The objective of this study was to determine how final stocking influences tree growth and radial and longitudinal variation in wood properties at a Pinus radiata D. Don plantation located at one of the warmest forest sites in New Zealand, Forsyth Downs forest in Northland. This thesis addressed both the effect of stocking on stand basal area, height, diameter and branch diameter and the effect of stocking on wood properties microfibril angle (MFA), module of elasticity and density. Finally, how ring width influences wood properties and whether this variable accounts for the treatment effects was investigated. Stocking, height and ring number and all interactions between these variables significantly affected ring width. Ring width by itself was significant as a predictor of density, but when it was combined with other class level variables it was insignificant (i.e. does not account for treatment effects), and it did not add anything to a model with only class effects. There was a significant impact of ring number on density while ring width was insignificant in the same model. MFA was significantly affected by ring width, height and ring number in the tree, and all interactions, apart from the three way interaction, but not by stocking. Ring width was significant in the MFA model both by itself and when it was combined with other variables. Ring width accounted for the stocking effect. The best model of MOE included the class level effects of stocking, height and ring number within the tree, and all interactions between these variables, and ring width, as a continuous variable. While there was a significant effect between stockings this was relatively weak compared to the other main effects. Ring width largely accounted for the effect of stocking, but not that of ring number, or height.

Low embodied energy, ability to act as a carbon store and ease of recycling gives forest products an important role within a low carbon built environment. Almost 25 % of the coniferous resource within the South West of England is Douglas-fir, a species reputed for producing high quality timber. Despite this, the region is facing challenges in delivering the resources full potential, a contributing factor to which is a loss of knowledge regarding its quality. The aim of the work presented is to gain an improved understanding of the quality of Douglas-fir grown within the region, from the perspective of uses in structural applications, the factors which influence material quality and their interrelationships. Flexural modulus of elasticity, flexural and compressive strength were determined utilising small clear specimens derived from 1.3 and 8 m heights within 27 trees from six sites across the South West. Results showed a rise in the magnitude of properties with increasing cambial age, particularly so at younger ages. Differences in values were also recorded between stem heights and with rate of growth. These were however less than age related variations. Results compared favourably to those reported in other studies conducted on the species. Utilising SilviScan-3, anatomical properties including density, microfibril angle and cellular dimensions were measured. Significant variations were recorded with cambial age, and in some instances sampling height. The influence of growth rate on anatomical properties was small. Through statistical and composite modelling, microfibril angle was found to be strongly associated with changes in modulus of elasticity within juvenile wood. Within mature wood and for strength properties, density was the controlling factor. It was shown that a moderate proportion of variations in mechanical properties can be accounted for utilising visually identifiable wood characteristics. The new understanding that has been gained through this work presents opportunities for improved utilisation, the implementation of effective management practices and the development of more efficient visual grading techniques.

The heritability of microfibril angle (MFA) in loblolly pine, Pinus taeda L., and its genetic relationships with height, diameter, volume and specific gravity were examined in two progeny tests with known pedigrees. Significant general combining ability (GCA), specific combining ability (SCA), and SCA x block effects indicated that there are both additive and non-additive genetic influences on MFA. Individual-tree narrow-sense heritability estimates were variable, ranging from 0.17 for earlywood (ring) 4 MFA to 0.51 for earlywood (ring) 20 MFA. Genetic correlations between MFA, specific gravity and the growth traits were non-significant due to large estimated standard errors. Multiple-trait selection and breeding in a mainline and elite population tree improvement program were simulated using Excel and Simetar (Richardson 2001). The effects of four selection indices were examined in the mainline population and the effects of seven selection indices and four breeding strategies were examined in the elite population. In the mainline population, selection for increased growth caused decreased wood quality over time. However, it was possible to maintain the overall population mean MFA and mean specific gravity at levels present in the base population by implementing restricted selection indices. Likewise, selection for improved wood quality in the elite population resulted in decreased growth unless restricted selection indices or pulp indices derived from those of Lowe et al. (1999) were used. Correlated phenotypic responses to selection on indices using economic weights and heritabilities were dependent on breeding strategy. When a circular mating system (with parents randomly assigned to controlled-crosses) was used, the index trait with a higher economic weight was more influential in determining correlated responses in non-index traits than the index trait with a lower economic weight. However, when positive assortative mating was used, the index trait with a greater variance was more influential in determining correlated responses in non-index traits than the index trait with a lower variance regardless of economic weight.

This study approaches wood quality in young trees by very early screening – and consequent selection for propagation – on the basis of physical and mechanical properties. In chapter 1 corewood properties are reviewed and the importance and problems associated with early screening are discussed. Due to randomly distributed reaction wood in young trees it is advantageous to lean trees to avoid intermixing of the two wood types and minimise any uncertainty in the results. In chapter 2 physical and mechanical properties are described for opposite and compression wood in a population of Pinus radiata comprising of 50 families, at a young (<3 years) age. The dynamic stiffness was determined using the resonance acoustic technique. Density was measured using water displacement method, and longitudinal and volumetric shrinkage were measured from green to ~5% moisture content. The compression wood and opposite wood differ significantly in all the measured properties. Compression wood was characterised by high density and high longitudinal shrinkage. The mean stiffness of opposite wood was 3.0 GPa with a mean standard deviation of 0.39, and the mean longitudinal shrinkage of opposite wood was 0.99% with mean standard deviation of 0.31 across the samples examined. This variation in stiffness and longitudinal shrinkage in opposite wood can be exploited to screen for wood quality. The variation in stiffness and longitudinal shrinkage within a family was comparable to variation among families. In spite of large within site variability it was possible to distinguish between the worst and the best families in opposite wood at young age. In chapter 3 ranking of selected families of Pinus radiata was done based on microfibril angle, which is considered as the main factor influencing both stiffness and longitudinal shrinkage. The ranking was compared with ranking done using acoustic velocity which is more practical and fast method of screening trees. The mean MFA in opposite wood was 39° with a mean standard deviation of 3.7 and in compression wood the mean MFA was 44° with a mean standard deviation of 2.9. The variation in MFA in opposite wood offers opportunities to breed for trees with low MFA. A strong negative correlation (R=-0.68) between acoustic velocity squared and MFA in opposite wood suggested that the resonance technique can be used effectively to screen very young wood rather than using MFA. At high MFA, the cell wall matrix also plays an important role in determining the mechanical and physical properties of the wood. At present the chemical composition of wood samples is determined by wet chemical analysis, which is time consuming and laborious. Therefore, it is impractical to characterise large numbers of samples. Mechanical properties, particularly tanδ (dissipation of energy), which changes with temperature and frequency as the structure of the material changes at the molecular level, was studied using dynamic mechanical analysis (DMA). The idea was to assess if it can be used as a quality trait for tree screening instead of wet chemical analysis. Compression wood and opposite wood were characterised for storage modulus and tanδ at constant moisture content. In practice the instrument used, TA instrument Q800, was unable to provide the desired range of temperature and humidity so no glass transition at 9% moisture content in the temperature range of 10°C to 85°C at 1 and 10 Hz frequency was observed that might be attributed to the hemicelluloses (or lignin). In spite of the huge difference in chemical composition of opposite and compression wood, the difference in their mean tanδ at 25°C and 1 Hz values was just 7%. The positive correlation between MFA and tanδ in opposite wood suggested that MFA also plays a role in the dissipation of energy. The strong relationship between storage modulus and dynamic modulus (R=0.74) again justifies the reliability of resonance technique to screen young wood for stiffness. Concurrently eighty seven, two-year-old leant Eucalyptus regnans were studied for growth strains along with other physical and mechanical properties, independently in tension and opposite wood. The leant trees in Eucalyptus regnans vary in their average growth strain. Strong correlation between measured and calculated strain (R=0.93) suggests that the quick split method can be used to screen large populations for growth stresses. Tension wood was characterised by high density and was three times stiffer than opposite wood and twice as high in volumetric shrinkage. The high longitudinal shrinkage in opposite wood could be due to comparatively high MFAs in opposite wood of the young trees. There was no correlation between growth strain values and other measured properties in opposite wood. It is possible to screen for growth strain at age two, without any adverse effect on stiffness and shrinkage properties.

The content of this study is focused on the influence of the structure of wood at microscopic and submicroscopic level on its mechanical properties. The wood cell wall consists of several layers, the dominant layer being layer S2, which occupies up to 80 % of the total thickness of the wood cell wall. Unique feature of this layer is that cellulose microfibrils placed in this layer are highly aligned and spirally wound around the cell axis. The inclination of these microfibrils is called microfibril angle (MFA) and is the key feature that affects mechanical properties of wood and its shrinkage. In theoretical part of this thesis methods for measuring microfibril angle are described. A method for measuring mechanical properties of the wood cell wall called nanoindentation is discussed in detail. In the practical part of this thesis, microfibril angle is measured by means of polarized light microscopy and mechanical properties of wood cell wall is determined by means of nanoindentation.

京都大学 / 0048 / 新制・課程博士 / 博士(農学) / 甲第17904号 / 農博第2027号 / 新制||農||1018(附属図書館) / 学位論文||H25||N4800(農学部図書室) / 30724 / 京都大学大学院農学研究科森林科学専攻 / (主査)教授 杉山 淳司, 教授 矢野 浩之, 教授 髙部 圭司 / 学位規則第4条第1項該当 / Doctor of Agricultural Science / Kyoto University / DFAM

Wood fibres can be used as reinforcement in plastics for load carrying purposes. Some advantages compared with conventional man-made fibres are that wood fibres come from a renewable resource, have high specific stiffness and strength, are generally less hazardous to health, biodegradable, and can be manufactured at low cost and high volumes. A clear disadvantage with cellulose-based materials for structural use is their dimensional instability in humid environments. The hygroelastic properties are of high importance in materials development of improved wood-fibre composites. This work deals with the stiffness and hygroexpansion of wood fibres for composite materials. The long-term aim is to design engineered wood fibre composites based on better basic knowledge of wood fibres. Mechanistic models have been used to link the fibrous microstructure with macroscopic composite engineering properties. The properties have been characterized experimentally for various wood-fibre composites and their fibre-mat preforms, by means of curvature measurements at various levels of relative humidity, as well as tensile and compressive tests. From these test results and microstructural characterization, the longitudinal Young’s modulus and transverse coefficient of hygroexpansion of wood fibres were identified by inverse modelling. Some effects of various pulp processes and fibre modifications on the elastic properties of the fibre were observed, illustrating how the mixed experimental-modelling approaches can be used in more efficient materials screening and selection. An improved micromechanical analysis for wood-fibre composites has been presented. The model is more appropriate to combine with laminate analogy, to link fibre properties on the microscale to the macroscopic composite properties and vice versa. It also offers the possibility to include the effects of ultrastructure since it can account for an arbitrary number of phases. An approach to model ultrastructure-fibre property relations has been demonstrated. It includes analytical modelling of multilayered cylindrical fibres as well as finite element modelling of fibres with irregular geometry characterized with microscopy. Both approaches are useful and could be combined with experiments to reveal insights that can pave way for a firmer link between the wood fibre ultrastructure and wood fibre properties. / QC 20100914

The genetic manipulation of perennial woody tree species presents a range of additional challenges compared to that of annual weedy crop species. These include long generation times and reproductive cycle, the heterogeneity of plants under investigation and, when investigating xylogenesis, a number of physical and biochemical limitations to microscopic and molecular experimentation. Efforts have been made to understand molecular aspects of xylogenesis and have involved functional gene testing using transgenic approaches. These methods involve the production of plantlets from a variety of plant tissues using in vitro full plant regeneration techniques. Although these systems are effective, the time taken from transformation event, to plant establishment and growth, then finally to secondary wood production can take up to several years and requires high labor and technical inputs. (For complete abstract open document)

Paper is used in a wide range of applications, each of which has specific requirements on mechanical and surface properties. The role of paper strength on paper performance is still not well understood. This work addresses the mechanical properties of paper by utilizing fiber network simulation and consists of two parts.In the first part, we use a three-dimensional model of a network of fibers to describe the fracture process of paper accounting for nonlinearities at the fiber level (material model and geometry) and bond failures. A stress-strain curve of paper in tensile loading is described with the help of the network of dry fibers; the parameters that dominate the shape of this curve are discussed. The evolution of network damage is simulated, the results of which are compared with digital speckle photography experiments on laboratory sheets. It is concluded that the original strain inhomogeneities due to the structure are transferred to the local bond failure dynamics. The effects of different conventional and unconventional bond parameters are analyzed. It has been shown that the number of bonds in paper is important and that the changes in bond strength influence paper mechanical properties significantly.In the second part, we proposed a constitutive model for a fiber suitable for cyclic loading applications. We based the development of the available literature data and on the detailed finite-element model of pulp fibers. The model provided insights into the effects of various parameters on the mechanical response of the pulp fibers. The study showed that the change in the microfibril orientation upon axial straining is mainly a geometrical effect and is independent of material properties of the fiber as long as the deformations are elastic. Plastic strains accelerate the change in microfibril orientation. The results also showed that the elastic modulus of the fiber has a non-linear dependency on a microfibril angle,with elastic modulus being more sensitive to the change of microfibril angle around small initial values of microfibril angles. These effects were incorporated into a non-linear isotropic hardening plasticity model for beams and tested in a fiber network in cycling loading application model, using the model we estimated the level of strains that fiber segments accumulate at the failure point in a fiber network.The main goal of this work is to create a tool that would act as a bridge between microscopic characterization of fiber and fiber bonds and the mechanical properties that are important in the papermaking industry. The results of this work provide a fundamental insight on mechanics of paper constituents in tensile as well as cyclic loading. This would eventually lead to a rational choice of raw materials in paper manufacturing and thus utilizing the environment in a balanced way. / <p>QC 20130605</p>