Dans cette thèse, des systèmes nano-opto-mécaniques (NOMS) sont explorés et deux composants nano-opto-mécaniques sont conçus, simulés, fabriqués et analysés. Premièrement, un générateur de moment angulaire composé d'un résonateur en anneau, un guide d'onde et un ensemble de nano-plots est conçu, analysé théoriquement et simulé. L'analyse théorique et les résultats numériques montrent qu'une série de champs tournants optiques (ROFs) sont générés lorsque différentes longueurs d'onde de résonance sont couplées dans le générateur. Par la suite, la force optique, le potentiel optique et le couple optique du ROF généré sont analysés théoriquement, simulés numériquement et discutés. Les distributions de forces optiques sont affectées par le ROF en fonction des ordres angulaires et des différents nano objets considérés. Les couples optiques sont analysés et discutés pour des objets différents, àsavoir les nano-particules sphériques, des nano-fils et un nano-rotor. Enfin, un système accordable de transparence induite par résonateurs couplés (Coupled-Resonator-Induced Transparency –CRIT), qui est entraîné par la force optique exercée entre le résonateur en anneau et le substrat, est conçu, analysé théoriquement, simulé,fabriqué et mesuré expérimentalement. Le système CRIT accordable est constitué d'un guide d'onde et de deux résonateurs en anneau couplés, dans lequel un anneau est fixe et l’autre libre de se mouvoir. Différentes puissances d'entrée produisent différentes forces optiques sur l'anneau libéré, qui produisent différentes déformations et changements de l'accumulation du champ optique, et ainsi différents décalages du spectre de transmission optique et une variation du retard de groupe / In this PhD thesis, the nano-opto-mechanical system (NOMS) is explored and two nano-opto-mechanical devices are designed, analyzed, simulated and fabricated. Firstly, an angular momentum generator consisting of a ring resonator, a wave guide and a group of nano-rods is designed, theoretically analyzed and simulated. The theoretic alanalysis and numerical results show that a series of rotating optical field (ROF) are generated when different resonant wave lengths are coupled into the generator. Subsequently, the optical force, the optical potential and the optical torque of the generated ROF are theoretically analyzed, numerically simulated and discussed. The optical force distributions are affected by the ROF with different angular orders and different objects. The optical torques are analyzed and discussed for different objects, i.e. spherical nano-particle, nano-wire and nano-rotor. Finally, a tunable coupled-resonator-induced transparency (CRIT) system, which is driven by the optical force between the ring resonator and the substrate, is designed, theoretically analyzed, simulated, fabricated and experimented. The tunable CRIT system consists of a bus wave guide and two coupled ring resonators, in which one is the released ring and the other is the fixed ring. Different input powers produce different optical forces on the released ring, which produce different final deformations, change the optical field buildup, shift the transmission spectrum and vary the group delay

Thesis (Ph. D.)--University of Missouri-Columbia, 2007. / The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file (viewed on December 13, 2007) Vita. Includes bibliographical references.

<p>The purpose of the diploma work is to investigate the possibilities to combine three different areas; reflectometry, microfluidics and laser ablation in a microstructured single-mode fiber, thus obtaining a controlled technique for positioning for ablation and collection of liquids from small inclusions.</p><p>Each of the three areas is thoroughly described in different sections of this report. The first part of the experiments in this diploma work consisted of combining reflectometry and microfluidics, the second part combining reflectometry with laser ablation and the final experiment setup consisted of a combination of all three areas. An artificial system for liquid collection was then designed for that purpose.</p><p>The results obtained from experiments and measurements clearly demonstrate that combining reflectometry, laser ablation and fluid collection in a single optical fiber is promising. Future work will include improvements of the technique towards a medical application for bone marrow transplantation.</p>

Microscale fluid processes are an increasingly important subgroup of fluid mechanics. Applications for heat transfer and micro-electro-mechanical devices use flows on the scale of less than one hundred microns. This study is part of a larger work in which a multiphase, high shear environment is studied in a microchannel that has a depth of approximately 130 μm. Velocities are obtained using non-invasive imaging schemes. Laser induced fluorescent Particle Image Velocimetry (PIV) is used to analyze the velocity distribution in the microchannel. Multiple image processing techniques are used to optimize the images for correlation calculations. Velocity profiles for three flow rates and three void fractions (one of which is zero) are developed experimentally. The effect of the microbubbles on the PIV analysis is shown to flatten the profile through one primary mechanism and possibly a secondary, less dominant mechanism. / Graduation date: 2006

An experimental study was performed in which an ammonia-water solution was desorbed within a branching fractal-like microchannel array. The solution entered in the center of a disk, and flowed out radially until discharging in to a gravity-driven separation chamber. Heat was added to the ammonia-water through a thin wall, above which flowed heat transfer oil in a separate branching fractal-like microchannel array. Such arrays have been shown to utilize the increased heat transfer coefficients seen in parallel channel arrays; however, they do so with a lower pressure drop. An experimental flow loop consisting of ammonia-water and heat transfer oil sub-loops was instrumented along with a test manifold for global measurements to be taken. Temperature, pressure, density and mass flow rate measurements permitted calculation of desorption and heat transfer characteristics. Parameters included oil mass flow rate, oil inlet temperature, and strong solution flow rate, while strong solution concentration, temperature, and weak solution pressure were kept constant. The desorber was assumed to achieve equilibrium conditions between the vapor and weak solution in the separation chamber. The exit plenum was large and acted as a flash chamber, making the assumption reasonable. The vapor mass fraction was determined from knowledge of the weak solution saturation temperature. Heat exchanger analyses (LMTD and ε-NTU) were done to determine the heat transfer characteristics of the desorber. Calculated values of UA are shown to be as high as 5.0 W/K, and desorber heat duties were measured as high as 334 W. Strong solution, at 0.30 mass fraction, was desorbed into weak solution and vapor with concentrations ranging from 0.734 to 0.964. Circulation ratios, defined as strong solution mass flow rate per unit desorbed vapor mass flow rate, varied in this study from 3.4 to 20. A method for specifying desorber operating conditions is described, in which a minimum desorber heat input per unit vapor flow rate is determined at an optimum circulation ratio. A description of how the circulation ratio behaves as a function of strong solution mass flow rate, oil flow rate, and the maximum temperature difference between oil and ammonia-water solution is shown. / Graduation date: 2006

Over the last decade, the miniaturization of analytical systems has become an increasingly important and interesting research area. Miniaturized systems offer many advantages, including reduced reagent and sample consumption, shorter analysis times, portability and disposability. This dissertation describes novel approaches in this direction, focusing on two areas: the miniaturization of existing column chromatographic systems and the development of microfluidic systems in which the separation is performed in a channel on a microchip. A new type of methacrylate-based monolithic capillary columns for liquid chromatography and capillary electrochromatography were prepared within the confines of fused-silica tubing using Starburst dendrimers to affect porosity. The polyamidoamine (PAMAM) dendrimers were incorporated into a solution of functionalized monomer, cross-linker, solvents, and polymerization initiator. Thermal polymerization, followed by the removal of solvent and dendrimers, produced a continuous rod of polymer with uniform porosity. Different column porosities were obtained by varying the amount of the dendrimer template. The chromatographic performance of these monolithic columns was evaluated using a peptides mixture obtained by tryptic digestion of chicken egg lysozyme. A distinct advantage of polymer monolithic stationary phases over conventional packed chromatographic beds is the ability to prepare them easily and rapidly via free radical polymerization within the channels of a microfluidic device. In this work, continuous polymeric beds were prepared within a channel of three different microchip substrates: glass, poly(dimethylsiloxane) and polycarbonate. The methacrylate-based monolith was cast in-situ via UV-initiated polymerization. The functionalization of the inner wall of the channel with methacryloyl groups enabled the covalent binding of the monolith to the wall. The morphology of the wall-anchored monolith was studied by SEM of chip sections, and by SEM of an extruded segment of non-anchored monolith from a separate chip. / Graduation date: 2005

Graduation date: 2005

The effect of unsteady thermocapillary convection on the mass transfer rate of a solute between two immiscible liquids within a rectangular microscale channel with differentially heated sidewalls was numerically investigated. A computational fluid dynamic code in Fortran77 was developed using the finite volume method with Marker and Cell (MAC) technique to solve the governing equations. The discrete surface tracking technique was used to capture the location of the moving liquid-liquid interface. The code produced results consistent with those reported in published literature. The effect of the temperature gradients, the aspect ratio, the viscosity of liquid, and the deformation of the interface on the mass transfer rate of a solute were studied. The mass transfer rate increases with increasing temperature gradient. The improvement of the mass transfer rate by the thermocapillary convection was found to be a function of the Peclet number (Pe). At small Pe, the improvement of the mass transfer rate increases with increasing Pe. At high Pe, increasing the Pe has no significant effect on increasing the mass transfer rate. Increasing the aspect ratio of the cavity up to 1 increases the mass transfer rate. When the aspect ratio is higher than 1, the vortex moves only near the interface, resulting in decreasing the mass transfer rate. By increasing the viscosity of the liquid in top phase, the maximum tangential velocity at the interface decreases. As a result, the improvement of the mass transfer rate decreases. The deformation of the interface has no significant effect on the improvement of the mass transfer rate. By placing the heating source at the middle of the cavity, two steady vortices can be induced in a cavity. As a result, the mass transfer rate is slightly enhanced than that in the system with one vortex. By reversing the direction of the temperature gradient, the mass transfer rate decreases due to the decrease in the velocity of bulk fluid. The thermocapillary convection also promotes the overall reaction process when the top wall of the cavity is served as a catalyst. / Graduation date: 2005

A two-dimensional model was developed to predict concentration profiles from passive, laminar mixing of concentration layers formed in a fractal-like merging channel network. Both flat and parabolic velocity profiles were used in the model. A physical experiment was used to confirm the results of the model. Concentration profiles were acquired in the channels using laser induced fluorescence. The degree of mixing was defined and used to quantify the mixing in the test section. Although the results of the experiment follow the trend predicted by the two-dimensional model, the model under predicts the results of the experiment. A three-dimensional CFD model of the flow field in the channel network was used to explain the discrepancies between the two-dimensional model and the experiment. For the channel network considered, the degree of mixing is a function of Peclet number. The effect of geometry on the degree of mixing is investigated using the two-dimensional model by varying the flow length, the width of the inlet channels, and the number of branching levels. A non-dimensional parameter is defined and used to predict an optimum number of branching levels to maximize mixing for a fixed inlet channel width, total length, and channel depth. / Graduation date: 2003

The purpose of the diploma work is to investigate the possibilities to combine three different areas; reflectometry, microfluidics and laser ablation in a microstructured single-mode fiber, thus obtaining a controlled technique for positioning for ablation and collection of liquids from small inclusions. Each of the three areas is thoroughly described in different sections of this report. The first part of the experiments in this diploma work consisted of combining reflectometry and microfluidics, the second part combining reflectometry with laser ablation and the final experiment setup consisted of a combination of all three areas. An artificial system for liquid collection was then designed for that purpose. The results obtained from experiments and measurements clearly demonstrate that combining reflectometry, laser ablation and fluid collection in a single optical fiber is promising. Future work will include improvements of the technique towards a medical application for bone marrow transplantation.