Thesis (M.S.)--Bowling Green State University, 2008. / Document formatted into pages; contains xi, 221 p. : ill. (some col.), maps. Includes bibliographical references.

Detailed information on diet and foraging behavior is necessary for understanding predator-prey interactions and food-web dynamics. The primary objective of this dissertation was to gain a more complete understanding of the natural foraging behavior of Weddell seals (Leptonychotes weddellii) in McMurdo Sound, Antarctica using a video data recorder to document the seal's three-dimensional movements and encounters with prey. Seals exhibited a variety of dive types that could be sorted into five groups based on 18 dive descriptors. Three of these groups (deep aerobic, deep anaerobic, and shallow aerobic) were identified as foraging dives, the frequency of which varied with bathymetry. Deep aerobic foraging dives were similar in depth and duration to foraging dives in previous studies and were more common at offshore breathing holes. However, differences occurred between offshore free-ranging and isolated-hole dives in the behaviors involving descent and the frequency of certain behavioral transitions. These differences were responses by the seals to variations in prey abundance, rather than responses to a change in breathing hole availability. Even with an apparently homogenous sample of seals, there was significant individual variability in foraging success, behavior, diet, and foraging tactics. Dive depth, duration, distance, and energetic cost were important for explaining foraging success when seals dove in shallow areas where Antarctic silverfish (Pleuragramma antarcticum) were more difficult to reach and less abundant. However, the relationship between those variables was not the same for all individuals. Diet and foraging tactics also varied significantly among individuals diving near the coastline. Two coastal seals specialized on silverfish, while two others consumed silverfish and benthic prey. Although benthic prey were more accessible along the coastline than offshore, silverfish, which have a high lipid content, required less handling to consume. Thus, it may be energy-efficient for seals to specialize on silverfish at coastal locations despite the additional time and energy required to travel to depths where silverfish are located. These results helped us understand variability within Weddell seal populations and the basis upon which foraging decisions are made in response to changes in bathymetry, access to breathing holes, and prey abundance and availability.

The aim of this study is to characterise the structure of refrozen cracks, and to deduce the details of their formation. Surveys and experiments are conducted on straight-sided, linear, refrozen cracks of width 80 mm to 340 mm in land-fast first-year sea ice in McMurdo Sound, Antarctica. Refreezing of cracks is simulated analytically, and with a numerical fluid dynamics model of brine movement in the porous sea ice and in the ocean. Systematic arch-shaped patterns of inclusions, upstream-growing crystals, and two-dimensional variations in salinity are identified in completely and partially refrozen, natural cracks, and in artificial cracks. Using a two-dimensional thermistor array, a relationship between the development of the sea ice structure and the temperature records is found, which identifies the transition from the porous, skeletal layer to consolidated ice in artificial cracks. A two-dimensional analytical model is developed that predicts the measured thickness of consolidated ice in refreezing cracks for this study and for the studies of others. From a heat balance within the refreezing cracks, it is concluded that some of the experiments were conducted in the presence of a negative ocean heat flux. A two-dimensional thermistor array beneath the ice-water interface of a refreezing crack provides evidence for sporadic, cold temperature, advective events at night. A two-dimensional, numerical fluid dynamics model based on the finite volume method is developed to simulate desalination and fluid flow in refreezing cracks. This requires a permeability-porosity relationship for sea ice, which is deduced from data of other groups, combined with the numerical model. To make comparisons among data sets, an analytical approximation is derived for the relationship between connected pore space and total pore space of a random porous medium, based on a Monte Carlo model that is adapted to the crystal structure of sea ice. The permeability-porosity relationship derived in this study is in good agreement with permeability functions published recently. The refreezing of cracks simulated with the numerical fluid dynamics model is consistent with experiments and with the analytical model. In addition, the numerical model simulates the high porosity, arch-shaped freezing front and inclusion structure. Supercooling of the liquid is found to cause excessive heat loss in the simulation. Since a large oceanic heat flux was not observed in the experimental heat balance of refreezing slots, it is suggested that this indicates platelet ice formation or frazil ice formation at the vertical crack interface in Antarctic experiments.

Thesis (Ph. D.)--University of Canterbury, 2009. / Typescript (photocopy). Includes bibliographical references (leaves 177-204). Also available via the World Wide Web.

Satellite investigations have documented Antarctic sea ice area, but are restricted in their ability to provide volume, as the procedure to derive thickness is still under development. This procedure requires the measurement of sea ice freeboard, the segment of ice held above the ocean surface by buoyancy. This measurement can be made by satellite altimeters and in conjunction with density and snow depth information; sea ice thickness can be estimated via the hydrostatic equilibrium assumption. The ability to monitor the spatial and temporal characteristics of the thickness distribution must be improved as we strive to understand the linkages between the glaciological, atmospheric and oceanic components of the Antarctic climate system. A key sector in which these components interact is the Antarctic coast. There, offshore winds drive coastal polynyas creating vast amounts of sea ice, and ice shelf interaction modifies ocean properties. Together they condition the ocean for downwelling, driving the global oceanic circulation. In light of this, the coastal Antarctic is a fundamental region in regard to Antarctic sea ice processes and the Earth climate system. McMurdo Sound occupies a coastal area in proximity to an ice shelf in the south-western corner of the Ross Sea. The sound has witnessed scientific investigation for over a century with a fully established research programme since the 1960s. However, the sea ice research in this region is spatially restricted. This thesis aims to expand the knowledge of sea ice in McMurdo Sound to a larger area using space-borne remote sensing instrumentation and design of in situ measurement campaigns. In doing so, this work evaluates the capabilities of satellite platforms to record sea ice freeboard in the coastal Antarctic, whilst developing knowledge of ice shelf-sea ice interaction. This work provides the first satellite altimeter based investigation of sea ice freeboard in McMurdo Sound using ICESat over the period 2003-2009. No observable trend was observed for first-year sea ice freeboard in the region in line with larger scale assessments in the Ross Sea. However, there was significant increase in the freeboard of a temporary multiyear sea ice regime, the segment of the largest increase linked to the outflow of supercooled Ice Shelf Water (ISW) from the McMurdo and Ross Ice Shelf cavities. This remote sensing assessment supports the in situ and modelling work of many others who have identified the influence of ISW on sea ice processes in this region, in particular, that it is thicker than it would otherwise be. The influence of ISW on altimetric sea ice thickness retrievals was also quantified using a Global Navigation Satellite System (GNSS) evaluation of freeboard to thickness conversion. This revealed that a sub-ice platelet layer, created by supercooled ISW and with an estimated solid fraction of 0.16, accumulates beneath the sea ice cover and influences the thickness estimates from the GNSS-derived surface elevation. A cautionary conclusion is reached that within 100 km of ice shelves this buoyant influence should be considered, and in close proximity (< 50 km) can result in overestimations of sea ice thickness of ~ 12 %. It is also suggested that the sea ice freeboard anomalies that result from enhanced growth, driven by supercooled water advection could be used to map the presence of ISW in the coastal Antarctic. Looking to future ability to monitor Southern Ocean sea ice thickness from space, the first comprehensive evaluation of CryoSat-2 (CS-2) over Antarctic sea ice is provided. Using three separate retracking procedures, CS-2 is shown to be capable of detecting the development of a fast ice cover in McMurdo Sound. The role played by a snow cover with layering typical of the Antarctic appears to cause a positive bias in the ice freeboard for a waveform fitting procedure currently used over Arctic sea ice. The identification of open water and the establishment of accurate sea surface heights are also indicated as causing errors (in the order of cms) in the study region. CS-2 is shown to be capable of recording sea ice growth over two growth cycles in McMurdo Sound. This work has advanced the application of satellite investigative techniques to Antarctic sea ice, providing hope that such techniques may be capable of revealing larger scale connections between sea ice and ice shelves.

Reactive halogen species (RHS) are responsible for ozone depletion and oxidation of gaseous elemental mercury and dimethyl sulphide in the polar boundary layer, but the sources and mechanisms controlling their catalytic reaction cycles are still not completely understood. To further investigate these processes, ground– based Multi–Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of boundary layer BrO and IO were made from a portable instrument platform in McMurdo Sound during the Antarctic spring of 2006 and 2007. Measurements of surface ozone, temperature, pressure, humidity, and wind speed and direction were also made, along with fourteen tethersonde soundings and the collection of snow samples for mercury analysis. A spherical multiple scattering Monte Carlo radiative transfer model (RTM) was developed for the simulation of box-air-mass-factors (box-AMFs), which are used to determine the weighting functions and forward model differential slant column densities (DSCDs) required for optimal estimation. The RTM employed the backward adjoint simulation technique for the fast calculation of box-AMFs for specific solar zenith angles (SZA) and MAX-DOAS measurement geometries. Rayleigh and Henyey-Greenstein scattering, ground topography and reflection, refraction, and molecular absorption by multiple species were included. Radiance and box-AMF simulations for MAX-DOAS measurements were compared with nine other RTMs and showed good agreement. A maximum a posteriori (MAP) optimal estimation algorithm was developed to retrieve trace gas concentration profiles from the DSCDs derived from the DOAS analysis of the measured absorption spectra. The retrieval algorithm was validated by performing an inversion of artificial DSCDs, simulated from known NO2 profiles. Profiles with a maximum concentration near the ground were generally well reproduced, but the retrieval of elevated layers was less accurate. Retrieved partial vertical column densities (VCDs) were similar to the known values, and investigation of the averaging kernels indicated that these were the most reliable retrieval product. NO₂ profiles were also retrieved from measurements made at an NO₂ measurement and profiling intercomparison campaign in Cabauw, Netherlands in July 2009. Boundary layer BrO was observed on several days throughout both measurement periods in McMurdo Sound, with a maximum retrieved surface mixing ratio of 14.4±0.3 ppt. The median partial VCDs up to 3km were 9.7±0.07 x 10¹² molec cm ⁻ in 2007, with a maximum of 2.3±0.07 x 10¹³ molec cm⁻², and 7.4±0.06 x 10¹² molec cm⁻² in 2006, with a maximum of 1.05 ± 0.07 x 1013 molec cm⁻². The median mixing ratio of 7.5±0.5 ppt for 2007 was significantly higher than the median of 5.2±0.5 ppt observed in 2006, which may be related to the more extensive first year sea ice in 2007. These values are consistent with, though lower than estimated boundary layer BrO concentrations at other polar coastal sites. Four out of five observed partial ozone depletion events (ODEs) occurred during strong winds and blowing snow, while BrO was present in the boundary layer in both stormy and calm conditions, consistent with the activation of RHS in these two weather extremes. Air mass back trajectories, modelled using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model, indicated that the events were locally produced rather than transported from other sea ice zones. Boundary layer IO mixing ratios of 0.5–2.5±0.2 ppt were observed on several days. These values are low compared to measurements at Halley and Neumayer Stations, as well as mid-latitudes. Significantly higher total mercury concentrations observed in 2007 may be related to the higher boundary layer BrO concentrations, but further measurements are required to verify this.

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