Thesis (M.Sc. (Hons))--University of Western Sydney, 2001. / "A thesis presented for the Degree of Master of Science (Honours), Centre for Electrochemical Research and Analytical Technology, School of Science, Food and Horticulture, University of Western Sydney, March 2001." Bibliography: leaves 62-67.

The environmental impact and sustainability of irrigation with coal-mine water was investigated from an agricultural point of view on different coal-mines in the Republic of South Africa. Field trials were carried out on a commercial and plot scale, on sites that could offer a range of soil, crop, weather conditions and water qualities such as gypsiferous, sodium sulphate and sodium bicarbonate waters. Crop production under irrigation with gypsiferous mine water is feasible on a field scale and sustainable if properly managed. No symptoms of foliar injury due to centre pivot sprinkler irrigation with gypsiferous water were observed. The presence of high Ca and Mg in the water suppressed plant uptake of K. This could be corrected by regular application of K containing fertilizers. The bigger problem experienced was waterlogging due to poor site selection, especially during the summer months. The problem is not related to the chemistry of the gypsiferous water used for irrigation. Pasture production with Na2SO4 rich mine effluent was also feasible, at least in the short term, but would need a well-drained profile and large leaching fraction to prevent salt build up. Forage quality was not affected by the Na2SO4 water used. NaHCO3 water was of very poor quality for irrigation and is not recommended for irrigation. Salt tolerant crops that are not susceptible to leaf scorching can be produced with this water, but only with very high leaching fractions and careful crop management. Regular gypsum application will be required to prevent structural collapse of the soil. Most of the salts applied will leach from the soil profile, and will probably need to be intercepted for treatment or reuse. The Soil Water Balance (SWB) model was validated successfully. The model predicted crop growth, soil water deficit to field capacity and soil chemistry reasonably well, with simulated results quite close to measured values. Soluble salts have to be leached from the soil profile, so that crop production can be sustainable, but will externalize the problem to the receiving water environment. To assess the environmental impact of irrigation with coal-mine water, it is valuable to develop a tool that can assist with prediction of offsite effects. SWB was validated for runoff quantity and quality estimations, and was found to give reasonable estimates of runoff quantity and quality. SWB also predicted the soil water and salt balance reasonably well. This gives one confidence in the ability of the model to simulate the soil water and salt balance for long-term scenarios and link the output of SWB to ground and surface water models to predict the wider impact of large scale irrigation. This will also link the findings of this work to other research oriented towards the management of mine water and salt balances on a catchment scale. It will also help authorities make informed decisions about the desirability and consequences of permitting mine water irrigation on a large scale. Irrigation with gypsiferous mine water can be part of finding the solution to surplus mine water problems. Appropriate irrigation management of mine water is essential for the long-term sustainability of irrigation. / Thesis (PhD)--University of Pretoria, 2009. / Plant Production and Soil Science / unrestricted

Please read the abstract in the section 00front of this document / Dissertation (MSc (Agronomy))--University of Pretoria, 2006. / Plant Production and Soil Science / unrestricted

This thesis has been prepared for DIAMO, Branch GEAM Dolní Rožínka. Literature research includes a description of the ionizing radiation, natural radionuclides, mining of uranium ore and mineral deposits; Běstvina and Licoměřice. The experimental part includes sampling, analysis and evaluation of the content of selected radionuclides in the two selected locations. The content of uranium and radium in sludge from mine water treatment plant is determined annually by an external laboratory, using of semiconductor gamma-spectrometric analysis (GSA). Determination of both radionuclides in waters in these areas is carried out in the Centre of testing laboratories (SZLAB) in Dolní Rožínka. Uranium and radium activity is below the detection limit. Sludges from Běstvina, according to the results of external laboratories, routinely show activity of both radionuclides. But activity in the waters from this locality is below the detection limit. The goal of this diploma thesis is to verify the radionuclide content in sludge from CDV Běstvina by another method. As a comparative method was chosen determination of uranium using the UV-VIS spectrophotometry with separation on silicagel. Location Licoměřice was chosen as a reference. Like a supplementary method for determining the concentration of uranium was chosen ICP-MS. For the determination of the radium was chosen radiochemical method scintillator ZnS (Ag).

the ground-water system was studied in Burnout Canyon, Northern Wasatch Plateau, Utah to provided hydrogeologic information relative to the impacts of longwall coalmining induced subsidence. The longwall panels of coal are overlain by approximately 600 feet of interbedded sand, silt, and shale. The water-bearing zones are comprised of local 1enticular sand lenses. Well analysis and locations of springs indicated that multiple ground-water systems are operating within the study area.A modular three-dimensional, finite-difference flow model (MODFLOW) was used to simulate the multiple water-bearing zones and associated hydrostratigraphy above the mine. The model was used to assess the distribution of head over space both pre- and post-subsidence, using absolute heads and measured values of mine-inflow for model calibration. Longwall retreat was simulated with two model runs, each representing a new face position. Model calibration indicated that spatial head distributions were affected by subsidence. / Department of Geology

This diploma work is performed at Sandvik Mining and Rock Technology, Rock Tools division, a world-leading mining equipment manufacturer. The aim is to study the wear of cemented carbide rock drill inserts worn against granite and sandstone countersurfaces, with focus on the impact of binder phase composition and flushing agent chemistry. A brief introduction to rock drilling, cemented carbides and the wear and degradation mechanisms of cemented carbides in rock drilling is given. Wear is induced in a lab test by sliding cemented carbide inserts against granite and sandstone countersurfaces while flushing with deionized water or synthetic mine water. The wear is quantified by measuring material weight loss, and worn inserts are studied by SEM. All wear marks feature crushed, fragmented and heavily deformed WC grains and cavities left after individually removed WC grains. Rock adhere strongly on inserts worn against both granite and sandstone, and adhered material from both rock types sometimes endure the mechanical contact between insert and rock without significant spalling. Inserts tested with deionized water against sandstone wear 2.2 - 5.1 times more relative to against granite, and the only distinct difference observed is the distribution of adhered rock. The use of synthetic mine water relative to deionized water impacts the wear of all inserts, though corrosion products are only found on some of them. Further, the tribological contact greatly impacts the corrosive attack. The relative wear difference using different water chemistries is larger for inserts with a smaller relative amount of binder. In most cases, increased wear is measured for inserts tested with synthetic mine water. For reasons yet unknown, this trend is reversed for inserts with a high relative amount of binder tested against sandstone, where a decrease in wear is measured instead. / Detta examensarbete har utförts åt Sandvik Mining and Rock Technology, Rock Tools avdelningen, som är en världsledande utrustningstillverkare inom gruvindustrin. I arbetet undersöks nötningen av så kallade bergborrstift av hårdmetall. Berg är generellt ett mycket hårt och sprött material, och borrning i berg går därför i huvudsak ut på att krossa och spola bort krossad sten. Längst fram på bergborrar sitter borrkronor som till största del är gjorda i stål. Då stål är för mjukt för att effektivt kunna avverka berg monterar man in stift av hårdmetall längst fram på borrkronan. Hårdmetall är ett kompositmaterial av mycket hårda men spröda wolframkarbidkorn (WC) som hålls ihop av en, jämfört med WC, mjuk och formbar metall som kallas bindefas. Resultatet är ett mycket hårt men fortfarande relativt segt material som dessutom klarar de mycket höga temperaturer som uppstår vid bergborrning. Traditionellt används kobolt som bindefas, men nu tros det finnas hälsorisker med kobolt och dessutom sker en stor del av världens koboltutvinning under oetiska förhållanden i konfliktländer i Afrika. Detta i kombination med att koboltpriserna ökat dramatiskt de senaste åren leder till att man nu söker efter alternativa bindefaser. Bland annat undersöker man olika legeringar av nickel och järn. I detta arbete jämförs nötningen av stift med nickel-, järn- och olika koboltbindefaser. I ett labtest fås nötning genom att stiften trycks mot en roterande stencylinder av antingen granit eller sandsten. I verkliga förhållanden används ofta så kallat gruvvatten som sipprar in i gruvan som spolvatten för att ta bort stenkrosset och kyla borrkronan. För att se hur kemin i spolvattnet påverkar nötningen spolas kontaktytan mellan stift och stencylinder med antingen avjoniserat vatten eller syntetiskt gruvvatten under testerna. Stiftens materialförlust under provningen beräknas genom att mäta deras vikt innan och efter. För att se om skillnader i nötningshastighet mellan olika stifttyper eller testvillkor avspeglas i olika utseenden på slitytorna undersöks stiften med hjälp av ett svepelektronmikroskop (SEM). Från SEM-bilderna ser man att alla stift från alla testvillkor har krossade och fragmenterade WC-korn på ytan och att stora delar av slitytorna täckts av påkletat berg. Bergpåsmetningarna är ibland mycket tunna (< 1 μm) och delvis inblandade i bindefasen, och ibland betydligt tjockare (flertal μm). De tjockare påsmetningarna är bundna så pass hårt till ytan att de kan upprätthålla delar av kontakten mellan stiftet och berget under testningen utan att lossna. Huruvida detta skyddar hårdmetallen från att nötas eller om det påkletade berget reagerar med, och därmed ökar den kemiska nedbrytningen av stiftet är inte utrett. Berget skyddar dock den underliggande hårdmetallen mot den korrosion som uppstår i kontakt med spolvattnet. Resultaten visar att stiften nöts betydligt mer mot sandsten än mot granit. Förutom att bergpåsmetningarna har en annan fördelning över ytan så syns inga tydliga skillnader mellan stiften testade mot de båda bergarterna. De flesta stiften nöts mer när de testas med gruvvatten än med avjoniserat vatten. Detta gäller alla stift utom de som har hög relativ mängd bindefas och som testats mot sandsten. Dessa stift nöts tvärt om mindre när de testas med gruvvatten än med avjoniserat vatten. Hittills har ingen anledning till denna konsekventa avvikelse hittats.

PUMPS mimics natural geothermal vents as a conceptual model designed for the remediation of acid mine water (AMW) in voids of abandoned gold mines of the Witwatersrand Basin in South Africa. In this system, a reaction chamber containing Desulfotomaculum kuznetsovii sulfate reducing bacteria will be set at the bottom of a 3-4 km deep mine that will be flooded. A geothermal system with at least one (1) doublet will be drilled from the bottom of the mine to the depth of 8km, where the temperatures are sufficient for geothermal energy harvesting. AMW, used as a geothermal fluid, will be pumped down the injection well and circulate through hot rock. The hot water is then used to generate electricity and then channelled into the reaction chamber to undergo bio-remediation. Following treatment, the water flows back into the mine voids where it will improve the quality of untreated AMW through dilution. Eventually, the mine will be flooded with clean water that can be stored underground and/or pumped up to surface for social and ecosystem services. Following an introduction and proof of concept for the PUMPS, the research builds further on the technical and economic evaluation of the PUMPS in order to assert its viability and sustainability. The technical viability includes testing the ability for Desulfotomaculum kuznetsovii to survive in high pressure condition; quantifying the amount of energy that can be drawn from the geothermal reservoir; determining the placement and scheme of the geothermal wells; and, finally, developing a robust economic model of the system. Experiments show that Desulfotomaculum Kuznetsovii can tolerate high pressure conditions in of at least 100bar at their ideal sulfate reducing temperature of 63°C. Geochemical modelling shows that AMW can be used effectively as a geothermal fluid for PUMPS. To achieve highest efficiency and minimal fluid loss, the geothermal wells should be placed along the SSE-NNW direction, based on the known stress field across the Witwatersrand Basin. With a flow rate of 30l/s the energy drawn from the geothermal reservoir is sufficient to drive PUMPS and the surplus energy is determined by the volume of AMW treated per day. All results indicate that the PUMPS is technically and economically viable. The economic model shows that the value and viability of the PUMPS is best reflected with a comprehensive inclusion of potential revenue (for example from chemical solution mining of deep seated gold) and financial/environmental incentives.

Abstract Lime precipitation has been used for the treatment of mine water for decades; however, the impact of precipitation conditions is not adequately known. In this thesis, four aspects related to the removal of sulphate from mine water by lime precipitation are considered: the effect of magnesium on lime precipitation, the utilisation of by-products in lime precipitation, enhancement of lime precipitation, and utilisation of the precipitate. Sulphate removal in the presence of magnesium at the commonly used lime precipitation treatment pH of 9.6 was found unefficient as magnesium was keeping the sulphate soluble in the form of magnesium sulphate. At higher treatment pH of 11.5, magnesium that was naturally present in the mine water was shown to precipitate as magnesium hydroxide, which could serve as seed crystals for gypsum or co-precipitate sulphate thus enhancing sulphate removal. Quicklime manufacturing generates by-products that, currently, have few applications. The by-products examined in this study were successfully applied for mine water neutralization replacing commercial lime products. These by-products were found to remove sulphate equally well from the mine water. However, differences between by-products were observed in the consumption, and produced sludge quantities and qualities. An enhanced lime precipitation method is the precipitation as ettringite, which was used to reduce the sulphate content in mine water to less than the value set as the drinking water guideline in Finland. Furthermore, the formed precipitate was found to remove arsenate from the model solution. / Tiivistelmä Vaikka kalkkisaostusta on käytetty kaivosten vesienkäsittelyyn useiden vuosikymmenten ajan, tieto olosuhteiden vaikutuksesta käsittelyn tehokkuuteen sulfaatin poiston osalta on puutteellista. Tämä väitöskirja käsittelee sulfaatinpoistoa kaivosvesistä kalkkisaostuksen avulla neljällä eri osa-alueella: magnesiumin vaikutus kalkkisaostukseen, kalkinpolton sivutuotteiden hyödyntäminen kalkkisaostuksessa, kalkkisaostuksen tehostaminen ja muodostuvan saostuman hyödyntäminen. Magnesiumin todettiin kokeellisesti ja laskennallisesti haittaavan sulfaatin poistoa kaivosvedestä kalkkisaostuksessa yleisesti käytetyssä pH:ssa 9.6 pitämällä sulfaattia liukoisessa muodossa magnesiumsulfaattina. Korkeammassa pH:ssa 11.5 puolestaan kaivosveden luontaisesti sisältämän magnesiumin havaittiin kokeellisesti ja laskennallisesti saostuvan magnesiumhydroksidina, joka voi toimia siemenkiteinä kipsille tai kerasaostaa sulfaattia ja siten tehostaa sulfaatin poistoa. Kalkinpolton sivutuotteina muodostuu jakeita, joille ei tällä hetkellä ole juurikaan käyttökohteita. Tässä työssä käytettiin kalkinpolton sivutuotteita korvaamaan kaupallista kalkkia kaivosveden neutraloinnissa. Sivutuotteet poistivat sulfaattia yhtä tehokkaasti kuin kaupalliset kalkkituotteet. Sivutuotteiden välillä havaittiin eroja niiden kulutuksessa sekä muodostuvan lietteen määrässä ja laadussa. Saostuksella ettringiittinä, joka on tehostettu versio perinteisestä kalkkisaostuksesta, saavutettiin sulfaattipitoisuuden lasku alle Suomessa juomavedelle käytetyn suositusarvon. Lisäksi havaittiin muodostuneen ettringiittisaostuman olevan potentiaalinen materiaali arsenaatin poistoon vedestä.

Magister Scientiae - MSc / The objective of this study was to investigate the feasibility of the application of low cost high capacity inorganic ion exchange material, synthesized form collected fly ash and acid mine drainage solid residues, for the decontamination of secondary co-disposal process waters, with emphasis on investigating the processes governing the solid/solution interface. / South Africa

This study’s main goal was to evaluate Bacillus subtilis inoculation and mine water irrigation effect on germination, growth, nodulation, physiology and shoot/grain quality of cowpea genotypes exposed to extreme climatic conditions (elevated temperatures). The first experiment evaluated the interactive effect of Bacillus subtilis (BD233) inoculation and elevated temperature on germination indices and plumule lengths of three genotypes (Asetanapa, Soronko and Nyira) of cowpea. The results showed that interaction between B. subtilis (BD233) and temperature significantly (p<0.05) influenced the germination indices (germination percentage (G%), germination index (GI) and germination rate index (GRI)) and plumule length of cowpea seedlings and genotype responses were significantly different. At elevated temperature (35oC), inoculation with B. subtilis (BD233) enhanced seed germination and growth of cowpea. The second experiment evaluated the effect of temperature on growth and nutritional content of cowpea incubated for seven days in a growth chamber. The results showed that when cowpea genotype, Soronko, was incubated at different temperature regimes, the whole plant biomass, shoot carbon and crude protein contents were significantly affected with temperature increases at all three stages of the plants’ life cycle. The results suggest that the pre-flowering (40 DAP) and flowering (90 DAP) stages of cowpea compared to post-flowering (123 DAP) are more susceptible to elevated temperatures (30-35oC). The third experiment evaluated Bacillus subtilis inoculation and mine water irrigation effect on growth, nodulation, physiology and nutritional content of cowpea under glasshouse conditions. The results revealed that the interaction of B. subtilis (BD233) inoculation and mine water (75% AMD) irrigation was significant for the growth, nodulation, stomatal conductance, chlorophyll contents and shoot/grain nutritional quality of cowpea genotypes. In comparison with control, generally, B. subtilis inoculation enhanced the growth, nodulation and yield of all tested cowpea genotypes and irrigation with mine water significantly influenced the mineral contents in both shoot and grain of cowpea. Taken together, findings in this study have implications for cultivation of cowpea, an important candidate for food/nutrition security in Africa, under future climate change scenarios. / Environmental Sciences / M. Sc. (Environmental Sciences)