<p>Regarding the use of material, modern lightweight car bodies are becoming more and more complex than previous constructions. The materials nowadays are used for a more specific field of application and more high strength steels are used and also other materials like aluminium, stainless steel, reinforced polymers are used more frequent. The joining of these materials often requires new or modified joining processes. The aim with this thesis is concerned with the development of simulation models of the joining process as well as mechanical properties of self piercing riveted (SPR) joints and pierce nut joints. In both of these joining methods problems occur when introducing more high strength steel sheets. For SPR, fractures occur in the rivet, and for pierce nut the thread will be damaged.</p><p>Since both the SPR process and the pierce nut process expose the material for plastic deformation up to 150%, correct material properties for very large strain and a simulation program that could handle this was required. With the commercial finite element program Deform2D an axi-symmetric model has been built for the SPR process and the pierce nut process. Because of the computational time, 3D simulations were only used where it was necessary. The developed 3D models use the commercial finite element program ABAQUS-Explicit. All simulation models have been verified with satisfactory agreement to experimental results.</p><p>For SPR, an axi-symmetric simulation model was used for evaluating and optimising the setting process in the stainless steel sheets EN1.4301, HyTens 800 and HyTens 1200. Subsequently, 3D models were used for predicting the mechanical properties of new SPR joints that have showed reduced risk for rivet cracking. In pierce nut simulations, nuts with hardness 8 and 10 have been set in the high strength steel sheet DP600. An axi-symmetric simulation model was used for centred nut setting and two different simulation models in 3D were used to evaluate eccentric nut setting and torque resistance.</p><p>This work resulted in more knowledge about the fracture risk in the rivet and how to reduce it. The strain and stress, which was used as fracture indicators, were reduced to the half with modifications of the rivet and the die geometry. Mechanical property simulations in shear and peel load resulted in satisfactory results for new SPR joints that have showed reduced fracture risk during rivet setting. New die and rivet designs can be developed effectively by combining the process and mechanical property simulations.</p><p>For a pierce nut joint in high strength steel sheets (1.5mm DP600), the simulations show that the cutting of the sheet in combination with eccentric setting over the die causes the thread damage. The thread damage can be avoided by changing the dimension of the nut or by increasing the strength of the nut material. The simulation models can also be used to develop new nut and die geometries for future applications.</p>

<p>The aim of the present work was to clarify the mechanisms of hydrogen removal during vacuum degassing. The main reason for this was because the primary source of hydrogen pick-up in steel-making is the moisture in the furnace atmosphere and the raw material charged into the ladle furnace. Previous studies showed that the presence of hydroxyl ions in the ladle slag results in hydrogen transfer from the slag back into the steel bath. The main focus of this thesis was therefore to gain deeper knowledge of the ladle slag and its properties. For this purpose a number of slag compositions were examined in order to clarify whether these slags were single liquids at 1858 K. 14 out of 27 compositions in the Al₂O₃ CaO MgO SiO₂system was completely melted. These results were in disagreement with the existing phase diagrams.</p><p>Water solubility measurements were carried out by employing a thermo gravimetric technique. The temperature was found to have negligible effect on the water solubilities. The experimental results showed that the water capacity values varied between 1x10³and 2x10³ in the majority of the composition range. However, for compositions close to CaO saturation the water capacity value could reach higher than 3x10³. The experimental determined water capacity was further used to develop a water capacity model for the quaternary slag system Al₂O₃CaO MgO SiO₂. The model was constructed by considering the affects of the binary interactions between the cations in the slag on the capacity of capturing hydroxyl ions. The model calculations agreed well with the experimental results as well as with the literature data.</p><p>An attempt was made to develop a preliminary process model for dehydrogenation by using the results from CFD calculation. For this purpose industrial sampling was made during vacuum treatment. The hydrogen concentrations decreases fast in the initial stages of the degassing, but is slowed down in the final stage. The model calculations fit the initial stage of the dehydrogenation process well. In the final stage of the process the predicted values are somewhat lower than the plant data. The results from the model prediction showed that a dynamic process model could be satisfactorily constructed using the results from CFD calculation.</p><p>The present work aimed at determining how big impact hydroxyl ions in the slag have on the final hydrogen concentration in the liquid steel. It was found that the effect is of less importance regarding the final concentration of the metal after the degassing treatment.</p>

<p>Lead chalcogenides and tin chalcogenides and their alloys are IV−VI family semiconductors with unique material properties compared with similar semiconductors. For instance, Pb<i>Y </i>(<i>Y </i>= S, Se, and Te) are narrow-gap semiconductors with anomalous negative pressure coefficient and positive temperature coefficient. It is known that this behavior is related with the symmetry of wave functions in first Brillouin zone L-point, which moves the edges of valence band maximum and conduction band minimum towards each other with pressure increasing. SnTe has opposite behavior since its wavefunction symmetry is different from Pb<i>Y</i>. Therefore, by alloying PbTe and SnTe one can change and control the band gap energy and its pressure or temperature dependence. These chalcogenides alloys have therefore a huge potential in industrial low-wavelength applications and have been attracted the attention of researchers.</p><p>This thesis comprises theoretical studies of Pb<i>Y</i>, Sn<i>Y</i> (<i>Y </i>= S, Se and Te) and the Pb₁−<i>x</i>Sn<i>x</i>Te alloys (<i>x</i>= 0.00, 0.25, 0.50, 0.75, and 1.00) by means of a first-principles calculation, using the full-potential linearized augmented plane waves method and the local density approximation.</p><p>The optical properties of Pb₁−<i>x</i>Sn<i>x</i>Te alloys are investigated in terms of the dielectric function <i>ε</i>(<i>ω</i>) = ε₁(<i>ω</i>) + <i>iε</i><i>2</i><i>(ω</i>). We find strong optical response in the 0.5–2.0 eV region arising from optical absorption around the LW-line of the Brillouin zone. The calculated linear optical response functions agree well with measured spectra from ellipsometry spectroscopy performed by the Laboratory of Applied Optics, Linköping University. The calculations of the electronic band-edges of the binary PbY and SnY compounds, show similar electronic structure and density-of-states, but there are differences of the symmetry of the band-edge states at and near the Brillouin zone L-point. PbY have a band gap of E<i>g</i><i> </i>0.15−0.30 eV. However, SnY are zero-gap semiconductors<i> E</i><i>g</i> = 0 if the spin-orbit interaction is excluded. The reason for this is that the lowest conduction band and the uppermost valence band cross along the LW line. When including in Pb<i>Y</i>. Although Pb<i>Y</i> and Sn<i>Y </i>have different band-edge physics at their respective equilibrium lattice constants, the change of the band-edges with respect to cell volume is qualitatively the same for all six chalcogenides. The calculations show that the symmetry of band edge at the L-point changes when lattice constant varies and this change affects the pressure coefficient. the spin-orbit interaction a gap <i>E</i><i>g</i><i> </i>≈ 0.2 eV is created, and hence this gap is induced by the spin-orbit interaction. At the L-point, the conduction-band state is a symmetric state and the valence-band state is antisymmetric thereby the L-point pressure coefficient ⁺₄L−₄Lp<i>E</i><i>g</i>∂∂/)L( in SnY is a positive quantity. In contrast to Sn<i>Y</i>, the Pb<i>Y</i> compounds have a band gap both when spin-orbit coupling is excluded and included; this gap is at the L-point, and the conduction-band state has and the valence-band state has symmetry, and thereby this band edge yields the characteristic negative pressure coefficient ⁺₄L−₄Lp<i>E</i><i>g</i>∂∂/)L(</p>

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No description available.

QC 20101216

The main objective of this industrially important work was to gain an increasing understanding of the properties of materials such as CMSX-4 nickel base super alloy, mould powder used in continuous casting of steel and coke used in blast furnace, with special reference to the thermal diffusivities. The measurements were carried out in a wide temperature range, solid, liquid, glassy and crystalline states. For CMSX-4 alloy, the thermal conductivities were calculated from the experimental thermal diffusivities. Both the diffusivities and conductivities were found to increase with increasing temperature. Microscopic analysis showed the presence of intermetallic phases such as NiTi and NiTi2 below 1253 K. In this region, the mean free path of the phonons is likely to be limited by scattering against lattice defects. Between 1253 K and solidus temperature, these phases dissolved in the alloy adding to the impurities in the matrix, which, in turn, caused a decrease in the thermal diffusivity. This effect was confirmed by annealing the samples at 1573 K. The thermal diffusivities of the annealed samples measured at 1277, 1403 and 1531 K were found to be lower than the thermal diffusivities of non-annealed samples and the values did not show any noticeable change with time. It could be related to the attainment of equilibrium with the completion of the dissolution of γ and γ´ phases during the annealing process. Liquid CMSX-4 does not show any change of thermal diffusivity with temperature. It may be attributed to the decreasing the mean free path being shorter than characteristic distance between two neighbouring atoms. On the other hand thermal diffusivities of mould powder having glassy and crystalline states decrease with increasing temperature at lower temperature and are constant at higher temperature except for one glassy sample. Analogously, the thermal diffusivity measurements of mould powder did not show any significant change with temperature in liquid state. It is likely to be due to the silicate network being largely broken down. The thermal diffusivity is increased with increasing crystallisation degree of mould powder, which is expected from theoretical considerations. The coke sample, taken from deeper level of the blast furnace, is found to have larger thermal diffusivity. This could be correlated to the average crystallite size along the structural c-axis, Lc, which is indicative of the higher degree of graphitisation. This was also confirmed by XRD measurements of the different coke samples. The degree of graphitisation was found to increase with increasing temperature. Further, XRD measurements of coke samples taken from different levels in the shaft of the blast furnace show that the graphitisation of coke was instantaneous between room temperature and 1473 K. / QC 20101123

In the present work studies were performed to provide understanding for further model development of the two-phase phenomena, film formation from o/w emulsions and slag foaming. The drying of o/w emulsions of different oil viscosities on hydrophobic and hydrophilic substrates was studied. The hydrophobic substrate was found to destabilise the oil droplets and to result in a different mechanism for forming continuous oil film. Studies of adsorption behaviour of a series of non-ionic diblock copolymers at relevant interfaces showed that the adsorption behaviour at hydrophobic and hydrophilic solid surfaces differed at high polymer concentration. Emulsion droplets were found to interact with the hydrophobic interface. Adsorption at silicone oil-water interface resembled adsorption at solid hydrophobic surfaces. Gas was generated through chemical reaction at the interface between two immiscible liquids and the bubbles formation from the generated was studied optically. The gas bubble size was seen to be uninfluenced by the reaction rate. However, bubble formation was seen to take place in one of the phases, held up at the interface before detaching from the interface with a surrounding aqueous film. It was argued that this may affect the final bubble sizes. Slag foaming at high temperatures was studied in laboratory scale with X-ray imaging under dynamic conditions. The foam displayed a fluctuating behaviour, which the presently available models are not able to take into account. The concept of foaming index was found to be unsatisfactory in describing the foaming behaviour under dynamic conditions, thus emphasizing the need for alternative theories. The rate of fluctuations was seen to be related to the difference between rate of gas generation and rate of gas escape from the system (Ug-Ue) as well as the bubble sizes. Thus, it seems like model development of dynamic foaming phenomenon has to take the effective chemical reaction rate as well as the bubble sizes into consideration

<p>The present work has been carried out in order to investigate Al-Mg-Si alloys that are deformed at moderate temperatures. These temperatures are in the range between 200 C and 300 C. Also some experiments are performed at room temperatures. Two deformation models have been applied in the experiments: material deformation by compression testing and by forward extrusion. </p><p>The investigated alloys are AA6063, AA6082 and an alloy that is named “Alloy R” in this work. The latter alloy is the industrial alloy AA6082 without the Mn-addition (0.56wt%Mn in the AA6082). The “R” denotes the recrystallized microstructure in the material after hot forming operations.</p><p>The investigations show the effect of changing the temperature in the given temperature interval on the stress-strain relationship for each alloy. From the compression testing, it is found that none of the alloys AA6063 or Alloy “R” reaches a steady state condition as true strain approaches 0.8 for deformation temperatures between 200 C and 250 C. At compression testing performance at 300 C, the alloy “R” reaches a steady state condition at a true strain equal to 0.4.</p><p>As true stress-true strain relationship has been investigated for the “Alloy R” and the AA6063 at comparable deformation parameters, it is shown that the alloy “R”, with the highest Si-content, requires the highest true stress for a given true strain value (AA6063: 0.45wt%Si, Alloy “R”: 0.87wt%Si).</p><p>From the compression testing, the effect of Mn on the material properties in the AA6082-alloy has been determined. For the Alloy “R” and the AA6082, the true stress reached the same value after a certain amount of deformation. As deformation temperature increases, this common value of true stress corresponds to a decrease in true strain.</p><p>The AA6082 and Alloy “R” are also compared in experiments performed in forward extrusion. One observes that for the same deformation temperature and at identical die diameters, the ram force is identical. It is worth noticing that these alloys did not show the same relationship during the compression testing at low values of true strain (<0.8). On a microscopic scale, one concludes that Mn has no significant effect on the stress-strain relationship for the applied deformation parameters in the forward extrusion equipment.</p><p>Hardness measurements indicate that the age hardening potential in the extruded test specimen decreases as the deformation temperature increases. The hardness data is similar for both the AA6082 and the Alloy R, thus indicating that the Mn content has no significant effect on the strength of the material.</p><p>The deformed material has been annealed in order to investigate the recrystallization process in the AA6082 and the Alloy “R”. The recrystallization grain size in the Alloy “R” is significantly larger than in the AA6082 at comparable deformation parameters after annealing at 530 C for 15 minutes. This result is due to the effect of Mn-containing dispersoids in the AA6082. The recrystallization grain size in the Alloy “R” seems to be unaffected by the deformation temperature after annealing for 15 minutes. The observation of the AA6082 is quite different. A small increase in grain size is observed for both reduction ratios as the deformation temperature is elevated from 20C to 200 C and further to 250 C. At extrusion temperatures of 300 C the recrystallization grains are significantly larger.</p><p>Annealing experiments performed at 430 C on the AA6082 indicates that a change in the deformation temperature from 200 C to 250 C does not affect the amount of stored energy in the material significantly.</p><p>The Forge2 programme has been used to perform numeric simulations of the forward extrusion experiment. From this the temperature distribution, strain rate variation and true strain development in the test piece had been investigated. As the simulated true strain values are compared to the grain size in the annealed material, the recrystallization grain size is related to the amount of stored energy in the material in a very convincing way. It is also shown that the recrystallization grain diameter is related to the amount stored energy as the grain diameter is investigated in the radial and the extrusion direction separately.</p>

<p>The major issue concerns how the different lignosulfonate types changes the rheological properties of the cement based material (concrete, mortar and cement paste) as a function of temperature and time. In such terms, it is demonstrated that the high molecular weight lignosulfonates performs far better than the low molecular weight ones. The former type also performs considerable better compared to a naphthalene based polymer. </p><p>The above investigation is done with help from the second part of this thesis, which identifies some of the parameters p1, p2,... affecting the shear viscosity η = η ( p1, p2,...) of the cement based material. This is done by investigating the thixotropic behavior of cement paste mixed with either lignosulfonates or naphthalene. The thixotropic behavior is directly related to coagulation, dispersion and re-coagulation of the cement particles. In making the analysis, a modification is applied to the Hattori-Izumi theory, which is a theory about the bookkeeping of the number of reversible coagulated connections between the cement particles. The modification consist, among other things, of include a fading memory to the analysis. That is, the cement paste is allowed to remember its recent past. By a combination of experimental results and numerical simulations, it is demonstrated that such memory term is very important.</p><p>An experimental error is present during a viscometric measurement on concrete (a coaxial cylinders viscometer is used). The error is generated by particle migration. Investigating and compensating for this error constitutes the third part of this thesis. Realizing the nature of this error, some corrections are applied. However, with these corrections, one is only extracting the viscometric values of a "fat'' concrete that surrounds the inner cylinder of the viscometer after the particle migration is basically complete, and not of the concrete in the original homogenous state.</p>