Diss.--Eidgenössische technische hochschule. / "Diss. no. 4611." Includes biography.

Diss.--Eidgenössische technische hochschule. / "Diss. no. 4611." Includes biography.

Thesis (Ph. D.)--University of Wisconsin--Madison, 1982. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.

Thesis (Ph. D.)--University of Wisconsin--Madison, 1959. / Typescript. Abstracted in Dissertation abstracts, v. 19 (1959) no. 12, p. 3150. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 73-74).

Thesis--Virginia Polytechnic Institute and State University. / Vita. Abstract. Includes bibliographical references (leaves 113-116). Also available via the Internet.

The object of this research was the construction of a microwave spectroscope at 1.25 cm. wavelength. The double modulation method, which was used here, is discussed. The system was tested with ammonia, and the inversion spectrum identified. The effect of using various harmonies of detection is shown. / Science, Faculty of / Physics and Astronomy, Department of / Graduate

A new technique has been devised to obtain time-resolved measurements of small spectral line shifts. Two linear neutral density wedges with opposite transmission gradients were placed over the top and bottom of a monochromator exit slit in such a way that a wavelength shift of a spectral line resulted in a change in light intensity transmitted through the wedges, which was monitored by two photomultipliers. To test this technique, an N II line, for which Griem has calculated the Stark shift as a function of electron density, was observed in the emission spectrum of a small theta-pinch using a monochromator of 10 Å/mm inverse dispersion. Space and time resolved line shift measurements were made and were associated with the axial velocity and the electron density fluctuations of the plasma. An uncertainty of 0.015 Å was estimated, which, for the 1.5 Å line used, corresponds to a shift to width ratio of 10⁻², believed to be lower than any previous shift measuring technique. Time of flight velocity measurements and conservation of mass considerations have confirmed the results as both reasonable and self-consistent. / Science, Faculty of / Physics and Astronomy, Department of / Graduate

The microwave spectra of three unstable molecules, bromine isocyanate (BrNCO), iodine isocyanate (INCO), and bromine thiocyanate (BrSCN), have been observed and analyzed in the frequency range 16-54 GHz. The infra-red spectrum of aminodifluoroborane (BF₂NH₂) has been investigated in the region 3700-400 cm⁻¹, and one band, the 2¹₀ vibrational band has been recorded at a resolution of 0.004 cm⁻¹, and the rotational structure analyzed. BrNCO: BrNCO was generated from the flow reaction of Br₂ with silver cyanate. The spectra of two isotopic species were observed: ⁷⁹BrNCO and ⁸¹BrNC0. They contain strong a-type transitions as well as some weaker b-type transitions which could not initially be assigned. In addition, the transitions show both Br and N quadrupole hyperfine structure. A novel method has been developed which uses perturbations in the Br structure to evaluate all the rotational constants, as well as the Br quadrupole tensor, entirely from a-type R branch transitions using a global least-squares fitting programme. This has allowed some b-type transitions to be assigned. The molecule has been shown to be planar and a partial r₀ structure was determined. The principal values of the Br quadrupole tensor have been evaluated and have provided some information about the type of bonding involved in the Br-N bond. INCO: INCO was observed in the flow reaction of I₂ with silver cyanate. Many strong a-type transitions were observed as well as some very weak b-type transitions. These transitions showed I and N quadrupole hyperfine structure; many perturbations in the I structure were observed. The method developed in the analysis of the spectrum of BrNCO using such perturbations to obtain otherwise unobtainable rotational constants was extended to include centrifugal distortion constants. The planarity of INCO has been confirmed and a partial r₀ structure was determined. The principal values of the I quadrupole tensor have been evaluated and have provided some information about the type of bonding involved in the I-N bond. BrSCN: BrSCN was generated in the flow reaction of Br₂ with silver thiocyanate. The spectra contained both a- and b-type transitions, all of which showed Br quadrupole hyperfine structure. The rotational constants and all five quartic centrifugal distortion constants were obtained for two isotopic species: ⁷⁹BrSCN and ⁸¹BrSCN. The rotational constants confirm the thiocyanate configuration, and a partial r₀ structure has been obtained. Also, the principal values of the Br quadrupole tensor were evaluated which show that the Br-S bond is essentially covalent, with small amounts of π and ionic character. BF₂NH₂ : BF₂NH₂ was generated by heating solid BF₃ NH₃. The wavenumbers of 7 of the vibrational fundamentals have been obtained, and from the analysis of the 2¹₀ band, an accurate set of rotational and quartic centrifugal distortion constants of the ground vibrational state have been obtained and the rotational and quartic centrifugal distortion constants of the 2¹ level have been evaluated. Also a Coriolis type perturbation was observed, probably due to the combination level v₇ + v₁₁ , which has provided an estimate of the wavenumber of the v₁₁ fundamental which has not yet been observed. / Science, Faculty of / Chemistry, Department of / Graduate

The microwave absorption spectra of ortho pairs in low ortho concentration samples of solid hydrogen is studied theoretically and experimentally. A theory is developed for several line broadening mechanisms and a comparison made with experiment. Phonon induced lifetime effects are calculated to be less than 2 MHz in the temperature range T=1.2-4.2 K but have not yet been observed experimentally. Inhomogeneous broadening due to isolated ortho molecules and to isotopic mass defect impurities is observed and found to be consistent with theory. Several new lines in the out-of-plane pair configuration are reported which confirm the assignments made previously, whereas two new lines in the next nearest neighbor configuration support a reassignment of these transitions. Also, three excited state transitions which fix the position of the 10 P level are reported and compared with the theoretical predictions of Harris et al. (1977) and Luryi and Van Kranendonk (1979). / Science, Faculty of / Physics and Astronomy, Department of / Graduate

No description available.