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X-ray diffraction studies on lithium intercalated MoS[2]Wainwright, David Stanley January 1978 (has links)
Li[sub x]MoS₂. samples were prepared by cathodically intercalating a MoS₂ powder cathode with lithium. X-ray diffraction patterns of these samples were taken using the Debye-Scherrer method. From these patterns, the crystal structure of the lithium intercalated M0S₂ was determined as a function of cell voltage.
There is no apparent change in the powder patterns until a phase transition occurs in the sample at ≃1.1 V. This transition appears to involve a slipping of lattice planes in the M0S₂ crystal. Straining of the lattice is evident after this phase transition takes place. Non-uniform
straining blurred the X-ray pictures with the result that the structure of the new phase could not be unambiguously determined. It does seem certain though, that an aligning of the Mo atoms takes place in this transition.
The new phase could be fit to a hexagonal unit cell. The lattice parameters were measured over a charge-discharge cycle in the new phase. The unit cell parameters reversibly change throughout a cycle, implying that intercalation takes place. The c axis exhibits a maximum with increasing lithium content, while the a axis increases monotonically. The volume of the unit cell increases smoothly however, reaching a maximum value some 15% larger than the original.
Another phase transition may take place at ≃ 0.55 V. Samples discharged below this voltage appear almost amorphous in the powder patterns, possibly due to extreme non-uniform straining of the lattice.
Some decomposition products of the Li-MoS₂ cells have also been discovered. / Science, Faculty of / Physics and Astronomy, Department of / Graduate
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THE EXTRACTION OF MOLYBDENITE FROM CERTAIN COPPER AND IRON SULFIDE MINERAL CONCENTRATESShirley, Joseph Floyd, 1932- January 1969 (has links)
No description available.
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Identification of the Mo₃S₄ intercalation system in lithium batteries made with natural MoS₂Mulhern, Peter John January 1982 (has links)
Investigations of the lithium/molybdenum disulfide intercalation battery showed that naturally occurring molybdenite, MoS₂, from the Endako mines had a type of capacity not found in synthetic MoS₂. The behaviour of this extra capacity was examined and attempts were made to find its source. Materials were synthesized that could indirectly produce the same electrochemical behaviour, and in-situ X-ray diffraction determined MO₃S₄ to be the crystal responsible for this capacity.
The lithium/Mo₃Si, system was found to be an intercalation battery with an energy density of about 275 watt-hours per kilogram of cathode material. Over half of the capacity was at 2.09V in a first order phase transition which did not greatly alter the host lattice. Most of the remaining capacity was divided evenly between regions of continuous lattice expansion near 2.46V and 2.05V. / Science, Faculty of / Physics and Astronomy, Department of / Graduate
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The effect of nitrogen gas and particle size on the selective separation of molybdenite from chalcopyriteJones, David Mark, 1960- January 1986 (has links)
No description available.
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A study of the treatment of some Arizona molybdenite oresKelley, Mose Eggleston, 1910- January 1935 (has links)
No description available.
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SURFACE CHEMISTRY OF MOLYBDENITE (MOLYBDENUM-DISULFIDE) WITH SPECIAL REFERENCE TO ITS FLOATABILITY FROM PORPHYRY COPPER ORESHsu, Lie Ko Land January 1982 (has links)
No description available.
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Geology and geochemistry of molybdenite showings of the Ackley City batholith Fortune Bay, Newfoundland /Whalen, Joseph Bruce. January 1976 (has links)
Thesis (M.Sc.) -- Memorial University of Newfoundland. / Typescript. Bibliography : leaves 181-195. Also available online.
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Collector-depressant equilibria in the flotation of molybdeniteAndelin, Robert Létrenne 01 June 1952 (has links)
This dissertation presents the results of research on the flotation system potassium n-amyl xanthate - sodium sulfide - molybdenite. The purposes of the research were (1) to determine the theoretical collector-depressant equilibria conditions of this system necessary for the flotation or depression of molybdenite, (2) to ascertain the mechanism of adsorption or the collector potassium n-amyl xanthate and the depressant sodium sulfide on molybdenite, and (3) to calculate the standard free energy of adsorption on molybdenite of the collector and depressant in this system. To accomplish these purposes it was necessary to develop a satisfactory experimental method for the controlled testing of collector and depressant action in this system. Because of the physical properties of molybdenite, attempts to employ the methods of other investigators were unsuccessful. The experimental method finally devised was a modification of the "captive bubble" technique of Wark and Cox. The smooth surfaces of pressed molybdenite pellets were used in place of polished mineral surfaces. Tables 1 and 2 list the data obtained in ascertaining the collector-depressant equilibria conditions of this system and Figures 5, 6 and 7 are plots of these data. Strong evidence was given in support of the Cook hydrolytic free acid absorption theory, and it was found that the Cook single site free acid model best describes the adsorption ef n-amyl xanthic acid and hydrosulfuric acid on molybdenite. The adsorption potential for the adsorption of hydrosulfuric acid on molybdenite at 25°C. was calculated to be -11,548 cal./mole. The adsorption potential for the adsorption of n-amyl xanthic acid on molybdenite was calculated to be -15,173 cal./mole assuming 25 % surface coverage and -15,826 cal./mole assuming 50 % surface coverage.
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Beneficiation Studies On Molybdenite Ore From Harur Area, Tamil NaduRavindran, Indira 01 1900 (has links) (PDF)
Molybdenum is a versatile alloying and refractory metal of strategic importance. In India almost all molybdenite is obtained currently as st byproduct from copper and uranium deposits. The present Indian production is only about 66 tonnes while the demand is over 1000 tomes. It thus becomes important to explore newer deposits of molybdenum and develop efficient beneficiation strategies to recover the metal. A potential source of primary
rnolybdenite has been found in the Ham area of Dharmapuri district in Tamil Nadu.
In the present investigation, taking into consideration the importance of the problem beneficiation studies have been undertaken on core - drill molybdenite ore samples from the Hanu area. Initially, detailed characterization of the molybdenite ore has been carried out with respect to its mineralogy and chemical composition. The X-ray diffkactogam of the ore has also been recorded These studies have indicated that quartz and sericite are the major
minerals followed by carbonates and feldspar. Among the sulphide minerals, pyrite is dominant with trace amounts of galena, sphalerite, chalcopyrite and molybdenite. The molybdenum content in the ore sample has been determined to be about 0.1%. Liberation studies have revealed that molybdenum is more or less uniformly distributed in the different size fractions from 1.7 mm down below to 75 microns. However, mineralogical analysis of the different size fractions has indicated that about 85% of the molybdenite is liberated. from associated silicate and carbonates below 2 12 microns.
The results of the flotation kinetic tests have shown that percentage recovery and grade of molybdenum foLZow an inverse relationship with time. Studies carried out to evaluate different reagent - combinations, reveal that optimum values of grade and recovery could be achieved using kerosene and M1IBC. Further, these studies have shown that flotation time of 4 minutes is adequate, as beyond this time the grade of molybdenum is found to deteriorate.
Detailed mesh-of-grind studies have indicated that 20 minutes of grinding yields optimum values of molybdenum and lead in the float product and this time was fixed for all subsequent experiments.
Preliminary experiments conducted to evaluate djfferent depressants for galena have shown that satisfactory results are obtained only with sodium dichromate. Optimisation studies performed to arrive at the dosage of sodium dichromate have shown that the addition of 0.25kg/t of sodium dichromate gives optimum results with respect to overall recovery and grade of molybdenum, copper and lead in the float and tailing fractions. In a similar manner, the optimum dosage of kerosene (collector for molybdenite) has been arrived at to be 0.8kg/t taking a holistic view of the grades and recoveries of the different metal values of interest. Based on the studies carried out with respect to optimization of the mesh-of-grind, depressant and collector concentrations, it became apparent that a grade of about 0.8% Mo only could be achieved with over 80% recovery. The redeeming feature however was that over 90% of the feed could be rejected at the rougher flotation stage itself with a negligence loss of about 0.02% Mo in the tailings.
It was thus considered logical to further upgrade the Mo content by regrinding. An extensive flotation campaign was therefore mounted, adopting the following strategies:
(1) Ist stage regrinding and one cleaning
(2) IInd stage regrinding and three cleanings
(3) IIIrd stage regrinding and two cleanings
Based on the first stage regrinding tests it was found that by regrinding to 100% passing 106 microns, the Mo assay could be enhanced to over 32% from a initial value of about 0.1% in the feed. The enrichment ratio at this stage corresponds to about 340.After the second stage regrinding followed by three stages of cleaning, close to 75% recovery of Mo with an assay value of about 52% could be achieved, further enhancing the enrichment ratio to about 540. A few experiments were conducted using sodium cyanide during second stage regrinding tests and it was found that copper assay could be brought down to 0.3% from about 0.8%, without affecting the grade of lead and molybdenum. The results of the third stage regrinding tests have highlighted that a final concentrate assaying about 55% molybdenum with over 70% recovery could be obtained. It is worthy to mention that the concentrate so produced meets the specification of metallurgical grade molybdenite. The overall enrichment ratio obtained, commencing from a feed assaying 0.1% Mo, corresponds to about 580.
In order to explore the efficacy of organic depressants, which are more acceptable on environmental grounds, detailed flotation studies were carried out using dextrin with particular emphasis on galena depression. A series of experiments was carried out in an identical manner to those conducted using sodium dichromate. Here again, three stages of regrinding/cleanings test where carried out, akin to those performed using sodium dichromate. A dextrin concentration of 0.01 kg/t was found to be an optimum value from the point of grade, wt. % recovery and distribution of molybdenum, lead and copper in the cleaner concentrate.
It is noteworthy that after second stage regrinding followed by four stages of cleaning, the molybdenum assay value has significantly improved from 16% to about 53% with over 70% recovery. Another notable feature is that copper content in the concentrate is only about 0.2% even without the addition of sodium cyanide. The results of the third stage regrinding/cleaning tests have shown marginal improvement in the molybdenum assay values without affecting the grade of copper and lead. On a comparative basis, it can be inferred that dextrin holds promise to be used as a potential substitute for the inorganic depressants such as sodium dichromate and sodium cyanide. On the basis of the extensive investigations carried out on the beneficiation of molybdenite ore, a comprehensive flowsheet has been developed.
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Spectrographic determination of rhenium in molybdenite with the D.C. arcHo, Show-Jy. January 1964 (has links)
Call number: LD2668 .T4 1964 H67 / Master of Science
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