Currently, our ability to predict the flux of fine sediment at the watershed scale is limited by the precision of erosion rate estimates for the many potential sources distributed throughout a landscape as well as our understanding of the connectivity of sediment pathways during transport. In absence of a robust predictive model which can be validated by measurements of sediment fluxes and use of geochemical tracers. Predicting fine sediment yield at the watershed scale requires multiple redundant lines of information. This thesis outlines the methods used, and the data sets collected in the Root River watershed in Southeastern Minnesota, all of which are multiple lines of evidence to the sediment dynamics in the Root River. The research indicates that the Root River is a very dynamic watershed. The hydrologic regime of the watershed has shifted over the last half century. Due to this shift sediment fluxes are very dependent of the magnitude and sequence of events. Geomorphic analysis of the landforms and the use of a developed tool, TerEx, indicate that many reaches of the river have easily accessible near-channel sources of sediment. Sediment fingerprinting results illustrate that source tracer concentrations are variable across the landscape, that as a whole, upland sources are still a major contributor to the suspended sediment load, and that in some sub-watersheds near-channel sources are dominate in the suspended load. Over all the channel-floodplain exchange exerts strong control on the flux of sediment through this river system.

<div><div><div><p>The radionuclide 10Be is produced in the atmosphere and is delivered to Earth’s surface in meteoric rain and aerosols. The stable nuclide 9Be is present in trace concentrations within rocks in Earth’s crust and is released via chemical weathering. Together, these two isotopes have been employed to study a wide range of Earth processes. Here I explore new terrestrial archives of Be isotopes: cave speleothems and terrestrial Mn-oxides. Until this point, these archives have barely been studied. Only one published dataset of Be isotopes in cave speleothems exists (Lundblad, 2006), and to my knowledge, terrestrial manganese oxides are yet to be explored. However, since speleothems and Mn-oxides precipitate from groundwater, they have the potential to encode temporal variations in the 10Be/9Be ratio of water and colloids in the vadose zone.</p><p>I develop a framework for using the 10Be/9Be ratio in the dissolved phase and/or secondary weathering products as a metric of chemical weathering rate. I am motivated by several over-arching questions:</p><ol><li><p>1) Which factor, or factors, is/are dominant in controlling Be isotopes in speleothems and terrestrial Mn-oxides?</p></li><li><p>2) Can Be isotopes in speleothems be used as a metric of weathering rate over time, particularly across glacial/interglacial cycles?</p></li><li><p>3) Can Be isotopes be used to date the formation of terrestrial Mn-oxides?</p></li></ol><p>I measure Be-isotope concentrations in speleothems from Soreq Cave, Israel. By applying an equation that I derive in this thesis, I use the temporal variation in the speleothem10Be/9Be ratio to calculate chemical weathering rates over the last 168 ka. Chemical weathering varies with independent proxies for temperature. The weathering-temperature relationship can be fit to an Arrhenius relationship, and the calculated activation energy (Ea) matches other field-based estimates for feldspar, an abundant mineral in the soil above the cave. In the Appendices I present additional results of Be-isotope measurements in a flowstone from Buffalo Cave in South Africa, as well as Mn-oxides from the Appalachians.</p></div></div></div>