight K-type thermocouples were used for temperature recording. These were sampled with a Pico Technology TC-08 temperature thermocouple data logger which in turn was connected, via USB, to a computer running PicoLog Recorder software. Thus far all component testing has been carried out with test rigs that model the relevant parts of the engine. The displacer actuation system and phase angle control of the displacer and power piston has been tested. Temperature and pressure measurement systems have been independently tested. Motor/generator speed control and switching has been simulated and tested. Unfortunately completion of the engine assembly was not achieved within the scope of this project and therefore fully integrated testing of all components was not carried out. Once mechanical assembly is completed fully integrated testing of displacer actuation, piston position, generator speed control and measurement systems can be achieved.

Thesis (MTech. degree in Mechanical Engineering)--Tshwane University of Technology, 2008. / The sun is known to be the main source of energy to earth. It is further more outstanding since it is clean and comes to the earth with no costs. However, mankind does not utilize most of this precious energy effectively. In South Africa, emerging farmers need their agricultural products preserved in storage or in transit. Solar adsorption cooling machines would be of benefit to these farmers as they do not require any additional source of energy and are completely autonomous. This study presents a theoretical and experimental analysis of a solar assisted adsorption fridge, as well as the cost effectiveness when compared with the vapour compression method. The cooling machine was designed, developed and tested. It does not contain any moving part; nor consume any mechanical energy. The results show that the refrigerator can chill 25 litres of water from 35 to 5 °C per day. Vegetables and fruits with preservation temperatures in the range 4 -10 °C are within the scope of the present system. The best useful cooling obtained was 1785 kJ per day, and the best coefficient of performance was 0.058.

This study investigated the overpotential performance enhancement of cathodes in low temperature solid oxide fuel cells (LT-SOFCs) due to the addition of carbonates to traditional Ce0.9Gd0.1O2 solid oxide fuel cell (SOFC) electrolytes. It was postulated in this study that this enhancement was due to the protonic conductivity of the carbonates. This provided an electrolyte with a dual conduction mechanism which improves the catalytic performance of the cathode. The cathode systems investigated were characterised for overpotential loss, conductivity and thermal expansion matching with the electrolyte. This produced results which predicted power outputs for a standard SOFC configuration as high as 970, 524 and 357 mW/cm2 at operational temperatures of 650oC, 600oC and 550oC. The benefits of these high power outputs and their potential to further reduce SOFC operational temperature was discussed. This study developed a cost-effective, reliable and commercially scalable manufacturing process for carbonate/Ce0.9Gd0.1O2 electrolytes. This pressureless sintering method is the first reported in literature, and is a promising replacement for the current hot-pressing technique currently used for these electrolytes. The electrolyte composition examined was 70 wt% Ce0.9Gd0.1O2 with 30 wt% carbonates (67 mol% Li2CO3 / 33 mol% Na2CO3). The cathode examined in this study was a composite cathode consisting of 50-90 wt% functional cathode material (Gd1-xSrxCoO3 with 10 to 30 mol% Sr doping on the Gd site) with a balance of electrolyte. It was determined that the composite cathode system with 10 wt% electrolyte and 20-30 mol% Sr doping was the optimal composition when operating at 600oC and above, with predicted power densities of 524 and 510 mW/cm2 at 600oC. At operational temperatures between 550oC and 600oC (and potentially lower), it was determined that a composite cathode system with 30 wt% electrolyte and 10-30 mol% Sr doping was the optimal composition. It was found that the presence of carbonates in the electrolyte decreased the overpotential losses of the cathode by 50-70% at 600oC for system studied; indicating that an improvement in cathodic performance coupled with the high conductivities of the electrolyte is most likely responsible for the high power outputs seen in literature. / Thesis (Ph.D, Mechanical and Materials Engineering) -- Queen's University, 2009-04-25 15:53:37.928

Microorganisms have developed ways to preserve cellular functions under low temperature conditions using a variety of biochemical adaptations including the modification of ice formation. In order to conduct a limited survey of microbial ice-associating strategies, a bacterial community associated with frost-exposed leaves was assessed by the construction of a 16S rDNA library, followed by the characterization of some isolates. Fifteen different species were identified based on their 16S rDNA. Among these, Pseudomonas syringae J6 had ice nucleation activity (INA), which promoted ice formation close to 0ºC, whereas Erwinia billingiae, Flavobacterium sp. and Sphingobacterium kitahiroshimense inhibited the recrystallization of small ice crystals at temperatures close to melting. The Erwinia billingiae isolate showed adhesive and swarming behaviour, which can be associated with biofilm formation. Visualization using negative staining, transmission electron microscopy and scanning electron microscopy confirmed the presence of flagella in addition to the presence of slimy biofilm architecture in these Erwina billingiae cultures. Subsequent purification of the extracellular polymeric substance followed by mass spectrometry allowed the identification of a putative outer membrane protein A, which may be involved in the protection of this bacterium to freeze-thaw cycles. To further explore bacterial ice nucleation activity, an ice nucleation protein was cloned from Pseudomonas borealis, a bacterium originating from tundra soil, using degenerative PCR and chromosome walking. The sequence of the putative ice nucleation protein gene (inaPb) was cloned and expressed in Escherichia coli, and its identification was confirmed in the recombinant cells. Although the INPPb was more divergent than other plant-related bacterial INPs, it retained the highly conserved, repetitive core region. The protein may fold so that it has two flat faces, one for protein-protein interactions and the other for ice binding. Expression of the INPPb coding region fused to jelly fish green fluorescent protein showed a temperature-dependent polarized distribution of the recombinant protein in E. coli. In summary, results from this thesis suggests that low temperature survival may be associated with a number of ice-associating adaptations including the presence of biofilm formation in Erwina billingiae amongst other bacteria, INA in P. borealis and INA-expressing recombinant E. coli. / Thesis (Ph.D, Biology) -- Queen's University, 2010-01-27 11:47:02.385

In this thesis, I present the work performed towards a proposal to couple a piezoelectric, nanomechanical beam to a radio frequency single electron transistor (RF-SET). Lumped element RF circuit theory is applied to 50 kOhm single electron transistors acting as the resistor in an RLC circuit. It is shown that for the expected inductances and stray capacitances, at an operating frequency of 1.25 GHz, the RF-SET is expected to have a usable half-bandwidth of 175-200 MHz and a charge sensitivity on the order of 10^(−5) e/√Hz. A fabricated RF-SET device is cryogenically cooled and used to find experimental values of the stray capacitance. A heterostructure made of gallium arsenide and aluminum gallium arsenide from which piezoelectric beams can be made is designed to contain a 2-dimensional electron gas (2DEG). Quantum Hall effect samples are fabricated from the wafer, and magnetoresistance measurements for each sample are presented. It is shown that the 2DEG has a high electron concentration of about 8 × 10^11 cm−2 but a low mobility of about 3.5 × 10^4 cm^2/(V·s) for this type of heterostructure. / Thesis (Master, Physics, Engineering Physics and Astronomy) -- Queen's University, 2010-03-01 22:55:56.427

In the past decade, nanomechanical resonators have found use in the work towards understanding mesoscopic quantum systems and the necessary validation of quantum mechanics on this scale. In 2010, the observation and state manipulation of a nanomechanical quantum system was achieved for the first time by O'Connell et al.. In 2002, Knobel and Cleland proposed to use a radio frequency superconducting single-electron transistor (RF-SSET), a fast and sensitive charge amplifier, to sense the quantum-limited motion of a piezoelectrically coupled nanomechanical resonator. The work presented in this thesis is towards the realization of the RF-SSET component of this device. An in-house fabrication recipe for making SETs with tunnel junction areas < 100^2 nm^2 and resistances between 20 kΩ and 150 kΩ was developed, in the end producing six SETs with resistances (36 ± 8) kΩ that were not susceptible to aging effects. Three measurement circuits were designed and used to characterize one of these SETs in the superconducting state (SSET) and operated in the DC and RF modes in a cryostat at a base temperature of 320~mK. Lock-in measurements revealed the SSET junction capacitances as 206 and 305 aF, contributing to a charging energy of (296 ± 11) x 10^(-6) eV. The resonant LC tank, which permitted RF operation, was also characterized at base temperature. The charge sensitivity of the RF-SSET was 6.8 x 10^(-5) e/√Hz (with uncertainty between 9.6 x 10^(-4) e/√Hz and 3.5 x 10^(-5) e/√Hz). With moderate improvements to the impedance matching network formed with the LC tank and greater junction resistances, an RF-SSET charge sensitivity on the order of 10^(-6) e/√Hz, required for sensing the quantum-limited motion of the nanomechanical resonator, should be achieved. / Thesis (Master, Physics, Engineering Physics and Astronomy) -- Queen's University, 2010-08-10 17:38:43.798