There is great interest in the plant Cannabis sativa (hemp) as a source of technical fibres for the reinforcement of polymers in composite materials due to its high mechanical properties. As a natural fibre hemp also offers biodegradabilty and is therefore an inexpensive and renewable alternative to glass fibres However, the environmental benefits of natural fibres cannot be fully exploited if the manufacturing of their composites involves polluting processing steps. Unfortunately, there is still a lack of environmetally sustainable processing methods yielding technical fibres of sufficient quality. Enzyme application as a biotechnological processing method is a good candidate for this aim and is therefore actively investigated at present. In this work the effects of a range of enzymes on the morphological, compositional and mechanical properties of hemp was investigated. The enzymes were firstly characterised and then applied to hemp fibre for differing periods of time. After visual inspection, a set of fibre samples were selected and subjected to further analysis by Fourier-Transform Infrared Spectroscopy (FTIR), tensile testing and scanning electron microscopy (SEM). The commercial formulation Pectinex® Ultra-SL emerged as the most efficient in terms of treatment time and fibre quality. The effectiveness of treatments was further investigated by developing a novel experimental method that correlates the adhesion forces measured by atomic force microscopy (AFM) on the fibre surface to the properties of the fibres or composites. In order to identify correlations between the adhesion forces and fibre or composite properties, hemp fibre was subjected to four distinctly different treatments to obtain significant differences between fibre properties. The fibres and composites were then analyzed using a combination of FTIR, tensile testing, 3-point bend testing, dynamic mechanical analysis (DMA) and SEM. Based on this comprehensive dataset the AFM data was correlated using the software SPSS. The information derived from AFM (adhesion forces and surface topology) was useful in the clarification of fibre modifications evoked by the treatments.

Wood plastic composites (WPCs) were made using matrices of recycled high-density polyethylene (rHDPE) and polypropylene (rPP) with sawdust (Pinus radiata) as filler. Corresponding WPCs were also made using virgin plastics (HDPE and PP) for comparison with the recycled plastic based composites. WPCs were made through melt compounding and hot-press moulding with varying formulations based on the plastic type (HDPE and PP), plastic form (recycled and virgin), wood flour content and addition of coupling agent. The dimensional stability and mechanical properties of WPCs were investigated. Durability performances of these WPCs were studied separately, by exposing to accelerated freeze-thaw (FT) cycles and ultraviolet (UV) radiation. The property degradation and colour changes of the weathered composites were also examined. Dimensional stability and flexural properties of WPCs were further investigated by incorporation of nanoclays in the composite formulation. To understand the changes in WPCs stability and durability performance, microstructure and thermal properties of the composites were examined. Two mathematical models were developed in this work, one model to simulate the moisture movement through the composites in long-term water immersion and the other model to predict the temperature profile in the composites during hot-press moulding. Both rHDPE and rPP matrix based composites exhibited excellent dimensional stability and mechanical properties, which were comparable to those made from virgin plastics. Incorporation of maleated polypropylene (MAPP) coupling agent in composite formulation improved the stability and the mechanical properties. The incorporation of 3 wt. % MAPP coupling agent to WPCs showed an increase in tensile strength by 60% and 35 %, respectively, for the rHDPE based and rPP based composites with 50 wt. % wood flour. Scanning electron microscopy (SEM) images of the fractured surfaces of WPCs confirmed that the MAPP coupling improved the interfacial bonding between the plastic and the wood filler for both series of composites. Long-term water immersion tests showed that the water transport mechanism within the WPCs follows the kinetics of Fickian diffusion. Dimensional stability and flexural properties of the WPC were degraded after 12 accelerated FT cycles as well as 2000 h of UV weathering for both recycled and virgin HDPE and PP based composites. However, the MAPP coupled composites had improved stability and flexural property degradation. The surface of the weathered composites experienced a colour change, which increased with the exposure time. The MAPP coupled composites exhibited less colour change as compared to non-coupled composites. Regarding the effect of the plastic type, the PP based composites experienced higher colour change than those based on HDPE. With weathering exposure, flexural strength and stiffness of the WPCs were decreased, but elongation at break was increased regardless of plastic type and wood flour content. MAPP coupled rPP and rHDPE based UV weathered WPCs lowered the degradation of stiffness by 50% and 75%, respectively compared to non-coupled WPCs. SEM images of the fractured surfaces of FT and UV weathered WPCs confirmed a decrease in the interfacial bonding between the wood flour and matrix. Thermal properties of weathered composites changed with weathering, but the extent of the changes depended on WPCs formulation and matrix type. From the experimental studies on nanoclay-filled rHDPE composites, it is found that stability, flexural properties of WPCs could be improved with an appropriate combination of coupling agent, and nanoclay contents processed by melt blending. Incorporation of 1-5 wt. % nanoclay in the maleated polyethylene (MAPE) coupled wood plastic composite improved the dimensional stability and flexural properties. The thermal properties changed with the addition of nanoclay and MAPE in WPCs. In this work, a hot press-moulding model was proposed based on the one-dimensional transient heat conduction to predict the temperature profile of the WPCs during hot pressing cycle. The results from this work clearly show that rHDPE and rPP can be successfully used to produce stable and strong WPCs, which properties and performances are similar to or comparable to composites made of wood and virgin plastics. Therefore, WPCs based on recycled PP and HDPE matrix could have potential to use as construction materials.

No description available.

Chitin is an important reinforcing component in load-bearing structures in many organisms such as insects and crustaceans (i.e. shrimps, lobsters, crabs etc.). It is of increasing interest for use in packaging materials as well as in biomedical applications. Furthermore, biological materials may inspire the development of new man-made material concepts. Chitinmolecules are crystallized in extended chain conformations to form nanoscale fibrils of about 3 nm in diameter. In the present study, novel materialshave been developed based on a new type of chitin nanofibers prepared from the lobster exoskeleton. Improved understanding about effects of chitin from crustaceans and chitin material preparation on structure is provided through Atomic Force Microscopy(AFM) (paper I&amp;II), Scanning Transmission Electron Microscopy(STEM) (paper I&amp;II), X-Ray Diffraction (XRD), Intrinsic Viscosity, solid state 13C Nuclear Magnetic Resonance (NMR) (paper II), Field Emission Scanning Electron Microscopy(FE-SEM) (paper I, II, III, IV &amp; V), Ultraviolet-Visible Spectrophotometryand Dynamic Light Scattering (DLS) (paper III). The presence of protein was confirmed through colorimetric method(paper I &amp; II). An interesting result from the thesis is the new features of chitin nanofiber including small diameter, high molar mass or nanofiber length,and high purity. The structure and composition of the nanofibers confirms this (paper I &amp; II). Furthermore, the structure and properties of the corresponding materials confirm the uniqueness of the present nanofibers: chitin membrane (I &amp; II), polymer matrix composites (III),and hydrogels (paper IV). Improved mechanical properties compared with typical data from the literature were confirmed for chitin nanofiber membranes in paper II, chitin-chitosan polymer matrix composites in paper III, and chitin hydrogel in paper IV. Mechanical tests included dynamic mechanical analysis and uniaxial tensile tests. Mechanical properties of chitin hydrogels were evaluated based onrheological and compression properties (paper IV). The values were the highest reported for this kind of chitin material. Furthermore, the relationships between materials structure and properties were analyzed. For membranes and polymer matrix nanocomposites, the degree of dispersion is an important parameter. For the hydrogels, the preparation procedure is very simple and has interesting practical potential. Chitin-binding characteristics of cuticular proteins areinteresting fornovel bio-inspired material development. In the present work(paper V), chitin nanofibers with newfeaturesincluding high surface area and low protein content were combined with resilin-like protein possessing the chitin-binding characteristics. Hydrated chitin-resilin nanocomposites with similar composition as in rubber-like insect cuticles were prepared. The main objective was to improve understanding on the role of chitin-binding domain on mechanical properties. Resilin is a rubber-like protein present in insects. The exon I (comprising 18 N-terminal elastic repeat units) together with or without the exon II (a typical cuticular chitin-binding domain) from the resilin gene CG15920 found in Drosophila melanogasterwere cloned and the encoded proteins were expressed as soluble products in Escherichia coli.Resilin-like protein with chitin-binding domain (designated as ResChBD) adsorbedin significant amount to chitin nanofiber surface andprotein-bound cuticle-like soft nanocomposites were formed. Although chitin bindingwas taking place only in proteinswith chitin-binding domain, the global mechanical behavior of the hydrated chitin-resilin nanocomposites was not so sensitive to this chitin-resilin interaction. In summary, chitin is an interesting material component with high potential as mechanical reinforcement in a variety of nanomaterials. The present study reports the genesisof novel chitin nanofibers and outlines the basic relationships between structure and properties for materials based on chitin. Future work should be directed towards both bio-inspired studies of the nanocomposite chitin structures in organisms, as well as the industrial applications of chitin waste from the food industry. Chitin nanofibers can strengthen the properties of materials, andprovide optical transparency as well as biological activities such as antimicrobial properties. / <p>QC 20141110</p>

The purpose of the study was to investigate the effects of fatigue on the lower extremity landing strategies of males and females. Twelve recreationally active males (n = 6) and females (n = 6) (nine used for analysis) performed repetitive drop jumps until they could no longer reach 20% of their initial drop jump height. Kinematic and kinetic variables were assessed during the impact phase of all jumps. At initial ground contact, males exhibited greater extension at the hip and knee and less plantar flexion than females. However, females performed more eccentric work during the impact phase of landing. Fatigue resulted in an increased extension at the hip, knee, and ankle for both genders, but did not have an effect on the peak VGRF. Fatigue also resulted in an increase in work performed at the ankle and an approximately equal reduction in work performed at the knee for both genders. Investigation of the peak powers revealed that as a result of fatigue, females utilized a landing strategy in which more energy was absorbed at the knee during the early part of the impact phase. The increased reliance on the knee musculature to dissipate kinetic energy during the impact phase of landing demonstrated by females may be a reason for the commonly seen gender disparities in injury rates. Furthermore, the shift towards energy absorption during the initial part of the impact phase when noncontact injuries are known to occur, exhibited by females, may indicate a greater injury risk for females. / School of Physical Education, Sport, and Exercise Science

The purpose of this study was to devise a simple mechanical power formula for both peak and average power using a countermovement jump and reach test for both college male and female athletes. Forty-nine female and 69 male athletes were measured for height, weight, thigh circumference, thigh skinfold, upper leg length, and lower leg length. The athletes performed a countermovement jump and reach test off of a force platform. A Vertec jumping apparatus was used to measure vertical jump height and the force platform was used to acquire force/time data to determine actual peak and average power output. Eight anthropometric measurements, vertical jump height, and gender were the variables presented to develop the equations. A stepwise multiple regression statistical procedure was used to develop the prediction equations. Vertical jump height, mass, and body height were the significant (p<.05) variables loaded into both peak and average mechanical power prediction equations. Gender was not significant (p>.05) and, therefore, not loaded into either equation. Predicted peak power and actual peak power values were 4,707 t 1,511 and 4,687 ± 1,612 watts, respectively. Predicted averagepower and actual average power values were 2,547 ± 760 and 2,463 ± 753 watts, respectively. The following best model regression-derived equations produced R2 values of .91 for peak power and .82 for average power:Peak Power (W) = 78.47 • VJ (cm) + 60.57 • Mass (kg) - 15.31 • Ht (cm) - 1,308 Average Power (W) = 41.41 • VJ (cm) + 31.18 • Mass (kg) - 13.86 • Ht (cm) + 431 Results of this study conclude that the two regression equations are good predictors of peak and average mechanical power output. / School of Physical Education

Whole body vibration (WBV) is a training modality that involves an individual standing on a plate that provides vibrations at multiple frequencies and amplitudes. Improvements in muscular concentric force production such as power and strength have been extensively studied, however little work has been conducted looking at the effects of WBV on eccentric actions. The landing phase of a jump is an eccentric mechanism to decelerate the body as it prepares to stop or initiate another movement. This study sought to identify the effects of WBV on ground reaction forces, loading rates, valgus knee angles, frontal plane knee moment and jump height, as well as a higher order interaction between gender and time as a result of the vibration. An individualized frequency WBV protocol was utilized as 10 female and 9 male subjects completed drop jumps pre-vibration, post vibration and at 10 and 20 minutes post vibration. Baseline valgus knee angle increased 0.857 degrees post vibration, while remaining increased by 0.917 and 1.189 degrees at the 10 and 20 minute post vibration time intervals, respectively. Repeated measure ANOVA’s revealed that valgus knee angle significantly (p=0.011) increased post vibration. Gender comparisons revealed that females had a significantly greater knee moment (p=0.038) and males significantly jumped higher than females (p<0.001). As an end result following WBV, the subjects landed in significantly greater knee valgus, regardless of sex. Since it has been demonstrated that a knee in a valgus position increases the potential risk for anterior cruciate ligament injury, caution should be taken when combining WBV and jump training protocols. / School of Physical Education, Sport, and Exercise Science

Access to abstract permanently restricted to Ball State community only. / Access to thesis permanently restricted to Ball State community only. / School of Physical Education, Sport, and Exercise Science

Recycled concrete aggregate (RCA) is a construction material, which is being used in the Canadian construction industry more frequently than it was in the past. The environmental benefits associated with RCA use, such as reduced landfilling and natural aggregate (NA) quarrying, have been identified by industry and government agencies. This has resulted in some incentives to use RCA in construction applications. Some properties of RCA are variable and as a result the material is often used as a structural fill, which is a low risk application. The use of RCA in this application is beneficial from an overall sustainability perspective but may not represent the most efficient use of the material. Efficient use of a material means getting the most benefit possible out of that material in a given application. The initial step in efficient material use is evaluating how a material affects its potential applications. In the case of RCA, this includes its use in concrete as a coarse aggregate. RCA is made up of both aggregate and cement mortar from its original application. Its make-up results in absorption capacities, which are higher than NA. Its high absorption capacity indicates that RCA can retain a relatively large proportion of water. Internal curing of concrete is the practice of intentionally entraining reservoirs of water within concrete. This water is drawn into the cement at a beneficial point in the cement hydration process. This water allows for a more complete hydration reaction, less desiccation, a less permeable concrete pore system, and less susceptibility to the negative effects of poor curing. The potential for RCA to act as an internal curing agent was evaluated in this research. Two RCA types were studied in the course of this research, one RCA of high-quality and one low-quality. These were compared to one NA type, which served as experimental control. Neither RCA type was found to desorb significant amounts of entrained water at relative humidity levels between 85% and 93%. This behaviour indicates that they would not behave as a traditional internal curing agent. Within concrete, the initial saturation levels of these RCAs were 0%, 60% and 100% of their full absorption capacity. The mixtures ranged from 30% RCA (by volume of coarse aggregate) to 100% RCA. These mixtures were subjected to two curing regimes, MTO-specified curing conditions and moist curing, in order to gauge the internal curing potential of the RCA. Fully saturated RCA mixtures were found to retain water throughout the course of testing. They were also found to increase the rate of compressive strength gain at early ages in comparison to similarly cured NA mixtures. Full saturation was found to have a negative effect on the thermal expansion behaviour of the concrete at 28 days concrete age. Permeable porosity of concrete was measured as an indicator of more thorough hydration in RCA concrete, but any potential benefits were masked by the increase in permeable porosity associated with permeable RCA. When compared with NA control mixtures and RCA mixtures cured under ideal conditions, it was found that saturated RCA mixtures provided compressive strength benefits. Low-quality RCA, which lost entrained water earlier in the testing period than high-quality RCA, benefitted in terms of early age compressive strength gains under specified curing conditions. High-quality RCA, which retained a relatively higher proportion of its entrained water throughout the early testing period, improved later age compressive strength under spec-curing conditions. Mixtures with 30% RCA (by volume of coarse aggregate) were generally found to not significantly affect the tensile strength, elastic modulus, and permeable porosity of the concrete. Tensile strength and elastic modulus were found to be consistently lower in RCA concretes, while permeable porosity was consistently higher. However, the magnitudes of these changes were not large enough to be statistically significant based on the testing regime employed. Compressive strength was significantly improved at 28 days when the 30% RCA was fully saturated. 30% RCA mixtures significantly reduced the thermal expansion of concrete at 28 days, which could provide particular benefit to concrete pavement applications. Overall, RCA saturation in new concrete had both positive and negative effects on the properties of concrete, which should both be considered in the context of the application for which RCA concrete is being considered. Specifically, concrete applications with the potential for poor curing and the need for reduced thermal expansion could benefit through the inclusion of coarse RCA. For example, these benefits could manifest in reduced thermal cracking at slab joints and reduced thermal stresses due to temperature gradients in pavements.

In this thesis a parameter recovery method for use in ultrasound elasticity imaging is developed. Elasticity imaging is a method for using a series of ultrasound images (and the displacement field between them) to estimate the spatial variation of the stiffness of the tissue being imaged. Currently iterative methods are used to do this: a model of tissue mechanics is assumed and a large number of simulations using varying parameters are compared to the actual displacement field. The aim of this work is to develop a solution method that works back from the known displacement field to determine the tissue properties, reducing the number of simulations that must be performed to one. The parameter recovery method is based on the formulation and direct solution of the 2-d linear elasticity inverse problem using finite element methods. The inverse problem is analyzed mathematically and the existence and uniqueness of solutions is described for varying numbers of displacement fields and appropriate boundary conditions. It is shown to be hyperbolic (and so difficult to solve numerically) and then reformulated as a minimization problem with hyperbolic Euler-Lagrange equations. A finite element solution of the minimization problem is developed and implemented. The results of the finite element implementation are shown to work well in recovering the parameters used in numerical simulations of the linear elasticity forward problem so long as these are continuous. The method is shown to be robust in dealing with small errors in displacement estimation and larger errors in the boundary values of the parameters. The method is also tested on displacement fields calculated from series of real ultrasound images. The validity of modelling the ultrasound elasticity imaging process as a 2-d problem is discussed. The assumption of plane strain is shown not to be valid and methods for extending the parameter recovery method to 3 dimensions once 3-d ultrasound becomes more widely used are described (but not implemented).