Thesis (MSc)--University of Stellenbosch, 1989. / AFRIKAANSE OPSOMMING: Senosoiese sedimente langs die suidooskus van die Kaapprovinsie is periodiek deur verskeie outeurs vir meer as 'n eeu bestudeer. In hierdie aanbieding word die Iiteratuur saamgevat en vele dubbelsinnige stratigrafiese onderverdelings en definisies opgeklaar. Die Senosoiese afsettings kan volgens oorsprong geklassifiseer word as marien, eolies en fluviaal. Die mariene afsettings, synde strand-, nabystrand-, estuarien of lagunale afsettings geassosieerd met transgressiewe/ regressiewe kusIyne, word nou op grond van kenmerkende litologiese, paleontologiese sowel as ouderdomsverskille onderverdeel in die Paleogeen Bathurst, Neogeen Alexandria en Kwaternere Salnova Foraasies. Die Laat-Plioseen tot Vroeg-Pleistoseen Nanaga Formasie, Middel- tot Laat- Pleistoseen Nahoon Formasie en die Holoseen Schel• Hoek Formasie vorm die kus-eoliese afsettings. AI die mariene en marienverwante (eoliese} formasies, gekenmerk deur kalkige klastiese afsettings, is saamgegroepeer in 'n nuutgedefinieerde Algoa Groep. Fluviale afsettings word onderverdeel in die Martindale, Kinkelbos, Bluewater Bay, Kudus Kloof en Sunland Formasies. Die onderskeie afsettings word gekorreleer met verskillende seevlakstande deur geologiese tye. Die vroegste Senosoiese transgressiewe/regressiewe siklus het in die Vroeg-Paleoseen begin en die hoogste aangetekende elevasie vir die era bereik. Die Bathurst Formasie is waarskynlik gedurende hierdie regressie afgeset. 'n Tweed~ kleiner transgressie/ regressiesiklus het plaasgevind gedurende die Laat-Eoseen tot Vroeg-Oligoseen. Sover tans bekend, kan geen afsetting in die dagsoomgebied van die Algoa Groep definitief met hierdie siklus in verband gebring word nie. Die volgende siklus, wat 'n transgressiewe maksimum van c. 250 m bereik het, het begin in die Middel-Mioseen en verstryk in die Vroee Plioseen. Mariene planasie van die kusplatform het gedurende die transgressie plaasgevind terwyl die Alexandria Formasie wat tans bo 120 m geleë is, gedurende die regressie afgeset is. Die Vroeg-Plioseen transgressie het waarskynlik 'n maksimum huidige hoogte van c. 120 m bereik, waartydens o.a. die 120 m branderstoep en "Humansdorpterras" gekerf is. Die Alexandria Formasie tans geleë tussen 60 en 120 m, is afgeset gedurende die Laat-Plioseen regressie. Hierdie regressie het verskeie relatief lang stilstande, wat waarskynlik die 106-m, 90- tot 100-m en 84-m branderstoepe verklaar, ondervind. Selfs die 60-m en 52-m kuslyne kon tydens hierdie regressie gevorm het. Voorlopige paleontologiese getuienis dui egter daarop dat die 60-m kuslyn 'n transgressiewe maksimum van 'n daaropvolgende siklus verteenwoordig, gevolg deur 'n regressie met minstens een beduidende stilstand by 52 m. Die Alexandria Formasie geleë tussen c. 60 en 30 m, is waarskynlik gedurende hierdie regressie gedeponeer, waartydens ook die Bluewater Bay, Kinkelbos en Kudus Kloof Formasies afgeset is. Gedurende die Kwaternêre transgressie/regressiesiklusse, waarvan minstens vier aangedui word, is die Salnova Formasie (afwesig bo 30 m) afgeset. Die Nahoon Formasie, wat ook op groot skaal op die kontinentale bank ontwikkel is, is gedeponeer gedurende die laaste twee Pleistoseen glasiale toe seevlakke tot benede -100 m gedaal het. Die Schelm Hoek Formasie wat tans nog afgeset word, het ontstaan uit die transgressiewe maksimum van die Flandriese transgressie aan die begin van die Holoseen. / ENGLISH ABSTRACT: Cenozoic sediments along the south-east coast of the Cape Province have been studied intermittently for more than a century by various authors. In this presentation the literature is reviewed and many ambiguous stratigraphic subdivisions and definitions are clarified. The Cenozoic deposits can be classified, according to origin, as marine, aeolian and fluvial. The marine deposits, being lagoonal deposits either beach, nearshore, estuarine or associated with transgressive/regressive shorelines, are now subdivided on the grounds of distinct lithological, palaeontological as well as age differences into the Palaeogene Bathurst, Neogene Alexandria and Quaternary Salnova Formations. The Late Pliocene to Early Pleistocene Nanaga Formation, the Hiddle to Late Pleistocene Nahoon Formation and the Holocene Schelm Hoek Formation constitute the coastal and marine-related aeolian deposits. All the marine (aeolian) formations, which are characterised by calcareous clastics, have been grouped together in a newly defined Algoa Group. Fluvial deposits are subdivided into the Martindale, Kinkelbos, Bluewater Bay, Kudus Kloof and Sunland Formations. The various deposits are correlated with different stands of sea-level through geological time. The earliest Cenozoic transgression/regression cycle started in the Early Palaeocene and reached the highest recorded altitude for the era. The Bathurst Formation was probably deposited during this regression. A second lesser transgression/regression cycle occurred in the Late Eocene to Early Oligocene. As far as is presently known, no deposit in the outcrop area of the Algoa Group can be definitely related to this cycle. The next cycle, which reached a transgressive maximum of c. 250 m, started in the Middle Miocene and terminated in the Early Pliocene. Marine planation of the coastal platform took place during the transgression, whilst the Alexandria Formation presently situated above 120 m, was deposited during the regression. The Early Pliocene transgression is considered to have reached a maximum present-day elevation of c. 120 m, during which the 120 m marine bench and "Humansdorp Terrace", amongst others, were carved. The Alexandria Formation presently situated between 60 and 120 m, was deposited during the Late Pliocene regression, which experienced several relatively long stillstands which probably account for the 106 m, 90 t.o 100 m and 8.4 m benches. Even the 60 m- and 52 m-shorelines could have been formed during this regression. Preliminary palaeontological evidence, however, suggests that the 60 m shoreline represents a transgressive maximum of a subsequent cycle followed by a regression with at least one significant stillstand at 52 m. The Alexandria Formation situated between c. 60 and 30 m, was probably deposited during this regression, which also saw the deposition of the Bluewater Bay, Kinkelbos and Kudus Kloof Formations. During the Quaternary transgression/regression cycles, of which at least four are indicated, the Salnova Formation (absent above 30 m) was deposited. The Nahoon Formation, which is also extensively developed on the continental shelf, was deposited during the last two Pleistocene glacials, when sea-levels receded to less than -100 m. The Schelm Hoek Formation, which is still being deposited, originated from the transgressive maximum of the Flandrian transgression at the start of the Holocene.

Thesis (MSc)--University of Stellenbosch, 2006. / ENGLISH ABSTRACT: The Barremian to Albian siliciclastic deep-water deposits of the central Bredasdorp Basin were investigated primarily in terms of their stratigraphic evolution, depositional characteristics and facies distribution. Cores from the deep-water deposits reveal that the facies successions are composed of massive, ripple cross- to parallel-laminated sandstones, conglomerate, massive claystone, alternating laminated to interbedded sandstone/siltstone and claystone, laminated and clay-rich siltstone. These facies are grouped into channel-fill, sheet-lobe, overbank and basin plain deposits, by inference. The application of sequence stratigraphy, based on gamma ray and resistivity log patterns, reveals that all 3rd-order depositional sequences comprise 4thorder cycles. The latter are subdivided into three components (lowstand, transgressive and highstand systems tracts), based on vertical facies changes and internal stratigraphic key surfaces. Taking the 13Amfs as the stratigraphic datum for each well, correlation was possible on a regional basis. Lowstand deposits, comprising thick amalgamated massive sandstones, were interpreted to represent channelfills. Their vertical and horizontal stacking forms channel-fill complexes above Type 1 unconformities. Adjacent thin-bedded intervals, comprising parallel- to ripple cross-laminated sandstones, were interpreted as levee/overbank deposits, whereas clay-rich intervals were interpreted to represent basin plain deposits of hemipelagic origin. Facies associations and their distribution have revealed that channel-fills are associated with overflow deposits and sheet sand units. These deposits, as well as downdip sheet sands associated with small channel-fills within the 9A, 11A/12A, 13A Sequences and the 14A Sequence were interpreted to have been deposited in a middle fan to upper fan setting. A similar association occurs in the 10A Sequence, except that thick conglomerate units are present at the base of proximal channel-fills. This led to interpret the 10A Sequence as being deposited in a base-of-slope to upper fan setting. The thickness of each sequence, as revealed by isochore maps, shows sinuous axial flow path which corresponds to channel-fill conduit. The continuous decrease of this sinuosity upward in the succession was interpreted as being related to basin floor control along the main sand fairways. Successive flows result in erosion-fill-spill processes, which locally favour connectivity of reservoirs over large areas. Recognition of higher-order sequences and key stratigraphic surfaces helps to understand internal stratigraphic relationships and reveals a complex and dynamic depositional history for 3rd-order sequences. However, sparse well control and uneven distribution of boreholes, as well as lack of seismic and other data, limited the models derived for this study. / AFRIKAANSE OPSOMMING: Die Barremiaanse tot Albiaanse silisiklastiese diepwater afsettings van die sentrale Bredasdorp Kom is hoofsaaklik in terme van stratigrafiese evolusie, afsettingskarakteristieke en fasies distribusie ondersoek. Kerne van die diepwater afsettings toon dat die fasies opeenvolgings uit massiewe, riffelkruis- tot parallel-gelamineerde sandstene, konglomerate, massiewe kleistene, afwisselende gelamineerde tot intergelaagde sandstene/slikstene en kleistene, sowel as gelamineerde en klei-ryke slikstene bestaan. Hierdie fasies word onderverdeel in kanaalopvulsel, plaatlob, oewerwal en komvlakte afsettings. Die toepassing van opeenvolgingsstratigrafie gebaseer op gammastraal en resistiwiteit log patrone toon dat alle 3de-orde afsettingsopeenvolgings uit 4deorde siklusse bestaan. Laasgenoemde word onderverdeel in drie komponente (lae-stand, transgressie en hoë-stand sisteemgedeeltes), gebaseer op vertikale fasies veranderinge en interne stratigrafiese sleutel vlakke. Korrelasie op ‘n regionale basis is moontlik gemaak deur die 13Amfs as die stratigrafiese verwysing vir elke boorgat te neem. Lae-stand afsettings, wat uit dik saamgevoegde massiewe sandstene bestaan, word geïnterpreteer as kanaalopvulsels. Die vertikale en horisontale stapeling van die sandstene vorm kanaalopvulsel komplekse bo Tipe 1 diskordansies. Naasliggende dungelaagde intervalle, wat uit parallel- tot kruisgelaagde sandstene bestaan, word geïnterpreteer as oewerwal afsettings, terwyl klei-ryke intervalle geïnterpreteer word as verteenwoordigend van komvlakte afsettings van hemipelagiese oorsprong. Fasies assosiasies en hul verspreiding toon dat kanaalvul geassosieër word met oorvloei afsettings en plaatsand eenhede. Hierdie afsettings, sowel as distale plaatsande geassosieër met klein kanaalopvulsels binne die 9A, 11A/12A, 13A en die 14A Opeenvolgings, word geïnterpreteer as afgeset in ‘n middelwaaier tot bo-waaier omgewing. ‘n Soortgelyke assosiasie bestaan in die 10A Opeenvolging, behalwe dat dik konglomeraat eenhede teenwoordig is by die basis van proksimale kanaalopvullings. Dit het gelei tot die interpretasie van die 10A Opeenvolging as afgeset in ‘n basis-van-helling tot bo-waaier omgewing. Die dikte van elke opeenvolging, soos verkry vanaf isochoor kaarte, toon ‘n kronkelende aksiale vloeipad wat ooreenkom met ‘n kanaalopvulling toevoerkanaal. Die aaneenlopende afname van hierdie kronkeling na bo in die opeenvolging word geïnterpreteer as verwant aan komvloer-beheer langs die hoof sand roetes. Opeenvolgende vloeie veroorsaak erosie-opvul-oorspoel prosesse, wat lokaal die konnektiwiteit van reservoirs oor groot areas bevoordeel. Herkenning van hoër-orde opeenvolgings en sleutel stratigrafiese vlakke dra by tot ‘n goeie begrip van die interne stratigrafiese verhoudings en ontbloot ‘n komplekse en dinamiese afsettingsgeskiedenis vir 3de-orde opeenvolgings. Beperkte boorgatbeheer en ‘n tekort aan seismiese en ander data het egter ‘n beperkende rol gespeel in die daarstel van modelle vir hierdie studie.

The spatio-temporal patterns in concentrations of selected metals within the sediment (Cd, Co, Cu, Fe, Pb, Ni and Zn) and water (Cd and Pb) of three permanently open estuaries (Kariega, Kowie, Great Fish) and six temporary open-closed estuaries (Mpekweni, East Kleinemonde, West Kleinemonde, Riet, Kasouga, Boknes) were investigated. The concentrations of metals were influenced by size composition and total organic content of the sediments. Enrichment factors (EFs), using Fe as a reference element, and baseline linear regression models for metals vs. Fe were calculated to assess the extent of metal enrichment in the sediments. The mean concentrations of metals in the sediments(mg·kg⁻¹) showed ranges of 0.28 – 2.31 for Cd, 1.26 – 6.24 Co, 0.69 – 6.93 for Cu, 2119 – 14912 for Fe, 2.29 –14.01 for Ni, 4.81 – 22.20 for Pb and 5.77 – 21.75 for Zn. Mean normalized enrichment factors ranged between 0.75 – 6.19 for Cd, 0.53 – 2.71 for Co, 0.22 – 0.84 for Cu, 0.30 – 1.87 for Ni, 0.99 – 3.17 for Pb and 0.14 – 0.98 for Zn. All nine estuaries had average enrichment factors of greater than 1 for Cd. In general there was no enrichment of Cu and Zn in the sediments of any of the estuaries included in this study (EFs < 1). The Kariega, East Kleinemonde, West Kleinemonde, Riet and Great Fish Estuaries showed some degree of enrichment for Co (1 < EF < 4), Ni (1 < EF < 2) and Pb (1 < EF < 4), while the Mpekweni, Kasouga, Boknes and Kowie Estuaries were unenriched with these metals (EF < 1). Enrichment factors for Cd, Co and Pb typically followed the development gradient along the estuaries, suggesting anthropogenic enrichment. The concentrations of Cd and Pb in the water of the nine estuaries were also determined. The average concentrations of Cd and Pb in the water (μg·ℓ⁻¹) ranged between 0.05 – 3.32 and 0.75 – 34.13 respectively. On average the concentrations of Cd and Pb in the water of all the estuaries were below the South African recommended water quality guidelines for coastal marine waters. Variations in metal concentrations associated with changes in hydrology (wet vs. dry season) were determined in the water and sediment of the Kariega, East Kleinemonde and Riet Estuaries. Cobalt, Pb and Ni enrichment in the Kariega Estuary sediment was significantly higher during the dry season, and the mean concentrations of Pb and Cd in the water column were 19-fold and 66-fold higher in the dry season. The elevated concentration of metals during the dry season could be related to accumulation of diffuse pollution from human activities within the catchment area. Conversely, inflow of fresh water into the estuary had the net effect of reducing the concentration and enrichment of these metals within the Kariega Estuary due to scouring and outflow of estuarine water and sediment into the marine environment. The temporal variations in metal concentrations and enrichment factors were less pronounced in the temporary open-closed estuaries than the permanently open Kariega Estuary. The observed trend can probably be related to the low anthropogenic impact within the catchment areas of these systems, and the relatively smaller size of the catchments. Significant spatial variations existed in metal enrichment in the sediment of both the East Kleinemonde and Riet estuaries, with the highest degrees of enrichment occurring in the sediments from the marine environment and lower reaches.