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Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Earth and Planetary Sciences, 1981. / Microfiche copy available in Archives and Science. / Accompanied by 7 folded plates inserted in back pocket. / Bibliography: leaves 256-263. / by John Michael Bartley. / Ph.D.

A combined petrologic, structural, and geochronologic approach has been used to characterize a zone in southwestern New England affected by superimposed metamorphisms, and the unroofing history of an area that records only the youngest metamorphism. The area chosen for the study of polymetamorphism, northwestern Connecticut and adjacent New York and Massachusetts, records Taconian (Ordovician) peak metamorphic effects in the west and Acadian (Devonian) peak effects in the east. In between, a complicated zone of overlap contains predominantly Taconian mineral assemblages that have been variably affected by Acadian processes. ⁴⁰Ar/³⁹Ar data presented here indicate that the timing of the Taconian thermal maximum was approximately 445 Ma, and that of the Acadian was approximately 390 Ma. Cooling ages suggest that the highest-grade Taconian assemblages at the present erosion surface remained at elevated metamorphic conditions between the Taconian and Acadian thermal maxima. Rim compositions of the highest-grade porphyroblasts in the Taconian zone generally yield P-T estimates that are inconsistent for subareas within a given thin section. With the onset of Acadian metamorphic overprinting conditions of approximately 500°C, the rim compositions of porphyroblasts yield P-T estimates that are much more consistent, and vary by only a maximum of ±50° C and 1 kb. These results are interpreted to indicate that the rims of preexisting Taconian porphyroblasts reequilibrated pervasively at approximately 500°C and above, whereas reequilibration was incomplete at lower Acadian overprinting temperatures. Garnet developed texturally and chemically distinct rims which appear to reflect prograde Acadian metamorphism in higher-grade parts of the Acadian metamorphic zone. Previous studies of garnet zoning have emphasized volume and surface diffusion as the primary means of changing mineral composition. However, in this polymetamorphic zone changes in the composition of preexisting garnet occurred by metasomatic dissolution and reprecipitation along porphyroblast surfaces in the presence of a metamorphic fluid. Diffusion seems significant for changing the garnet composition during the initial overprint only as an agent to move material in an intergranular fluid. The pressures and temperatures of the Acadian metamorphism a consistent metamorphic field gradient of 16 bar/°C, increasing eastward. In an area mainly affected by Acadian metamorphism, peak. metamorphic temperatures were 8.2 kb and 575°C. Nonlinear unroofing rates from ~10 to less than 1 mm/yr following the high-pressure Acadian metamorphism have been documented using combined petrologic, fluid inclusion, thermochronometric, and thermal modeling techniques. The calculated unroofing path is initially nearly isothermal and is followed by more isobaric cooling. Comparison of the inferred path to those predicted by thermal models suggests unroofing was characterized by initial rapid upward <i>en bloc</i> velocity (~ 1 cm/yr) of brief duration, followed by much slower unroofmg rates (≤ 0.3 mm/yr). This proposed unroofing history is consistent with the Paleozoic sedimentary and igneous record of western New England. / Ph. D.

Garnet-bearing gneisses from the vicinity of Passo del Sole, Central Swiss Alps, have undergone a complex history of metamorphism and deformation that has imbued them with unique compositional and textural variations. Complex, concentric zoning patterns in garnet may be correlated between porphyroblasts on the scale of a hand sample; however, the character of the Ca, Mn, and Y zoning patterns in garnet vary within single layers on the meter-scale. Within a hand sample, individual compositional zones can be correlated from crystal to crystal on the basis of chemical similarities (e.g., intricate yet identical variations in calcium concentration; equivalent manganese concentrations at zone boundaries) and textural similarities (e.g., initiation of inclusiontrail curvature). These relationships allow the identification of individual compositional zones as time markers during garnet growth. Detailed examination of garnet growth zoning patterns, in combination with measurements of inclusion-trail curvature within garnet porphyroblasts and detailed thermodynamic models of the garnet growth history in selected samples, together with an assumed heating rate associated with Alpine metamorphism, allows quantification of strain-rates during prograde amphibolite-facies metamorphism along the northern margin of the Lucomagno nappe. Constraints on the nucleation and timing of garnet growth and garnet growth rate mechanisms permit further insight into the relationship between strainrate and metamorphism at Passo del Sole than had previously been possible with this method: variations in strain-rate magnitude of over a factor of ten (10⁻¹⁴ - 10⁻¹³ s⁻¹) are observed, which correlate with core-to-rim changes in compositional zoning. The source of the incredible diversity of compositional zoning patterns in garnet is hypothesized to be open-system infiltration of ephemeral, channelized Ca- or Mn-rich fluids derived from magmatic sources or equilibrated with metamorphic rocks deeper in the section. Stages of garnet growth associated with increased strain rates are also correlated with the high-Ca or high-Mn zones within the garnet porphyroblasts, presumably as the result of strain softening associated with the passage of these fluids. In-situ oxygen isotope analysis using SIMS demonstrates that the changes in majorelement zoning patterns correlate with small shifts in the isotopic composition of garnet. / text

Thesis (MSc)--University of Stellenbosch, 2004. / ENGLISH ABSTRACT: The southern portions of the Early- to Mid-Archaean Barberton granitoid-greenstone terrain of South Africa consists of a high-grade metamorphic granitoid-gneiss terrain that is juxtaposed against the low-grade metamorphic supracrustal sequence of the Barberton Greenstone Belt. The boundary of the two different crustal domains corresponds to the Theespruit Formation, an amphibolite-facies, highly tectonized mélange of metabasites, felsic volcanics and rare, aluminous clastic sediments that occurs along the granitoidgreenstone margins. Amphibolite-facies lithologies in the Theespruit Formation are characterized by strongly prolate mylonitic fabrics that formed in a constrictional tectonic regime. Away from the granitoid-greenstone margin and towards the central parts of the greenstone belt, these rocks grade to, and are overprinted by, greenschist-facies S-L mylonites that formed during non-coaxial deformation. Both peak and retrograde minerals define, and are aligned parallel to, the fabrics in these rocks, indicating that shearing was initiated under peak metamorphic conditions and continued during retrogression. S-C’ fabric relationships indicate that shearing occurred in an extensional tectonic regime and that, during deformation, the gneiss terrain was uplifted relative to the greenstone belt. Peak metamorphic assemblages of grt-st-bt-chl-pl-qtz and ky-st-btms- pl-qtz in metasediments and grt-ep-hbl-pl-qtz in amphibolite constrain peak metamorphic conditions of 7.4 ± 1.0 kbar and 560 ± 20 ºC that were attained during the main accretionary episode in the Barberton terrain at 3229 ± 25 Ma. Peak assemblages in all rocks are pre-tectonic and were deformed and re-equilibrated during retrogression, resulting in these being minimum estimates of peak metamorphic conditions. Petrographic evidence and retrograde pressure-temperature estimates indicate that retrogression involved near-isothermal decompression of ca. 4 kbar prior to cooling into the greenschist-facies. The style and timing of metamorphism in the Theespruit Formation is similar to that of the granitoid-gneiss terrain, suggesting that the Theespruit Formation shares a geological history with the gneiss terrain and that it is allochtonous to the greenstone belt. The main deformational and fabric-forming event exhibited in the Theespruit Formation occurred during the exhumation of the granitoid-gneiss terrain subsequent to peak metamorphism. Consequently, the juxtaposition of this terrain againstthe greenstone belt was achieved by tectonic underplating and core complex formation at ca. 3.23 Ga. The occurrence of high-grade constrictional mylonites that are overprinted by low-grade non-coaxial mylonites as well as extension in an overall compressional tectonic regime is consistent with exhumation by extensional orogenic collapse. Burial of the high-grade terrain to depths of 25 – 30 km is only possible in a relatively cold and rigid crustal environment, while the extremely low apparent geothermal gradients of ca. 20 ºC/km preserved in this terrain suggest that burial and exhumation occurred rapidly, within a time-span of ca. 15 – 20 Ma. These parameters strongly suggest that metamorphism occurred in response to a lateral plate tectonic process that was operational in the Barberton terrain at 3230 Ma. / AFRIKAANSE OPSOMMING: Die suidelike dele van die Vroeg- tot Middel-Argaïese Barberton graniet-groensteen terrein van Suid-Afrika bestaan uit ‘n hoë-graad metamorfe graniet-gneiss terrein wat die lae-graad metamorfe groenstene van die Barberton Groensteen Gordel begrens. Die grens tussen die twee verskillende kors-domeine hang saam met die Theespruit Formasie, ‘n amfiboliet-fasies, getektoniseerde melange van metabasiete, felsiese vulkaniese gesteentes en skaars, alumineuse klastiese sedimente wat langs die graniet-groensteen kontakte voorkom. Amfiboliet-fasies gesteentes in die Theespruit Formasie word gekenmerk deur sterk prolaat milonitiese maaksels wat in ‘n vernouende tektoniese omgewing gevorm het. Hierdie rotse word weg van die graniet-groensteen kontak en na die sentrale dele van die groensteen gordel oordruk en vervang deur groenskis-fasies S-L miloniete wat tydens nie-koaksiale vervorming gevorm het. Beide piek en retrograad minerale definieer, en is georienteer parallel aan, die maaksel in die rotse, wat daarop dui dat skuifskeur onder piek metamorfe toestande begin het en volgehou het tydens retrogressie. S-C’ maaksels dui daarop dat skuifskeur in ‘n verlengende tektoniese omgewing plaasgevind het en dat die gneiss terrein opgehef is relatief tot die groensteengordel tydens vervorming. Piek metamorfe versamelings van grt-st-bt-chl-plqtz en ky-st-bt-ms-pl-qtz in metasedimente en grt-ep-hbl-pl-qtz in amfiboliet bepaal piek metamorfe toestande van 7.4 ± 1.0 kbar en 560 ± 20 ºC wat bereik is gedurende die hooffase van akkresie in die Barberton terrein teen 3229 ± 25 Ma. Die piek metamorfe versamelings in alle rotse is pre-tektonies en is vervorm en geherekwilibreer tydens retrogressie, wat maak dat die beramings minimum skattings van piek metamorfe toestande is. Petrografiese getuienis asook druk-temperatuur beramings dui daarop dat retrogressie gepaard gegaan het met byna-isotermiese drukverligting van naastenby 4 kbar voor afkoeling tot in die groenskis-fasies. Die styl en tydsberekening van metamorfose in die Theespruit Formasie is vergelykbaar met metamorfose in die granietgneiss terrein, wat daarop dui dat die Theespruit Formasie ‘n geologiese geskiedenis met die gneiss terrein deel en allochtoon is tot die groensteen gordel. Die hooffase van vervorming en maakselvorming in die Theespruit Formasie het plaasgevind gedurende die herontbloting van die graniet-gneiss terrein na piek metamorfose. Gevolglik is dieteenplasing van dié terrein teen die groensteen gordel vermag deur tektoniese onderplasing en kernkompleksvorming teen ongeveer 3.23 Ga. Die verskynsel van hoëgraadse vernoude miloniete wat oordruk word deur lae-graadse nie-koaksiale miloniete asook verlenging in ‘n algeheel saamdrukkende tektoniese omgewing dui daarop dat herontbloting plaasgevind het deur middel van verlengende orogenetiese ineenstorting. Die begrawing van die hoë-graadse terrein tot dieptes van 25 – 30 km is net moontlik in ‘n relatief koel en star kors-omgewing, terwyl die uitermate lae geotermiese gradiente van ongeveer 20 ºC/km wat in die terrein behoue gebly het daarop dui dat begrawing en herontbloting vinnig geskeid het, binne ‘n tydsverloop van ongeveer 15 – 20 Ma. Hierdie beperkings is ‘n sterk aanduiding dat metamorfose plaasgevind het as gevolg van ‘n laterale plaattektoniese proses wat werksaam was in die Barberton terrein teen 3230 Ma.

Combined Lu-Hf, Sm-Nd and Rb-Sr isotopic studies of continental crustal rocks were undertaken to assess the relative effects of secondary crustal processes on isotopic systematics of whole-rock systems. The processes studied include ductile deformation, and three cases of hydrothermal alteration, involving fluids of varying composition. The Rb-Sr system proved to be easily disturbed during all secondary processes, while Sm-Nd and Lu-Hf systems were, for the most part, resilient. These results show that Nd or Hf isotopic information obtained from old rocks that have undergone typical crustal deformational and alteration events can be counted on to be equally reliable. Nd and Hf isotopic analyses were performed on four suites of Early Archean felsic gneiss complexes from Greenland, Labrador, Swaziland, and Michigan to explore questions associated with Early Archean crustal growth. The Sm-Nd isotopic data yield initial ∊(Nd) values that are mostly consistent with published age data for the suites. Calculations show limited scatter may be attributed to subtle changes in the Sm/Nd ratio or Nd isotopic composition. The Hf isotopic results are more variable and complex than the Nd results. The relevance of the studies on isotopic mobility in the first part of this work is that they have demonstrated that Nd and Hf isotopes are equally resilient during a range of secondary crustal processes. Given the robustness of the Nd isotopic data from the Archean samples, however, it seems unreasonable to attribute the much wider variation in Hf isotopic data to post-Archean isotopic disturbances. Differences in initial Hf isotopic ratios from differing magma sources seem called for. Nd and Hf whole-rock analyses of a Late Archean pristine garnet-bearing granitoid complex from northern Canada point out the importance of garnet in fractionating Lu/Hf ratios, and in developing anomalous ∊(Hf) signatures in potential source regions. Calculations show that even short-lived upper mantle/lower crustal heterogeneities, products of previous partial melting events involving garnet fractionation, can develop the range of positive and negative ∊(Hf) values seen in the Early Archean samples.

Abstract not available

The Llano Uplift of central Texas contains the largest exposure of Mesoproterozoic rocks along southern Laurentia and is thus crucial to the understanding of orogenesis and plate reconstructions along a portion of one of the largest orogens in the world. Most of the current understanding of the Mesoproterozoic tectonic evolution of southern Laurentia comes from the southeastern portion of the Llano Uplift. To fully characterize the tectonic evolution Llano Uplift, detailed mapping is necessary in the less-studied western Llano Uplift. The Mesoproterozoic Llano Uplift exposes mid-crustal, poly-deformed and metamorphosed schists and gneisses and abundant pre- to post-tectonic granites through an erosional window of Phanerozoic sedimentary rocks. Three lithologic groups were mapped in the western Llano Uplift, from structural highest to lowest these are the Valley Spring Gneiss (VSG), Lost Creek Gneiss (LCG) and Packsaddle Schist (PS). The VSG consists of pelitic schists and pink quartzofeldspathic schists and gneisses. The LCG is a thick, homogeneous package of medium- to coarse-grained augen granite gneiss, interpreted to be a deformed, coarse-grained, porphyritic pluton. The PS consists of a heterogeneous package of interlayered quartzofeldspathic gneisses, amphibolites and minor marbles. These lithologies are consistent with the PS and VSG domains described in the southeastern Llano Uplift (Mosher, 1998; Reese et al., 2000). The exotic Coal Creek Domain (CCD) of the southeastern Llano Uplift is not observed in the western Llano Uplift. The western Llano Uplift, including the VSG, LCG and PS, records a deformational history that resulted in multiple fold generations (F1-F5) and is characterized by a penetrative axial planar foliation (S1-S5). F2s are isoclinal folds of S0 (primary layering) and S1 that locally fold F1 axial planes and have steeply plunging and generally easterly trending hinge lines. F3 folds are locally developed, nearly colinear and coplanar with F2s, tight to open, and fold all previous structures (F1/F2) and fabrics (S1/S2). F4s are open folds with northeast-trending axial traces that occur on a regional-scale. F5s are open to tight folds of all previous structures, with hinge lines that are primarily southeast trending and steeply plunging. S0 to S3 orientations vary from north to east dipping because of reorientation by younger folds. S4 foliations strike to the northeast and S5 foliations are northwest striking and nearly vertically dipping. Late left-lateral shear zones (D6) with generally an easterly trend and boudinage affects the VSG, LCG and VSG in this study area and is commonly associated with unfoliated granite material. Four generations of intrusive granitic sills and dikes are documented and provide relative and absolute age constraints on deformation. The oldest recognized deformation (D1-D3) is constrained between 1253 +5/-3 Ma and 1126 +5/-4 Ma (Roback, et al., 1999). D4 and D5 deformation are constrained between 1126 +5/-4 Ma and 1076 ± 5 Ma (Roback, et al., 1999). Although a change in metamorphic conditions is documented to have occurred between D2 and D3, metamorphic fabrics and assemblages indicate granulite facies conditions during D1, D2 and D3. Amphibolite facies metamorphism occurred during D4 and presumably D5. Deformation in the eastern Llano Uplift has a similar polyphase deformational history to that recorded here for the western Llano Uplift. Deformation in the eastern Llano Uplift is similarly constrained between ca. 1238 to 1091 Ma. In addition, the youngest fold generation (F5) can be directly correlated in orientation and timing from the western to the eastern Llano Uplift, and is constrained between ca. 1119 and 1091 Ma in the eastern uplift. Both the western and eastern Llano Uplift contain late shear zones and extensional structures. Structural differences between the western and eastern Llano Uplift include differences in style and orientation of all but the latest (D5 and D6) structures. In addition, dip of fabrics and, therefore, structural stacking of lithologic domains is opposite, and no mylonite zones were identified in the west. In conclusion, the lithologic domains appear to correlated across the Llano Uplift based upon gross lithologic similarities and the tectonic evolution is similar to the well-studied eastern Llano Uplift, though the kinematics and orientations differ. These conclusions may require that the kinematics of deformation in the southeastern uplift were controlled by the presence of the exotic island arc terrane (CCD) whereas the kinematics of deformation in the western uplift were controlled by continent-continent collision. / text

The Condrey Mountain Schist (CMS) occupies a window through Late Triassic amphibolite facies melange in the north central Klamath Mountains in northern California and southwest Oregon. The schists owe their present level of exposure to a large structural dome centered on the Condrey Mountain Window. Transitional blueschist-greenschist facies assemblages are widespread in mafic schists in the structurally lowest levels of the window; structurally higher CMS near the window margins contains medium- to high-pressure greenschist facies parageneses. An ⁴⁰Ar/³⁹Ar crossite age indicates a late Middle Jurassic age of metamorphism. All subunits of the CMS contain evidence of progressive, polyphase deformational and metamorphic histories. The styles and geometries of minor structures in the central part of the window suggest that early folding and transposition was the result of noncoaxial deformation, and that rotational strains were replaced by irrotational flattening strains with time. Rotational strains were accompanied by the development of epidote-crossite assemblages and the growth of deerite in meta-ironstones; irrotational flattening strains were accompanied and followed by the growth of albite, actinolite, spessartine, and the Ba-silicate, cymrite. Pressure-temperature estimates, the relative ages of mineral growth and deformation, and strain geometries are consistent with, but not restricted to, a subduction zone environment. High shear strains may reflect descent and burial, whereas flattening and late, static mineral growth occur during uplift. Pressure-temperature estimates for the overlying CMS greenschists suggest temperatures similar to those in the central part of the window, but at slightly lower pressures. Thrusting of the overlying amphibolites at 150-156 Ma occurred while the amphibolites were above about 500°C. Stretching lineations indicate a movement vector of about N45W. Comparisons of the sequence and timing of metamorphic and structural events, radiometric ages, and movement directions during thrusting indicate the CMS does not represent an inlier of Klamath Western Jurassic Belt flysch but is instead an older, isolated thrust plate. Similarities with the age of metamorphism and plutonism in the overlying amphibolites suggest the two plates may be remnants of the same Middle Jurassic paired metamorphic belt. / text

published_or_final_version / abstract / Earth Sciences / Master / Master of Philosophy