M.Tech. (Chemical Engineering) / Please refer to full text to view abstract

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Microfluidics is a constantly evolving area of research. The implementation of new technologies and fabrication processes offers novel methodologies to solve existing problems. There are currently a large number of established techniques to address issues associated with microscale mixing and valving. We present mixing and valving techniques that utilize simplified and inexpensive techniques. The first technique addresses issues associated with microscale mixing. Exercising control over animal locomotion is well known in the macro world but in the micro-scale world, control requires more sophistication. We present a method to artificially magnetize microorganisms and use external permanent magnets to control their motion in a microfluidic device. This effectively tethers the microorganisms to a location in the channel and controls where mixing occurs. We use the bulk and ciliary motion of the microswimmers to generate shear flows, thus enhancing cross-stream mixing by supplementing diffusion. The device is similar to an active mixer but requires no external power sources or artificial actuators. The second technique examines a methodology involving the integration of electroactive polymers into microfluidic devices. Under the influence of high applied voltages, electroactive polymers with fixed boundary conditions undergo out-of-plane deformation. We use this finding to create a valve capable blocking flow in microchannels. Electrolytic fluid solutions are used as electrodes to carry the voltage signal to the polymer surface. Currently we have demonstrated this methodology as a proof of concept, but aim to optimize our system to develop a robust microvalve technology. / Master of Science

Negatively buoyant jets are turbulent flows that are frequently employed by the desalination industry to disperse reject brines into oceanic environments. Although such brines are characterised by elevated concentrations of the same elemental components as the discharge environment contains, there is significant potential for marine ecosystem damage if this waste is not diluted properly. Numerous workers have analysed the dilution and spatial characteristics of negatively buoyant jets, but published data demonstrates notable inconsistencies. An important reason for these discrepancies is the variety of bottom-boundary conditions employed. This complicates comparison with predictions by integral models typically employed for discharge design, as these generally have not been developed with consideration to boundary interaction. In the present study, negatively buoyant jet experimental data is collected where bottom boundary distances are sufficiently large to avoid boundary influence at the point where the discharge returns to its source height (the return point). Near-field centreline dilution data is measured under still ambient conditions, for the source inclinations of 15–75°. Considerable attention is paid to experimental data quality, and all relevant issues are mitigated where possible. In order to ensure the boundary has no influence, source heights in this study range between 2.33 d F0 and 8.07 d F0. A variety of time-averaged and temporal statistics are calculated, and these statistics are compared with published experimental data and predictions by integral models. Normalised trajectory and dilution data from the source through to the return point collapses well at each inclination. The attention to signal quality and the self-consistency of derived experimental results in this study suggest a high level of accuracy, and large distances to the bottom boundary ensure that results are not confused by boundary interaction. Data for dilution rate at the return point supports the use of higher source inclinations (60° and 75°) to maximise dilution capability. A new ‘forced jet’ model is developed that incorporates the concept of a reducing buoyancy flux as the flow rises to maximum height. While this model is not applicable above source inclinations of 60°, predictions at other inclinations are reasonable. Dilution predictions are notably improved when compared to those from existing integral models. Finally, CFD simulations of negatively buoyant jets are conducted using the k-ε turbulence model. Despite the sophistication of this model, the quality of spatial and dilution bulk flow predictions at the centreline maximum height are no better than those obtained from the forced jet model or analytical solutions of Kikkert et al. (2007).

There is now convincing evidence that the Standard Model of electroweak and strong interactions is not the end of the story but only a low energy effective theory. In particular, new flavour physics is required to explain the fermion mass spectrum. Most of the proposed extensions of the Standard Model fail to meet this criterion. We may hope that the LHC or some future colliders could help to clarify the situation by discovering new particles or spotting some unexpected events. In the meantime, more precise measurements of masses and mixing parameters could also play an important role. In this work, we do not aim at finding a new mechanism that could explain this spectrum, but we rather assume that fermion masses and mixings are calculable in a yet-to-be-found more fundamental theory. Our goal is to glean as much information as possible from the observed fermion masses and mixings in order to find some hidden structures that could significantly lower the number of free parameters and help us to get some clues about what could be this fundamental theory. We analyse first the various parametrizations of the flavour mixing and single out a specific decomposition. The parameters of this decomposition can be independently and accurately computed if we impose some simple textures to the Yukawa couplings. We propose then a straightforward combination of these interesting textures which reproduces quite well the observed quark flavour mixing. We study then the properties of a successful mass relation for the charged leptons. We propose some generalizations of this relation in order to be valid also for the neutrinos and the quarks. One of them successfully combines the masses and mixings while another one describes the lepton masses via an accurate geometric description. Hopefully, these two studies lead to similar conclusions and allow us to speculate on some interesting properties for new flavour physics.

Mixing is a common feature of stratified fluids. In stratified fluids the density varies with the height. This is true for the most fluids in geophysical environments, like lakes, the atmosphere or the ocean. Turbulent mixing plays a crucial role for the overall energy budget of the earth and has therefore an huge impact on the global climate. By introducing the mixing efficiency, it is possible to quantify mixing. It is defined as the ratio of gain of potential energy to the injection of mechanical energy. In the ocean energy provided by tidal forces leads to turbulence and thus highly dense water is lifted up from the deep sea to the surface. For this process, a mixing efficiency of 0.2 is estimated. Until now it is not completely understood how this high value can be achieved. Thus we measured the mixing efficiency by using a Couette-Taylor system, which can produce steady-state homogeneous turbulence. This is similar to what we find in the ocean. The Couette-Taylor system consists of two concentric cylinders that can be rotated independently. In between a stratified fluid is filled using salt as a stratifying agent. In the laboratory experiment, we obtained mixing efficiencies in the order of 0.001 as a result. Moreover we found that the mixing efficiency decreases with decreasing stratification like previous laboratory experiments have shown. As this value is two orders of magnitude smaller than what we find in the ocean, further studies will be necessary. / text