Thesis (MTech. degree in Environmental management.)-Tshwane University of Technology, 2008. / Aims to generate information on the quality of water from boreholes and the Steelpoort river in order to ascertain the level of pollution within the vicinity of Vantech mine. The information is envisaged to help a better water management within the area. The following objectives were pursued: to measure water quality parameters ; to investigate the extent of the pollution plume movement ; to study the composition and geological factors in the area in relation to mobility of groundwater and to determine the impacts of Geo hydrological characteristics.

Extensive research conducted over the last decade has demonstrated the great potential of phytostabilization for the reclamation of abandoned mine tailing piles. The right combination of plant species and soil amendments can facilitate the growth of a permanent vegetative cover on the tailings that will help minimize the mobilization of metal-bearing particles by means of wind dispersion and water erosion. Despite previous research efforts, the diversity and potential role of microbial populations inhabiting the root zone of the plants on the stabilization of the metal(loid) contaminants remains mostly unresolved. The study presented in this dissertation represents one of the first comprehensive efforts aimed to understand the ecology and dynamics of microbial communities colonizing both bulk and rhizosphere tailings during phytostabilization as an initial step towards elucidating the role of microbes in the stabilization of metal(loid) contaminants during the remediation treatment. This study was divided into two main projects: (1) the first aimed to monitor the temporal variations in functional and taxonomic diversity of prokaryotic populations in acid-generating metalliferous mine tailings during phytostabilization to determine how they respond to and/or influence changes in environmental parameters and to identify key patterns in their composition that may serve as bioindicators of soil health and the success of the remediation treatment; and (2) the second aimed to expand our understanding of the dynamics of root-associated bacterial, fungal and archaeal communities during mine tailing phytostabilization and how the dynamic behavior of the communities correspond to the growth of plants, the addition of soil amendments, and fluctuations in environmental conditions. The results presented here demonstrate that different microbial groups respond differently to changes in environmental conditions during phytostabilization, suggesting that by monitoring the behavior of specific microbial groups in the systems (as bioindicators) we may be able to assess the effectiveness of the remediation treatment. Furthermore, the results from the taxonomic and functional analysis of the microbial communities served as the basis for the development of a model that explains the ecology and distribution of dominant microbial groups in the tailings that may significantly contribute to the oxidation of iron-sulfides, the production of acid mine drainage, and to facilitate plant establishment and survival during phytostabilization.

<p>This study evaluated SO4 2- removal from circumneutral mine water (CMW) collected from Middleburg coal mine using coal FA collected from Hendrina power station. The following parameters were investigated: the effect of the amount of FA, the effect of the final pH achieved during treatment, the effect of the initial pH of the mine water and the effect of Fe and Al on SO4 2- removal from mine water. The precipitation of ettringite at alkaline pH was evaluated to further reduce the SO4 2- concentration to below the DWAF limit for potable water. Removal of SO4 2- from mine water was found to be dependent on: the final pH achieved during treatment, the amount of FA used to treat the mine water and the presence of Fe and Al in the mine water. Treatment of CMW using different CMW:FA ratios / 5:1, 4:1, 3:1, and 2:1 resulted in 55, 60, 70 and 71 % SO4 2- removal respectively. Treatment of CMW to pH 8.98, 9.88, 10.21, 10.96, 11.77 and 12.35 resulted in 6, 19, 37, 45, 63 and 71 % SO4 2- removal respectively. When the CMW was modified by adding Fe and Al by mixing with Navigation coal mine AMD and treated to pH 10, 93 % SO4 2- removal was observed. Further studies were done to evaluate the effects of Fe and Al separately. Treatment of simulated Fe containing AMD (Fe-AMD) to pH 9.54, 10.2, 11.8, and 12.1 resulted in 47, 52, 65, and 68 % SO4 2- removal respectively. When Al containing AMD was treated to pH 9.46, 10.3, 11.5 and 12 percentage SO4 2- removal of 39, 51, 55 and 67 % was observed respectively.</p>

<p>Fly ash and AMD samples were characterised by standard analytical methods for selection of the test materials. Active treatment by means of mixing fly ash with AMD in beakers and a large tank at pre-determined ratios have shown that fly ash is capable of neutralising AMD and increasing the pH beyond neutral values, which optimises the removal of heavy metals and ions. The trend was: the more fly ash added the quicker was the reaction time and higher the pH values achieved. Iron was reduced by as much 99 % in beaker scale experiments via Fe(OH)3 precipitation at pH values &gt / 4.0. A 99 % decrease in aluminium concentration was observed which was attributed to the precipitation of primarily gibbsite and various other mineral phases at pH values &gt / 5.5. As the pH increases, sulphate is adsorbed via Fe(OH)3 and gypsum precipitation at elevated pH. Sulphate attenuation with fly ash was excellent, achieving 98 % attenuation with beaker scale experiments and 1:1 fly ash:AMD ratio. Sulphate attenuation with fly ash was comparable to membrane and ion exchange systems and exceeded the performance of limestone treatment. Except for the larger volumes of fly ash needed to neutralise the AMD, fly ash proved to be a feasible and cost efficient alternative to limestone treatment. Fly ash produced competing results to limestone concerning acidity removal and sulphate attenuation. The comparison highlighted the advantages of utilising fly ash in comparison to limestone and demonstrated its cost effectiveness. The results of this study have shown that fly ash could be successfully applied for the neutralisation of acid mine drainage (AMD) and effectively attenuate the sulphate load in the treated water. The critical parameters to this technology are the variations of chemical composition and mineralogy of fly ash, which could influence the pH, contact time of the neutralisation reaction, and the same is true if the AMD quality varies.</p>

Current mining methods used to extract coal from underground mine workings disturb the natural environment and the existing stable geological structures. As a result, the ingress of water into the mines increases and the quality of the water passing through the mine workings deteriorates, irrespective of the operational status of the mines. Water ingress is generated by regional aquifers, local aquifers, recharge from the surface through rainfall, natural drainage paths on the surface, and surface water bodies. The quality of water in the mines deteriorates as a result of contact with the remaining coal in the mine workings. Mining can therefore cause an increased influx of water into a mine and the degradation of this water. The solution to reducing the impact of mines on the environment is to prevent, or at least reduce, the amount of water entering the mines, and to manage this water to prevent further degradation in water quality. This study focused on afforestation with Eucalyptus viminalis trees to manage or inhibit ingress of water into underground mine workings. The hypothesis of this study was that a change in vegetation, from grassland to fast-growing and potentially high water-using trees like Eucalyptus. could possibly reduce the drainage of water below the root-zone and into the mine workings. The hypothesis was tested by estimating the components of the soil water balance for a grassland site and a Eucalyptus tree site. The research site was situated in Mpumalanga, (260 36' Sand 290 08' E, 1650 m a.m.s.l.), one of South Africa's major coal bearing areas. Although the Secunda area is a treeless environment and conditions are not optimal for forestry, some Eucalyptus species are suited for conditions (frost and periodic droughts) encountered in this area. The soil water balance of grassland and E. viminalis trees were studied through a field experiment and a long-term (30 years) modelling exercise. Total evaporation of the grassland site was estimated using the Bowen ratio energy balance technique. The transpiration of six representative E. viminalis trees were estimated using the heat pulse velocity technique. The soil water storage changes at both sites were determined from the soil water content, estimated using water content reflectometers. Measurements were performed in a smectic clay soil which resulted in measurements difficulties. Vertical cracks were formed under soil drying. To establish the importance of climate and plant growth on the drainage beyond the root-zone, the soil water balance of a grassland and an E. viminalis site were simulated over a 30-year period with the Soil Water Atmosphere Plant (SWAP) model. It was concluded from the comparative field experiment and modelling, that a change in vegetation from grassland to E. viminalis will reduce the drainage of water below the root-zone, especially under above-average rainfall conditions. The reduction in drainage beyond the root-zone at the E. viminalis sites, compared to the grassland site, was demonstrated in the modelling exercise and can be deduced from the total evaporation and soil water storage estimated at both sites. The results from the field experiment confirmed the modelling results and showed that usually there were higher transpiration rates for the E. viminalis tree site, compared to the grassland site. The higher transpiration rates for E. viminalis trees resulted in lower relative saturation of soil layers and lower profile soil water contents at the E. viminalis site, and higher daily soil water storage changes at the E. viminalis site compared to the grassland site. These differences were more pronounced during winter when the grassland was dormant. The results from the modelling exercise showed that an E. viminalis tree stand, with a closed canopy, reduced drainage below the root-zone compared to a grassland. The drainage at the grassland site contributed to up to 54 % of the rainfall, compared to the 43 % at the E. viminalis site. However, under below-average rainfall conditions the annual drainage at both sites, were similar. Further, the absolute magnitude of the drainage was similar to the total evaporation at the grassland site under certain conditions. The results not only suggest that a change in vegetation, from grassland to E. viminalis trees, would reduce the drainage beyond the root-zone, but that it may delay the onset of drainage. Under above-average rainfall conditions, the modelled drainage at the E. viminalis site only exceeded 20 mm, a month later than at the grassland site. The simulation results also showed that under conditions of aboveaverage rainfall, drainage occurs whenever the rainfall exceeds the long-term average rainfall, irrespective of the existing vegetation. However, when the rainfall is belowaverage drainage at both sites are limited to large rainfall events. This simulation showed that over a period of eight years, E. viminalis trees could potentially reduce the drainage by 1235 mm more than grassland, which is equivalent to 1540 m3 ha- I a-I, or 1.54 Me ha- I a-I. The annual average reduction in drainage below the root-zone caused by E. viminalis trees (1.79 Mf ha-1 a-\ is a small reduction when compared to the influx of water into mineworkings. E.g. the influx of water into a bord-and-pillar mine range between 0.5 and 4 Mt d-I per area mined and up to 17000 Mt d-I per area mined under high extraction mining (Hodgson and Krantz, 1998; Hodgson et aI., 2001). This work gave a comprehensive account of the differences in the soil water relations of grassland and E. viminalis trees overlying coal mine working. Few other studies in South Africa compared the total evaporation and soil water relations of grassland and E. viminalis trees in so much detail. State of the art monitoring techniques were used and produced valuable comparison of their use in expansive clay profiles. The work should contribute to management decisions focussed on limiting ingress of water into mine workings. / Thesis (Ph.D.)-University of Natal, Pietermaritzburg, 2003.

Acid mine drainage (AMD) is a significant environmental issue worldwide, which often causes severe contamination and marked species losses in receiving streams. However, little is known about how this stress alters food webs and ecosystem function. I conducted a literature review, which revealed that AMD-impacted streams generally had depauperate benthic communities dominated by a few tolerant species and impaired ecosystem processes. Next, using survey and experimental-based approaches, I investigated food web structure and energy flow in these highly stressed streams, which typically have low pH (< 3), high concentrations of dissolved metals (Al, Fe), and substrata coated with metal hydroxide precipitates, on the South Island, New Zealand. Inputs of AMD caused substantial loss of consumers and reduced the overall number of links between species generating small and simplified food webs, with few invertebrates and no fish. Comparative analysis of food webs from a survey of 20 streams with either anthropogenic or natural sources of acidity and metals, indicated that anthropogenic sources had a stronger negative effect on food web properties (size, food chain length, number of links); an effect driven primarily by differences in consumer diversity and diet. However, the presence of fewer trophic levels and reduced trophic diversity (detected using isotopic metrics), were common structural attributes in AMD-impacted webs along a pH gradient, regardless of impact level. Furthermore, complementary dietary analyses of consumer gut contents and stable isotope signatures (δ13C and 15N) confirmed that primary consumers fed generally on basal resources and that there were few predatory interactions, which reflected low densities of small-bodied chironomids. This suggests that food quantity was unlikely to limit primary consumers but that reduced prey availability may be an additional stressor for predators. In these radically re-structured food webs, trophic bottlenecks were generated at the primary consumer level and energy flow to higher consumers was disrupted. However, streams still retained some limited function, including slow leaf litter breakdown, which provided detrital resources and supported the small food webs. Overall, my findings have furthered our understanding of these highly stressed stream ecosystems by providing new insights into interactions among species and trophic levels that structure food webs and enable function.

Acid mine drainage (AMD) is a major environmental issue worldwide. On the West Coast of the South Island, New Zealand, numerous catchments receive AMD, with significant negative impacts on in-stream flora and fauna. Diatoms are commonly regarded as powerful biological indicators and may be found in high abundance in AMD-contaminated streams; however, relatively little work has been done on diatoms in mining environments in New Zealand. Initially, I conducted a survey of epiphytic diatom communities in 39 streams ranging from non-impacted reference streams to those severely impacted by AMD. Streams were assigned to one of four classes along an AMD gradient: circum-neutral reference, naturally acidic reference, moderately impacted, and severely impacted. There was a wide range in diatom taxonomic richness in reference and moderately impacted streams (8 – 33 taxa). Taxonomic richness was greatly reduced in severely impacted streams (1 – 5 taxa) at a threshold of pH 3.4 and was dominated by Pinnularia cf. acidophila (69 – 100% relative abundance). Community composition differed between circum-neutral reference, moderately, and severely impacted streams; however, naturally acidic and moderately impacted streams had similar diatom communities primarily composed of acid-tolerant Eunotia and Frustulia species. This indicated that diatoms are strongly structured by pH and able to tolerate moderate conductivity and metal concentrations without a corresponding shift in community composition. Survey data were then used to develop two diatom-based indices for streams impacted by AMD: a single Biotic Index and a Multimetric Index. While neither index was able to distinguish naturally acidic from moderately impacted streams, both indices successfully categorised streams as circum-neutral reference, moderately or severely impacted by AMD. These indices may be useful in assessing AMD impact on circum-neutral streams or in identifying when a stream has crossed a threshold from moderately to severely impacted by AMD. Diatoms would be especially useful as bioindicators of AMD if they respond rapidly to a change in mine discharge. To test this, mature algal biofilms were reciprocally transferred between circum-neutral reference streams and streams of varying degrees of AMD over a period of 13 days. Diatom mortality increased rapidly in the reciprocal transfer between reference and severely impacted streams. Reference communities resembled the ambient diatom community of severely impacted streams 13 days post-transfer. However, in the reverse transfer, a change in community composition was slow to occur. Diatoms respond faster to an increase in pollution than to pollution amelioration. Overall, results indicated that diatom communities may be a useful tool for monitoring the presence and magnitude of AMD in New Zealand streams.

The treatment of Mn and SO42- contaminated mine drainage via a sulfate reducing bioreactor is expected to result in near-permanent immobilization of significant amounts of Mn and a portion of the sulfates within the matrix. This study tested several different combinations of organic amendments and inorganic substrates in an attempt to optimize sulfate reducing conditions and Mn removal capacity. Five different organic carbon sources, including corn mash, wood mulch, biosolids, soybean oil, and sorghum syrup in combination with five different inorganic substrates, including creek sediment, marble and limestone chips, polished gravel, and sand were tested in batch experiments. Results indicate a widely Mn variant removal potential among the treatments, ranging from 35% for soybean oil to 97% for the mulch mixture, with respective Eh ranges of +60 mV and -320 mV. Sulfate removal ranged from less than 10% to 85%. The most favorable combinations were tested in small scale bioreactors under dynamic conditions. Greater than 90% of Mn and 70% of sulfate was removed over a 65 day test period. Results indicate Mn removal mechanisms include sulfide, oxide, and carbonate formation and simple sorption and SO42- removal mechanisms of sulfide gas evolution, gypsum and MnS precipitation, and anion sorption/cation bridging.

Thesis (doctoral)--TU Bergakademie Freiberg, 2006. / "International Mine Water Association." Includes bibliographical references (p. [337]-420) and index.

Thesis (M.Sc. (Hons)) -- University of Western Sydney, 2002. / "Master of Engineering (Honours), 2002, University of Western Sydney - Nepean" Bibliography : leaves 135-141.