Wasserdampf in der Stratosphäre und Troposphäre ist eines der wichtigsten atmosphärischen Treibhausgase. Neben seiner Bedeutung für das Klima hat es großen Einfluss auf die Bildung von polaren stratosphärischen Wolken sowie auf die atmosphärische Chemie. Weltweit erstmalig soll innerhalb eines Forscherverbundes in Deutschland ein leistungsstarkes, mobiles, abtastendes Wasserdampf-DIAL zur dreidimensional hochaufgelösten Messung des atmosphärischen Wasserdampfs entwickelt werden. Mit dem Wasserdampf-DIAL können Wasserdampfkonzentrationen in der Atmosphäre mit hoher zeitlicher und räumlicher Auflösung gemessen werden. Das DIAL basiert auf einem Titan-Saphir-Laser oder einem dazu alternativen OPO-Laser (optisch parametrischer Oszillator). Der für das optische Pumpen dieser Laser nötige Pumplaser wurde im Rahmen dieser Arbeit in der Arbeitsgruppe Nichtlineare Optik des Instituts für Physik der Universität Potsdam entwickelt. Ein hochauflösendes, mobiles DIAL erfordert einen Pumplaser mit großen Pulsenergien, guter Strahlqualität und einer hohen Effizienz. Um diese Ziele zu erreichen, wurde ein MOPA-System (Master Oscillator Power Amplifier) mit Frequenzstabilisierung auf der Basis von doppelbrechungskompensierten, transversal diodengepumpten Laserstäben entwickelt und untersucht. Auf dem Weg dahin wurden unterschiedliche Realisierungsmöglichkeiten des MOPA-Systems geprüft. Im Rahmen dessen wurden die Festkörperlasermaterialien Yb:YAG [1], kerndotierte Nd:YAG-Keramik [2] und herkömmliches Nd:YAG vorgestellt und hinsichtlich ihrer Eignung für dieses MOPA-System untersucht. Nachdem die Entscheidung für Nd:YAG als laseraktives Material gefallen war, konnte darauf aufbauend die Konzeptionierung des Lasersystems auf der Basis von Verstärkungsrechnungen vorgenommen werden. Die entwickelte Verstärkungsrechnung trägt den Tatbeständen von realen Systemen Rechnung, indem radiusabhängige Intensitäten und eine radiale, nicht homogene Inversionsdichte berücksichtigt werden. Die Frequenzstabilisierung des gepulsten Oszillators (Frequenzstabilität von 1 MHz) wurde mittels des Pound-Drever-Hall-Verfahrens vorgenommen. Mit der Heterodynmethode wird die Frequenzstabilität des Oszillators gemessen. Nach Untersuchungen über verschiedene Konfigurationen für lineare und ringförmige Oszillatoren, wurde ein Ringoszillator mit zwei Laserköpfen aufgebaut, in welchen von außen mit einem Laser fester Frequenz eingestrahlt wird. Dieser emittiert bei einer Wiederholrate von 400 Hz eine Pulsenergie von Eout = 21 mJ bei nahezu beugungsbegrenzter Strahlqualität (M2 < 1,2). Die Verstärkung dieser Laserpulse erfolgte zunächst durch eine Vorverstärkerstufe und anschließend durch zwei doppelbrechungskompensierte Hauptverstärker im Doppeldurchgang. Eine gute Strahlqualität (M2 = 1,75) konnte unter anderem erzielt werden, indem der Doppeldurchgang durch die Hauptverstärker mit einem phasenkonjugierenden Spiegel (SF6), auf der Basis der stimulierten Brillouin Streuung, realisiert wurde. Der entwickelte Laser emittiert Pulse mit einer Länge von 25 ns und einer Energie von 250 mJ. Insgesamt wurde ein bisher einmaliges Lasersystem entwickelt. In der Literatur sind die erreichte Frequenzstabilität, Strahlqualität und Leistung in dieser Kombination bisher nicht dokumentiert. In der Zukunft soll durch den Einsatz von kerndotierten, keramischen Lasermaterialien, höheren Pumpleistungen der Hauptverstärker und phasenkonjugierenden Spiegeln aus Quarz die Pulsenergie des Systems weiter erhöht werden. [1] M. Ostermeyer, A. Straesser, “Theoretical investigation of Yb:YAG as laser material for nanosecond pulse emission with large energies in the joule range”, Optics Communications, Vol. 274, pp. 422-428 (2007) [2] A. Sträßer and M. Ostermeyer, “Improving the brightness of side pumped power amplifiers by using core doped ceramic rods”, Optics Express, Vol. 14, pp. 6687- 6693 (2006) / Vapour in the stratosphere and troposphere is one of the most important atmospheric greenhouse gases. Apart from its importance for the climate it has a great influence on the formation of polar stratospheric clouds as well as the atmospheric chemistry. A German research group is currently developing the world’s first powerful, mobile, screening vapour-DIAL, which can measure the atmospheric vapour three-dimensionally and in high resolution. Vapour concentrations in the atmosphere can be measured in high temporal and local resolution with this vapour-DIAL. The DIAL is based on a titan-saphire-laser or an alternative OPO-laser (Optical Parametric Oscillator). The seeding-laser, which is needed in order to seed those lasers, was developed in the course of this work by the research group for nonlinear optics in the institute for physics at the University of Potsdam. A highly-resolutive, mobile DIAL needs a seeding-laser with high pulse energy, excellent beam quality and high efficiency. In order to realise this, a frequency stabilised MOPA-System (Master Oscillator Power Amplifier) was developed, which based on birefringence-compensated, transversally diode-pumped laser rods. During the research process several ways to realise the MOPA-System were investigated. In this process the solid laser materials Yb:YAG [1], core-doped Nd:YAG-Ceramics [2] und conventional Nd:YAG were introduced and their suitability for the MOPA-System was investigated. After the choice for Nd:YAG as laser-active material was made, the concept of the laser-system could be developed based on amplification-calculations. The amplification-calculation meets the requirements of real systems, because intensities depending on diameter and a radial, non-homogeneous inversion density are being taken into consideration. The frequency of the pulsed oscillator (frequency stabilisation of 1 MHz) was stabilised by means of the Pound-Drever-Hall-Method. The frequency stability of the oscillator is measured using the Heterodyn-Method. After the investigation of different configurations for linear and circular oscillators a circular oscillator with two laser heads was set up, which is injection-seeded by a second laser with a stable frequency. At a repetition rate of 400 Hz the circular oscillator emits a pulse energy of Eout = 21 mJ with almost diffraction-limited beam quality (M2 < 1.2). These laser pulses were first amplified by a pre-amplifier and afterwards by two birefringence compensated main-amplifier in doublepass. Among other factors, an excellent beam quality (M2 = 1.75) could be reached by the doublepass through the main amplifier realised with a phase conjugating mirror (SF6) based on stimulated Brillouin-scattering. The developed laser emits pulses that are of 25 ns length and have an energy of 250 mJ. A currently unique laser system was developed. In the research findings there are no previous documents of the combination of the reached stability of frequency, beam quality and power in one system. In the future the pulse energy of the system is to be further increased through the use of core-doped, ceramic laser material, a higher pump power of the main amplifiers and phase-conjugating mirrors made of quartz. [1] M. Ostermeyer, A. Straesser, “Theoretical investigation of Yb:YAG as laser material for nanosecond pulse emission with large energies in the joule range”, Optics Communications, Vol. 274, pp. 422-428 (2007) [2] A. Sträßer and M. Ostermeyer, “Improving the brightness of side pumped power amplifiers by using core doped ceramic rods”, Optics Express, Vol. 14, pp. 6687- 6693 (2006)

Master Oscillator Power Amplifiers (MOPA) are laser systems that utilize a seed and pump amplification system to boost the output power of high-quality lower power seeding signals. MOPAs can generate high gain while avoiding many of the nonlinearities that negatively affect resonance-based lasers that are known to feature higher internal intensities. Additionally, MOPAs provide an easy alternative to the construction of novel laser technologies for higher output power as they can be easily combined with existing laser sources to amplify their output power. This thesis outlines the design of an ytterbium-doped fiber laser (YDFL), featuring a MOPA architecture. The YDFL is constructed to amplify a continuous wave single mode signal, at 1064nm, from 366mW to 16.4W while maintaining high spectral purity and beam quality. This laser is being developed with the intention to seed a subsequent MOPA YDFL for amplification to 1.5kW, for use in following thermal blooming experiments. As a result, the laser being developed in this work must have high spectral purity, centered near 1064nm, and a narrow linewidth, less than 0.25nm. Methods for limiting instabilities within the MOPA amplification stages are developed and the final seed laser emission quality is demonstrated in this work.

The thulium fiber laser has gained interest due to its long emission wavelength, large bandwidth (~1.8 – 2.1 µm), high efficiencies (~60 %), and high output power levels both in cw as well as pulsed regimes. Applications like remote sensing, machining, medical tissue ablation, and mid-infrared generation benefit from high peak power thulium laser sources. Pulsed thulium fiber laser systems are advancing rapidly towards higher peak power levels and are becoming the preferred sources for these applications. This dissertation work describes the development of novel nanosecond pulsed thulium fiber laser systems with record high peak power levels targeting mid-infrared generation. The peak power scaling in thulium fiber lasers requires new fiber designs with larger mode field area (MFA) than commercially available step index large mode area (SI-LMA) fibers. Two different prototypes of thulium doped photonic crystal fibers (PCF) were investigated for high peak power generation. The first prototype is a flexible-PCF with MFA twice as large as SILMA fiber and the second prototype is a PCF-rod with six times larger MFA. A robust single stage master oscillator power amplifier (MOPA) source based on flexible-PCF was developed. This source provided narrow linewidth, tunable wavelength, variable pulse duration, high peak power, and high energy nanosecond pulses. The PCF-rod was implemented as a second stage power amplifier. This system generated a record level of ~1 MW peak power output with 6.4 ns pulse-duration at 1 kHz repetition rate. This thulium doped PCF based MOPA system is a state of the art laser source providing high quality nanosecond pulses. iv The single stage MOPA system was successfully implemented to pump a zinc germanium phosphide (ZGP) crystal in an optical parametric oscillator (OPO) cavity to generate 3 - 5 µm wavelengths. The MOPA source was also used to demonstrate backside machining in silicon wafer. The PCF based laser system demonstrated an order of magnitude increase in the peak power achievable in nanosecond thulium doped fiber laser systems, and further scaling appears possible. The increase in peak power will enable additional capabilities for mid-infrared generation and associated applications.

Cette thèse de doctorat a été réalisée au sein du III-VLab, en partenariat avec l’Institut d’Electronique du Sud (IES). L’objectif de ce travail de thèse vise d’une part à l’optimisation des performances des diodes laser DFB émettant à 780 nm et le développement d’une source plus compacte (MOPA) à 780nm, intégrant de façon monolithique l’oscillateur maître (laser à rétro-action répartie ou DFB) et l’amplificateur de puissance, et d’autre part, à appréhender les phénomènes de bruit, permettant d’évaluer la qualité technologique des lasers. Les développements autour de la longueur d’onde 780 nm, se sont organisés en plusieurs thématiques : les lasers Fabry-Perot et DFB, les amplificateurs (SOA), les MOPA et l’étude du bruit des lasers. Nous avons étudié des structures de différentes épaisseurs de puits quantiques (160Å, 135 Å et 145 Å). La comparaison des performances globales des différentes structures de lasers larges, loin d’être évidente, nous a permis de choisir celle intégrant un puits quantique de 160 Å, pour la réalisation des lasers Fabry-Perot à ruban étroit (3µm à 4µm). Nous avons obtenu sur des lasers larges, de 3 mm de long, bruts de clivage, une puissance d’environ 5 watts par face pour un courant d’injection continu autour de 10 A. Les simulations et caractérisations électro-optiques menées sur des lasers ridge Fabry-Perot, ont servi à affiner le dessin des DFB à 780 nm, par rapport aux briques de base existantes du III-V Lab, et à proposer des structures à cavités optiques larges et super-large (LOC et SLOC) optimisées, en termes de puissance, qualités de faisceau et spectrale.Les mesures de bruits, appuyées d’un modèle de bruit électrique, ont permis d’extraire une valeur du paramètre de Hooge de 2,1.10^-3 pour les lasers ridge, en accord avec la littérature, et qui correspond à une bonne qualité de matériau et technologique des lasers. Différents types d’amplificateurs optiques évasés ont été dessinés, réalisés et caractérisés. Les caractérisations des diverses géométries de SOA, ont donné dans l’ensemble, des valeurs de gain comprises entre 19dB et 25dB. Nous avons obtenu respectivement pour les structures d’amplificateurs à guidages entièrement par l’indice (GI), entièrement par le gain (GG) et mixte (GM), des puissances de 500mW, 750mW et 1W. L’ensemble des résultats obtenus avec ces structures sont prometteurs pour l’intégration monolithique avec le DFB. En ce qui concerne le MOPA, trois approches ont été étudiées: MOPA droit, DFB et amplificateur tiltés de 7° (par rapport à la normale aux faces clivées), et la plus prometteuse mais plus complexe, intégrant le DFB droit et l’amplificateur tilté de 7°, avec une section courbe entre les deux. La prise en compte de l’ensemble des résultats lasers Fabry-Perot, DFB et des résultats d’amplificateurs, nous ont permis de proposer des dessins MOPA originaux. Le dessin du masque réalisé, intègre toutes ces configurations de MOPA, et en plus, des SOA et DFB, qui seront utilisés comme témoins de test lors des caractérisations. / This thesis has been realized in III-VLab in collaboration with the South Electronic Institute in Montpellier. The aim of this work focuses in one hand, on the performance improvement of DFB's diode lasers emitting at 780 nm, and the advanced design of a compact semiconductor laser diode (Master Oscillator Power Amplifier), integrating monolithically the master oscillator (DFB for Distributed Feedback laser); in the other hand, using the noise phenomenon’s studies as a tool, for validating of our laser technologies. The Developments round the 780 nm wavelength, have been divided into different thematic: Fabry-Perot and DFB, Semiconductor Optical Amplifiers (SOA), MOPA, and the lasers noise’s study. We have studied structures with different quantum well thickness (160Å, 135 Å and 145 Å). The comparison of global performances of broad area lasers from these different structures, far to being obvious, allowed us to choose the one that integrates the 160-Å-thickness of quantum-well, for the realization of ridge Fabry-Perot lasers of 3 to 4-µm-of width. We obtained with broad area lasers, as cleaved, with 3-mm cavity lengths, an output power around 5 watts per facet, in continuous bias current around 10 AModellings and electro-optics characterizations performed on ridge Fabry-Perot lasers, allowed to refine DFB lasers at 780 nm, in comparison of the existing building blocks in the lab; we proposed new optimized structures with Large and Super Large Optical Cavities(LOC and SLOC), in terms of optical output power, beam and spectral qualities.The noise measurements with electrical noise modelling, allowed us to extract a value of Hooge’s parameter of 2,1.10^-3, quite in agreement with literature for such lasers, which corresponds to a good material quality and laser technology.Different types of flared SOA have been designed, realized and characterized. The characterizations of various SOA geometries, have given in general, values of gain between 19 dB to 25 dB. With SOAs of types: fully Index Guiding (IG), fully Gain Guiding (GG) and Mixed Guiding (MG), we have respectively obtained 500 mW, 750 mW and 1 W. All the results obtained with these structures are promising for monolithic integration with DFB. Regarding the MOPA, three approaches have been studied. The straight MOPA, the approach of SOA and DFB with 7° tilt(relative to the normal to cleaved facets), and the most complex, but promising approach, integrating the SOA with 7° tilt, and straight DFB, with a bend section between them. By taking into account all the results obtained on Fabry-Perot lasers, DFB, and SOA results, we were able to propose original MOPA designs. The layout drawing has been realized, all the MOPA configurations and additional, DFB and SOA devices, have been included on it. They will be used as test structures for characterizations.

Ce mémoire présente des travaux portant sur le développement de trois sources lasers pompées longitudinalement par diodes laser et déclenchées activement par modulateur électro-optique pour deux applications spécifiques : la LIBS et le marquage par laser. Ces travaux ont été réalisés en collaboration avec deux sociétés : Bertin Technologies et SDAE.Le premier chapitre de ce manuscrit présente le développement d’une nouvelle source laser compacte, réalisée pour la société Bertin Technologies dans le cadre d’un projet de tri de matériaux plastiques par analyse spectroscopique de plasma induit par laser (LIBS). Cette technique d’analyse ponctuelle ainsi que le contexte spécifique du projet sont détaillés dans la première partie de ce chapitre. Ensuite, les différentes étapes de recherche et de développement qui ont permis d’aboutir à cette nouvelle source laser innovante, compacte et de hautes performances seront décrites en détail. Le second chapitre présente le développement de deux sources lasers pour le marquage industriel réalisées en partenariat avec la société SDAE. Après avoir présenté les principes et techniques généraux de l’application marquage ainsi que les contraintes spécifiques au projet, les deux sources lasers développées seront décrites. Des tests de LIBS et de marquage ont été réalisés grâce aux lasers développés / This thesis deals with the development of three lasers end-pumped by laser diode and actively Q-Switched by electro-optic Pockels cells for two specific applications: Laser Induced Breakdown Spectroscopy (LIBS) and marking. This work was done in collaboration with two companies: Bertin Technologies and SDAE.In the first part, we present the development of a new compact laser source, made for Bertin Technologies as part of sorting of plastics waste by LIBS. This analysis technique and the specific context of the project will be detailed in the first part of this chapter. Then, the different steps of research and development which have resulted in this innovative, compact and high performance new laser are described in detail. The second part is devoted to the development of lasers for industrial marking accomplished in partnership with SDAE. More precisely, the general principles and techniques of laser marking are described as well as the specific constraints of this project. LIBS and laser marking tests will be done with these lasers